A Method for Using Air Pollution Measurements and Public Opinion to Establish Ambient Air Quality Standards

Air quality was comprehensively evaluated by means of sampling at 21 locations over metropolitan Birmingham during a period of one year. Thousands of integrated samples of three common atmospheric gaseous pollutants and two common particulate pollutants were collected and analyzed. Following the year of sampling in 1964, a random household survey was completed by conducting personal interviews at more than 7200 households over metropolitan Birmingham. Statistical reduction of household survey results by census tract and by neighborhood area provided domestic fuel and waste burning emission data as well as public (resident) opinion on specific air pollution effects. The relationship between ambient air quality and neighborhood opinion of air pollution effects on health and property are evaluated statistically. Ambient standards are suggested which are based upon those air pollution levels shown to have adverse effects on approximately one-third of the people.     

An Air Pollution Incident Due to a Stationary Front

In January 1971, the New York City area experienced a period of high pollution in which concentrations exceeded the present criteria for Stage I of the New York City Alert-Warning System. The incident was unusual because the high concentrations were associated with a weak frontal system which moved back and forth over the area and not with a stagnating anticyclone. Concentrations of pollutants were found to be closely related to the movement of the frontal system as well as to changes in wind speed and stability. Climatological criteria for identifying-periods of potential high air pollution and the criteria for mixing heights, transport wind speed and ventilation factors necessary for the issuance of an official advisory from the National Meteorological Center were not met during this incident. Therefore, some re-evaluation and redefinition of these criteria are recommended.     

Airflow Related to Denver Air Pollution

A continuous process for the disposal of halogen-containing organic residues has been developed. This process is based on the decomposition of wastes into gaseous byproducts by high temperature reactions with air and steam. The exit gases, which are essentially carbon dioxide, nitrogen, and hydrogen halides, can be scrubbed with water, thereby completely eliminating atmospheric pollution.

A unique refractory-lined recuperative heat furnace has successfully operated in this fashion to dispose of more than 20 million pounds of liquid residues (average decomposition: 60% Cl₂; 35% carbon; and the remainder oxygen, hydrogen, and others) during the last year.

This process is cheaper than most conventional disposal methods (i.e., ground burial) and offers the added advantage of complete and permanent disposal.     

Black Liquor Oxidation as a Method for Reducing Air Pollution from Sulfate Pulping

This paper will discuss the sources of odorous air pollutants from sulfate pulping operations. One of the major sources is the recovery furnace. Odors from this source can be reduced considerably by oxidation of the black liquor prior to evaporation and burning. The procedure has been used with considerable success in the northwestern and northeastern parts of the United States. Unfortunately, the majority of sulfate pulp production occurs in areas where southern pine is the basic raw material. For several reasons the black liquor resulting from southern pine operations presents problems when the usual oxidation procedures are used. Although not as effective as normal black liquor oxidation strong black liquor can be oxidized without too much difficulty. Various procedures for oxidation of black liquor will be discussed. Results of stack sampling in U. S. pulp mills with and without the oxidation unit in operation will be reported.     

Some Applications of Microscopy to Air Pollution

The microscope as it has been and is now applied to air pollution work is discussed. A summary of the most common particulate sampling equipment is presented and distinctions as to the area of usage (suspended, or settled particulates) are made in each instance. Actual cases are discussed in which the polarizing microscope was used to determine identities and source of particulate pollutants. Particles from such sources as power plants, feed mills, and combustion sources are discussed and photomicrographs of known samples and unknown particles causing complaints are presented and compared as part of the discussion. References are given which deal with sampling equipment and microscopic analysis of various particulates.     

