Electrostatic Precipitation Of Fly Ash Reaches Fiftieth Anniversary

Fifty years ago electrostatic precipitation, which had been used successfully for collection of sulfuric acid mist, was first applied to a power plant installation for control of fly ash from pulverized fuel. This is the history of the design and application of the principle as the power generation industry adapted to changing environmental problems and concerns.     

“Hot” versus “Enlarged” Electrostatic Precipitation of Fly Ash: A Cost-Effectiveness Study

An article in the February 1974 issue of the Journal of the Air Pollution Control Association entitled “Hot” versus “Enlarged” Electrostatic Precipitation of Fly Ash: A Cost Effectiveness Study,¹ by D. R. Selzler and W. D. Watson, Jr., arrives at the generalized conclusion that “enlarged” precipitation is likely to be a less costly method of attaining high collection efficiencies for low sulfur fly ash. The basis of this conclusion is a multivariate regression analysis of 37 full-scale cold electrostatic precipitators. Using the predictive ability of the resulting equation, modified to include a 95% probability of attaining design efficiency, together with functions describing capital and operating costs, the authors arrived at the above conclusion.

It is our contention that while the overall approach presented is a good attempt to develop a more systematic method of attacking the problem and arriving at a generalized solution, there are many errors in the development which have resulted in incorrect conclusions. Among the more serious errors in this work is the development and acceptance of a regression model based on cold precipitation performance data which is not compatible with the observed performance of cold precipitators. The use of the same equation for hot precipitator sizing can also be shown to be invalid. Additionally, one of the basic parameters used by the authors to distinguish precipitation performance of coals is not meaningful for hot precipitation and of questionable validity for cold precipitation. And, finally, the authors do not appear to recognize that power input to the precipitator (actually power density) is a constrained function which can hardly ever be increased to levels defined by their “optimum” precipitator sizing.     

Progress in High-Temperature Electrostatic Precipitation

Current-voltage relationships for negative corona are given for a pilot-scale electrostatic precipitator with 3-in. electrode spacing at 80°–1500°F and 35–80 psig. Direct comparison is made with the electrical characteristics for a 1-in. spacing at 1200°F over the same pressure range. Experimental results on both spacing agree well with electrostatic theory. Initial dust removal efficiencies for the pilot-scale precipitator ranged from 90 to 98% at 1460°F and 80 psig, but continuous operation was not achieved owing to excessive thermal expansion of the internal parts of the unit.     

Factors Affecting Resistivity in Electrostatic Precipitation

The following material is taken from a new book, “The Art of Electrostatic Precipitation,” authored by Mr. Katz and based on his 30 years of field experience with the subject. The book provides practical information on maintaining and upgrading precipitators; chapter titles include fundamentals, operation and maintenance, trouble solving, corrosion factors, methods to improve performance, test evaluation techniques, gas distribution and conditioning, case histories, and optimum designs.     

Adhesive Behavior of Dust in Electrostatic Precipitation

In 2-stage precipitators particles are driven to the collecting plates by electrostatic forces but then the electrostatic force reverses and tends to pull the particles off so that dust is held on the collecting electrodes only by adhesion. In Cottrell or single-stage precipitators the corona current can provide a significant force tending to hold the collected dust to the electrode provided that the resistivity of the dust is 10¹⁰ ohm-cm or more. Adhesion is still essential in the collection of lower resistivity dust and is of vital importance in the transfer of dust from the collecting electrodes to the hopper. As the dust falls from the plates to the hopper it must be held in agglomerations or chunks. There are many peculiarities in the adhesive behavior of electrostatically collected dust. A better understanding of this adhesive behavior is essential if we are to improve the transfer of dust from the collecting electrodes to the hopper.     

High Temperature,High Pressure Electrostatic Precipitation

This paper presents the results of work conducted by Research-Cottrell under EPA contract 68-02-2104. The feasibility of electrostatic precipitation at temperatures and pressures varying from ambient condition to 1366°K and 3550 kPa, respectively, has been demonstrated in a laboratory wire-pipe electrode system. Stable corona discharges are obtained at all temperatures subject to appropriate choices of electrode dimension, polarity, and pressure. Current-voltage characteristics are reported for dry air, a simulated combustion gas, and a substitute fuel gas. The effects of temperature, pressure, electrode geometry and polarity on sparkover voltage, corona-starting voltage, and current are evaluated. A precipitator performance model is included to incorporate this data into a high temperature, high pressure precipitator design. This model has been evaluated for an electrostatic (HTHP) precipitator following a pressurized fluidized bed combustor at 1089 K and 920 kPa. It is recommended that prototype HTHP electrostatic precipitators be applied to pilot coal gasifiers and fluidized bed combustors to obtain detailed design data and to verify the accuracy of the performance model under actual operating conditions.     

