化工过程开发中本质安全化设计策略

本质安全化设计是预防人为失误及设备失效、降低化工过程风险应优先采用的技术。在比较传统设计方法与本质安全化设计方法的基础上,讨论了化工过程开发各阶段实现本质安全的机会,认为在开发初期,实施本质安全化的成本低,难度小;通过分析可行性研究、工艺研究、概念设计、基础设计、工程设计等阶段本质安全化设计的影响因素、设计目标和设计方法,探索化工过程开发中本质安全化设计策略,提出了化工过程本质安全化设计流程。通过工艺过程本质安全设计、工艺流程的简化和优化、不同设计方案的本质安全度评估等措施,可提高化工过程本质安全水平。     

试论石化企业本质安全与本质安全化

试论石化企业本质安全与本质安全化马祖健一、本质安全与本质安全化的涵义及由来１．本质安全。简单他讲，就是指机器、设备本身所带有的安全。是指一般水平的操作者，即使发生人为的误操作，虽然发生有不安全行为，但人身、设备和系统仍能保证安全。本质安全主要起始于电...     

安全本质化与本质安全化概念初探

对“安全本质化”和“本质安全化”两个概念进行分析、比较。认为“安全本质化”作为“安全科学”的基本概念,具有更大的适用性。“本质安全化”亦是可用的,但在使用时受到一定前提条件的限制。     

论系统本质安全化和安全作业标准化

阐述了系统本质安全化的原理,其基本内容是用设备本质安全化技术的方法建立企业系统本质安全化的体系;安全作业标准化是系统本质安全化体系中最重要的内容,本文阐述了它的基本原理及其安全作业标准的理论探讨。     

本质安全化的居家安全环境设计

1 提高居家环境安全的重要性 社区是现代城市社会的基本载体,家庭是社区的基本单位.家庭应该是每个人最安全的生活和休息场所,然而由于家庭中存在着如电、燃料、燃气等危险源,决定了家庭内也有发生事故伤害的可能.此外,除了这些固定的危险源外以外,还有另一类危险源,那就是家里的各种工具或机具.这些东西当使用或保管不当时,也会给家人、特别是儿童或老人,造成意外伤害.     

人机环境系统本质安全化原理

首先定义了人机环境系统的安全本质及人机环境系统本质安全化的概念，阐述了人机环境系统本质安全化的理论模型，进而定义了事故隐患的概念，最后给出了人机环境系统本质安全化实际模型。     

基于本质安全的化工工艺物质危险指数研究

建立了基于本质安全的化工工艺物质危险性的评价体系,包括火灾危险性、爆炸危险性以及毒性等3个评价指数.基于风险的思想,各个评价指数均包括概率指标与后果指标.为了全面反映化工工艺的实际情况,在各个评价指数中均对所有物质的相应指数值加和.参数的取值以以往的指数法为基础,为了消除边界波动效应,取值采用内插法.由于各个指数的量纲...     

论系统本质安全化和安全作业标准化

阐述了系统本质安全化的原理,其基本内容是用设备本质安全化技术的方法建立企业系统本质安全化的体系;安全作业标准化是系统本质安全化体系中最重要的内容,本文阐述了它的基本原理及其安全作业标准的理论方法。     

人机环境系统本质安全化原理

首先定义了人机环境系统的安全本质及人机环境系统本质安全化的概念，阐述了人机环境系统本质安全化的理论模型，进而定义了事故隐患的概念，最后给出了人机环境系统本质安全化实际模型。     

Inherently safer design based on rapid risk analysis

The importance of inherently safer design (ISD) as a strategy to minimize risk of accidents in chemical process industries is being repeatedly stressed in recent years. The increasing number, frequency, and extents of damage caused by such accidents across the world have contributed to this thinking. However even as the need for ISD is being underscored, there are very few reports on precise methods to implement this concept. Significant recent reports are by Berge (1993Berge, 1995)who has suggested a scenariobased design procedure in which construction of accident scenarios in a structured manner is made the basis of ISD. We have been developing and applying the concept of rapid risk analysis ( [Khan & Abbasi, 1995] , [Khan & Abbasi, 1996] , [Khan & Abbasi, 1997a] , [Khan & Abbasi, 1997b] , [Khan & Abbasi, 1998a] and Khan &; Abbasi, 1998b). In this paper we present an approach to ISD utilizing this concept. We believe, as detailed in this paper, that this approach is a significant improvement upon Berge's procedure in terms of ease, speed, and effectiveness.     

