餐厨垃圾不同“收集-处理”模式的碳排放估算对比

为明确我国餐厨垃圾不同处理模式下碳排放情况,以中国南方某城市为研究对象,结合实地调研数据,对比研究了集中式好氧堆肥、集中式厌氧发酵和分散式好氧堆肥3种处理模式下的碳排放量。结果表明,集中式好氧堆肥的碳排放总量最高,而集中式厌氧发酵碳排放总量最低。此外,分散式好氧堆肥的主要优势在于可减少收集运输过程的碳排放且可避免其他温室气体的无组织排放;在先进节能手段和控制电耗的措施下,相比于集中式好氧堆肥模式,分散式模式可实现760.91 kg的碳减排(以CO_2计)。然而,餐厨垃圾厌氧发酵模式因其可实现有机质产沼气,总碳减排空间是好氧堆肥的22倍,是一种绿色、低碳的餐厨垃圾处理方式,对实现餐厨垃圾资源化、无害化和减量化具有现实意义。     

青岛市餐厨垃圾现状调查及分析

通过问卷与实地跟踪形式调查青岛市4个主城区餐厨垃圾现状并提出关于餐厨垃圾管理和处置的建议,力求为该市餐厨垃圾的资源化利用提供参考.调查结果显示:餐厨垃圾产量为265.00 t/d,含水率为74.93％、含油率为6.06％、营养物为12.22％(质量分数);54.4％的调查餐饮单位将餐厨垃圾分为剩饭菜、废油和生活垃圾3类排放,需进一步加强餐厨垃圾分类放置的管理工作;所调查餐饮单位中有64.4％的剩饭菜、54.3％的废油由政府统一收运,统一收运率有待进一步提高;正规回收的餐厨垃圾为197.66 t/d,被用于堆肥或进行填埋处置.     

应用生命周期模型评价餐厨垃圾处理技术

运用生命周期模型对餐厨垃圾常用处理技术——厌氧发酵、好氧堆肥、饲料化技术、生化处理机进行评价和筛选。结果表明,厌氧发酵、好氧堆肥、饲料化技术、小型生化处理机的环境影响潜力分别为1.35×10-3、4.42×10-3、3.78×10-2和1.18×10-2,单位处理成本为2.1、5.65、0.37和1.4元/（人.a）,综合评估得出厌氧发酵和饲料化是当前具有优势的餐厨垃圾处理技术。     

2种典型餐厨垃圾资源化处理工艺的环境影响分析

为了评估餐厨垃圾资源化处理工艺对环境的影响,运用生命周期评价的方法,比较了2种典型的资源化处理工艺——好氧堆肥和湿热处理对环境的影响。结果表明,2种餐厨垃圾资源化处理工艺对全球变暖、生态毒性、酸化和富营养化的影响各有不同。其中,好氧堆肥对全球变暖的贡献较大,碳排放为337.7 kg CO_2eq./t。湿热处理为163.1 kg CO_2eq./t。在环境影响负荷方面,湿热处理工艺中的高能耗加重了毒性的影响。但由于其对环境的酸化、富营养化的不利影响较小,湿热处理的环境影响负荷总值是好氧堆肥的62.5%。总体上,湿热处理是一种对环境影响较小的餐厨垃圾处理工艺。     

餐厨垃圾厌氧共消化研究进展

餐厨垃圾厌氧发酵系统长期运行时极易失衡,且失衡机制错综复杂;而且,目前缺乏对餐厨垃圾厌氧发酵消化性能的有效调控策略,这限制了餐厨垃圾厌氧消化技术的发展和应用。餐厨垃圾与其它基质进行厌氧共消化不仅能解决餐厨垃圾单一消化的性能限制问题,还可以实现废物的互相利用和资源回收。梳理了餐厨垃圾厌氧消化面临的问题及挑战,深入探讨了餐厨垃圾与其它生物质联合厌氧共消化的协同效应及影响因素,总结了提升餐厨垃圾厌氧共消化性能的强化策略,以期为餐厨垃圾厌氧共消化技术研究提供参考。     