Precipitation of Charged Dust Particles on Electrostatic Screen

The purpose of this paper is to present collection performance dependence upon the parameters of channeled electrodes in a twostage precipitator. The practical channeled electrostatic screens are classified into two types and the respective theoretical collection efficiency equations are obtained by employing idealized models. It is shown that In normal operating conditions the most effective particle collection mechanism in the device is electrostatic precipitation rather than the Inertlal separation. It is also pointed out that the channeled electrode, in comparison with the plate-type, should be a narrow width. An empirical efficiency equation is recommended and the agreement between experimental data and empirical equation is within 6%.     

Feasibility Demonstration of Electrostatic Precipitation at 1700°F

An experimental high-temperature, high-pressure electrostatic precipitator module has been designed, fabricated and then evaluated in a gaseous environment having the characteristics anticipated for the combustion chamber of a system for generating electric power from the incineration of municipal solid wastes.

Stable positive and negative corona discharges were established in combustion gases from the burning of methanol and air (temperature and pressure approximately 1700°F and 100 psig, respectively) without any apparent deleterious effects due to thermal ionization and/or emission. At gas conditions of about 1700°F and 50 psig, positive polarity energization of the discharge electrode appeared superior to that of negative polarity in terms of voltage level that could be applied and electrical stability.

However, precipitator performance on removal of alumina dust injected under controlled conditions with the methanol fuel, showed negative polarity to be superior to positive polarity at the selected conditions of 1650°F and 100 psig which closely correspond to those required for optimum operation of the gas turbine presently under consideration. Removal efficiencies ranging from 25% for positive polarity to as high as 87% with negative polarity were measured.

In order to check whether materials having a low ionization potential would thermally ionize to such an extent that the voltage-corona current characteristics of the precipitator would be impaired, rendering it ineffective, potassium chloride salt in solution was injected with the fuel. Results indicated that amounts of approximately one part by weight of potassium ion in 2500 to 3000 parts by weight of gas at 1700°F tripled the current measured for a given voltage when compared to non-injection.

Although a limited test program was conducted, sufficient data were obtained to allow preliminary design and sizing of larger scale units.     

Fly Ash from Electrostatic Precipitators: Characterization of Large Spheres

The body of information contained in this paper is directed towards individuals concerned with the toxicology and physical state of airborne effluents from pulverized coal-fired stationary sources. A flotation/sedimentation technique was used to separate fly ash from power plant clean-up devices into light, medium, and high density fractions. Large spherical particles were selected from each fraction and examined by optical and scanning electron microscopy. Attempts were made to identify pleurospheres (filled hollow spheres) by crushing the spheres in situ under the optical microscope. In no cases were filled spheres observed, suggesting that they are not a common structure in fly ash. Several phenomena which generate hollow spheres are discussed.     

Design and Application of High Voltage Power Supplies in Electrostatic Precipitation

Proper electrical energization methods and equipment are the keys to successful electrostatic precipitation. The design, operation, and application of conventional high voltage power supplies in this process are reviewed. Emphasis is on requirements and methods of achieving the high performance and reliability necessary in modern air pollution control systems. Typical field data on operations and effects in various precipitator applications, including high resistivity ash, high temperature, and/or high pressure gas treatment, are discussed.     

静电除尘器声波清灰原理及设计要点

介绍了静电除尘器声波清灰的特点,原理和声波发生器的性能以及静电除尘器声波清灰设计要点。     

Issues and Trends in Electrostatic Precipitation Technology for U.S. Utilities

The pace and direction of electrostatic precipitator (ESP) technology evolution in the United States will be governed by two key forces. The first is new clean air legislation passed by the U.S. Congress and signed by President Bush on November 15,1990. This law requires electric utilities to further reduce SO₂ and NO_x emissions, which may impact particulate controls. In addition, very fine (< 10 micron) participates and potentially toxic trace emissions from utility power plants may be regulated. The second major factor is the expected upsurge in new plant construction beginning in the late 1990s. Together, these forces should define the performance requirements and market for new ESPs.

