Arizona Hazardous Air Pollutants Monitoring Program

ABSTRACT

In order to evaluate the existing risk to public health in Arizona related to hazardous air pollution, ambient air monitoring for selected hazardous air pollutants (HAPs) was carried out in 1994-1996 in several representative urban and rural areas of Arizona. A wide range of organic HAPs was monitored, requiring a variety of sampling and analysis methods. Stainless steel SUMMA canisters were used for collection of volatile hydrocarbons and halocarbons, which were analyzed by capillary gas chromatography with flame ionization and electron capture detection (GC-FID/ECD). Carbonyl compounds were collected using 2,4-dinitrophenylhydrazine-impregnated cartridges and analyzed by high performance liquid chromatog-raphy with ultraviolet detection. Semi-volatile and non-volatile polycyclic aromatic compounds were collected using a sampling train consisting of a filter followed by a PUF/XAD-4/PUF sandwich cartridge. Following extraction, samples were analyzed by capillary GC with mass spectrometric detection (GC-MS). Database software was developed for data processing and reporting functions. This paper describes the sampling strategy and the sampling and analysis methods employed in the monitoring program and presents a summary of all the results obtained during the duration of the sampling program.     

Standardization of Methods For Measurement of Air Pollutants

Currently available compilations of methods of air analysis are listed. Collaborative testing is urgently needed to reconcile differences and to demonstrate the accuracy of these methods. The Analytical Methods Evaluation Service of the National Center for Air Pollution Control conducted a survey of the instruments and manual methods of analysis in use. Responses are tabulated from about 80 laboratories, in 28 states and 3 foreign countries. Sulfur dioxide was the most widely measured pollutant. The first collaborative study organized by the Analytical Methods Evaluation Service is described. The purpose was to evaluate the permeation tube technique as a primary standard method for generating known sulfur dioxide concentrations for instrument calibration and methods testing. Although a good beginning has been made, the testing of methods for measuring air pollutants has barely begun.     

Fading of Selected Drapery Fabrics by Air Pollutants

A statistically designed laboratory study to assess both direct and synergistic effects of air pollutants and other environmental factors on six different classes of materials was recently completed.¹ One of the material classes was dyed textile fabrics. Drapery fabrics were specifically selected because they are economically important, are designed to have a fairly long life, and are subject to atmospheric fading. In fact, fading, whether caused by sunlight, pollution or both, frequently limits the useful life of draperies.     

Formation and Removal Reactions of Hazardous Air Pollutants

Current regulatory policies for hazardous air pollutants (HAPs) target the sources of direct emissions. In addition to direct emissions, some of the aromatic, nitrogenated, and oxygenated HAPs can be formed in the atmosphere. Formaldehyde and acetaldehyde, in particular, are produced by almost every hydrocarbon photooxidation reaction. Estimates have been made that, in some urban areas, in situ formation contributes as much as 85 percent of the ambient levels of formaldehyde and 95 percent for acetaldehyde. Over 40 percent of the HAPs being regulated under Title III of the 1990 Clean Air Act Amendments have atmospheric lifetimes of less than one day. The transformation products of these HAPs with low atmospheric persistence are important for assessing risks to human health, especially for cases where the transformation products are more toxic than the HAP itself.     

Collaborative Testing of Methods to Measure Air Pollutants

A collaborative test was conducted to determine the precision of the chemiluminescent method which has been specified for measuring ozone, to determine photochemical oxidant. Ten laboratories participated in a test involving the analysis of an urban atmosphere containing a photochemical smog mixture. Ozone generators were used to increase the O₃ level over that naturally occurring, in order to cover an adequate range of concentrations. The range tested was 0 to 0.5 ppm.

A statistical analysis of the data obtained was used to derive equations for within laboratory and between laboratory standard deviations. In order to evaluate sampling data, these equations can be used in various statistical procedures to estimate repeatability, reproducibility, lower detectable limit, and other measures that establish the precision of the method.