Incorporating inherent safety during the conceptual process design stage: A literature review

This paper reviews principal concepts, tools, and metrics for risk management and Inherently Safer Design (ISD) during the conceptual stage of process design. Even though there has been a profusion of papers regarding ISD, the targeted audience has typically been safety engineers, not process engineers. Thus, the goal of this paper is to enable process engineers to use all the available design degrees of freedom to mitigate risk early enough in the design process. Mainly, this paper analyzes ISD and inherent safety assessment tools (ISATs) from the perspective of inclusion in conceptual process design. The paper also highlights the need to consider safety as a major component of process sustainability. In this paper, 73 ISATs were selected, and these tools were categorized into three groups: hazard-based inherent safety assessment tools (H-ISATs) for 22 tools, risk-based inherent safety assessment tools (R-ISATs) for 33 tools, and cost-optimal inherent safety assessment tools (CO-ISATs) for 18 tools. This paper also introduces an integrated framework for coordinating the conventional process design workflow with safety analysis at various levels of detail.     

Systematic review on the implementation methodologies of inherent safety in chemical process

The accomplishments of inherent safety in the field of loss prevention thus far are impressive due to its scientific philosophy: reducing risks at source rather than adding engineered and procedural protections. Generally, the implementation of inherent safety can be done through a cohesive set of fourteen principles elucidated by Kletz and Amyotte. This work, guided by the fourteen principles, presents a systematic review on the implementation methodologies of inherent safety. Firstly, PRISMA procedure was adopted to select eligible literatures according to inclusive and exclusive criteria. After obtaining the selected literatures, the preference, level of application, and gaps in using these principles were critically analyzed. Of the fourteen principles, intensification, substitution, attenuation, simplification, limitation of effects, and avoidance of knock-on effects are preferable to implementing inherent safety in chemical process. Although the remaining principles are also potentially useful, they are not commonly used due to their costs and complexities of implementation. Overall, this work presents a complete spectrum to look across the implementation methodologies of inherent safety and concludes with some holistic and inclusive approaches as future research recommendations.     

An index to account for safety and controllability during the design of a chemical process

Inherent safety is well known as the best technique of risk management, but its implementation is a challenge when there is a conflict with other factors, in particular with the process dynamic performance when the application of the minimization principle is considered. In this work, a combined safety-controllability index applicable during the design stage of a process is presented. The index accounts for the process controllability and the risk of the chemical inventory inside the process. The condition number is used to assess controllability, and the quantitative risk analysis technique is carried out to obtain a distance of affectation as a metric for individual risk. The index, based on a combination of normalized values of metrics for controllability and risk, was applied to three case studies dealing with distillation processes that separate flammable and toxic chemicals. The effect of relevant design variables such as column diameter and residence time was analyzed. It is shown how conflicts between safety and controllability exist for different values of those design variables and how a proper controllability-risk compromise can be identified with the use of the proposed index.     

Study of chemical supply system of high-tech process using inherently safer design strategies in Taiwan

The photoelectric, semiconductor and other high-tech industries are Taiwan's most important economic activities. High-tech plant incidents are caused by hazardous energy, even when that energy is confined to the inside of the process machine. During daily maintenance procedures, overhauling or troubleshooting, engineers entering the interior of the machines are in direct contact with the source of the energy or hazardous substances, which can cause serious injury. The best method for preventing such incidents is to use inherently safer design strategies (ISDs); this approach can fully eliminate the dangers from the sources of hazardous energy at a facility.This study first conducts a lithography process hazard analysis and compiles a statistical analysis of the causes of the fires and losses at high-tech plants in Taiwan since 1996, the aim being to establish the necessary improvement measures by using the Fire Dynamics Simulation (FDS) to solve relevant problems. The researchers also investigate the lithography process machine in order to explore carriage improvement measures, and analyse the fires' causes and reactive materials hazardous properties, from 1996 to 2012. The effective improvement measures are established based on the accident statistics. The study site is a 300 mm wafer fabrication plant located in Hsinchu Science Park, Taiwan.After the completion of the annual maintenance jobs improvement from September 2011 to December 2012, the number of lithography process accidents was reduced from 6 to 1. The accident rate was significantly reduced and there were no staff time losses for a continuous 6882 h. It is confirmed that the plant safety level has been effectively enhanced. The researchers offer safety design recommendations regarding transport process appliances, chemical storage tanks, fume cupboard devices, chemical rooms, pumping equipment, transportation pipelines, valve manual box (VMB) process machines and liquid waste discharge lines. These recommendations can be applied in these industries to enhance the safety level of high-tech plants, facilities or process systems.     

