有机污染物半导体多相光催化氧化机理及动力学研究进展

本文系统总结了有机污染物半导体多相光催化氧化机理及动力学研究进展现状，阐述了几种特定有机污染物的光催化氧化机理，并对有关机理方面进一步研究的必要性和方向进行了探讨。     

TiO2纳米粒子气-固复相光催化氧化VOCs作用的研究进展

本文总结了90年代以来TiO2纳米粒子气-固复相光催化氧化气相有机污染物的影响因素、反应机理和动力学,阐述了几种特定有机污染物的光催化氧化过程,并对应用前景作出展望.     

水中有机污染物的光催化氧化

本文系统综述了十余年来光催化氧化法去除水中有机污染物的基础研究成果，讨论了光催化氧化法的机理、影响光催化氧化反应速率的因素及提高光催化反应效率的途径，旨在为该方法的应用开发研究提供有益的帮助。     

TiO2纳米粒子气—固复相光催化氧化VOCs作用的研究进展

本文总结了９０年代以来ＴｉＯ２纳米粒子气－固复相光催化氧化气相有机污染物的影响因素,瓜是和动力学,阐述了几种特定有机污染物的光催化氧化过程,并对应用前景作出展望。     

二氧化钛光催化氧化研究进展

光催化氧化是日益引起重视的污染治理的新技术。对国内外有关水中污染物的光催化氧化过程的研究结果进行了总结,讨论了该过程所涉及的反应机理,催化剂备及提高催化活性的方法,并提出了光催化氧化法今后的研究方向。     

固定化催化剂光反应器降解有机物研究进展

本文系统介绍了在TiO2的非悬浆式体系中，光催化氧化有机污染物效率的影响因素、新型光反应器的特点以及污染物的降解动力学规律。可以预见，光催化氧化与传统的处理方法相比，有着良好的应用前景。     

多相光催化在水污染治理中的应用

多相光催化过程是近年来日益引起重视的污染治理新技术，具有适用范围广、可使污染物彻底破坏、适用于低浓污染物治理等优点，本文对国外近年有关多相光催化在水污染治理中应用的研究结果进行了总结，包括各种有机污染物的氧化及各种无机离子的治理，并讨论了多相光催化过程的优点及实用性。     

光催化降解有机污染物的进展

综合国内外资料,探讨了半导体光催化氧化降解不中有机污染物的机理,综述了半导体光催化剂在降解水中有机物方面的研究现状及其进展情况。并对半导体光催化氧化法催化剂本身存在的问题提出了一些看法。     

TiO2光催化脱除NOx的研究进展

利用TiO2的光催化效应脱除大气污染物是近十年来国内外学术界的研究热点之一。本文对TiO2光催化脱除NOx方面的研究工作进行了综述,郑重论述了光催化氧化反应及光催化还原反应脱除NOx的反应机理及影响因素,并对应用前景作了展望。     

TiO2光催化脱除NOx的研究进展

利用TiO2的光催化效应脱除大气污染物是近十年来国内外学术界的研究热点之一.本文对TiO2光催化脱除NOx方面的研究工作进行了综述,着重论述了光催化氧化反应及光催化还原反应脱除NOx的反应机理及影响因素,并对应用前景作出展望.     

Photocatalytic degradation of volatile organic compounds at the gas-solid interface of a TiO2 photocatalyst

In the present work, photocatalytic degradation of volatile organic compounds including gas-phase trichloroethylene (TCE), acetone, methanol and toluene over illuminated TiO2 was closely examined in a batch photoreactor as a function of water vapor, molecular oxygen and reaction temperature. Water vapor enhanced the photocatalytic degradation rate of toluene, but was inhibitive for acetone, and, there was an optimum water vapor concentration in the TCE and methanol removal. In a nitrogen atmosphere, it showed lower photocatalytic degradation rate than in air and pure oxygen. Thus, it could be concluded that oxygen is an essential component in photocatalytic reactions by trapping photogenerated electrons on the semiconductor surface and by decreasing the recombination of electrons and holes. As for the influence of reaction temperature, it was found that photocatalytic degradation was more effective at a moderate temperature than at an elevated temperature for each compound.     

二氧化钛纳米管光催化降解水中百草枯

二氧化钛纳米管被用于光催化氧化水体中的百草枯,对光催化反应条件、常见Fe3+离子的干扰情况和百草枯光催化降解动力学规律进行了研究。结果表明,浓度为25 mg/L的百草枯溶液,在二氧化钛纳米管(TNT)1.0 g/L,H2O20.5 mL/50 mL,pH=5.0的最优光催化氧化条件下,经过30 min反应可以被100%从水体中去除,表现出非常高的光催化降解效率;动力学方程拟合表明,百草枯光催化氧化反应符合拟一级动力学规律,动力学方程为ln(C0/C)=1.0267t-0.1282,反应速率常数K为1.0267 h-1;双氧水存在时常见的Fe3+能够进一步提高百草枯光催化降解率;该光催化反应体系对低浓度百草枯废水有很好的处理效果,预示着光催化氧化技术适合地表或地下水体中百草枯的去除。     