我国餐厨垃圾厌氧处理技术现状分析及建议

随着我国餐厨垃圾排放量的持续增加,已造成严重的环境污染防控压力。为促进我国餐厨垃圾的资源化利用和无害化处理处置,在文献调研的基础上,梳理了我国大中型餐厨沼气工程的发展现状,分析了导致沼气产率低、沼气回用量大等餐厨沼气亟待解决的低经济效益难题的根本原因,并结合实际情况提出餐厨垃圾厌氧消化技术相关的建议,以期为我国提高餐厨垃圾的资源化、无害化处理能力和水平提供参考。     

餐厨垃圾高温厌氧消化

在中试规模下,研究餐厨垃圾高温厌氧消化试验,通过监测餐厨垃圾厌氧消化过程中产气量、气体组成等产气情况和消化液中pH值、SCOD、NH4+-N、VFAs等化学指标含量变化,确定餐厨垃圾厌氧消化的最大有机负荷,并分析餐厨垃圾高温厌氧消化技术的可行性,结果表明,在工程上餐厨垃圾单独进行高温厌氧消化产甲烷具有技术可行性,但难以保证系统长时间安全稳定运行;餐厨垃圾厌氧消化正常运行时最大有机负荷可达2.551 kg VS/(m3.d);当系统有机负荷为2.551 kg VS/(m3.d)时,每天每千克VS最高可产生甲烷量0.622 m3;氨氮对餐厨垃圾厌氧消化产甲烷影响明显;餐厨垃圾中固有Na+含量对厌氧消化产甲烷影响不明显。     

酸化餐厨垃圾厌氧消化产氢研究

分析了餐厨垃圾酸化过程中的pH、挥发性脂肪酸(VFA)产量及含水量等参数的变化,考察了酸化餐厨垃圾厌氧消化过程中的产氢情况,并探讨了调节初始pH对酸化餐厨垃圾产氢的影响.结果表明,餐厨垃圾的酸化是一个前期极为快速的过程,经过1d的酸化,新鲜餐厨垃圾的pH就从6.0左右下降到4.5左右,而后pH缓慢下降,经过5～6 d的酸化,pH下降到4.0以下;餐厨垃圾酸化过程中,产生的VFA主要是异戊酸,其浓度变化与VFA的浓度变化趋势较为一致;酸化时间为1、3、4、5、6d的餐厨垃圾体系产生的氢气的最高体积分数呈递减趋势,产氢量也呈现出相同的变化趋势;初始pH对酸化餐厨垃圾体系的产氢影响是很大的,调节到相同初始pH的不同体系,产氢的结果可以相近.因此,pH是酸化餐厨垃圾厌氧消化产氢过程中必须控制的关键因素之一.     

竹叶与餐厨垃圾厌氧共消化工艺

将黄金竹和毛竹的竹叶分别与餐厨垃圾厌氧共消化,通过分析消化过程中的产气量、pH、COD、NH4+-N和VFAs变化,探讨添加不同竹叶对餐厨垃圾厌氧消化效果的影响.实验结果表明,添加毛竹叶显著增强了餐厨垃圾的厌氧消化能力.毛竹叶+餐厨垃圾组的总产气量是餐厨垃圾对照组单独厌氧消化总产气量的3.28倍,甲烷总产量为10.1 L,COD去除率高达83.0％.而添加黄金竹叶对餐厨垃圾厌氧消化的影响则不明显,可能因为黄金竹叶在消化过程中释放了大量挥发性脂肪酸(VFAs),造成体系酸中毒.     

微生物燃料电池与好氧堆肥协同处理餐厨垃圾

实验主张将餐厨固体垃圾和餐厨废水分开处理,并研究微生物燃料电池(MFC)作为餐厨废水和堆肥渗滤液处理工艺的可行性,通过调节不同的有机负荷,分析其生物产电的潜力和处理效率。对于餐厨废水而言,3 000 mg/L是较为理想的处理浓度,输出电压最高,始终维持在0.5 V以上;高于此浓度时电压输出特性与底物浓度呈现反相关,输出电压略低于0.5 V。极化曲线,电化学阻抗分析等也都表明3 000 mg/L是较为理想的处理浓度。而且在各种浓度下经MFC处理后的餐厨废水去除率均在90%左右,出水COD均低于400 mg/L。至于堆肥渗滤液,虽然在产电性能、去除效果上较餐厨废水稍差一些,但整体上与餐厨废水呈现出相似的规律。以上结果表明,餐厨垃圾中的废水可以通过MFC有效的去除和实现能量的回收。     

