A COLORIMETRIC METHOD FOR THE DETERMINATION OF TRACE COPPER CONCENTRATIONS IN WATER1

Trace quantities of copper (II) ion can be found in natural water as waste products from industrial, mining, and agricultural operations. Because low concentrations of copper can be toxic to plant life, many workers have devised methods of analysis for this metal in water. These methods require expensive equipment and skilled technicians. The described study illustrates a simple method in which copper (II) ion is concentrated by a batch ion exchange technique and estimated colorimetrically after formation of the blue triethylenetetramine complex. Using the visible absorption peak of the complex at 600 nm it was possible to obtain accurate estimations of original copper concentrations in the range 0.5-3 ppm. Using the complex absorption peak at 260 nm in the ultra-violet region of the spectrum increased the sensitivity by a factor of twenty. Because of the dependence of the complex formation reaction on solution acidity it is possible to optimize conditions for the detection of copper (II) in the presence of other metal ions. This type of method, which could be extended to the analysis of other metal ions, could be performed by a relatively unskilled technician under field conditions.     

LIMITS ON THE INSTITUTIONAL FRAME OF REFERENCE IN WATER RESOURCE DECISION-MAKING1

Study of water resource decision-making in Massachusetts demonstrates the existence of many institutional constraints such as the established fee system for consulting engineers, the funding of certain agencies, the institutionalization of equity concerns, overrepresentation of interests, and incompatibility of agency goals. These institutional constraints are attributable in part to certain broadly-based value-orientations such as the American pragmatic tradition. However, various lines of evidence indicate that these constraints are less important than other factors in the etiology of decisional outcomes. The outcomes of the decision processes were found to be at variance with the decisions studied, a fact leading to the conclusion that choice of decisions for study should be given more attention. The authors conclude that institutional constraints are important if one is interested in studying how decisions are made, but that what actually happens in the long run cannot be easily ascertained by studying either institutions or the decision-making process. They suggest the need for more research utilizing the incremental theories of Carl Lindblom and the side-effect theories of Albert O. Hirschman.     

THE IMPORTANCE OF PERCEPTIONS IN THE DETERMINATION OF INDIAN WATER RIGHTS1

ABSTRACT The American Indian occupies a unique place in the federal system of government There are indications that this relationship will continue and that Indian reservations are at the threshold of economic development. As this occurs, the nature and extent of Indian water rights becomes more important to Indian and non-Indian alike. The determination of these rights is a matter of more than judicial decisions. To a large degree the determination of these rights will rest in the non-judicial arena and will be influenced by the perceptions of those rights held by Indians and water allocation officials, both state and federal. If the perceptions of these political actors are not congruent, then political conflict will occur as the rights become more important. To depend solely upon the judicial system to resolve these conflicts entails risks and costs to both Indians and to allocating officials. Indians are taking seriously the federal policy of Indian self-determination, and water allocation officials run decided risks in failure to realize this. An alternative suggested is to include Indians as consulting parties when decisions are being made that affect Indian interests.     

THE ENHANCED ROLE OF WATER CONSERVATION IN THE COST-BENEFIT ANALYSIS OF WATER PROJECTS1

The concept of water conservation has increased in importance because of revisions in the rules and procedures for performing cost-benefit analyses of federal water projects. These revisions include a requirement that nonstructural and water conservation measures be incorporated into economic assessments of projects. Project analyses will now proceed as if water supplies were allocated “most effectively,” that is, to their highest valued uses. A related requirement provides that the net benefits of any project should now be valued using willingness to pay measures. A specific cost-benefit methodology accommodating the revisions is constructed and discussed. Informational requirements for applying this methodology are identified. In addition to being consistent with federal mandates, this technique offers important advantages over the traditional “requirements” approach to water supply planning.     

A MATHEMATICAL MODEL FOR EVALUATING THE POTENTIAL OF DESALTING1

ABSTRACT The Office of Saline Water, which has federal responsibility for developing low-cost, saline sources of fresh water, has recognized the need for an improved method of forecasting the future potential of desalting in this country. The magnitude of the role of desalting will influence the plans of federal, state, and local water resource agencies and the research and development programs of manufacturers. A dynamic simulation model has been developed by Arthur D. Little, Inc. under contract by OSW to translate relevant factors of water supply and demand into a forecast of desalting potential. The model projects the needs for desalting in 20 hydrologic regions of the U.S. Model performance has thus far been demonstrated by the development of a forecast and a battery of related sensitivity tests. Current results indicate the following potential desalting capacities: 225 MGD in 1980; 2,250 MGD in 2000; and 7,000 MGD in 2020. Significant improvements in desalting economics promise to increase these potentials by a factor of four or five by 2000-2020. Model inputs and results are continuing to be refined. When completed, OSW will have a dynamic tool with which to guide its R&D program.     

