Mobile Air Quality Monitoring Systems: Present Problems and Future Needs

This overview represents much of the discussion and summarizes many of the concerns emerging from the recent APCA Specialty Conference, “In-Situ Air Quality Monitoring from Moving Platforms.”

Users of mobile air quality monitoring systems have been hampered in their attempts to generate dependable data because of a lack of suitable instrumentation. Most equipment used in mobile systems was designed for laboratory or stationary monitoring applications and cannot cope well with the harsh environment encountered in aircraft or other mobile platforms. Only through innovative modifications have investigators been able to utilize off-the-shelf equipment. The technology exists, however, for manufacturers to build a much higher quality product if only a market incentive could be created.

This paper outlines problem areas which need to be addressed in the production of reliable “mobile quality” instrumentation, and suggests some market incentives.     

Graphic Arts Technical Foundation Holds First Air Quality Control Conference

On November 18–19, 1970, the Environmental Control Division of the Graphic Arts Technical Foundation, Pittsburgh, Pa., and its Air Pollution Control Advisory Committee held a Conference on “Air Quality Control in the Printing Industry.” This first nation-wide meeting at the Chicago-Sheraton brought together management and production people from the various printing processes, regulatory officials from all levels of government, control equipment manufacturers, consultants, and ink and solvent suppliers.

In due course, the Foundation will publish the proceedings of the Conference; however, because of the intense interest expressed by the audience, the Environmental Control Division has prepared this summary until the proceedings are published.     

The United Nations Conference on the Human Environment Its Implications for Air Pollution Prevention Associations

In today's world of misunderstanding, confusion, and conflict man is sadly in need of some force for pulling together and unifying his efforts for peace, progress, safety, and health upon his native Planet. During the latter days of the Conference, when delegates from large nations and small nations and rich nations and poor nations were working tirelessly to reach agreement on a Declaration on the Human Environment, and during the closing hours of the Conference when the Declaration was approved by unanimous vote, it appeared to many persons that the environment might well be such a unifying force for mankind. Throughout the early days of the Stockholm sessions, the conflict of ideologies and political Dr. Barthel is the Director of the Institute of Environmental Sciences, Miami University, Oxford, Ohio 45056. He attended the Stockholm Conference as an accredited representative of the International Union of Air Pollution Associations. principles and severe disagreement on specific issues relating to the environment were all too apparent, but through pertinacity and splendid Conference leadership, differences were resolved and wide-scale agreements reached.     

Modeling Analyses of the Effects of Changes in Nitrogen Oxides Emissions from the Electric Power Sector on Ozone Levels in the Eastern United States

Abstract

In this paper, we examine the changes in ambient ozone concentrations simulated by the Community Multiscale Air Quality (CMAQ) model for summer 2002 under three different nitrogen oxides (NO_x) emission scenarios. Two emission scenarios represent best estimates of 2002 and 2004 emissions; they allow assessment of the impact of the NO_x emissions reductions imposed on the utility sector by the NO_x State Implementation Plan (SIP) Call. The third scenario represents a hypothetical rendering of what NO_x emissions would have been in 2002 if no emission controls had been imposed on the utility sector. Examination of the modeled median and 95th percentile daily maximum 8-hr average ozone concentrations reveals that median ozone levels estimated for the 2004 emission scenario were less than those modeled for 2002 in the region most affected by the NO_x SIP Call. Comparison of the “no-control” with the “2002” scenario revealed that ozone concentrations would have been much higher in much of the eastern United States if the utility sector had not implemented NO_x emission controls; exceptions occurred in the immediate vicinity of major point sources where increased NO titration tends to lower ozone levels.     

Report from the Symposium on Air Quality Criteria

Neither time nor space permitted full reporting of the Symposium on Air Quality Criteria, held June 4-5, 1968, in New York City. The Symposium was sponsored by the Air Pollution Control Association, the American Industrial Hygiene Association, the American Petroleum Institute, and the Industrial Medical Association and its educational affiliate, The Occupational Health Institute.

Published here are excerpts from, or author’s abstracts of, the eight principal papers presented at the Symposium.

Not included are the prepared discussions which followed the delivery of the papers.

A full proceedings, including prepared discussions, general discussions, and summation, will be published in the September issue of the Journal of Occupational Medicine, 55 E. Washington Street, Chicago, Illinois 60602.     

