Spatial variations in selected metal contents and particle size distribution in an urban and rural atmosphere of Islamabad, Pakistan

Spatial variations in total suspended particulate matter (TSP) were investigated for distribution of metals and particle size fractions in the urban and rural atmosphere of Islamabad, Pakistan. The metals Na, K, Fe, Mn, Pb, Cd, Cr, Zn, Ni and Co, and the particle fractions <2.5, 2.5-10, 10-100 and >100 microm were included in the study. TSP samples were trapped on glass fibre filters using high volume samplers and quantification of metals was done using Atomic Absorption Spectrometry employing HNO(3) based wet digestion. At the urban site, Na was dominant at 2.384 microg/m(3) followed by K, Fe and Zn with 0.778, 0.667 and 0.567 microg/m(3) as mean concentrations, respectively. The metal levels for the rural site ranged from 0.002 microg/m(3) for Cd to 1.077 microg/m(3) for Na. However, compared with the urban site, mean Pb concentration showed an almost two-fold enhancement, i.e., 0.163 Vs. 0.327 microg/m(3). Metals and particle size source identification was done using Principal Component Analysis and Cluster Analysis. Five sources were traced out for the urban site: industrial, soil, automobile emissions, metallurgical industries and excavation activities. For the rural site, four sources were recorded: agricultural, automotive emissions, excavation activities and metallurgical units. Collectively, for both the sites, PM(10-100) emerged as a major contributor to TSP, followed by PM(2.5-10), PM(<2.5) and PM(>100) in that order. The metals showed in general positive relationship with fine particulate fractions (PM(2.5-10), PM(<2.5)), and negative correlation with coarse fractions (PM(10-100), PM(>100)). Comparison with the corresponding data from various Asian sites revealed that the levels of Na, K, Fe, Mn, Co and Ni for the present study were lower than those reported for grossly polluted cities of the world.     

南充市空气中可吸入颗粒物污染水平分析

本文在连续1年又5个月同步采样的基础上，测得南充市市辖三城区5个采样监测点环境空气中PM10的浓度及其时空变化进行了分析。结果表明，PM10的日平均浓度范围为0．020～1．030mg／m^3，超标率达38．0％；周日均浓度在0.040～0．520mg／m^3之间，超标率达到了37．8％。空气污染最重为嘉陵城区，其次为高坪城区，再次为石油学院、炼油厂和市府二院。浓度季节变化特征表现为冬季最高，其次为秋季，再次为春季，最轻为夏季。     

Nutrient requirements for the growth of waterleaf (Talinum triangulare) in Uyo metropolis, Nigeria

The all-season vegetable known as waterleaf (Talinum triangulare) is extensively grown in Nigeria's metropolistan market gardens. This paper examines the soil compositions of some of the cultivation areas for this crop to determine the impacts of its very intensive repetitive cultivation. In general, the regular application of organic manures and mineral fertilizers has maintained the fertility status of the market garden soils. Multiple regression analysis indicated that base saturation, available phosphorus and organic matter were the most significant determinants to variations in crop production.     

Sedimentation rate of settleable particulate matter in Santiago city,Chile

Settleable particulate matter (SPM) is an atmospheric pollutant harmful to human health and the environment in high concentrations. Despite this fact, no up‐to‐date information on SPM levels exists for the capital of Chile, Santiago (7 million inhabitants). To address this knowledge gap, SPM sedimentation rates, including soluble and insoluble components, were measured at three different urban sites from July to November of 2016. We compare the measurements with ambient and meteorological information, as well as urban typology settings. Our results indicate SPM deposition rates between 2.5 and 3.9 g/(m²·30 days). Only one site exceeded the national limit of 4.5 g/(m²·30 days), but we found an increasing trend in all three sites. SPM and its insoluble sedimentation rates increased during warm and dry months and presented significant correlations with meteorological parameters. The highest sedimentation rates were measured at the location with the least permeable surfaces and the lowest green spaces, while the lowest sedimentation rates were found in the sites with abundant green spaces and permeable soil. No significant differences were detected in the soluble components. Our results suggest that SPM levels in Santiago are close to the national limit and may increase with climate change and urban expansion.     

资阳市空气可吸入颗粒物的污染水平及变化规律

本文对资阳市两年间城区环境空气中PM10的监测数据进行分析,揭示了该污染物的时空分布特征及变化规律,并有针对性的提出了一些防治对策.     