Air Pollution Damage to Exterior Household Paints

ABSTRACT

The present study focuses on the elemental characterization of fine and coarse particles collected at a coastal site of southwestern Italy, in a suburban area of the Calabria region. A chemical tracer analysis was carried out to identify the major emission sources influencing on the atmospheric aerosol levels. Size-resolved particulate samples were collected during three 2-week seasonal sampling campaigns: autumn (19 October to 2 November 2003), winter (19 January to 2 February 2004) and spring (26 April to 10 May 2004). Ambient concentrations of selected elements (Fe, Mn, Mg, Ca, V, Cu, Cr, Ni, Zn, Pb, and Cd) associated to fine and coarse size fractions were determined using atomic absorption spectrometry (AAS). The enrichment factor method was applied, suggesting a prevailing anthropogenic component for all the detected elements, with Fe, Mg, Mn, and Ca as exceptions. Trajectory sector analysis was used in order to discriminate the influence of different air mass origins and paths. Long-range transport from both the continental Europe and the Saharan region proved to be the main influencing factors. African dust outbreaks, whose occurrence frequency was greater during the autumn and spring seasonal monitoring periods, gave rise to a total of eight exceedances of the European Commission (EC) PM₁₀ daily limit value as well as an increase in values of the crustal-derived elements (Fe, Mg, and Ca). Long-range transport from the heavily industrialized area of Central/Eastern Europe contributed to the high levels of Zn, Cd, and Pb that were recorded during the winter sampling campaign. Seasonal trend and comparison with measurements previously performed across the Mediterranean basin were also presented and discussed.

IMPLICATIONS This paper, which investigates both natural and anthropogenic aerosol sources, contributes to the characterization of fine and coarse particles in a suburban area of the southern Italian region of Calabria whose air quality assessment is still being defined. The monitoring site involved in this study, located at the interface between continental Europe and the Mediterranean basin, offers an important platform to study the influence of seasonal meteorology and predominant circulation patterns on the aerosol concentration levels and their chemical composition.     

A Cost-Benefit Approach to Air Pollution Control

Air pollution has plagued the urban areas of our Nation for many years, both as a serious health hazard and as a costly economic burden. Users of the air as a waste disposal medium have treated it as a free resource with no regard for the damages incurred by receptors of the dirty air. Unfortunately, no self-regulating market forces exist that will bring this diseconomy into an acceptable equilibrium. An outside regulating force, which can affect abatement of air pollution, is needed to achieve control of air pollution to a level acceptable to a community. A prerequisite of any proposed regulatory action to be applied by an outside force, however, is the need to define an acceptable level of pollution. One means of accomplishing the task is to apply an economic evaluation, in the form of a cost-benefit analysis, to the problem. Previous analyses of the economic aspects of air pollution have stressed only one side of the problem. That is, they have dealt only with the cost of control or the damages caused by air pollution. No analysis has combined both aspects into a meaningful analysis of the overall economic impact. The objective of this paper is to present a technique that can be used to find the level of pollution abatement in an area that balances the cost of controlling pollution with the benefits received from its control. To present a clearer picture of this technique and its results, it has been applied to the Washington, D. C. area to find the optimum level of particulate abatement. This method is generally applicable to any area, in which an air pollution problem exists.     

Progress Toward a Uniform Air Pollution Index

Recently, various authors^1–4 have indicated that a need exists to establish a uniform air pollution index for communities throughout the nation.Although the literature reveals several attempts to develop air pollution indices,^5–7 none of these indices has received widespread acceptance by state and local air pollution control agencies, probably because none has received the active support or endorsement of the federal government. We now wish to report that significant progress has been made at the federal level toward the goal of a recommended national air pollution index.     

Government Sponsored Air Pollution Research Relating to Agriculture

The absorption of hydrogen sulfide and methyl mercaptan by aqueous solutions of chlorine, sodium hydroxide, and chlorine plus sodium hydroxide was studied using a two-inch diameter absorption column packed with ¼ inch Intalox saddles. Absorption rates were noticeably affected by chemical reactions occurring in the aqueous chlorine and hydroxide media. These solutions were studied as a means of controlling sulfur-containing gas emissions from kraft paper mills. The absorption studies indicated that aqueous chlorine solutions at a pH above 12 were effective absorbents for hydrogen sulfide removal in absorption equipment designed to tolerate sulfur in suspension. The absorption of methyl mercaptan in aqueous chlorine solutions appeared to be impractical since dimethyl disulfide was apparently the only product formed and was stripped from the tower by the gas stream. Sodium hydroxide solution was an effective absorbent for both methyl mercaptan and hydrogen sulfide when hydroxide to sulfide or mercaptan feed ratios were greater than 1 or 1.8, respectively. The mercaptan absorption coefficient was approximately twice that for sulfide absorption.