This paper identifies and briefly describes technologies that the Electric Power Research Institute (EPRI) is developing to help U.S. utilities meet these challenges cost-effectively. Among the technologies addressed are: advanced digital voltage controls, flue gas conditioning, intermittent energization, temperature-controlledprecharging (i.e., two-stage ESP), wide plate spacing, positive energization of corona electrodes for hot-side ESPs, and integration of conventional ESPs with pulse-jet baghouses.     

Some Problems in the Application of the Deutsch Equation to Industrial Electrostatic Precipitation

The Deutsch equation assumes that all particles are identical and that there is complete mixing of the gas at any point along the gas path. In industrial precipitators complete mixing is probably a good approximation but the diversity of sizes and kinds of particles results in an efficiency curve which increases less rapidly with precipitator length than would be predicted by the Deutsch equation. By choosing a different drift velocity for each condition, the Deutsch equation can be effectively used by an expert but this procedure can be very confusing to the engineer with limited experience.     

Electrostatic Precipitation of Ultrafine Particles Enhanced by Simultaneous Diffusional Deposition on Wire Screens

Abstract

A laboratory-scale electrostatic precipitator has been designed and constructed in which the grounded collector plate has been substituted by a set of wire screens placed perpendicularly to the gas flow. Particles are deposited onto the screens by two mechanisms—electrostatic deposition and diffusional deposition—which act simultaneously. On the one hand, electrostatic deposition is effective for relatively large particles, but it is quite ineffective for the smallest ones because their charging probability in the corona field is too low. On the other hand, the diffusional collection efficiency of particles on fibers is high for small particles but low for the larger ones. Therefore, the simultaneous diffusional-electrostatic precipitation may become a useful technique for efficient filtration of particles below 0.1 μm. A preliminary experimental evaluation of this filtering device has shown that submicrometer particles with diameters down to a few nanometers can be collected with number efficiencies greater than 99%.     

Fuel Oil Additives for Controlling Air Contaminant Emissions

An addition of additives to fuel oils prior to combustion is one way of reducing combustible contaminant emissions to the outer air. Reported test results show that some additives improve, moderately, the combustive properties of fuel oils. Combustion is also improved but to a lesser degree, in boiler systems that are deficient in operation and design. Being combustible, polynuclear hydrocarbons emissions would be reduced by use of additives. Other types of additives to reduce slagging and inhibit corrosion from combustion of fuel oils are also available. The cost of using additives is low. Improved additives are required, especially ones to better combustion in the deficient boiler systems. These can be found by research and literature surveys. Their effectiveness and nontoxicity would be confirmed by laboratory and field testing.     

Collection of Fly Ash with High Electrical Resistivity in a Pilot Plant Electrostatic Precipitator Preceded by the EPA/SoRI Precharger

It is well known that dust with high electrical resistivity is difficult to collect in electrostatic precipitators (ESP). The difficulty is primarily due to poor particle charging. This poor particle charging is not because particles having high electrical resistivity are intrinsically difficult to charge, but because back corona (which results from deposition of material on the collection electrode) produces a bipolar ion field. When ions of both positive and negative polarity are present in the charging region, the competing effects of the two, plus low values of electric field, produce low electrical charge on particles.     

Some Technical and Economic Aspects of Residual Fuel Oil Desulfurization

Combustion of residual, the most common type of fuel oil used in industrial and commercial steam generating plants, accounts for about 600,000 tons or 37 percent of the sulfur oxide emissions in New York state. On the average, residual oil available in New York state contains about 2.2 percent sulfur and is consumed at an annual rate of approximately 85 million barrels. The removal of sulfur from many types of residuals should become economically feasible as a result of the development of the HDS and H-Oil hydrodesulfurization processes. From studies recently made, these methods of desulfurization have been estimated to vary from a minimum of no appreciable increase in overall cost to a maximum of about one cent per gallon. The by-product distillates produced in hydrodesulfurization are a very significant factor in making the process economical and the demand for these is increasing at a greater rate than residual.