Building contraventions and incidence of flood in the Lagos Metropolis,Nigeria

Frequent floods have led to loss of lives and destruction of property in both coastal and landlocked cities across the globe, particularly where floodplains have been developed without recourse to space standards. This paper investigated the contributions of contravention of building codes to flooding in flood-prone areas in the Lagos metropolis. Global Positioning Systems (GPSs) were used to determine the location and elevation above sea level of 1,025 buildings situated in 211 streets that were prone to flooding. The distance of buildings from drainage channels/the lagoon was determined in ArcGIS 10.2 environment. Findings revealed that building code contravention contributed significantly to flooding (r = 0.926). About 63.5% and 63.3% of sampled buildings contravened building-plot ratio and statutory setbacks from drainage channels/the lagoon, respectively. Proactive urban planning, strict enforcement of building codes and development control regulations are required to reduce flooding and its consequences in cities of developing nations where flooding has become an annual occurrence.     

Estimating the effectiveness of a vehicle miles travelled tax in reducing particulate matter emissions

This study estimates the effectiveness of a vehicle miles travelled (VMT) tax in controlling mobile-source emissions of particulate matter (PM_2.5) in a non-attainment area located in northern Utah. Using a recently updated household-level dataset, the study finds no evidence of an endogenous relationship between choice of vehicle type and VMT. VMT elasticities are also estimated with respect to cost per mile that are in some cases larger in magnitude than those reported in previous studies. Based on vehicle emissions tests performed by the Houston Advanced Research Center, the study estimates the reduction in particulate emissions that would occur with two different sets of VMT tax rates. Principal findings are that a VMT tax rate of $0.003 per passenger car mile and $0.01 per light-duty truck mile (resulting in a mean annual tax burden of $128 per household in the first year) would reduce annual particulate emissions by between 7% and 11%, depending upon the degree of heterogeneity in household driving behaviour. Assuming constant elasticity, this means that at tax rates of $0.006 and $0.02 per mile for passenger cars and light-duty trucks, respectively (resulting in double the mean annual tax burden), annual particulate emissions would be reduced by between 12% and 23%. Both the advantages and limitations of the VMT tax are discussed.     

Acute toxicity of acaricide in lizards (Agama agama) Inhabiting dog kennel in Ibadan, Nigeria: An environmental hazard in urban vector control

Acute toxicity of an acaricide (Nuvan^® 1000 EC) in lizards (Agama agama) was observed within 2 minutes spraying of the acaricide in an enclosed dog kennel; heavily infested by ticks in urban area of Ibadan city, South western Nigeria. The acaricide was used at the 0.5% concentration recommended by the manufacturer (Novartis). A lizard which emerged from the kennel during the acaricide spraying exhibited acute signs of toxicity which consisted of shivering, gasping and death. The clinical signs of the acute toxicity manifested in the affected lizard resembled central nervous system (CNS) breakdown or neurotoxicity. Also, two lizards (one female and one male) were found dead in the kennel in the second and third days after the single acaricide spraying operation. The acute acaricide toxicity in lizards observed in this study portrayed the danger of environmental hazard to non-target commensal organisms and it is the first reported case in the area.     

Analysis of Roadside Inhalable Particulate Matter (PM10) in Major Korean Cities

A data analysis of three major Korean cities was conducted to assess roadside inhalable particulate matter 10 μm or smaller in aerodynamic diameter (PM₁₀), including temporal and meteorological variations, over a recent period of 4 to 6 years. The yearly roadside PM₁₀ concentrations presented a well-defined increasing trend or no trend depending on the roadside monitoring station. Most mean values exceeded or approximated the Korean standard of 70 μg/m³ per year for PM₁₀. A representative roadside diurnal trend was characterized by a distinct morning maximum. In most cases, the Sunday roadside concentrations were similar to or somewhat lower than the weekday concentrations, and the PM₁₀ concentrations presented a well-defined seasonal variation, with the maximum concentration in March. The monthly maximum concentrations observed in March were most likely attributable to Asian dust storms. In two metropolitan cities (Seoul and Busan), the frequency of days with roadside PM₁₀ concentrations exceeding the standard of 150μg/m³ per 24 h was much lower for the roadside monitoring stations than for the residential monitoring station, whereas in the third city (Daegu), this result was reversed. Interestingly, the average maximum concentrations observed for the roadside sites in Seoul and Busan during March were higher than those for the residential sites, suggesting that the roadside concentrations responded more to the dust storms than the residential areas. The relationship between the pollutant concentrations and five important meteorological parameters (solar radiation, wind speed, air temperature, relative humidity, and precipitation) showed that the number and type of meteorological variables included in the equations varied according to the monitoring station or season. Finally, the current results confirmed that attention should be given to the PM₁₀ exposure of residents living near roadways.     