固定化催化剂TiO2膜光催化降解三氯乙醛的研究

研究了负载于玻璃上的固定化催化剂TiO2膜光催化降解水中三氯乙醛的效果,探讨了TiO2膜光催化降解三氯乙醛的机理,考察了溶液pH值和三氯乙醛初始浓度埘TiO2膜光催化降解三氯乙醛的影响,并研究了固定化催化剂TiO2膜光催化降解三氯乙醛的动力学.结果表明,固定化催化剂TiO2膜光催化降解水中三氯乙醛的效果良好,当三氯乙醛初始浓度为2.25 mg/L时,在紫外光照时间3 h下,三氯乙醛的降解率高达100%.在相司紫外光照时间下,三氯乙醛的光催化降解率随着三氯乙醛初始浓度的增大而下降.在溶液pH=6.5时,三氯乙醛的降解效率最高.固定化催化剂TiO2膜光催化降解三氯乙醛的反应遵循一级反应动力学,反应速率常数随三氯乙醛初始浓度的增大而减小.     

Photocatalytic degradation of the herbicide erioglaucine in the presence of nanosized titanium dioxide: comparison and modeling of reaction kinetics

The present work mainly deals with photocatalytic degradation of a herbicide, erioglaucine, in water in the presence of TiO2 nanoparticles (Degussa P-25) under ultraviolet (UV) light illumination (30 W). The degradation rate of erioglaucine was not so high when the photolysis was carried out in the absence of TiO2 and it was negligible in the absence of UV light. We have studied the influence of the basic photocatalytic parameters such as pH of the solution, amount of TiO2, irradiation time and initial concentration of erioglaucine on the photodegradation efficiency of erioglaucine. A kinetic model is applied for the photocatalytic oxidation by the UV/TiO2 system. Experimental results indicated that the photocatalytic degradation process could be explained in terms of the Langmuir-Hinshelwood kinetic model. The values of the adsorption equilibrium constant, K, and the second order kinetic rate constant, k, were 0.116 ppm-1 and 0.984 ppm min-1, respectively. In this work, we also compared the reactivity between the commercial TiO2 Degussa P-25 and a rutile TiO2. The photocatalytic activities of both photocatalysts were tested using the herbicide solution. We have noticed that photodegradation efficiency was different between both of them. The higher photoactivity of Degussa P-25 compared to that of rutile TiO2 for the photodegradation of erioglaucine may be due to higher hydroxyl content, higher surface area, nano-size and crystallinity of the Degussa P-25. Our results also showed that the UV/TiO2 process with Degussa P-25 as photocatalyst was appropriate as the effective treatment method for removal of erioglaucine from a real wastewater. The electrical energy consumption per order of magnitude for photocatalytic degradation of erioglaucine was lower with Degussa P-25 than in the presence of rutile TiO2.     

TiO2纳米管催化降解4，4’-二溴联苯的影响因素和动力学研究

利用TiO₂纳米管催化降解水中的4,4’-二溴联苯,对催化降解过程和影响因素进行研究。结果表明,TiO₂纳米管对其有较高的催化降解效率且降解过程符合Langmuir-Hinshelwood动力学模式。不同光源、4,4’-二溴联苯的初始浓度、纳米管添加量和pH值对催化降解过程都有较大影响,其中pH值的影响最为明显。反应液在中性状态下的降解率明显低于pH=1或11的情况。在pH=1时,4,4’-二溴联苯的降解率达86%。     

Study on the photocatalytic degradation of glyphosate by TiO(2) photocatalyst

In this paper, the photocatalytic degradation of glyphosate selected as the deputy of organic pollutant in aqueous solution with TiO(2) powder as a photocatalyst has been studied. The effects of various parameters, such as the amount of the photocatalyst, illumination time, initial pH value, electron acceptors, metal ions, and anions on the photocatalytic degradation of glyphosate were investigated. From the studies, the best condition for the effect of the parameters on the photocatalytic degradation of glyphosate was obtained. The results show that the optimum amount of the photocatalyst used is 6.0 g l(-1) for the photocatalytic reactions. The photodegradation efficiency of glyphosate increases with the increase of the illumination time. With the addition of Fe(3+), Cu(2+), H(2)O(2), K(2)S(2)O(8) or KBrO(3), the photocatalytic degradation of glyphosate is accelerated. However, with the addition of Na(+), K(+), Mg(2+), Ca(2+), Zn(2+), Co(2+) and Ni(2+), or with the addition of trace amounts of Cl(-), Br(-), SO(4)(2-), there are no obvious effects on the reactions. Acidic or alkaline mediums are favorable for the photocatalytic degradation of glyphosate. The possible roles of the additives on the reactions and the possible mechanisms of effect were discussed.     

