Fine Particle Control Using Sulfur Oxide Scrubbers

Compliance with sulfur oxides standards will in many cases result in the installation of scrubbing devices. If these devices operate on an effluent gas stream containing particulate as well as sulfur oxides, simultaneous removal would be expected. Since effective simultaneous removal of particulate matter and sulfur oxides is economically desirable, it is of considerable import to characterize scrubber designs being considered as sulfur oxide absorbers as particulate control devices; especially, for fine particulate control.

Data on the fine particle collection efficiency of sulfur oxides scrubbers at two power generating stations is presented. At the first, a venturi and a turbulent contacting absorber (TCA) both with capacities of 30,000 cfm were tested. At the second, a venturi with 600,000 scfm capacity was tested. Fine particle collection efficiency was determined at three pressure drops for the TCA using a cascade impactor. Results for the TCA show high removal efficiencies. It collected more than 90% of submicron particles when the pressure drop was nearly 10 in. H₂0. The overall particulate removal in the TCA scrubber as determined by modified method 5 or by Brink impactor was greater than 99% when the pressure drop was greater than 6 in. H₂0. For both the venturi scrubber at the Shawnee Steam Plant and that at the Mystic Power Station, the collection efficiency decreased rapidly with decreasing particle size in the fine particle region.     

Wetting properties and performance test of modified rigid collector in wet electrostatic precipitators

The fine particles are considered a significant pollution problem. The wet electrostatic precipitators (ESPs) have advantages of efficient collection of the fine particles with lower pressure drop and eliminating reentrainment. The wetting properties of the collector surfaces have significantly important effect on wet ESPs’ stable and secure operation. The modified rigid collector (MRC) was modified by coating specific vinyl ester resin composites and loose glass fiber cloth over the conventional carbon steel in a certain way. The rigid collector surfaces before and after modification had been characterized by scanning electron microscopy (SEM) and interface tensiometer. The effect of operating temperatures on the wetting properties of the rigid collector surfaces before and after modification was investigated. The temperature range was 40~90 °C, and the wetting properties contained liquid holdup, surface flow rate, film rate, average film thickness, and critical saturation time. The modified rigid collector surface exhibited excellent wetting properties at the operating temperatures. The fine particles collection performance compared among the MRC, the conventional rigid collector (CRC), and the flexible collector (FC) in the wet ESPs was investigated. The effects of the applied voltage, the water film, corona power, and the specific collecting area on the fine particles collection were evaluated. The modified rigid collector provided high fine particles collection effect with lower energy and water consumption.

Implications: To improve the submicron particles collection efficiency and decrease energy and water consumption, the formation of uniform water film over the collector surfaces has been widely studied. The modified rigid collector was modified by coating specific vinyl ester resin composites and loose glass fiber cloth (ERGF) over the conventional carbon steel (CCS) in a certain way. The modified rigid collector surface exhibited excellent wetting properties. The wet ESPs by the modified rigid collector exhibited significantly higher particles collection efficiency than by the conventional rigid collector.     

Gas Cleaning in a Wetted Butterfly Valve

An attempt was made to demonslrate the utility of a wetted butterfly valve for cleaning flue gases from industrial wastes. Butterfly valves are extensively in use to control the gas pressures in various processes. A small pilot plant with a maximum airflow rate of 400 cfm and water flow rate of 4 gpm was constructed to provide the desired testing conditions. The results indicate that for a pressure drop greater than 30 in. water a collection efficiency of greater than 95% for submicron particles can be obtained. For particles larger than 1.7;u diameter efficiencies of greater than 99% were obtained. The exceptional suitability of wet butterfly valves for gas cleaning is demonstrated by the flexibility to adjust to large variations of gas and liquid flow rates.     

旋风除尘器流场及浓度场实验与模拟

在研究旋风除尘器内气固两相的运动状况及分离机理方面,计算机模拟替代部分实验的方法能够优化设计旋风除尘器结构参数,提高其对微细颗粒的捕集效率,减少运行压力损失。本研究采用RSM模型和随机轨道模型对旋风除尘器内流场及浓度场进行模拟及实验。研究表明,旋风除尘器压力损失模拟结果与实验结果吻合较好,对于大于5μm的颗粒其捕集效率模拟结果与实验结果基本吻合;旋风除尘器外壁的颗粒浓度呈螺旋带状分布;如将排气管管径减少至原直径0.8倍,可使其对2μm颗粒捕集效率提高6.6%,但压力损失提高36.5%;颗粒的凝并作用有利于提高旋风除尘器微细颗粒的捕集效率。     

Performance of Gas-Atomized Spray Scrubbers at High Pressure

A large number of pressurized coal gasification processes being developed propose to use venturi scrubbers for particulate removal at high pressures. Theoretical predictions based on venturi scrubber performance models indicate that particle collection efficiency will decrease severely in these high gas pressure applications.

