Evaluation of Dust Generated from Basic Oxygen Furnace Steel Making

Abstract

A detailed characterization has been made of the dust generated during steel making in basic oxygen furnaces (BOF). Chemical composition and particle size distribution have been analyzed. X-ray diffraction, scanning electron microscopy, and electron probe micro-analysis techniques have been used to identify the morphology and the nature of the major iron-bearing phases as well as the gangue constituents. The dust characteristics have been found to be widely different, depending on the type of process used in BOF steel making, namely, suppressed combustion or total combustion. The type of dust abatement system (dry or wet) additionally influences the nature of the gangue constituents. The possibility of utilizing the iron-bearing major phases has been examined.     

The Collection of Metallurgical Fumes from an Oxygen Lanced Open Hearth Furnace

This paper deals with the installation of electrostatic precipitators on a new oxygen lanced open hearth furnace. The considerations include the various factors pertinent in the design of the precipitators, i.e., gas volume, temperature, dewpoint, dust concentrations, oxygen lancing rates, etc., along with some comments on the operation of the units.     

两种空气自动监测系统的比较

国产长光程空气自动监测系统是中国自行研制的更为先进、更具自动化的系统，24h点式仪器是老式空气检测仪器，对这两种新、老仪器的比较可以看出在运行过程中的利弊。     

Simulation of Stack Plume Opacity

ABSTRACT

The visual impact of primary particles emitted from stacks is regulated according to stack opacity criteria. In-stack monitoring of the flue gas opacity allows plant operators to ensure that the plant meets U.S. Environmental Protection Agency opacity regulations. However, the emission of condensable gases such as SO₃ (that hydrolyzes to H₂SO₄), HCl, and NH₃, which may lead to particle formation after their release from the stack, makes the prediction of stack plume opacity more difficult.

We present here a computer simulation model that calculates the opacity due to both primary particles emitted from the stack and secondary particles formed in the atmosphere after the release of condensable gases from the stack. A comprehensive treatment of the plume rise due to buoyancy and momentum is used to calculate the location at which the condensed water plume has evaporated (i.e., where opacity regulations apply).

Conversion of H₂SO₄ to particulate sulfate occurs through nucleation and condensation on primary particles. A thermodynamic aerosol equilibrium model is used to calculate the amount of ammonium, chloride, and water present in the particulate phase with the condensed sulfate. The model calculates the stack plume opacity due to both primary and secondary particles. Examples of model simulations are presented for three scenarios that differ by the emission control equipment installed at the power plant: (1) electrostatic precipitators (ESP), (2) ESP and flue gas desulfurization, and (3) ESP and selective catalytic reduction. The calculated opacity is most sensitive to the primary particulate emissions. For the conditions considered here, SO₃ emissions showed only a small effect, except if one assumes that most H₂SO₄ condenses on primary particles. Condensation of NH₄Cl occurs only at high NH₃ emission rates (about 25 ppm stack concentration).     

Quantitation of Stack Gas Flow

The presently available standards for measurement of gas flow in stacks and industrial flues are reviewed. Various problems associated with probe traverse techniques using the pitot-static tube, the Type S pitot tube, a directional type pitot tube, and hot wire anemometers are described. Recommendations are made with respect to the selection of velocity measurement station, and the selective application of velocity measurement devices is discussed.     

Some Basic Consideration in the Design of an Air Pollution Monitoring System

Quantified air quality and meteorological information provided by an air pollution monitoring system must be geared to the legally prescribed functions of the control agency. The network must be treated as a vital component of the total integrated data system that supports agency activities in air resources management and control. It should be closely interphased with data systems for emission inventory, registration and permits, violations and complaints, fuel use, emission reduction plans, land use, demographic projections, and urban planning. Compatibility with neighboring and statewide or regionwide data systems is essential for coordination of effort, especially under episode conditions.

The network should be planned on three levels, static, semi-automatic, and fully automatic, to provide monthly, daily, and up-to-the-minute measurements, respectively. Optimization of network specifications requires a three-way balance of hardware, control objectives, and agency resources (capital facilities, manpower, funding, etc.), of which the first two are realistically governed by the third.