14C-dimethoate residues in olive oil during oil processing

An olive tree was treated twice in the field with 14C-dimethoate (237.7 muCi, 2.4 g) and 14C residues were determined in the olive fruits at harvest. The fruits were crushed and pressed to extract the crude oil, then refined by neutralization, bleaching and deodorization. The crude oil contained 14.1% of the total 14C in the olive fruits. Neutralization resulted in a reduction of 14C by about 50% of the total 14C residues in oil. Bleaching and deodorization processes further reduced the 14C residues and the refined oil contained 31.6% (which corresponds to 4.4% of 14C residues of the total 14C in olive fruits) of the total 14C in the crude oil. Industrially extracted crude oil was fortified with 14C-dimethoate at 1.8 mg kg-1 (0.02 muCi) level and subjected to the same refining process. A sharp decrease in the amount of 14C was observed by neutralization and the amount of 14C remaining in the refined oil was about 7.3% of the total 14C in the crude fortified oil. The data suggest that the 14C residues in the aged and the fortified oil amples were not of the same nature. The terminal 14C residue in the refined oil obtained from the field experiment did not contain dimethoate and/or its oxon.     

Pyrolysis-GC-MS analysis of crude and heavy fuel oil asphaltenes for application in oil fingerprinting

A Pyrolysis – Gas Chromatography – Mass Spectrometry (Py-GC-MS) method was developed for the analysis and profiling of crude and heavy fuel oil asphaltenes, for application in oil fingerprinting. Asphaltenes were precipitated from ten geographically different oils using n-pentane, and analysed by Py-GC-MS. Alkane profiles and sulphur/aromatic profiles were used to compare the oils, and to correctly differentiate oils from different geographical regions. Py-GC-MS could not differentiate a weathered oil sample and a fresh oil sample from the same source. The results of this study support the findings from a previously developed FTIR method for asphaltene profiling.     

Emissions tradeoffs among alternative marine fuels: total fuel cycle analysis of residual oil, marine gas oil, and marine diesel oil

Worldwide concerns about sulfur oxide (SOx) emissions from ships are motivating the replacement of marine residual oil (RO) with cleaner, lower-sulfur fuels, such as marine gas oil (MGO) and marine diesel oil (MDO). Vessel operators can use MGO and MDO directly or blended with RO to achieve environmental and economic objectives. Although expected to be much cleaner in terms of criteria pollutants, these fuels require additional energy in the upstream stages of the fuel cycle (i.e., fuel processing and refining), and thus raise questions about the net impacts on greenhouse gas emissions (primarily carbon dioxide [CO2]) because of production and use. This paper applies the Total Energy and Environmental Analysis for Marine Systems (TEAMS) model to conduct a total fuel cycle analysis of RO, MGO, MDO, and associated blends for a typical container ship. MGO and MDO blends achieve significant (70-85%) SOx emissions reductions compared with RO across a range of fuel quality and refining efficiency assumptions. We estimate CO2 increases of less than 1% using best estimates of fuel quality and refinery efficiency parameters and demonstrate how these results vary based on parameter assumptions. Our analysis suggests that product refining efficiency influences the CO2 tradeoff more than differences in the physical and energy parameters of the alternative fuels, suggesting that modest increases in CO2 could be offset by efficiency improvements at some refineries. Our results help resolve conflicting estimates of greenhouse gas tradeoffs associated with fuel switching and other emissions control policies.     

化学破乳絮凝与SBR二段法处理采油污水的试验研究

采用化学絮凝与 SBR生化联合的二段法工艺对采油污水进行处理 ,采油污水经第一段化学破乳絮凝后 ,CODCr去除率可达 85 %以上 ,油去除率可达 95 %以上 ;第一段处理出水再经第二段 SBR生化处理后可使出水中 CODCr≤ 60 mg/L、BOD≤ 3 0 mg/L、SS<3 0 mg/L、油 <10 mg/L,达到了油田回注水标准和含油污水的国家二级排放标准 ,可实现废水的资源化     

