A Comparison of the Size Distribution of Particulates Emitted from Air,Mechanical, and Steam Atomized Oil Fired Burners

Particulate size distributions were obtained in the effluent gases from three steam generating boilers of a power station employing mechanical, steam, and air systems for heavy fuel atomization. Samples were obtained with an eight-stage cascade impactor. The air atomized burner produced the lowest particulate loading, the greatest percentage of particulates by weight in the submicron range, and particulates with the lowest combustible content.     

Emissions and risks associated with oxyfuel combustion: State of the science and critical data gaps

Oxyfuel combustion is a promising technology that may greatly facilitate carbon capture and sequestration by increasing the relative CO₂ content of the combustion emission stream. However, the potential effect of enhanced oxygen combustion conditions on emissions of criteria and hazardous air pollutants (e.g., acid gases, particulates, metals and organics) is not well studied. It is possible that combustion under oxyfuel conditions could produce emissions posing different risks than those currently being managed by the power industry (e.g., by changing the valence state of metals). The data available for addressing these concerns are quite limited and are typically derived from laboratory-scale or pilot-scale tests. A review of the available data does suggest that oxyfuel combustion may decrease the air emissions of some pollutants (e.g., SO₂, NOx, particulates) whereas data for other pollutants are too limited to draw any conclusions. The oxy-combustion systems that have been proposed to date do not have a conventional “stack” and combustion flue gas is treated in such a way that solid or liquid waste streams are the major outputs. Use of this technology will therefore shift emissions from air to solid or liquid waste streams, but the risk management implications of this potential change have yet to be assessed. Truly useful studies of the potential effects of oxyfuel combustion on power plant emissions will require construction of integrated systems containing a combustion system coupled to a CO₂ processing unit. Sampling and analysis to assess potential emission effects should be an essential part of integrated system tests.

Implications: Oxyfuel combustion may facilitate carbon capture and sequestration by increasing the relative CO₂ content of the combustion emission stream. However, the potential effect of enhanced oxygen combustion conditions on emissions of criteria and hazardous air pollutants has not been well studied. Combustion under oxyfuel conditions could produce emissions posing different risks than those currently being managed by the power industry. Therefore, before moving further with oxyfuel combustion as a new technology, it is appropriate to summarize the current understanding of potential emissions risk and to identify data gaps as priorities for future research.     

Some Applications of Microscopy to Air Pollution

The microscope as it has been and is now applied to air pollution work is discussed. A summary of the most common particulate sampling equipment is presented and distinctions as to the area of usage (suspended, or settled particulates) are made in each instance. Actual cases are discussed in which the polarizing microscope was used to determine identities and source of particulate pollutants. Particles from such sources as power plants, feed mills, and combustion sources are discussed and photomicrographs of known samples and unknown particles causing complaints are presented and compared as part of the discussion. References are given which deal with sampling equipment and microscopic analysis of various particulates.     

Utilization of selected area electron diffraction patterns for characterization of air submicron particulate matter collected by a thermophoretic precipitator

A thermophoretic precipitator (TP) that uses a novelty of direct sampling of ambient air particulate matter (PM) onto transmission electron microscopy (TEM) grids was designed and utilized to determine its potential applicability for the collection and consequent qualitative analyses of representative PM in the air, especially those with aerodynamic diameter less than 1 microm (PM1.0). After a calibration process, preliminary field tests were performed under different weather conditions, locations, and time frames. TEM, selected area electron diffraction (SAED), and electron energy-dispersive X-ray spectrometry (EDS) analyses were performed on individual samples, and chemical species were analyzed. During this investigation, individual air PM with different sizes ranging from 10 microm to 10 nm for TEM analysis was collected. Two observations were made: (1) a large fraction of collected particulates were aggregates of very small particles of both organic and inorganic origin, and (2) a large fraction of the collected particulates were crystalline or polycrystalline. This study has demonstrated, by utilization of SAED patterns from TEM on air particles collected by a TP, the potential to analyze and identify individual air PM in a nanometer regime qualitatively by combining SAED and EDS data.     

A quantitative approach to the traffic air quality problem: the Traffic Air Quality index

The Traffic Air Quality (TAQ) model is a simple tool to estimate traffic fine particulate emissions on roadways (g/km) and can be used for both real-time analysis and for localized conformity analysis ("hot-spot" analysis for nonattainment areas) as defined by 40 CFR 93.123. This paper is a follow-up to a study published earlier regarding the development of the TAQ model. This paper shows how local air quality levels can be a factor in traffic management in nonattainment areas. Similar to the industrial source quotas measured in tons per year, it is proposed that road segments are to be assigned emission quotas (or TAQ indices) measured in pollutant mass emitted per road length (g/km) above which traffic-measures have to be taken to reduce the fine-particulates emissions on such road links. The TAQ model as well as traffic-rerouting measures along with the Intelligent Transportation System (ITS) protocols can be used to have a real-time control of the traffic conditions along expressways to maintain the fine-particulates emissions below the quota assigned per road link and consequently improving the over all local air quality in nonattainment areas.     