A monitoring network could serve a wide range of functions, and there are pressures and temptations to cater to all possible users. A number of functions are listed; an order of priority should be determined. Experience shows that far more data tend to be generated than can be analyzed, assimilated, and utilized. Rapid data acquisition and on-line processing capabilities of present-day automatic networks could, without effective planning, result in mountainous backlogs of unassimilated information.

A systems engineering approach to planning will ascertain that preliminary requirements are critically scrutinized, and only genuine requirements that meet the test of constraints (natural environment, economic, legal, social, political constraints, and manpower resources) will be translated into performance specifications. By means of this approach, design characteristics that are extraneous or peripheral to the principal network functions can be identified as low priority luxuries, whereas seemingly expensive items may be justified on the basis of data reliability or long-range savings in operation and maintenance requirements.     

传统手工法和自动监测法检测空气中颗粒物的对比

分别运用传统的中流量颗粒物采样器和RP1400 a自动测尘仪,对空气中颗粒物（TSP和PM10）进行同步采样检测,结果表明,两种方法的检测结果存在着明显的系统偏差,前者的检测结果较后者偏高。     

Automatic Air Monitoring and Telemetering to Central Points In Allegheny County

This year an automatic monitoring system will supplement existing air sampling stations in Allegheny County (Pittsburgh). This system will measure pollutant levels and weather conditions at several remote sites. “On-site” recorders are equipped to telemeter the data in analog form to a central station. At the central, a multipoint recorder is supplied for each pollutant measured. This basic system, purchased for a modest initial investment, has complete capabilities for future expansion. An estimated fifteen sites will provide representative pollution data for Allegheny County. However, the basic system can be expanded to include industry installed monitoring stations—a possibilty now being considered. Further expansion to a complete Data Management system including a computer based data logger to calculate emission inventory, peak averages, and other control data is also provided for.     

氨氮在线自动监测仪的现状与问题

氨氮在线自动监测仪已在国内水质自动监测系统中得到广泛应用。现在该仪器的生产厂家生产日趋成熟、相关标准逐步出台、仪器性能基本达标。但在实际应用过程中,该仪器仍有许多问题需要进一步认识与改进。因此从方法选择、干扰排除、国家标准、比对、质量控制等方面,分析了该仪器存在的问题,并提出了相关建议。     

水质自动监测站的取水问题及其处理方法

对水质自动监测站取水问题及常见原因进行了较为全面的分析和研究,并针对性的提出了解决办法。     

苏州市区环境噪声自动监测系统简介

简要介绍了苏州市区环境噪声自动监测系统的结构及配置.     

空气自动监测系统软件开发及数据整合模式探讨

空气自动监测系统的仪器仪表多样化，以及数据采集装置和数据格式的差异，给系统软硬件的集成，以及数据应用和管理带来了不便，也是构成空气自动监测信息化进程中的技术瓶颈之一，通过对空气自动监测系统软件开发和数据整合模式的对比分析，探讨了解决问题的途径。     

两种国产COD在线自动分析仪的性能探讨

COD在线自动分析仪，是用来对各类污水中COD排放浓度进行连续监控的仪器。通过对两种国产COD在线自动分析仪的原理、性能及性能测试结果的分析，初步探讨了两种仪器的特点。     

Mercury Balance on a Large Pulverized Coal-Fired Furnace

This paper presents results of a survey of mercury concentrations in coal, ash, water, fly ash, and flue gas discharges from a 5.5 × 10⁶ Ib/hr steam generator serving a 775 MW (net) turbine-generator set. Representative composite or grab samples were obtained for inlet coal and outlet ash and water. Stack samples were obtained for fly ash and mercury vapor emissions while the unit was operated at 660 MW (net) (85% of full load). Samples were analyzed by anodic stripping voltammetry, plasma emission spectroscopy, and neutron activation analysis to determine mercury concentration entering the furnace in the coal and leaving the furnace in the flue gas, fly ash, bottom and hopper ash, and water. Method inter-comparisons are discussed. A material balance for mercury has been calculated from fuel, ash, and stack gas flow rates. About 90% of the mercury in the coal is released and appears as vapor discharged in the stack gas while 10% remains in the residual ash. For a 700 MW (net) unit, about 5 lb/day of mercury vapor is released to the atmosphere.     