An exploratory theoretical and experimental program was performed to study the effect of gas pressure on venturi scrubber performance. Experiments were done on a 0.47 m³/s (1000 acfm) pilot scale venturi scrubber. Particle collection performance was determined as a function of scrubber pressure drop for venturi scrubbers operating In the range of 1-10 atm total pressure. Experimental results confirmed that the particle collection efficiency of venturi scrubbers decreases for a given scrubber pressure drop as total gas pressure Is increased. To achieve the same particle collection efficiency, the pressure drop across a venturi scrubber operated at 10 atm Is about 10 times that of the same scrubber operated at 1 atm pressure.     

Electrostatic Precipitation Tests with Fuel Oil Ash

The main characteristics of the electrostatic collection of fuel oil ash has been investigated at a pilot precipitator installed in a laboratory rig. The relationship between collection efficiency, dust concentration and air velocity is studied and the influence of the spacing between the collection plates on both efficiency and effective migration velocity is discussed. Emphasis is put on the high degrees of efficiency attainable under suitable operating conditions.     

The Prediction of Overall Collection Efficiency of Air Pollution Control Devices from Fractional Efficiency Curves

The application of air pollution control devices requires the prediction of overall collection efficiency from the particle size distribution of the dust and the fractional efficiency of the air pollution control device. The cumulative particle size distribution of dust resulting from industrial processes can usually be represented by a straight line on logarithmic probability paper or a log normal function. The fractional efficiency curves of many air pollution control devices such as cyclones or wet scrubbers can also be adequately represented by a log normal function. Only two parameters are required to define a log normal function, a median diameter and a geometric standard deviation. Both of these can easily be obtained from a plot on logarithmic probability paper. The overall collection efficiency has been found to be Very simply related to the four parameters required to define the log normal functions representing the particle size distribution and the collector fractional efficiency. These four parameters are: the mass median diameter and the geometric standard deviation of the dust size distribution, the cut diameter (50% efficiency diameter), and geometric standard deviation of collector fractional efficiency curve. Using this relationship the prediction of overall collection efficiency is greatly simplified with no loss of accuracy.     

Evaluation of Canisters for Measuring Emissions of Volatile Organic Air Pollutants from Hazardous Waste Incineration

Regulation to control air emissions of toxic organic compounds require the collection and analysis of effluent gas from low level sources such as hazardous waste incinerators. The standard SW- 846 Method specifies the use of Tenax and Tenax/charcoal adsorbent traps for collection of volatile organics from incinerators. This study evaluates passivated stainless steel canisters as an alternative to adsorbent traps to eliminate some of the problems associated with adsorbent sampling. Initially the stability of 18 nonpolar, volatile organic compounds was determined in Summa-treated stainless steel canisters with greater than 100 ppmv HCI and saturated with water vapor. All 18 components were stable for a twoweek period; however, an Interference caused a 10-fold increase In the FID response of trlchloroethylene, toluene, and chlorobenzene. No Interference of the ECD response was found for any of the 11 compounds detected with the ECD including trlchloroethylene. A pilot scale incinerator was sampled using canisters, and the destruction efficiency of 1,1,1-trichloroethane was determined at a concentration of less than 0.5 ppbv while determining 1,1-dichloroethylene, the major product of Incomplete combustion, at a concentration of 8000 ppbv from the same sample.     

ESP粉尘收集性能的影响因素

为了进一步提高电除尘器的收尘效率,尤其是对高比电阻粉尘的收尘效率,依据非稳态静电收集理论,对影响电除尘器粉尘收集性能各项因素的作用程度及机理进行了进一步研究。实验研究了粉尘收尘效率与不同比电阻粉尘的最优极间距、最优工作电压、粉尘层厚度和比电阻之间的相互关系。研究结果表明,随着极间距的增加,对应比收尘极面积,对于不同比电阻粉尘的收尘效率的增加幅度是不同的,其中高比电阻粉尘的收尘效率增加的趋势更加显著;粉尘比电阻越高,所对应的最优极间距越大,宽间距电除尘器对捕集高比电阻粉尘具有一定优越性;在最优极间距条件下,粉尘比电阻越高,其所对应的最优工作电压越小;相对于正常比电阻粉尘,随极板沉积粉尘层厚度的增加,高比电阻粉尘的最佳收尘效率所对应的最优工作电压升高幅度较大,而且最优工作电压所对应的收尘效率下降显著。随粉尘比电阻的增大,电除尘器收尘效率逐渐降低,特别是当粉尘比电阻大于1011Ω.cm后,粉尘收尘效率显著下降。研究结果与非稳态静电收尘理论提出的观点相吻合,有助于透彻理解电场结构和运行参数与粉尘收集性能的关系,特别是对于今后研发提高高比电阻粉尘收集性能的针对性技术措施具有指导作用。     