IMPACT OF DROUGHT ON QUALITY OF POTENTIAL WATER SUPPLY SOURCES IN THE SANGAMON RIVER BASIN1

ABSTRACT: The analysis of stream flow and several water quality parameters in six Illinois rivers showed both deterioration and improvement in quality indicators during 1976–1977 drought. The adverse impacts were an increase of ammonia and manganese concentrations and, to a lesser degree, increased concentrations of phenol and specific conductance. At the worst point during the drought, the 12-month moving average of monthly ammonia concentration in the Sangamon River was about 620 percent higher than the antecedent value. On the other hand, average concentrations of nitrites and nitrates, total iron, and the number of coliform bacteria significantly decreased. This positive response suggests that streams which are considered unsuitable for municipal supply due to high levels of these quality indicators may be used as emergency sources during droughts.     

CONJUNCTIVE MANAGEMENT OF WATER RESOURCES IN THE CONTEXT OF TEXAS WATER LAW1

ABSTRACT: This paper examines the critical interaction between existing Texas water law and the state's water resources. Conjunctive use and management of interrelated water resources, though seldom practiced, is generally considered desirable. However, a significant barrier to the coordinated, efficient use and management of water resources is the legal division of water in the various phases of the hydrologic cycle into different classes and recognition of well-defined water rights in the separate phases. Several examples of the problems which relate to, or result from, present Texas water law and which prevent correlated water resource management are discussed. Any substantive revision of Texas law, particularly ground water law, will apparently be difficult to achieve in the immediate future, primarily because of the large number of recognized private water rights and the political power inherent in them. Data necessary for operation of conjunctive management systems are gradually being acquired, and perhaps someday other hydrologic phases can be integrated with surface and ground water. Nevertheless, Texas courts and the legislature have sufficient information on the interrelated hydrologic cycle so that prospective water conflicts should be anticipated and avoided. Great care must be exercised in the recognition of new types of private water rights or extension of existing rights, because this institutional structure, once established, presents a formidable obstacle to desirable revisions of the law.     

CHANGES IN WATER POLICY IN THE PEOPLE'S REPUBLIC OF CHINA1

ABSTRACT: Ideology has predisposed the People's Republic of China against the use of prices to allocate water. Prolonged drought in north China has made the Chinese more aware of their unfavorable water resource inventory and the expense of expanding supply. Therefore, as part of the economic liberalization commenced since the death of Mao Zedong, China has started to make more active use of pricing to regulate demand and reduce the need for supply expansion.     

OPTIMAL CAPITAL INVESTMENT IN THE EXPANSION OF AN EXISTING WATER RESOURCES SYSTEMS1

The study of the optimal expansion of existing water resources systems is of continuing importance because of the rising demand and limited supply of water in many areas of the world, particularly in the southwestern part of the United States of America. This study is concerned with the investigation of the optimal expansion of a realistic water resources system to meet an increasing demand for municipal and industrial use, irrigation, energy, and recreation over a planning horizon of T years. A number of possible dam sites are available for the further regulation of river (canal) flows in the basin and/or the regulation of imported waters into the basin. To maximize, over the set of alternative projects, the sum of discounted present value of net earnings subject to the demands and various institutional, physical and budgetary limits, an optimization problem (Problem I) was formed as a 0-1 mixed integer programming problem and was decomposed into the set of all feasible combinations (Problem II). The economic return was determined for each combination (Problem III). Problem II was solved by a branch and bound procedure which selected each feasible combination of dams while the optimal return for each such combination (Problem III) was found by a network analysis code.     

IMPACT OF WATER CUTBACK ON SUGARCANE PRODUCTION IN THE FLORIDA EVERGLADES1

ABSTRACT: Sugarcane (Saccharum spp.) was planted in six lysimeters containing Pahokee muck (Lithic Mediaprist) where water tables were maintained at 30, 60, and 90 cm depths. The main objective was to study the impact of a 40 percent water cutback (108 mm) on sugarcane production during the period near the end of the dry season (i.e., May). The water cutback treatment was simulated through manipulation of water table depth. Due to the high available water capacity of the muck soil and selection of a sugarcane cultivar ‘CP63-588’ (which has a high tolerance of water table fluctuations), the sugarcane growth, and the yields of sugarcane biomass and sugar were not significantly different as a result of the treatments with and without 40 percent water cutback during a period of two months. This result is in good agreement with the 1981 cane yield in the Everglades Agricultural Area where a 35 percent water cutback was imposed during the 1981 drought.     