Using specific definitions for repeatability and reproducibility, the following approximate estimates were obtained in the range of zero to 0.5 ppm:

Repeatability—0.01 to 0.04 ppm (varies with concentration, linear).

Reproducibility—0.01 to 0.09 ppm (varies with concentration, non-linear).

The lower detectable limit depends on instrumental and other variables, and cannot be specified precisely. Under typical assumptions, this limit can be estimated at between 0.006 and 0.009 ppm.     

Some Heavy-Metal Pollutants in the Air of Naples

ABSTRACT

In this paper, assumptions regarding future land use as a key uncertainty is considered and its impact on risk analysis for contaminated sites is assessed. Risks are assessed for two land use scenarios (current-use industrial and future-use residential) using probabilistic models that incorporate uncertainty and variability in the exposure parameters. Residual risks are calculated for both industrial and residential cleanup standards. A Superfund site in northern California is considered.

In general, for the unremediated case, the future-use residential scenarios produce larger risks (1 to 3 orders of magnitude) than current- (continued) use industrial scenarios. For the Superfund site studied, the residual risks calculated for the remedy selected was not sufficiently protective of future-use residents in that it did not meet .S. Environmental Protection Agency (EPA) risk goals, but was protective of current-use workers, even though the cleanup criteria were based on residential use. Alternative risk management practices, such as deed restrictions, can be used in such cases.     

Recording the Response of Plants to Various Air Pollutants

A discussion of the methods used to determine the most economic design of chimney for a new thermal power station or large industrial plant is presented, with the objective that ground level concentration of pollutants will be kept at a minimum. Attention is paid to the geography and climatology of the site, with special reference to the frequency and height of inversions and the prevailing wind direction and speed.

A method is illustrated in using a large thermal power station as an example. The maximum sulfur dioxide concentrations at ground level are computed for several chimney heights and gas exit velocities. The values of these sulfur dioxide concentrations, the capital cost of the chimney, the pumping costs, and the gas pressures within the chimney are considered in selecting a suitable chimney height and a gas exit velocity which will meet most economically the stated objective.

The paper deals primarily with chimneys for industrial or power boiler plant of maximum continuous rating greater than 450 million Btu/hr (about 450,000 lbs of steam/hr), or to chimneys serving furnaces burning fuel at a maximum rate greater than 50,000 lbs/hr of coal, or 80,000 lbs/hr of oil. For chimneys serving plant with smaller heat inputs, chimney selection by reference to Clean Air Act 1956, Memorandum on Chimney Heights is suggested.     

The Regulation of Toxic Air Pollutants A Critical Review

ABSTRACT

Passage of the 1990 Clean Air Act Amendments launched the Acid Rain Program in the United States. This initiative, based on the market mechanism of a sulfur dioxide tradable “allowance” system, was a dramatic departure from traditional command and control strategies designed to reduce air pollution emissions. Power plant managers have flexibility under the program to select and implement a variety of options to reduce emissions below mandated levels. Federal agencies have collected annual performance data for affected facilities covered by the program for a number of years. Coal-burning plants are typically greater generators of sulfur dioxide (SO₂) than oil burners of equivalent size. This study examined the effect of fuel type as a significant factor influencing a plant's achievement in reducing pollution emissions. Achievement was measured by using a derived variable, delta (A), defined as the difference between pounds of SO₂ produced divided by the energy (in million Btu) generated, for the years 1990 and 1995. Rigorous nonparametric statistical analyses were used to compare the two populations of coal-fired and oil-fired plants. Results indicated that coal-burning facilities achieved greater program success, measured by the expected value of delta, than the oil combustors for the five-year period reviewed. Since utility managers must take steps to ensure all applicable requirements of the program are met, findings of the inquiry should prove to be useful in assessing achievable emissions reductions and aid in long-range facility planning.     

