Sustainable wood-based nanotechnologies for photocatalytic degradation of organic contaminants in aquatic environment

•Wood and its reassemblies are ideal substrates to develop novel photocatalysts. •Synthetic methods and mechanisms of wood-derived photocatalysts are summarized. •Advances in wood-derived photocatalysts for organic pollutant removal are summed up. •Metal doping, morphology control and semiconductor coupling methods are highlighted. •Structure-activity relationship and catalytic mechanism of photocatalysts are given. Wood-based nanotechnologies have received much attention in the area of photocatalytic degradation of organic contaminants in aquatic environment in recent years, because of the high abundance and renewability of wood as well as the high reaction activity and unique structural features of these materials. Herein, we present a comprehensive review of the current research activities centering on the development of wood-based nanocatalysts for photodegradation of organic pollutants. This review begins with a brief introduction of the development of photocatalysts and hierarchical structure of wood. The review then focuses on strategies of designing novel photocatalysts based on wood or its recombinants (such as 1D fiber, 2D films and 3D porous gels) using advanced nanotechnology including sol-gel method, hydrothermal method, magnetron sputtering method, dipping method and so on. Next, we highlight typical approaches that improve the photocatalytic property, including metal element doping, morphology control and semiconductor coupling. Also, the structure-activity relationship of photocatalysts is emphasized. Finally, a brief summary and prospect of wood-derived photocatalysts is provided.     

Microbial degradation of two carbamate insecticides and their main metabolites in soil

Degradation studies in soil of the insecticides aldicarb and carbofuran and their metabolites (aldicarb sulfoxide, aldicarb sulfone; 3-ketocarbofuran and 3-hydroxycarbofuran) were carried out using laboratory systems under controlled conditions (temperature, water content, light). The insecticides were added to soil samples and subsamples of the soil were analyzed at different times to assess both the bacterial abundance and the concentration of the different chemicals. The epifluorescence direct count method was applied to the subsamples to estimate microorganism numbers (N/g soil). Untreated samples of soil were used as controls for evaluating the effects of the application of the insecticides on microbial abundance. Subsamples treated with the pesticides were analyzed using HPLC and the DT 50 s of the different compounds studied were calculated. The DT 50 values show that neither the parent compounds nor the transformation products have a high persistence in soil and there is a general increase in the concentration of microorganisms as the pesticides diminish.     

The effect of temperature on leaching and subsequent decomposition of dissolved carbon from inundated floodplain litter: implications for the generation of hypoxic blackwater in lowland floodplain rivers

Dissolved organic carbon export from floodplain litter during flood events is an important energy subsidy for lowland rivers. Temperature affects both the release and decomposition of dissolved organic carbon from floodplain plant litter. Unseasonally warm flood conditions have resulted in the release and consumption of carbon at a rate so rapid that water column oxygen has been depleted, causing the death of aquatic organisms upon exposure to this ‘hypoxic blackwater’. To date, there has not been a systematic investigation of the role of temperature on hypoxic blackwater dynamics. In a series of laboratory experiments, we investigated the temperature dependence of both leaching and decomposition of carbon from a common floodplain litter component in south-eastern Australia – the leaves of the river red gum Eucalyptus camaldulensis. The leaching rate increased with temperature and approximated Arrhenius kinetics. Additionally, the solubility of the leaf carbon increased substantially at temperatures above ～25°C. The rate of organic carbon respiration also increased with temperature, and the relationship with temperature was approximately linear. These data can be used to improve models for the prediction of hypoxic blackwater risk.     

Participatory assessment of soil degradation in the uplands of southwestern Tanzania: Implications for sustainable agriculture and rural livelihoods

Rural household food insecurity and poverty are closely linked to soil degradation in Sub-Saharan Africa. However, causes, degradation processes, coping strategies and need for interventions may vary from one place to another. This study was conducted in Mbinga District, SW Tanzania, to investigate causes and biophysical processes of soil degradation; effects on livelihoods, coping strategies and entry points for interventions. Implications for sustainable production and rural livelihoods are discussed. Participatory Rural Appraisal (PRA), household surveys using a short open-ended questionnaire and biophysical exploration were the research tools used. Soil fertility depletion resulting from continuous cropping and erosion losses is the main form of soil degradation. Maize yield was 57% lower in fertility-depleted farms than in productive farms. Soil pH, Ca²⁺, Mg²⁺ and CEC accounted for 79% of variations in maize yield. Organic soil fertility amelioration was a common strategy used by smallholders. Use of beneficial tree and shrub fallows is the most environmentally, economically and socially promising improvement that can be used to build on the existing strengths of farmers' knowledge and strategies. Subsidy for the right type of fertilizers, infrastructure improvement and education of farmers on proper use of fertilizers should significantly contribute to improved and sustainable production and livelihoods.     