INTERBASIN WATER TRANSFERS IN RIPARIAN STATES: A CASE STUDY OF GEORGIA1

ABSTRACT: Under the riparian doctrine of eastern states, transfers of water to nonriparian lands and, thus, to different river basins, are only possible if the natural flow theory has been modified to allow for reasonable use. Even this adaptation is too nebulous to provide water managers and water users with certainty regarding water transfers. To provide a more precise mechanism for allocating water, 14 eastern states have adopted some form of administrative permitting process. Of these, five states statutorily allow for interbasin transfers of water. Thus far, no states have successfully issued permits for interbasin water transfers but Georgia and South Carolina are positioned to do so. Whether the permitting process will deter court action may rest on the ability of affected parties to negotiate an equitable agreement.     

ALLOCATION MODEL FOR IRRIGATION WATER COST: CASE STUDY OF THE NILE VALLEY IN EGYPT1

ABSTRACT: An allocation model for irrigation water cost, based on the Use of Facilities method, is presented. The model is developed for large-scale irrigation systems which may include multipurpose reservoirs, irrigation control works, pump stations and irrigation canals of various orders. The model accounts for the water conveyance losses as well as the water gains in the irrigation canals, and their effects on irrigation cost. It is applied to the irrigation distribution system of the Nile Valley in Egypt, which contains the High Aswan Dam, 16 irrigation structures, 12 pump stations, and numerous irrigation canals. The irrigation water cost at 29 areas representing the Nile Valley is determined.     

A GEOGRAPHICAL ANALYSIS OF VOTING PATTERNS FOR WATER RELATED CONSTITUTIONAL AMENDMENTS IN TEXAS, 1957-19811

ABSTRACT: Country level electoral data were used to analyze the voting patterns of eight water related constitutional amendment elections. Both water quality enhancement amendments (1971, 1976), and three of six water development amendments (1957, 1962, 1966) have been ratified, thus establishing a statewide policy of reservoir development, a funding mechanism to implement such a policy, and the creation of a water management agency. Begining with the 1969 election, a West Texas-East Texas regionalized voting pattern has emerged, resulting in the defeat of three amendments (1969, 1976, 1981) intended to provide additional funding for water development. This regionalization reflects different climatic, physiographic, economic, and locational factors, and represents a potential obstacle to coordinated water management in Texas.     

A PRELIMINARY QUANTIFICATION OF THE IMPACTS OF ASPEN TO CONIFER SUCCESSION ON WATER YIELD- II. MODELING RESULTS1

ABSTRACT: Heat pulse velocity techniques were developed for effective monitoring of water movement in aspen (Populus tremuloides), subalpine fir (Abies lasiocarpa), and Englemann spruce (Picea engelmannif). Water loss was monitored in replicated trees of each species for one year. These data were used to modify the plant activity index (a reflection of the ability of plants to transpire water at various times during a year) and the crop coefficient (a reflection of differences in consumptive use rates of water by different vegetation types when all other factors are held constant) for each species within the model ASPCON, a deterministic, lumped-parameter model describing the hydrology of aspen to conifer succession. Results of the modeling in dicate 18.6 cm net loss of moisture available for streamflow when spruce replaced aspen, and a loss of 7.2 cm when fir forests replaced aspen. The aspen to conifer successional trend appears, therefore, to be significantly reducing water yields in the western United States.     

DYNAMICS OF ADDED NITRATE AND PHOSPHATE COMPARED IN A NORTHERN CALIFORNIA WOODLAND STREAM1

ABSTRACT: Injections of NO₃ and PO₄ were made during September 1975 into Little Lost Man Creek, a small pristine stream in Redwood National Park, California. Chloride, a conservative constituent, was added in a known ratio to the nutrients. Nutrient loss at a downstream point was calculated using concentration of added Cl as a reference. Nitrate nitrogen (NO₃-N), added for 4 h, reached 920 μg/1 (above 5 μg/1 background) just below the injection point, but increased only to 405 μg/1 at 310 m downstream. The concentration decrease was attributed to dispersion and to uptake by stream biota. Percent of NO₃-N lost decreased with increasing concentration of NO₃-N. Phosphate phosphorus (PO₄-P) was added a week after the NO₃-N for 3 h, causing a concentration increase of 296 μg/1 (above 13 μg/1 background) just below the injection point, of 161 μg/1 at 90 m downstream, and of 98 μg/1 at 310 m. Percent loss of PO₄-P at downstream sites increased with increasing PO₄-P concentration and also for a short period after peak concentration occurred, but then decreased as PO₄-P concentration continued decreasing. Differences in stream response to added NO₃-N and PO₄-P are attributed to differing rates of reaction with biota and differing degrees of interaction with abiotic stream solids.     