Determination of direct and fugitive PM emissions in a Mediterranean harbour by means of classic and novel tracer methods

Remodelling works are frequent in harbour areas, given that they must adapt to rapidly changing market requirements. Depending on their nature (construction, demolition, etc.), these works may be carried out during long periods of time and thus exert a significant impact on the air quality at the harbours and their surroundings. The air quality at the Valencia harbour was studied during an enlargement project. Four sampling stations aimed to cover the major dust-emitting activities in the harbour. In addition, a sampling campaign was carried out to collect dust materials at their emission sources (e.g., loading and unloading of clinker and petroleum coke, as well as the enlargement works). Differences obtained between PM levels at the monitoring sites were correlated with the distance between sampling stations and enlargement works and/or harbour operations, as well as with the preferential wind direction. In all cases, the days with the highest PM_10 levels were linked to wind directions coinciding with the location of the enlargement works or the clinker and petroleum coke stocks. Classic source apportionment methodologies (PCA and CMB) were applied to the data, but their interpretation was complex due to the similar chemical signatures of PM originating from direct and fugitive emissions from stocked materials (e.g., clinker), and the enlargement works. To overcome this difficulty, a novel non-statistical approach was used to obtain quantitative estimations of the contributions from sources (petroleum coke and clinker), based on the correlation between specific PM components (e.g., carbonaceous species) and source tracers (e.g., V). Finally, a qualitative test using phenolphthalein was devised to identify the presence of clinker on the filters, which provided positive results. This novel tracer approach is thus recommended for harbour authorities.     

Environmental performance of urban roadside traders in Jos,Nigeria

In the last ten years official location policy in Nigeria for urban roadside traders, an enterprising group of urban poor operating at the lowest level of the informal sector of the economy has been very negative. Government believes that they should be removed from the streets and tucked away in obscure locations because of their tendency to deface the streets with litter and for causing vehicular and pedestrian traffic congestion. This paper identifies and assesses the magnitude of pollution created by the traders as a prelude to evolving a planning policy and strategy for regulating and formally accommodating street traders in good locations while still ensuring good environmental quality.     

Impact of COVID-19 lockdown on the elemental profile of PM10 present in the ambient aerosol of an educational institute in Kolkata,India

Reduction in air pollution level was prime observation during COVID-19 lockdown globally. Here, the study was conducted to assess the impact of lockdown on the elemental profile of PM₁₀ in ambient aerosol to quantify the elemental variation. To quantify the variation, phase-wise sampling of air pollutants was carried out using the gravimetric method for PM₁₀, while NO₂ and SO₂ were estimated through the chemiluminescence and fluorescent spectrometric method respectively. The elemental constituents of PM₁₀ were carried out using an Inductively Coupled Plasma Optical Emission Spectrometer and their source apportionment was carried out using the Positive Matrix Factorization model. The results showed that PM₁₀, NO₂ and SO₂ reduced by 86.97%, 83.38%, and 88.60% respectively during the lockdown sampling phase. The highest mean elemental concentration reduction was found in Mn (97.47%) during the lockdown. The inter-correlation among the pollutants exhibited a significant association indicating that they originate from the same source. The metals like Mn and Cu were found at a higher concentration during the lockdown phase corresponding to vehicular emissions. The comparative analysis of the elemental profile of PM₁₀ concluded that the lockdown effectuated in reduction of the majority of elements present in an aerosol enveloping metropolitan like Kolkata.     

The direct influence of ship traffic on atmospheric PM2.5, PM10 and PAH in Venice

The direct influence of ship traffic on atmospheric levels of coarse and fine particulate matter (PM_2.5, PM₁₀) and fifteen polycyclic aromatic hydrocarbons (PAHs) has been estimated in the urban area of Venice. Data analysis has been performed on results collected at three sites over the summer, when ship traffic is at a maximum. Results indicate that monitoring of the PM daily concentrations is not sufficiently detailed for the evaluation of this contribution, even though it could be useful for specific markers such as PAHs. Therefore a new methodology, based on high temporal resolution measurements coupled with wind direction information and the database of ship passages of the Harbour Authority of Venice has been developed. The sampling sites were monitored with optical detectors (DustTrack^® and Mie pDR-1200) operating at a high temporal resolution (20s and 1s respectively) for PM_2.5 and PM₁₀. PAH in the particulate and gas phases were recovered from quartz fibre filters and polyurethane foam plugs using pressurised solvent extraction, the extracts were then analysed by gas chromatography- high-resolution mass spectrometry. Our results shows that the direct contribution of ships traffic to PAHs in the gas phase is 10% while the contribution to PM_2.5 and to PM₁₀ is from 1% up to 8%.     