Flexibility of X-Ray Emission Spectrography as Adapted to Microanalysis of Air Pollutants

Methods previously published by this laboratory for analyzing thin dust coatings of airborne particulates have been further evaluated, as applied to vast air pollution surveys. It was demonstrated that choice of glass fiber filters adapted to high-volume samplers restricts the analysis to a limited number of elements, such as lead. More flexibility and versatility are attained through the use of organic membrane filters mounted in small plastic monitors which permit multi-elemental analysis at least as accurately as with other popular but time-consuming techniques. These qualities of speed and accuracy allow shorter intervals of sampling which are normally required for better statistical assessment of broad air pollution surveys. Sensitivity of the technique reaches a value close to 0.05 μg/m³, while time of analysis required is about five minutes per element after receipt of the sample.     

Receptor Oriented Methods of Air Particulate Source Apportionment

Receptor models have evolved rapidly over the past 13 years but have just recently been recognized as a distinct discipline. The general category of receptor models includes both microscopic and chemical methods of apportioning source contributions to ambient air particulates. The number and variations of these methods have grown rapidly over the past few years and include such methods as automated scanning electron microscopy, chemical mass balance and multivariate procedures. These methods as well as hybrid procedures such as target transformation factor analysis, are reviewed and their boundary conditions, strengths, and weaknesses discussed.     

Pollutant Removal from Wood and Coal Flue Gases by Soil Treatment

If many homeowners convert to solid fuels for heating, residential flue gases will be a large source of air pollution. Control of this pollution requires an inexpensive, reliable, and effective method of flue gas treatment. One such method is to force flue gases through soil beds. Such soil treatment removes all detectable smoke, odor, and polynuclear organic matter (POM), up to 97% of the CO, and at least 97% of the SO₂ from flue gases of wood and coal combustion. The technique is low cost, reliable, almost maintenance-free, and also appears suitable for other small point sources of air pollution.     

On the Determination of Odor Thresholds in Air Pollution Control—An Experimental Field Study on Flue Gases from Sulfate Cellulose Plants

From the hygienic point of view, not only the health hazards caused by air pollutants but also the odor from emitted flue gases should be reduced to a minimum. An effective control of the risk of odor at ground level presupposes knowledge of the source concentration of the odoriferous gas as well as its odor threshold. This threshold has to be estimated empirically, as the flue gases often contain a complex mixture of different odoriferous substances, the odor thresholds of which are in most cases unknown. For this purpose a method has been developed for estimating the odor thresholds of flue gases emitted, from different industrial processes. The method, afield method, is based on an exposure procedure, a number of subjects compare different concentrations of the flue gas with samples of fresh air and decide at what concentration the flue gas is no longer noticeable. The gas samples used are neither compressed, nor absorbed or heated before the exposure test. The method has been used in two studies on gases from Swedish sulfate cellulose plants. In order to estimate the effect on the odor threshold of different deodorizing measures, gas samples were taken not only from the stack but also from different phases in the production process. The results and a brief discussion on the practical applications of the method are given.     

A System for Control of Aluminum Chloride Fumes

During primary aluminum processing the molten aluminum is periodically fluxed with chlorine to separate impurities from the metal. The gaseous effluent from the chlorination process contains submicron particulates and gaseous vapors which produce a dense, white plume. The plume is acidic with hydrogen chloride and chlorine vapors, which cause a variety of corrosion problems. Since the stack discharge temperature can range as low as 200°F-and aluminum chloride sublimates at about 360°F, blockage of ductwork can also occur. For effective removal of both the particulates and chloride gases in the effluent, a sodium hydroxide solution is recommended. However, such a scrubbing liquor produces a flocculent precipitate. Therefore, a nonplugging type of scrubber is required. The solution UOP advanced was a “mobile packing” type of scrubber, utilizing a bed of polypropylene spheres in random, turbulent motion. The motion of the packing prevents plugging. The paper describes the design for such a system, describing the optimum use of ductwork, scrubber placement, gas saturation, and recirculation equipment. Instrumentation requirements, both minimum and optimum are discussed.     