Determination of growth kinetics of microorganisms linked with 1,4-dioxane degradation in a consortium based on two improved methods

● Evaluated three methods for determining the consortia’s growth kinetics. ● Conventional method is flawed since it relies on the total biomass concentration. ● Considering only selected bacterial taxa improved the accuracy. ● Considering oligotrophs and copiotrophs further improved the accuracy. The conventional method for determining growth kinetics of microbial consortia relies on the total biomass concentration. This may be inaccurate for substrates that are uncommon in nature and can only be degraded by a small portion of the microbial community. 1,4-dioxane, an emerging contaminant, is an example of such substrates. In this work, we evaluated an improved method for determining the growth kinetics of a 1,4-dioxane-degrading microbial consortium. In the improved method, we considered only bacterial taxa whose concentration increase correlated to 1,4-dioxane concentration decrease in duplicate microcosm tests. Using PEST (Parameter Estimation), a model-independent parameter estimator, the kinetic constants were estimated by fitting the Monod kinetics-based simulation results to the experimental data that consisted of the concentrations of 1,4-dioxane and the considered bacterial taxa. The estimated kinetic constants were evaluated by comparing the simulation results with experimental results from another set of microcosm tests. The evaluation was quantified by the sum of squared relative residual, which was four orders of magnitude lower for the improved method than the conventional method. By further dividing the considered bacterial taxa into oligotrophs and copiotrophs, the sum of squared relative residual further decreased.     

The value of disappearing beaches: A hedonic pricing model with endogenous beach width

Beach nourishment is a policy used to rebuild eroding beaches with sand dredged from other locations. Previous studies indicate that beach width positively affects coastal property values, but these studies ignore the dynamic features of beaches and the feedback that nourishment has on shoreline retreat. We correct for the resulting attenuation and endogeneity bias in a hedonic property value model by instrumenting for beach width using spatially varying coastal geological features. We find that the beach width coefficient is nearly five times larger than the OLS estimate, suggesting that beach width is a much larger portion of property value than previously thought. We use the empirical results to parameterize a dynamic optimization model of beach nourishment decisions and show that the predicted interval between nourishment projects is closer to what we observe in the data when we use the estimate from the instrumental variables model rather than OLS. As coastal communities adapt to climate change, we find that the long-term net value of coastal residential property can fall by as much as 52% when erosion rate triples and cost of nourishment sand quadruples.     

森林枯枝落叶分解及其影响因素

枯枝落叶在森林生态系统中占有极其重要的地位,枯枝落叶的分解是一个以生物为主要参与者的过程,土壤动物使粗枯落叶实现物理性分解,土壤微生物则使枯落物碎片进一步分解为简单无机分子或转化为腐殖物质。土壤微生物的分解受枯落物自身成份的影响,粗脂肪与可溶性糖等在前期分解,木质素与纤维素等在后期分解,低w(C)/w(N)比枯落物易于分解,枯落物内的有机氮最终将降解为NH 4和NO-3,用于描述枯落物分解的最常用模型是指数方程x/x0=e-kt。自然因素与人为因素引起的火烧也是引起地面枯落物消失的重要因素,它有很强的负面效应,造成有机氮的损失。影响枯落物分解的因素很多,它们主要是通过影响分解生物而起作用,这些因素有树种、温度、湿度、酸碱度、污染等。阔叶树枯落物通常比针叶的分解快,温度与有机氮的矿化有线性关系,硝化作用可在大幅度的温度范围内发生,但最适温度通常在25℃。碳矿化的最适含水量约60%,在过于淹水条件下易于出现反硝化作用而造成氮损失。森林枯落物分解以真菌为主,适于在较高pH条件下进行,但与枯落物种类有关,云杉最适分解酸度为pH5～7,多种阔叶树最适分解酸度在pH3.5,土壤变酸时通常造成细菌数量显著下降,而以真菌占主导。枯落物的处理方式影响森林土地的生产力,移除地面枯落物或采伐剩余的枝叶可造成土地肥力的显著下降,相反,则有利于维持土地肥力。     