Notes From The National Air Quality Conference

The National Air Quality Conference, which was held during January 14-16 in San Francisco, promised to “provide decision-makers in government, business, and labor with information on the possible economic and employment impacts of the federal Clean Air Act along with strategies for change.” The meeting appeared to be important from the standpoint of who was speaking, who was attending, and who was reacting. JAPCA asked Francis J. O’Donnell, editor of Air/Water Pollution Report, to provide this special report.     

ESP Performance Capability and Utilization: Past and Future

The following paper was presented by Alan B. Walker at the International Conference on Electrostatic Precipitation held in Monterey, California, October 14–16, 1981. Mr. Walker’s candid remarks were part of the opening session on “Electrostatic Precipitation Today.” The proceedings of this outstanding conference will be published by the Air Pollution Control Association.     

“The Clean Air Act — A Time for Evaluation”

The Third Government Affairs Seminar sponsored by the Air Pollution Control Association was held in Washington, D. C. on April 16-17, 1975. The APCA South Atlantic Section was host for this very successful meeting. The General Chairman of the Seminar Committee was John V. Brink and the Program Chairman was Richard D. Grundy.

The seminar this year was conducted in three sessions. The first session, entitled “The Clean Air Act: State vs Federal Roles,” considered a topic that is receiving increasing emphasis as the national air pollution control program matures. This discussion was chaired by M. Barry Meyer, Chief Counsel and Chief Clerk, Senate Committee on Public Works.

The second session was “Land Use Planning Aspects of the Clean Air Act—Federal, State and Regional Roles.” Mrs. Mary Jane Due, Chairman of the Public Land and Land Use Committee, Natural Resources Section, American Bar Association, served as Moderator of this discussion of indirect source regulations, no significant deterioration, air quality maintenance—concepts that rely heavily on comprehensive land use planning.

“Clean Air Priorities—The Need for Flexibility,” was the title of the third session which was chaired by Austin H. Phelps, Manager Corporate Air Pollution Control, Procter and Gamble Company and President of APCA. The panelists considered the question of how appropriate the standard setting mechanisms of the Clean Air Act are for the resolution of present and future problems.

In this report condensed versions of the prepared statements of the participants are presented. A more extensive summary of the Proceedings, which includes questions and answers, is available from APCA headquarters. The remarks of John R. Quarles, EPA Deputy Administrator, who was the luncheon speaker, were summarized in the June APCA Journal(p. 642).     

Air Pollution Control and Public Apathy

The importance of public involvement in programs of air pollution control has been stressed by a number of writers in the field, most recently by Sterner in his comments to the Third National Conference on Air Pollution.¹ As he points out, public apathy appears to be a critical barrier in the development and implementation of effective control programs. Along the same line, Dixon and Lodge, in a digest of the report of the AAAS Air Conservation Committee, state that, “The best program in the world can fail in the face of opposition or apathy on the part of the public.”² It is the purpose of this paper to take a more analytical look at this problem, particularly in the light of recent data from an opinion survey in West Virginia. If such apathy exists, effective countermeasures require that we examine it more fully and understand its sources. Collective handwringing will do little to meet the problem.     

United States Seen 2.54 Centimeter-ing Its Way to Metric System

On May 3, 1971, the Engineers Joint Council sponsored a panel on metrication at its offices in New York City. Bryce MacDonald of EJC was chairman; he had been instructed to invite representatives of various societies. Its purpose was to “present to the Board of EJC a summation of the situation regarding plans for conversion to the metric system.” The EJC Board will later come to a decision whether it will assume a more active role.

George Arnold of Southern Illinois University, Edwardsville, was named to represent the Air Pollution Control Association on the panel because of his long-standing membership in the Metric Association and his efforts toward exclusive use of international units for pollution measurement.

Twenty-two societies were represented. These included ASME, ASTM, SNAME, ASQC, ASHRAE, ISA, ASEE, ASCE, and ESNE. Among those present was Gregory Schultz of the Material Management Society, who is prominent with the American National Standards Institute and the International Standards Organization. Of the societies present, only six have a firm policy in favor of the metric system. The others are cautiously in favor, or using dual units, or waiting to see what Congress will do about the 1971 Department of Commerce Metric Study Report.     