生物柴油促进原油污染砂粒释放油

对4种生物柴油促进原油污染砂粒释放油的效果进行了研究,并探讨了菜籽生物柴油投加量和砂粒粒径对促进效果的影响。结果表明,菜籽生物柴油的促进效果最好,8 h释放量达到73%,废油脂生物柴油的效果最差,仅为52%;生物柴油的促进效果随着投加量的增大而升高,当投加量超过海水体积的5%时促进效果不再明显增加;在生物柴油作用下,小粒径砂粒上原油的释放效果优于大粒径砂粒。     

海洋石油工程新型溢油监测系统的研究

随着海洋石油的开采力度的加大,海上平台溢油事故也不断发生。在对传统监测方式的不足和海上溢油监测技术未来发展的趋势进行了综合考虑之后,开发了一套基于紫外诱导荧光探测技术的溢油监测系统。监测系统主要由检测终端、数据采集及异常报警系统和计算机处理及显示终端3个子模块组成,可以实现对海上平台潜在油污染源头信息的实时收集、传输、预警等功能。     

14C‐dimethoate residues in olive oil during oil processing

Abstract

An olive tree was treated twice in the field with ¹⁴C‐dimethoate (237.7 (μCi, 2.4 g) and ¹⁴C residues were determined in the olive fruits at harvest. The fruits were crushed and pressed to extract the crude oil, then refined by neutralization, bleaching and deodorization. The crude oil contained 14.1% of the total ¹⁴C in the olive fruits. Neutralization resulted in a reduction of ¹⁴C by about 50% of the total ¹⁴C residues in oil. Bleaching and deodorization processes further reduced the ¹⁴C residues and the refined oil contained 31.6% (which corresponds to 4.4% of ^I4C residues of the total ¹⁴C in olive fruits) of the total ¹⁴C in the crude oil. Industrially extracted crude oil was fortified with ¹⁴C‐dimethoate at 1.8 mg kg^‐1 (0.02 μCi) level and subjected to the same refining process. A sharp decrease in the amount of ¹⁴C was observed by neutralization and the amount of ¹⁴C remaining in the refined oil was about 7.3% of the total ^l4C in the crude fortified oil. The data suggest that the ¹⁴C residues in the aged and the fortified oil amples were not of the same nature. The terminal ¹⁴C residue in the refined oil obtained from the field experiment did not contain dimethoate and/or its oxon.     

The biodegradation of cable oil components: impact of oil concentration, nutrient addition and bioaugmentation

The effect of cable oil concentration, nutrient amendment and bioaugmentation on cable oil component biodegradation in a pristine agricultural soil was investigated. Biodegradation potential was evaluated over 21 d by measuring cumulative CO₂ respiration on a Micro-Oxymax respirometer and ¹⁴C-phenyldodecane mineralisation using a ¹⁴C-respirometric assay. Cable oil concentration had a significant effect upon oil biodegradation. Microbial respiratory activity increased with increasing cable oil concentration, whereas ¹⁴C-phenydodecane mineralisation decreased. Bioaugmentation achieved the best cable oil biodegradation performance, resulting in increases in cumulative CO₂ respiration, and maximum rates and extents of ¹⁴C-phenyldodecane mineralisation. Generally, nutrient amendment also enhanced cable oil biodegradation, but not to the extent that degrader amendment did. Cable oil biodegradation was a function of (i) cable oil concentration and (ii) catabolic ability of microbial populations. Bioaugmentation may enhance cable oil biodegradation, and is dependent upon composition, cell number and application of catabolic inocula to soil.     

The effect of crude oil and oil spill chemicals on nitrogen fixation in the cyanobacteria Nostoc sp

The effects of crude oil and three oil spill dispersants (Corexit 9600, 9550 and 7664) on nitrogenase activity in the cyanobacteria Nostoc sp. were examined. The addition of oil to Nostoc sp. cultures resulted in a catastrophic decline in nitrogenase activity with activity ceasing 7 h after treatment. The addition of a dispersant with the oil did not ameliorate this effect. Cultures exposed to high concentrations of dispersants showed lower rates on nitrogenase activity than untreated cultures. However, it is unlikely that dispersant concentrations of this magnitude would occur in the field. At the lowest concentration tested, which approximates the manufacturer's recommended application rate, the effects of the dispersant appear to be negligible.