Comparison of catalytic activity of two platinised TiO2 films towards the oxidation of organic pollutants

Two types of platinised TiO2 films, i.e., Pt-TiO2/ITO and Pt(TiO2)/ITO, were prepared by a procedure of dip-coating and subsequent photo-deposition, and photo-deposition and subsequent dip-coating, respectively. They were well characterized by DRS, XRD spectra, SEM microscopy and photoelectrochemical measurement. Their photocatalytic, dark catalytic and photoelectrocatalytic activities were investigated using formic acid as a model organic pollutants. Compared with pure TiO2/ITO film, the photocatalytic activity of the platinised TiO2 films were apparently improved. However, the improvement was considerably dependent on the preparation method of these films. Pt-TiO2/ITO not only possessed higher photocatalytic activity but also showed a dark catalytic activity towards HCOOH degradation. As a sequence, it was first emphasized that the dark catalytic effect of Pt-TiO2/ITO was partly responsible for degradation of formic acid in the photocatalytic oxidation process. Although the Pt(TiO2)/ITO film does not exhibit the dark catalytic activity, its photocatalytic degradation efficiencies towards HCOOH are higher than that of Pt-TiO2/ITO film. Therefore, in view of enhanced photocatalytic activity, the Pt(TiO2)/ITO was more favored than Pt-TiO2/ITO film.     

光源对光催化降解甲醛效果的影响及预测模型

利用环境测试舱模拟不同光源种类和光照强度下的室内环境,以甲醛溶液的光催化降解为探针反应,分析Ce-TiO2光催化降解甲醛溶液效果与光源的关系。并且采用指数平滑法中的3次指数平滑模型,建立Ce—TiO2光催化降解甲醛溶液效果的预测模型,预测结果表明实测值与预测值误差小,预测值精确度高,这为光催化降解甲醛溶液的研究,提供了一个新的思路。     

Effect of ZnFe2O4 doping on the photocatalytic activity of TiO2

The photocatalytic oxidation of the organic pollutants with the TiO2 as photocatalyst has been widely studied in the world, and many achievements have been got. The degradation of pollutants is highly related with the photocatalytic activity of TiO2. It is demonstrated that doping ions or oxides to TiO2 is one way to enhance the photocatalytic activity of TiO2. In this paper, the ZnFe2O4-doped TiO2 nanoparticles were prepared from butyl titanate by a sol-gel method and characterized by means of X-ray diffraction (XRD) and transmission electron microscopy (TEM). The results showed that when TiO2 was doped with ZnFe2O4, its particle size will decrease and its crystal structure will partly transform from anatase to rutile. The photocatalytic activity of the elaborated powders was studied following the degradation of Rhodamine B. The results showed that doping ZnFe2O4 to TiO2 will enhance the photocatalytic activity of TiO2 and that ZnFe2O4-doped TiO2 in the coexistence of anatase and rutile has higher efficiency for the degradation of Rhodamine B than that in the anatase phase alone. Also the different role of O2 in the direct photolysis and photocatalysis of Rhodamine B was discussed.     

Photocatalytic Degradation of the Herbicide Erioglaucine in the Presence of Nanosized Titanium Dioxide: Comparison and Modeling of Reaction Kinetics

The present work mainly deals with photocatalytic degradation of a herbicide, erioglaucine, in water in the presence of TiO₂ nanoparticles (Degussa P-25) under ultraviolet (UV) light illumination (30 W). The degradation rate of erioglaucine was not so high when the photolysis was carried out in the absence of TiO₂ and it was negligible in the absence of UV light. We have studied the influence of the basic photocatalytic parameters such as pH of the solution, amount of TiO₂, irradiation time and initial concentration of erioglaucine on the photodegradation efficiency of erioglaucine. A kinetic model is applied for the photocatalytic oxidation by the UV/TiO₂ system. Experimental results indicated that the photocatalytic degradation process could be explained in terms of the Langmuir–Hinshelwood kinetic model. The values of the adsorption equilibrium constant, K, and the second order kinetic rate constant, k, were 0.116 ppm^{? 1} and 0.984 ppm min^{? 1}, respectively. In this work, we also compared the reactivity between the commercial TiO₂ Degussa P-25 and a rutile TiO₂. The photocatalytic activities of both photocatalysts were tested using the herbicide solution. We have noticed that photodegradation efficiency was different between both of them. The higher photoactivity of Degussa P-25 compared to that of rutile TiO₂ for the photodegradation of erioglaucine may be due to higher hydroxyl content, higher surface area, nano-size and crystallinity of the Degussa P-25. Our results also showed that the UV/TiO₂ process with Degussa P-25 as photocatalyst was appropriate as the effective treatment method for removal of erioglaucine from a real wastewater. The electrical energy consumption per order of magnitude for photocatalytic degradation of erioglaucine was lower with Degussa P-25 than in the presence of rutile TiO₂.