Review of Recent Studies of Sulfur Oxides as Air Pollutants

The current literature on the role of sulfur dioxide in air pollution     

A Viable System of Biological Indicators For Monitoring Air Pollutants

An air pollution monitoring biological indicator (AMBI) system for ambient ozone was tested in the South Coast Air Basin of California during the 1972 fall growing season. The basic unit or AMBI station was an inexpensive, portable plant station which operated independent of power sources. Reliability of these units was excellent as only three instances of missing data were observed from 330 possibilities. A photo-reference system of ozone injury evaluation utilizing direct comparisons of injured leaves with reference photographs was successful in standardizing assessments of ozone injury. Average weekly injury indices for field locations were correlated with average weekly ozone dosages and were found to be significant at the .01 level.     

Absorption of Gaseous Air Pollutants By a Standardized Plant Canopy

Concentration profiles for hydrogen fluoride(HF), sulfur dioxide(SO₂), ozone (O₃), nitrogen dioxide(NO₂), and nitric oxide(NO) generated in a standardized alfalfa canopy are presented. Wind, light, temperature, and carbon dioxide(CO₂) profiles, canopy pollutant uptake rates, and canopy structural data are also given. Canopy pollutant concentration profile characteristics were studied to evaluate the relative potentials for major air pollutants to penetrate into canopies. The study was conducted in an environmental growth chamber equipped to control automatically environmental conditions and monitor continuously gas exchange rates. HF, SO₂, and NO₂ profiles suggested that these gases were removed efficiently by the upper portion of the canopy as well as by the immediate subsurface vegetation. The steady state HF profile showed the greatest displacement within the canopy. The NO profile was displaced the least. The uptake rate of NO by plants was apparently too slow in comparison with gas transport and mixing within the canopy to affect the internal profile substantially. O₃ appeared to be readily deposited on the surface tissues, but the deeper tissues in the canopy had less effect on the concentration profile. Data are also presented to show the relationship between NO₂ concentration within the canopy and changes in the air concentration above the vegetation. The results indicated that gas transport between the atmosphere and canopy interior was rapid. The data presented should be of current interest to agriculturists, researchers, administrators, and environmental planners concerned with effects of air pollutants on plants and on the fate of pollutants in the microenvironment.     

Detection and Measurement of Air Pollutants by Absorptions of Infrared Radiation

A technique of detecting gaseous air pollutants by means of absorption of laser radiation is under development at the NASA Electronics Research Center. The iodine infrared laser and the carbon dioxide infrared laser are forced to emit spectral lines which fall on the infrared absorption bands of atmospheric pollutants. The attenuation of a laser line when passed through an air sample is the measure of the pollutant concentration. The narrow spectral width of the laser emission permits sensitive detection, minimizes interference between pollutants, and allows penetration of atmospheric water bands. The collimation and high power outputs available from lasers permit transmission of the radiation over long straight paths through the atmosphere and over long folded paths in multiple-pass absorption cells. A sample of absorbing gas placed within the laser cavity forces the emission of the selected wavelengths. With a one-half kilometer path to a retro-reflector and back, it is predicted that the following concentrations of air pollutants will be detected by means of the indicated laser lines: carbon monoxide at 2 parts per million in air (ppm), using the 4.86 micron iodine line; nitric oxide at 1 ppm, using the 5.5 micron iodine line; ethylene at 0.1 ppm, using the 10.53 micron carbon dioxide line; sulfur dioxide at 1.5 ppm, using the 9.08 micron carbon dioxide line; and ozone at 0.15 ppm, using the 9.52 micron carbon dioxide line. It seems feasible to extend the technique to other gaseous pollutants such as nitrogen dioxide, methane, butane, and peroxy acetyl nitrate. Continuing effort is being devoted to development and construction of the laser transmitting and receiving equipment. Field testing is planned for the near future.     

A Study of the Statistical Distribution of Chemical Pollutants in Air

The statistical distribution of air pollutants in Sofia has been investigated. It was established that the distribution is not normal. Application of logarithmic transformation brings the distributions closer to the log-normal, but does not completely normalize them. All of the distributions have considerable skewness and excess which remain after the logarithmic transformation.