Regional Photochemical Measurement and Modeling Studies: A Summary of the Air & Waste Management Association International Specialty Conference

Abstract

This paper summarizes the Air & Waste Management Association’s International Specialty Conference, "Regional Photochemical Measurement and Modeling Studies," held in San Diego, California, on November 8-12,1993. The purpose of the conference was to facilitate exchange of information and to initiate better communication and interaction among scientists, air quality managers, regulators, and others involved in or applying tools (models and measurements to support the modeling efforts) that can be used to develop equitable and effective emissions management practices for attainment of ozone standards. Attendees heard more than 350 presentations from authors representing nearly 30 air quality and meteorological measurement and modeling studies from 18 countries. While the primary emphasis of the conference was technical, two policy sessions were included (Plenary and Concluding Sessions) to place the technical results in perspective with the policy issues. The technical agenda was divided into three subjects: Analysis of Field Measurements (results and interpretation), Modeling (status and results), and Other Topics. Papers presented at the conference are being published in a variety of journals or books to meet the needs of the scientific and policy communities. A complete bibliographical listing of the papers presented at the conference is included with this paper.

An unexpected outcome of the conference has been the development of an initiative for continuing the intercomparison of goals and scientific findings from regional air quality studies in Europe and North America, entitled “Regional Oxidants Programs Intercomparison” (ROxPIn). This paper will also discuss the goals and objectives of ROxPIn.     

Consultant Guide/1979

The Journal of the Air Pollution Control Association presents its tenth directory of air pollution control consultants. This 17-page guide lists individual consultants and firms who have indicated a capability in this field by responding to a questionnaire published in the Journal.

Areas of competence are shown as categories within five geographical regions. Two new areas of competence, Monitoring and Modeling, have been added to the program for Consultant Guide/1979. Any certifications granted by the American Academy of Environmental Engineers (AAEE), American Board of Industrial Hygiene (ABIH) and the Board for Certified Consulting Meteorologists (BCCM) are shown adjacent to the phone number in the alphabetical listing.

The Air Pollution Control Association makes no representation regarding the competence of the consultants listed nor does it accept any responsibility for their performance as consultants.     

Reflecting on progress since the 2005 NARSTO emissions inventory report

Emission inventories are the foundation for cost-effective air quality management activities. In 2005, a report by the public/private partnership North American Research Strategy for Tropospheric Ozone (NARSTO) evaluated the strengths and weaknesses of North American emissions inventories and made recommendations for improving their effectiveness. This paper reviews the recommendation areas and briefly discusses what has been addressed, what remains unchanged, and new questions that have arisen. The findings reveal that all emissions inventory improvement areas identified by the 2005 NARSTO publication have been explored and implemented to some degree. The U.S. National Emissions Inventory has become more detailed and has incorporated new research into previously under-characterized sources such as fine particles and biomass burning. Additionally, it is now easier to access the emissions inventory and the documentation of the inventory via the internet. However, many emissions-related research needs exist, on topics such as emission estimation methods, speciation, scalable emission factor development, incorporation of new emission measurement techniques, estimation of uncertainty, top-down verification, and analysis of uncharacterized sources. A common theme throughout this retrospective summary is the need for increased coordination among stakeholders. Researchers and inventory developers must work together to ensure that planned emissions research and new findings can be used to update the emissions inventory. To continue to address emissions inventory challenges, industry, the scientific community, and government agencies need to continue to leverage resources and collaborate as often as possible. As evidenced by the progress noted, continued investment in and coordination of emissions inventory activities will provide dividends to air quality management programs across the country, continent, and world.

Implications: In 2005, a report by the public/private partnership North American Research Strategy for Tropospheric Ozone (NARSTO) evaluated the strengths and weaknesses of North American air pollution emissions inventories. This paper reviews the eight recommendation areas and briefly discusses what has been addressed, what remains unchanged, and new questions that have arisen. Although progress has been made, many opportunities exist for the scientific agencies, industry, and government agencies to leverage resources and collaborate to continue improving emissions inventories.     