Determination and Evaluation of Stack Emissions From Municipal Incinerators

A comprehensive incinerator air pollution control testing program was recently completed in New York City, and the results contain valuable particulate and gas sampling data. The information, which was obtained from a large number of test runs, is especially valuable since there is a shortage of reliable, valid test data of this nature. Since the test data now presented involved 1000 ton/day incinerators, which operate 24 hr/day, 6 days/wk, it is significant design criteria for consideration when upgrading a large incinerator or building a new one. The tests also provide information concerning the nature and concentration of gaseous constituents in the incinerator stack effluent.     

Cleaning of Stack Gases Containing High Concentrations of Nitrogen Oxides

Multistage gas absorption of 1–50% nitric oxide, nitrogen dioxide, and nitrogen tetraoxide from air with water or caustic solutions can produce colorless stack discharges. The rate at which NO is oxidized to No₂ in the gas phase and the solubility rate of No₂ in water or solution are highly concentration dependent so that reductions of stack gas concentrations of nitrogen oxides below approximately 200 ppm appear to be impractical. High efficiency absorption combined with elevated discharge of the cleaned, colorless gases is an acceptable method of air pollution control for many troublesome operations. Experiences in the fields of rocketry and nuclear energy are cited. Engineering modifications of metal pickling operations have been found especially helpful in producing effective control at an acceptable cost.     

Effectiveness of Odor Counteractants for the Treatment of Stack Gases

Successful control of some contaminant sources is extremely difficult to achieve technically and there remains a need for more information specific to control procedures. The cost of air cleaning equipment installations can be exceedingly high depending upon the performance standards to be satisfied and the physical and chemical characteristics of the contaminants. Control of emissions from the foundry cupola, the steel mill, metal refining operations, coal burning utilities, and incinerators still presents imposing cost and operational and performance problems—despite the technological progress made in recent years. The interrelationship of the source, the degree of control necessary, the equipment available to do the job, and the costs are discussed.     

Optimization of Flow for Forcing Stack Wastes to High Altitudes

It is difficult to control the emission of waste products from large stacks because of the large volume of material to be handled. However, if the waste gas is projected to relatively high altitudes, the problem is less severe in that pollution products are carried to regions of low pollution density. It is especially helpful to accomplish this high altitude dispersal during periods when the air is stable and pollution buildup is most severe. In this paper it is shown that dramatic improvements in the altitude to which stack wastes rise may be obtained by emitting the effluent in discrete vortex rings rather than in steady plumes or forced jets. The parameters of vortex rings required to reach given altitudes under given conditions are calculated. The flow at the stack required to give specific vortex ring parameters is also calculated. Some comments on the type of stack needed to create the desired flow are presented.     

The Cost of Stack Gas Cleaning in New York State

A cost estimating methodology has been applied to an emission point inventory to estimate the capital and operating costs of stack gas cleaning in the manufacturing sector of New York State. The study represents the first major attempt to estimate control costs on a source by source basis for a large region. The various control cost components are presented for each of the twenty manufacturing industry groups and the usefulness of the estimates for an abatement planning model is outlined.

In recent years a number of heroic efforts have been made to estimate the cost of air pollution abatement on a national or regional basis. Unfortunately, these studies have relied almost entirely upon emission factors, cost engineering functions, pilot plant operations, and average or ideal firms, because of the paucity of primary data.^1-6

In the estimates of capital and operating costs presented below, an attempt has been made to improve on previous research by making extensive use of primary data. The data were taken from an emission inventory of over 20,000 sources of air contamination in New York State. A cost estimating methodology was applied to engineering parameters of existing control operations on a source by source basis. The results have been aggregated to the two-digit SIC level.