泸州市主城区2019年3月至2020年2月大气颗粒物污染特征及防治对策研究

为了解泸州市主城区颗粒物污染变化特征及成因,选取2019年3月至2020年2月空气自动监测数据,运用Origin 2017等技术手段对PM2.5与PM10的时间变化特征、污染来源方向以及污染物之间的相关性进行了分析.结果表明:PM2.5与PM10在不同季节的变化趋势均具有较好的一致性,不同站点污染物相关性特征明显.分析...     

Spatial and temporal projected distribution of four crop plants in Egypt

This study focuses on the management of the local agroecosystems in order to adapt planting or sowing practices for the projected climate change scenarios. It is projected that there will be increased air temperature throughout all four seasons in the coming 100 years, from the southern towards the northern parts of Egypt. The objective of this study is to investigate the influence of that increased air temperature on the spatial and temporal distribution of four of the major economic crops in Egypt. The study species are cotton (Gossypium barbadense L., cv. Giza 89), wheat (Triticum aestivum L., cv. Gemiza 9), rice (Oryza stiva L., cv. Sakha 101) and maize (Zea mays L., cv. Hybrid 10). Optimum air temperature allowing maximum growth for each of the study crop cultivars and the current and projected air temperature patterns in the future years were used for projection of the seasonal and crop distribution maps in the years 2005, 2025, 2050, 2075 and 2100. Results showed that sowing dates of a target crop may be managed in order to allow maximum predicted planting area in the same region. The current maximum area suitable for planting the Cotton crop in Egypt (104 thousand Fadden/year; one Fadden = 0.96 hectare or 0.42 acre) showed few variations over the coming hundred years. In this case, the sowing dates should be changed from the hotter months (February to April) to the cooler months (January to February). Alternatively, a great reduction in the area planted by Wheat crop was predicted in the coming 100 years. Despite the early planting, a reduction of about 147 thousand Fadden/year was projected by the year 2075. On the other hand, with earlier sowing dates, the maximum areas that are planted by Rice and Maize may not be greatly affected by the projected increase in air temperature.     

Quantifying the sources of ozone, fine particulate matter, and regional haze in the Southeastern United States

A detailed sensitivity analysis was conducted to quantify the contributions of various emission sources to ozone (O₃), fine particulate matter (PM_2.5), and regional haze in the Southeastern United States. O₃ and particulate matter (PM) levels were estimated using the Community Multiscale Air Quality (CMAQ) modeling system and light extinction values were calculated from modeled PM concentrations. First, the base case was established using the emission projections for the year 2009. Then, in each model run, SO₂, primary carbon (PC), NH₃, NO_x or VOC emissions from a particular source category in a certain geographic area were reduced by 30% and the responses were determined by calculating the difference between the results of the reduced emission case and the base case.The sensitivity of summertime O₃ to VOC emissions is small in the Southeast and ground-level NO_x controls are generally more beneficial than elevated NO_x controls (per unit mass of emissions reduced). SO₂ emission reduction is the most beneficial control strategy in reducing summertime PM_2.5 levels and improving visibility in the Southeast and electric generating utilities are the single largest source of SO₂. Controlling PC emissions can be very effective locally, especially in winter. Reducing NH₃ emissions is an effective strategy to reduce wintertime ammonium nitrate (NO₃NH₄) levels and improve visibility; NO_x emissions reductions are not as effective. The results presented here will help the development of specific emission control strategies for future attainment of the National Ambient Air Quality Standards in the region.     

Spatial and temporal variation in nutrient parameters in stream water in a rural-urban catchment, Shikoku, Japan: effects of land cover and human impact

Seasonal and spatial variations in major ion chemistry and isotope composition in the rural-urban catchment of the Shigenobu River were monitored to determine the influences of agricultural and urban sewage systems on water quality. Temporal patterns of biochemical oxygen demand (BOD), total nitrogen (TN), total phosphorus (TP), and suspended sediment (SS) were examined at four sites in the rural-urban catchment. Urban land cover, incorporating the effects of increased population, domestic water use, and industrial wastewater, was positively associated with increases in water pollution and was included as an important explanatory variable for the variations in all water quality parameters. Significant trends were found in each parameter. BOD concentrations ranged widely, and were high in urban regions, due to the presence of a waste water treatment plant. TN and SS showed various trends, but did not vary widely, unlike TP. TP concentrations varied greatly, with high concentrations in cultivated areas, due to fertilizer use. Local water quality management or geology could further explain some of the variations in water quality. Non-point-source pollution exhibited strong positive spatial autocorrelation, indicating that incorporating spatial dimensions into water quality assessment enhances our understanding of spatial patterns of water quality. Data from the Ministry of Land Infrastructure and Transport (MLIT) and Environment Ministry (EM) were used to investigate trends in land management. Stepwise regression analysis was used to test the correlation between specific management practises and substance concentrations in surface water and sediment. MLIT and EM data for 1981-2003 showed an increase in TN, TP, and SS concentrations in surface water. High levels of fertilizer in dormant sprays and domestic water use were associated with high pesticide concentrations in water and sediment. This paper presents a novel method of studying the environmental impact of various agricultural management practises and recommends a management strategy that combines the use of reduced-risk pesticides with irrigation and non-irrigation periods in paddy fields.     