Detection Limits for Hazardous and Radioactive Elements in Airborne Aerosols Using Inductively Coupled Air Plasma – Atomic Emission Spectrometry

Abstract

This research presents investigations into the use of inductively coupled air plasma – atomic emission spectrometry (air-plasma ICPAES) to determine the presence of inorganic contaminants in airborne aerosols. Limits of detection (LOD) in the ppm to ppb range for 19 hazardous metals and radionuclides were determined for aerosols of solutions nebulized into the air plasma. For many elements, the determined LOD surpass the threshold limit values established by the American Conference of Governmental Industrial Hygienists by one to three orders of magnitude. The potential of air-plasma ICPAES for continuous on-line monitoring of airborne contaminants is discussed.     

developing a practical dispersion model for an air quality region

A series of computer models have been developed to predict air quality in the New York/New Jersey/Connecticut Air Quality Region. Efforts have been directed at models which have a shorter time scale than climatological models, and which are capable of providing better recommendations for effective abatement and planning, but use input data presently available.

The basic dispersion model for these investigations is a steady-state,nondivergent Gaussian-type model. A modified inventory of SO₂ sources,based on published data for the New York/New Jersey/Connecticut Air Quality Region, was prepared for use with the model. The basic model has been subjected to various internal sensitivity analyses, in which was isolated the variation produced in the pollutant concentration by a given change in each of the factors that contribute, e.g., wind speed, wind direction,mixing depth, stability conditions, source strengths, and grid size for the area sources.

To date, validation tests of the model have been made against the July and August 1969 data for the ten telemetering stations of the New York City Aerometric Network. Hourly as well as averaged concentrations were considered. Various sets of meteorological data from the network stations and the three area airports, were compared and tested. Additional tests, particularly for the winter season, are needed to substantiate the preliminary conclusions suggested by the results to date.

Considerable insight into the relative importance of model components has been acquired from the sensitivity studies. Furthermore the validation results lend support to the belief that a reasonably simple, practical dispersion model can be developed for the region.     

An Operational Assessment of the Application of the Relative Reduction Factors in the Demonstration of Attainment of the 8-Hr Ozone National Ambient Air Quality Standard

Abstract

The U.S. Environmental Protection Agency in 1997 revised the 1-hr ozone (O₃) National Ambient Air Quality Standard (NAAQS) to one based on an 8-hr average, resulting in potential nonattainment status for substantial portions of the eastern United States. The regulatory process provides for the development of a state implementation plan that includes a demonstration that the projected future O₃ concentrations will be at or below the NAAQS based on photochemical modeling and analytical techniques.

In this study, four photochemical modeling systems, based on two photochemical models, Community Model for Air Quality and the Comprehensive Air Quality Model with extensions, and two emissions processing models, Sparse Matrix Optimization Kernel for Emissions and Emissions Modeling System, were applied to the eastern United States, with emphasis on the northeastern Ozone Transport Region in terms of their response to oxides of nitrogen and volatile organic carbon-focused controls on the estimated design values. With the 8-hr O₃ NAAQS set as a bright-line test, it was found that a given area could be termed as being in or out of attainment of the NAAQS depending upon the modeling system. This suggests the need to provide an estimate of model-to-model uncertainty in the relative reduction factor (RRF) for a better understanding of the uncertainty in projecting the status of an area's attainment. Results indicate that the model-to-model differences considered in this study introduce an uncertainty of the future estimated design value of ～3–5 ppb.     

Introduction to the Air & Waste Management Association's 30th Annual Critical Review

This marks the 30th year of the Air & Waste Management Association's Critical Review Program. The Critical Review is a feature of A&WMA's Annual Conference, and is directed by the Critical Review Committee. The committee evaluates several topics each year, selects the best for presentation, and invites an individual (or group) to prepare the Critical Review Paper. This paper is thoroughly reviewed by the committee members and a panel of experts. After presentation of the review by the authors (typically on the Wednesday of the Annual Conference), there is a panel discussion and question-and-answer session. Panel members are invited to prepare their comments on the Critical Review, which, along with audience comments and the author's closing statements, are published in the Journal.     

Environmental Protection Agency Announces 1971–72 Chronological Schedule of Training Courses

Following are the chronological dates of course offerings of the Institute for Air Pollution Training, Office of Manpower Development, Environmental Protection Agency.

Courses are offered this Fiscal Year at nine regional centers as well as at the Institute headquarters at Research Triangle Park, North Carolina.

In addition to regular advanced courses offered each year, a three-weeks basic course “Principles and Practice of Air Pollution Control,” Course #452, will be offered nine times each year.     