A method of assessing air toxics concentrations in urban areas using mobile platform measurements

The objective of this paper is to demonstrate an approach to characterize the spatial variability in ambient air concentrations using mobile platform measurements. This approach may be useful for air toxics assessments in Environmental Justice applications, epidemiological studies, and environmental health risk assessments. In this study, we developed and applied a method to characterize air toxics concentrations in urban areas using results of the recently conducted field study in Wilmington, DE. Mobile measurements were collected over a 4- x 4-km area of downtown Wilmington for three components: formaldehyde (representative of volatile organic compounds and also photochemically reactive pollutants), aerosol size distribution (representing fine particulate matter), and water-soluble hexavalent chromium (representative of toxic metals). These measurements were,used to construct spatial and temporal distributions of air toxics in the area that show a very strong temporal variability, both diurnally and seasonally. An analysis of spatial variability indicates that all pollutants varied significantly by location, which suggests potential impact of local sources. From the comparison with measurements at the central monitoring site, we conclude that formaldehyde and fine particulates show a positive correlation with temperature, which could also be the reason that photochemically generated formaldehyde and fine particulates over the study area correlate well with the fine particulate matter measured at the central site.     

A case study for wintertime observation of atmospheric particulates by an eye-safe laser radar

Atmospheric particulates were monitored on a typical high concentration day in early winter in Osaka, Japan, using a compact and portable eye-safe laser radar system. The height of mixing layer was about 0.4 km at 8:00 and gradually increased to 0.8 km at 14:00. The development of the layer was in inverse proportion to the decrease of particulates near the ground surface. Analysis of particulates collected with high-volume air samplers showed that concentrations of elemental carbon (EC), lead and ammonium ion near the surface decreased significantly from morning to midday, while concentrations of sulfate, nitrate, sodium and calcium ions were almost constant. The results obtained in the preliminary study suggest that anthropogenic particulates such as EC and lead are on the rise with development of mixing layer from morning to midday.     

Characterization of Airborne Dust from Two Nonferrous Foundries by Physico-chemical Methods and Multivariate Statistical Analyses

Abstract

Airborne particulate matter was sampled at a copper smelter and at an aluminum casting plant. Size, shape, quantity, and microlocalization of chemical species in the particulates were measured using closed cassettes, cascade impactors, scanning electron microscopy, X-ray diffraction, infrared and atomic absorption spectrophotometries, secondary ion mass spectrometry, and photoelectron spectroscopy. Cluster and principal components analyses were used in interpreting results. Aerosol chemistry varies as a function of size, and composition becomes more complex as the aerosol size drops into the respirable fraction and lower. Surface chemical properties are evidenced where, generally, volatile species are enriched. A few site-specific elements and characteristics were identified. The formation of particulates may often be related to process and practices, yet the actual distribution of species in the air remains an intricate matter.     

Development of Instrumentation for Continuous On-line Monitoring of Non-Methane Organic Carbon in Air Emissions

ABSTRACT

Non-methane organic carbon (NMOC) is a measure of total organic carbon in an air emission, excluding that from methane. Thus, it measures the total amount of carbon, irrespective of the structure and functional groups in the molecule. The U.S. Environmental Protection Agency (EPA) Method 25 is used for quantification of NMOC in emission sources and in ambient air. This method involves laboratory analysis of collected air samples and cannot be used for real-time measurements. It is prone to interferences from CO₂, CH₄, and CO, as well as moisture. In this paper, a novel method for continuous, on-line monitoring of NMOC in air emissions and ambient air is presented. Detection limits are at ppb levels, and interference of permanent gases have been eliminated.     

Sizing of atmospheric particulates with a high volume cascade impactor

This article describes the development of a high volume cascade impactor with a sampling rate of 20 ft³/min that can be powered by high volume blowers in common use for air sampling. With this impactor it is now possible to collect enough sample of atmospheric particulates in a 24 hour period to conveniently determine an aerodynamic size distribution of suspended particulates by gravimetric analysis. The impactor has four stages and an after-filter and separates particles from the air stream by inertial impaction. The effective cutoff diameters for the stages are 7.0, 3.3, 2.0, and 1.1 microns. The after-filter traps the submicron material.     

Measurement of Indoor Air Emissions from Dry-Process Photocopy Machines

Abstract

Presently, no standard test method exists to evaluate the various emissions from office equipment (e.g., ozone, volatile organic compounds, inorganic gases, and particulates) so it is difficult to compare data from different studies.1 As a result, the authors are developing a standardized guidance document for measuring indoor air emissions from office equipment. The ultimate goal is to apply the test method to better understand emissions from office equipment and to develop lower emitting machines. This paper provides background information on indoor air emissions from office equipment with an emphasis on dry-process photocopy machines. The test method is described in detail, along with the results of a study to evaluate the test method using four dry-process photocopy machines.

The results from this study indicate that the test method provides acceptable performance for characterizing emissions; that it can adequately identify differences in emissions between machines both in compounds emitted and their emission rates; and that it is capable of measuring both intra- and inter-machine variability in emissions. Challenges and complications were encountered in developing and implementing the test method. These included heat generation, which can cause large increases in chamber temperature; finite paper supplies for photocopy machines, which limit test duration; varying power requirements that may require changes in chamber electrical supply; and remote starting of the machines, which is necessary to maintain chamber integrity.