Assessment of chemical process hazards in early design stages

A new method called SREST-layer-assessment method with automated software tool is presented that in a hierarchical approach reveals the degree of non-ideality of chemical processes with regard to SHE (safety, health and environment) aspects at different layers: the properties of the chemical substances involved (substance assessment layer (SAL)), possible interactions between the substances (reactivity assessment layer (RAL)), possible hazard scenarios resulting from the combination of substances and operating conditions in the various equipments involved (equipment assessment layer (EAL)), and the safety technologies that are required to run a process safely and in accordance with legal regulations (safety-technology assessment layer (STAL)). In RAL, EAL and STAL the main focus is put on process safety. A case study is used to show the principles of the method. It is demonstrated how the method can be used as a systematic tool to support chemical engineers and chemists in evaluating chemical process safety in early process development stages.     

Study of high-tech process furnace using inherently safer design strategies (I) temperature distribution model and process effect

High-tech industries, such as those producing semiconductor and TFT-LCD (Thin Film Transistor Liquid Crystal Display), have recently become the most important economic activities in Taiwan. Each of these industries has a complete chain of supply from raw material production, production pre-processing, product manufacturing, to waste handling. Any company in the chain is a critical component, since any accidents of fire, explosion, gas leakage, or power outage would cut off the supply chain, causing inability of continuous operation. In industries of semiconductor and TFT-LCD, great amounts of special gases and chemicals with many machinery equipments are used in the production processes. In cases of accidents or improper installation, this chain of supply, from raw material production, preproduction, product manufacturing, to waste handling materials and equipments may cause severe damages or incidents.This study used the existing model of the horizontal furnace to develop a simulation program. The simulation results were consistent with the existing model, and produced even slightly better results on temperature distribution and temperature sensitivity. The simulation model applied on a vertical furnace could provide data on furnace temperature control for industrial use. Meanwhile, this study also deduced actual temperature control and an ISD strategy, which are consistent with design strategy principles.The validation results on the proposed temperature distribution model suggested that the model can be applied in temperature distribution and sensitivity analysis to obtain adjustment and control models for various heating zones. In the case of a single tool, when processing reduction is 60 pieces, switching off the two heating zones can reduce 44% of power output, for a capacity utilization rate of 93.7% for the entire plant. The application of the proposed temperature control model can reduce power consumption by 121.4 kWh. In addition, with the same number of tools, facilities layouts in two cases have an area difference of 41.4775 m², thus shortening the evacuation time for operators. The experimental results proved that the proposed model has realized the ISD principles of intensification, attenuation, and limitation of effects.     

Inherently safer design review and their timing during chemical process development and design

This paper discusses the enhancement of inherent safety review and its implementation in the chemical process development and design. The aim is to update and improve the existing inherently safer design review (ISDR) practices during design of chemical process plant by exploiting major accident cases from the U.S. Chemical Safety Board (CSB) and Failure Knowledge Database (FKD). Although the basic guidelines to conduct ISDR during design phase are available, however they are too general and incomplete. The review criteria and their best timing for application are still missing. This paper attempts to develop the accident-based ISDR for chemical process plant design. The proposed accident-based ISDR is supported with detail review criteria for each phase of process design. The timing of ISDR application is corresponding to the common design tasks and decisions made in the design project. Therefore, timely design review could be done at the specific design task and the findings help designer to make a correct decision making.