Epidemiological Bases for Possible Air Quality Criteria for Carbon Monoxide

Exposures to adequate environmental levels of CO will increase COHb concentrations in human subjects. The amount of this increase is reasonably predictable, and must be considered in relation to exposure to CO in inhaled cigarette smoke as well as to occupational and domestic exposures. The increase in body COHb will result in some degree of impairment of tissue oxygenation.

Methods for estimating COHb levels in large populations are relatively simple. The assumption that an exposure to 30 ppm CO for eight hours will produce on the average, an increase in COHb of 5%, has been substantiated by available data.

Exposure for five hours to between 10 and 12 ppm of CO has been shown to increase the COHb levels in nonsmokers by at least 0.5%. Such an increase adds appreciably to the body burden of COHb in those who do not already have such a body burden from cigarette smoking. Longer exposures could have produced a somewhat greater increase.

Apart from increases in COHb, three possible effects have been a source of major consideration in epidemiologic studies. The first is the production of some persistent toxic reaction. This possibility has been examined with respect to occupational exposure, and the evidence for the occurrence of such a condition is insufficient.

The possible contribution of ambient community CO exposure to the mortality of persons hospitalized with myocardial infarction has been investigated. The evidence suggests that daily average CO values in excess of about 10 ppm may be associated with an increase in mortality in hospitalized patients with myocardial infarction. Substantiation of this impression will require a study of the prognosis of myocardial infarction patients in relationship to COHb levels measured at admission to the hospital.

Finally, in two studies, persons driving motor vehicles which were involved in accidents had higher COHb levels than "control" populations. Controls were not ideal, however. Possible mechanisms by which CO might affect the ability to drive a motor vehicle is suggested in the available data on CO effects upon visual sensitivity, psychological test performance and accurate estimation of time intervals. As little as 2 percent COHb can produce these effects in laboratory studies, and the available epidemiologic information confirms that such an increase in COHb levels among drivers might influence the frequency of accidents.

Specific areas where research is indicated to clarify uncertainties relating to health effects of CO are: 1. The increment in COHb which can be produced by exposures to an average of 20 ppm CO for an eight hour period and the increment which can be produced by 15 ppm for such a period and by 10 ppm for up to twenty-four hours.

2. The relationship of ambient CO levels and of COHb levels to the survival of hospitalized patients with myocardial infarction.

3. The prognostic significance with respect to cardiovascular conditions of elevated levels of COHb.

4. The relationship, if any, between ambient CO and COHb levels and the occurrence of motor vehicle accidents when weather and driving conditions, cigarette smoking, alcohol and drug use, and other factors are adjusted and controlled.

     

A System for Abatement Control Strategy Evaluation

The Air Quality Control Program of the Commonwealth of Massachusetts has developed an implementation plan for the Metropolitan Boston Intrastate Air Quality Control Region as required by PL 90-148. An essential part of the plan was a set of control regulations designed to achieve and maintain an air quality compatible with adopted standards. Control strategy modeling was used as a tool in selecting the most appropriate regulations to achieve this goal. The body of information presented in this paper is directed to those state and county air pollution control officials concerned with the formulation and evaluation of regulations.

The paper details the procedures developed and presents a case history of their use in the region. The system is a synthesis of generally-available software and newly-developed computer programs to provide ahighly automated computational structure. It permits rapid simulation of the emissions resulting from the application of various control regulations. Predictions on the changes expected in ambient air quality levels are then made by the use of the Air Quality Display Model (AQDM).

The initial step in the application was a calibration of the system using predicted and measured annual concentrations. This step yielded correlation coefficients of 0.92 for sulfur dioxide and 0.85 for particulates. Subsequently, the system was used to evaluate the baseline case of uncontrolled sulfur in fuel use. Alternative sulfur control strategies were tested for compatibility with air quality standards. The principal strategies tested were: (a) 1% sulfur uniformly throughout the region; (6) 1% sulfur in core area of region, 2.2% sulfur elsewhere; (c) 0.5% sulfur in core area of region, 2.2% sulfur elsewhere; (d) 0.5% sulfur in core area of region, 1.0% sulfur elsewhere.

Strategies (b) and (d) were implemented into a time phased set of control regulations for the region.

Experience with the system has shown it to be a convenient and rapid method for simulating the effects of control regulations. Furthermore, the utility of this initial model warrants expansion of its application to the other air quality control regions in the Commonwealth.