超低压反渗透膜处理垃圾渗滤液运行工艺的实验研究

采用超低压反渗透膜处理垃圾渗滤液,考察不同工艺条件下膜通量、脱盐率、COD和NH3-N去除率的变化规律.实验结果表明,不同压力条件下对应某一输出频率存在最大膜通量.在输出频率变化方面,压力高的最大膜通量滞后于压力低的最大膜通量.运用变频调速技术,可实时解决操作压力与泵送流量的对应关系,确定最佳流量参数,提高反渗透系统运...     

Recent Electrostatic Precipitator Experience with Ammonia Conditioning of Power Boiler Flue Gases

Motivated by heightened recent interest, Koppers Co. has been experimenting with ammonia conditioning of power boiler flue gases for the purpose of improving the precipitability of the emitted fly ash. Chemical reactions resulting from ammonia injection are postulated. Measurements on three pulverized coal and two cyclone fired boilers, all of which emit acidic ash, are described. In all five cases, considerable but varying, increase in precipitator power input and collection efficiency resulted when gaseous ammonia in the amount of 1 5 ppm was injected between the economizer and air preheater. The conditioned fly ash showed decreased acidity and inconsistent change in electrical resistivity. Unless air heater temperatures were unusually high (>400°F), tendency of the air heater to plug was an additional, but unwanted, result. At one station with high air heater outlet temperature ammonia injection has been adopted as a permanent solution to community pressure for reduction of stack discharge. Ammonia injection downstream of the air heater produced no effect. Future plans are presented to continue the program beyond results described here.     

Prospects for Reducing Particulate Emissions from Large Incinerators

Conventional types of municipal incinerators generate enormous quantities of stack gas because of high excess air and high temperatures. Under these conditions the size and cost of equipment to clean the flue gas to low dust contents are large. By burning the refuse in boiler furnaces at low excess air, and generating steam, the volume of flue gas to be cleaned is reduced to a minimum. Where high efficiency of flue-dust collection is required, steam generation from refuse firing permits a major saving on the cost of dust collection.     

The Effect of Scale-Up on the Performance of High Energy Scrubbers

An experimental investigation has been carried out to examine the effect of scale-up on the performance of scrubbers for a wide range of operating conditions. A pilot plant with a maximum air flow rate of 400 cfm and a water flow rate of 4 gpm was used for this study. For the same operating conditions, the performance of 1.5 in. orifice type scrubber was found better than that of 1.0 in. size. The results were categorized according to the size of the particles, classed as large (1.5 to 3.5μ diam), medium (0.6 to 1.5μ diam) and small (less than O.6μ diam). Although the magnitude of improvement of the collection efficiency was dependent on the operating conditions, differences to the extent of 20% were obtained. The improvement of the collection efficiency for the larger scrubber was found to be due to the influence of the main stream turbulence.     

An experimental study of air entrainment and oxygen transfer at a water jet from a nozzle with air holes.

An adequate supply of dissolved oxygen is important in natural rivers and in some water treatment processes. The dissolved oxygen concentration can be enhanced by entraining air bubbles in a receiving pool. When a water jet impinges a receiving pool at rest, air bubbles may be entrained and carried away below the pool free surface. This process is called plunging water jet entrainment and aeration. This paper describes an experimental study of the air entrainment rate and oxygen transfer efficiency of circular nozzles with and without air holes. In particular, the effect of varying the number, positions, and open/close status of the air holes is investigated. A negative pressure occurred depending on the air holes opened on the circular nozzles. This phenomenon affected the water jet expansion, water jet shape, air entrainment, and bubble penetration depth and, hence, the oxygen transfer efficiency. It was demonstrated that the air entrainment rate and the oxygen transfer efficiency of the circular nozzles with air holes were better than those of the circular nozzles without air holes. Therefore, adding air holes to a simple, circular nozzle could lead to a significantly increased air entrainment rate and oxygen transfer efficiency.     

Characterization of activated carbon fiber filters for pressure drop, submicrometer particulate collection, and mercury capture

The use of activated carbon fiber (ACF) filters for the capture of particulate matter and elemental Hg is demonstrated. The pressure drop and particle collection efficiency characteristics of the ACF filters were established at two different face velocities and for two different aerosols: spherical NaCl and combustion-generated silica particles. The clean ACF filter specific resistance was 153 kg m-2 sec-1. The experimental specific resistance for cake filtration was 1.6 x 10(6) sec-1 and 2.4 x 10(5) sec-1 for 0.5- and 1.5-micron mass median diameter particles, respectively. The resistance factor R was approximately 2, similar to that for the high-efficiency particulate air filters. There was a discrepancy in the measured particle collection efficiencies and those predicted by theory. The use of the ACF filter for elemental Hg capture was illustrated, and the breakthrough characteristic was established. The capacity of the ACF filter for Hg capture was similar to other powdered activated carbons.     