A CASE STUDY IN THE IMPLEMENTATION OF THE FEDERAL WATER POLLUTION CONTROL ACT AMENDMENTS1

ABSTRACT: A general model of the policy implementation process is utilized to facilitate a discussion of the way Section 208 of PL 92-500 is being carried out on an areawide basis. A study of four “208 areas” in the “New York-Philadelphia corridor” highlights the operation of several variables used in the model. The varying political and socioeconomic conditions in geographic areas which have similar water quality problems are leading to the evolution of vastly different implementing structures, or institutional arrangements. The analysis suggests that these differences may have important implications for the success of the program in each of these areas. A major underlying theme is that such problems are characteristic of the 208 process nationwide and reflect general difficulties associated with managing water quality in a federal system.     

A PRELIMINARY QUANTIFICATION OF THE IMPACTS OF ASPEN TO CONIFER SUCCESSION ON WATER YIELD - I. HEAT PULSE METHODOLOGY FOR MODEL CALIBRATION1

ABSTRACT: Twenty-six aspen (Populus tremuloides Michx.), 20 subalpine fir (Abies lasiocarps (Hook.) Nutt.), and 20 Engelmann spruce (Pices engelmanil (Parry) Engelm.) of various sizes were cut under water and suspended in permanent reserviors at a northern Utah site. The reservoirs were asealed so that all water loss was due to consumption by the trees. Sap velocities, as computed from heat pulse velocities, were related to conducting areas of the tree trunks. Computed transpiration volumes were then correlated with actual water losses from the reservoirs. Coefficients of determination (R²) of 0.87, 0.86, and 0.82 were obtained for the fir, aspen, and sprucs, respectively. Reservoir water loss for each species for each season was then used to adjust a plant activity index for computing transpiration within ASPCON, a model describing the hydrology of aspen to conifer succession. The plant activity index reflects the variation in the capability of a plant community to transpire water over the year. Assumptions and limitations of the heat pulse velocity technique are also outlined.     

THE COSTS OF CONFLICTING ENVIRONMENTAL POLICY: A CASE STUDY IN MILWAUKEE1

ABSTRACT: The history of the Milwaukee water pollution abatement program is examined as a case study to investigate the costs of conflicting environmental policy. The recent U.S. Supreme Court decision concerning the Milwaukee case is described as a milestone in U.S. water pollution abatement policy which will help preclude the type of environmental policy conflict which has been found to be so costly to Milwaukee. The implications to U.S. water pollution abatement policy of the 13-year history of conflict in Milwaukee are presented.     

A PRELIMINARY STUDY OF THE EFFECTS OF DRAINAGE AND HARVESTING ON WATER QUALITY IN OMBROTROPHIC BOGS NEAR SEPT-ILES,QUEBEC1

ABSTRACT: Runoff and ground-water samples were collected from four ombrotrophic bogs, representing undisturbed and drained/harvested conditions, at two-week intervals during the summer of 1984. Analyses of samples for water quality parameters revealed significant (P < 0.05 level) increases in specific conductance, NH4⁺-N, total dissolved P, Mg, K, and Na and a decrease in the E₄:E₆ ratio (suggesting increased proportions of humic acid) associated with drainage. There were no significant changes in dissolved organic carbon, Ca concentrations, or pH. Comparison of samples collected before, during, and after ditching showed increases in the dissolved organic carbon, NH₄⁺-N, total dissolved P, K, and Na and a decrease in the E₄:E₆ ratio, but these changes were short lived; water quality returned to preditching values after about a week. The observed changes in water quality are small, probably because the peat is very acid (pH 3.0 to 4.5).     

AIRBORNE THERMAL MAPPING OF A “FLOW-THROUGH” LAKE IN THE NEBRASKA SANDHILLS1

The Sandhills region represents a tremendous water resource for the State of Nebraska. Small shallow lakes, marshes, and subirrigated meadows are abundant due to interactions between ground water and surface water. One theory relating ground water to lake-flow systems in the Sandhills has been termed the “flow-through” concept. Thermal-infrared remotely acquired images document the flow-through model for a test site in Western Nebraska.