Mortality and morbidity benefits of air pollution (SO2 and PM10) absorption attributable to woodland in Britain

Forests in Britain produce social and environmental benefits, in addition to marketable timber outputs. One such non-market benefit is the reduction in air pollution, linked to health impacts (mortality and morbidity). This study assesses the benefits of SO2 and PM10 absorption by trees in terms of extending life expectancy of the population and reducing hospital admissions. Working at a resolution of 1 km2 with woodland over 2 ha, it is estimated that, for Britain as a whole, woodland saves between 5 and 7 deaths, that would otherwise have been brought forward, and between 4 and 6 hospital admissions each year. The economic value of the health effect of woodland is estimated to be at least 900,000 pounds Sterling per year. Smaller areas of woodland, often located closer to population, sometimes strategically planted close to pollution sources, will generate additional air pollution absorption benefits to those estimated here. Researching such benefits would require more detailed data than is available at present for a national study. However, the health benefits of woodland are relatively small in comparison to other non-market forestry benefits.     

Characteristics of Urban Natural Areas Influencing Winter Bird Use in Southern Ontario,Canada

Characteristics of urban natural areas and surrounding landscapes were identified that best explain winter bird use for 28 urban natural areas in southern Ontario, Canada. The research confirms for winter birds the importance of area (size) and natural vegetation, rather than managed, horticultural parkland, within urban natural areas as well as percent urban land use and natural habitat in surrounding landscapes. Alien bird density and percent ground feeding species increased with percent surrounding urban land use. Higher percent forest cover was associated with higher percentages of forest, bark feeding, small (<20 g) and insectivorous species. Natural area size (ha) was related to higher species richness, lower evenness and higher percentages of insectivorous, forest interior, area-sensitive, upper canopy, bark feeding, and non-resident species. Higher number of habitat types within natural areas and percent natural habitat in surrounding landscapes were also associated with higher species richness. Common, resident bird species dominated small areas (<6.5 ha), while less common non-residents increased with area, indicative of a nested distribution. Areas at least 6.5 ha and more generally >20 ha start to support some area-sensitive species. Areas similar to rural forests had >25% insectivores, >25% forest interior species, >25% small species, and <5% alien species. Indicator species separated urban natural areas from rural habitats and ordination placed urban natural areas along a gradient between urban development and undisturbed, rural forests. More attention is needed on issues of winter bird conservation in urban landscapes.     

Elemental contaminants in groundwater: A study of trace metals from residential area in the vicinity of an industrial area in Lagos, Nigeria

Groundwater (well water) from a residential area within the vicinity of an industrial estate in Lagos, Nigeria were sampled and analysed by Flame Atomic Absorption Spectroscopy for their heavy metals content. This was with a view of assessing the quality of the water, which was being used for domestic activities, especially, drinking usually without treatment. Total trace metal determination by mineral acid digestion of water samples was applied. This method proved to be better than an extractive concentration technique in the quality assurance protocols with the recovery range being 90.7 ± 0.006–97.6 ± 0.003%. Mean concentration of trace metals in water samples ranged from Fe: 0.05–0.47 mg l⁻¹; Al: 0.1–1.54 mg l⁻¹; Cu: 0.14–1.39 mg l⁻¹; Zn: 0.04–0.43 mg l⁻¹; Cd: trace–0.02 mg l⁻¹; Pb: trace–0.03 mg l⁻¹, Mn: 0.01–0.18 mg l⁻¹ and Ni: 0.02–0.11 mg l⁻¹. Physical parameters of water samples examined were within the drinking water safety limits except for conductivity. Results generally indicate the presence of heavy metal constituents in groundwater samples. Detection of metals such as cadmium and lead which have serious health implications above WHO and USEPA limits in drinking water gives cause for concern.