New and Improved Procedures for Gas Sampling and Analysis in the National Air Sampling Network

The NASN sampler for the collection of gaseous pollutants has been modified to increase its versatility and efficiency. Oxides of nitrogen are collected in bubblers employing a 70-100 μ frit with a collection efficiency of approximately 50% depending upon the frit porosity. Included in the sampler is a bubbler for the collection of aldehydes in which the aldehyde-MBTH complex is stable at least two weeks. This inert bubbler, which is constructed of polypropylene and Teflon, makes it possible for samples to be collected over the network and analyzed at a central laboratory. In addition, gaseous ammonia is collected in 0.1N H₂SO₄. This collecting system has an efficiency of greater than 85%. Low-level samples are analyzed automatically employing Nesslerization, whereas high-level samples from source emissions may be collected in indicating boric acid and titrated with 0.02N H₂SO₄. The sampler will accommodate either 50 or 100 ml polypropylene collecting tubes.     

Air bubble and oil droplet interactions in centrifugal fields during air-sparged hydrocyclone flotation

The interactions of air bubbles and oil droplets in centrifugal flotation have been considered with respect to process conditions present during Air-sparged Hydrocyclone (ASH) flotation. Encounter efficiency of oil droplets with air bubbles has been found to be significantly smaller when compared to encounter efficiency of mineral particles. Collision and sliding contact times have been determined. Collision has been found to be insufficient for successful contact between oil droplets and air bubbles while sliding allows for film rupture depending on specific system conditions. Although the tenacity of oil droplet attachment to an air bubble is believed to be greater than the tenacity of a mineral particle, emulsification makes oil flotation in centrifugal devices with large dissipation of energy inefficient and hence requires the use of high molecular weight polymeric flocculants.     

Effect of Diffusiophoresis and Thermophoresis on the Overall Particle Collection Efficiency of Spray Droplet Scrubbers

The overall particle collection efficiencies of spray scrubbers using monodisperse droplets of 100,500, and 1000 microns diameter were calculated for the cases of evaporating and condensing droplets. The properties of the gas at the inlet to the spray scrubber were maintained constant at 150°F, 100% relative humidity, and 1 atmosphere pressure. At the liquid entrance to the spray scrubber, the water droplet temperature was 50° F for the condensing case and 180° F for the evaporating case. The liquid to gas flow rate ratio for all the calculations was held constant at 4 gal/1000 acf. The gas velocity in the co-current spray tower was 1 ft/sec in the downwind direction. The calculation results show that for the particles in the 0.01 to 10 Mm diameter range, the overall spray scrubber particle collection efficiency is greater with the cooler 50°F water (condensing case) than with the warmer 180°F water (evaporating case). The effect of diffusiophoresis and thermophoresis is noticeable for all the water droplet sizes considered, but is more significant for the larger water droplets. This greater effect for the larger water droplets compared to the smaller droplets is due to the longer existence of the temperature and water vapor concentration gradients between the water droplets and the surrounding gas.     

低压供气式射流器工业化性能研究

简要介绍了低压供气式射流器的工作原理和作用,对其在氧化沟污水处理工艺中的氧利用率和动力效率等因素做了测试和分析,比较了不同水深对充氧性能的影响。结果表明,低压供气式射流曝气器氧利用率达23.17%,动力效率达2.43 kg O2/(kW.h),优于其他形式的曝气设备,可以有效降低能耗。     

Performance of Fabric Filters on Cyclone Fired Boilers

This paper documents operation of reverse air fabric filters on Baltimore Gas and Electric’s C. P. Crane Units 1 and 2 cyclone boilers. Beginning immediately after startup, tubesheet pressure drop increased to high levels. Following stabilization with sonic horns and spare reverse air fans, an investigation was mounted. Diagnostic tools included both laboratory and slipstream pilot baghouses to determine cause and evaluate candidate methods of reducing pressure drop. Fundamental ash properties determined through laboratory pilot testing were in conformance with predictions. Alternate fabrics and coatings did not eliminate the problem. The root cause of the problem was that the amount of variable cake, i.e. that ash removed during cleaning, plays an important role in the dynamics of bag cleaning. These dynamics were absent in the C. P. Crane filters. Confirmation was obtained in the full scale baghouse through modification of the variable cake weight using ash reinfection. Finally, offsetting pressure drop and power consumption reductions have been obtained to achieve satisfactory operation of the baghouses.