Results show that dry-process photocopy machines can produce emissions of ozone and volatile organic compounds that can potentially have a significant impact on indoor air quality. For the four machines tested in this study, the compounds with the highest emission rates overall were ethylbenzene (28,000 µg/hour), m,p-xylenes (29,000 µg/hour), o-xylene (17,000 µg/hour), 2-ethyl-lhexanol (14,000 µg/hour), and styrene (12,000 fig/hour). Although many of the same compounds tended to be detected in emissions from each of the four photocopiers, the relative contribution of individual compounds varied considerably between machines, with differences greater than an order of magnitude for some compounds.     

灰霾天气与大气颗粒物的相关性研究综述

随着城市化进程的迅速发展,城市大气污染加剧,灰霾天气也随之增多。综述了灰霾天气期间大气颗粒物在时空分布和污染水平2方面的污染特征,分析了大气颗粒物与能见度相关性,介绍了国内外对灰霾天气期间大气污染物的组成及源解析方面的研究进展,并提出了今后灰霾天气的研究方向。     

Congener profiles of PCB and a proposed new set of indicator congeners

In this study, a new method for calculating total PCB and toxic equivalents (TEQ) of coplanar PCB (Co-PCB) was proposed, called the 'PCB dual method'. This method analysed various kinds of technical PCB, samples contaminated by technical PCB and byproduct PCB. In the PCB dual method, a data set of 15 indicator congeners was utilized for the calculations, having IUPAC nos. #3, #8, #28, #52, #77, #101, #105, #118, #126, #138, #153, #180, #194, #206 and #209. The 15 congener set was chosen from the major congeners, determined by HRGC/HRMS analysis, in 18 technical PCB, Kanechlor, Aroclor, Clophen and Chlorofen, and 20 other samples, such as indoor air, flue gases, emission gases, municipal solid waste (MSW), ash and sealant. To obtain total PCB and TEQ of Co-PCB, the intermediate sum for the concentration of the 15 congeners was multiplied by each multiplication factor. As a result, we obtained the average factor used to calculate total PCB in technical PCB and other samples. For technical PCB, the factor was 3.01, while for indoor air samples, flue and emission gases, MSW, ash and sealants, the factors were 3.92, 4.16, 3.68, 4.52 and 4.77, respectively. Moreover, the factor used to calculate the TEQ of Co-PCB in Kanechlor and other source samples were also obtained. The factors for Kanechlor, indoor air samples and emission gases from a cement plant were in the order of 10(-5), while the factor for flue gases in a MSW incinerator was in the order of 10(-3). These data were valuable for the rough estimation of the TEQ of Co-PCB without separation from other PCB before individual measurements.     

Significant Relationships Concerning Exponential Transmission or Penetration

This paper reviews the statistical evidence linking human mortality with air pollution due to sulfur oxides and particulates. Three types of analyses are discussed: episodic increases in mortality coincident with high pollution, perturbations in mortality in a given city as a time-series in relation to perturbations in air quality, and comparisons of geographic differentials in both pollution and mortality rates. The paper concludes that there are no reliable statistical associations between SO _x and mortality, but that particulates are in some cases associated with excess mortality. Establishing whether the association is in fact causal would require elimination of potential confounding effects such as occupational exposures.     

Standard Reference Gases and Analytical Procedures for Use in Gas Turbine Exhaust Measurements

This paper is directed to people who are involved in the measurement of gas turbine exhaust emissions and as a consequence in the establishment of standard reference gases and attendant analytical procedures.

Several problems exist in connection with the establishment of these standards:

A number of standard reference gases have been developed by the National Bureau of Standards for use in the automotive industry which are also suitable for gas turbine exhaust measurements. However, there is a need for additional standard reference materials such as NO in nitrogen, intermediate levels of CO₂ in air, and higher concentrations of CO in nitrogen and propane in air.

There is difficulty in maintaining certain reference materials with confidence in assay, particularly due to instability in the cylinder.

Instrumental operational problems with flame ionization detector type units exist. Of particular importance is the difference in response per carbon atom in different organic molecules and the difference in response of a test sample as a function of the oxygen content of the sample.

Instrumental method problems such as converter efficiency in chemiluminescence units measuring NO₂ and calibration techniques involving CO to CH₄ conversion, also must be considered.

A number of problems occur in the use of wet chemical reference methods such as the phenoldisulfonic acid method for the determination of NO_x. These include both efficiency of collection, conversion of NO to NO₂, and subsequent analysis.

This paper considers the development of standards for the measurement of NO_x, CO, CO₂, total hydrocarbons, and O₂ and reviews the state-of-the-art with respect to these problems and their resolution.