Effects of visible light radiation on macrophyte litter degradation and nutrient release in water samples from a eutrophic shallow lake

Visible light is a major fraction of the solar spectrum; however, information on visible light radiation of macrophyte detritus is lacking. In this study, we conducted a microcosm experiment to assess the effects of visible light radiation on degradation of two litter species: Potamogeton malaianus (P. malaianus) and Phragmites australis (Ph. australis). This research represents an investigation of mass loss, microbial activity and nutrients released over a period of 168 days. Overall, we found that visible light radiation had significant effects on litter decomposition, but it did not affect the microbial activities which degrade cellulose and lignin. The decomposition rate order of the three components in P. malaianus and Ph. australis in treatments was: cellulose?>?hemicellulose?>?lignin. The visible light radiation mainly affected the degradation of lignin, which is the primary compound in litter susceptible to photodegradation. The exposure to visible light radiation up to 17.6?Wm^?2 stimulated the dissolved organic carbon release and reduced the molecular weight to less reactive. Meanwhile, no obvious difference in nutrient contents (TP, TN, NO₃–N, NO₂–N, and NH₃–N) was observed among different visible light intensities. The results of this study contribute to better understanding of the photochemical behaviour of macrophyte litter in shallow lakes.     

Rehabilitation of metropolitan beaches by local administrations in Catalonia: new trends in sustainable coastal management

The planning and management of coastal sites in Catalonia has been mainly concerned with rendering beaches functional for mass frequentation. This has caused serious problems for the beaches, including the alteration of dune formation processes and the destruction of beach vegetation and habitats. Municipal capacity to plan and manage beaches is theoretically very limited and relegated to the design of plans related to the maintenance of facilities for beach users. Nonetheless, a singular experience, led by a local council in the metropolitan area of Barcelona demonstrates the crucial role that a local administration can play in achieving a balance between habitat preservation and social use based on sustainable coastal management objectives, in spite of a restrictive legislation.     

The status of beaches and shoreline development options on the French Riviera: a perspective and a prognosis

Beach conservation and management on the high-value French Riviera in southeastern France have had mixed fortunes in shoreline economic development strategies over the past half century. Prior to 1965, socio-economic growth related to immigration and tourism resulted in considerable pressure on the coastal zone, leading in particular to beach erosion and degradation of beach environmental quality. Between 1965 and 1980, over 20% of the 132 km-long French Riviera was permanently altered through the implantation of yachting harbours and reclamation fill structures, while beach-based recreation had a rather low ranking as a development choice, except in the two major resorts of Cannes and Nice which exhibit a densely urbanized seafront. On this preponderantly boldrocky coast, the mediocre recreational value inherited by many of the beaches from the regional geologic setting, and from development pressures and earlier errors in coastal management, left them vulnerable to appropriation and so-called ‘valorization’ by yachting harbour and estate developers. Over the last decade, artificial shoreline development has virtually ceased, in response to several more or less interrelated factors. These include relative stagnation of socio-economic growth, increasing development and maintenance costs of yachting harbours, saturation of the yachting harbour market as a result of the burgeoning of new, often cheaper, resorts and of reconversion of commercial and shipbuilding ports to leisure ports in the Mediterranean, more stringent legislation, since 1986, on the implantation of residential and major engineering structures on the coastline, pressure for conservation of the cultural and environmental heritage, and greater demand for beach recreational space. This situation has forced a diversification of shore-based activities, as it has been realised that better managed beaches may balance economic aspirations while contributing to enhanced environmental quality and sensible shoreline conservation. This change in strategy has entailed considerable efforts and money on the improvement of coastal water quality, the provision of amenities for beach-goers, and especially the nourishment of eroding beaches and the creation of several artificial beaches. The extent to which beaches will continue to play a role in the sustainable development of French Riviera resorts will depend largely on the capacity of local authorities to maintain environmental quality in the face of inherited and persistent handicaps such as beach erosion.     

The status of beaches and shoreline development options on the French Riviera: a perspective and a prognosis

Beach conservation and management on the high-value French Riviera in southeastern France have had mixed fortunes in shoreline economic development strategies over the past half century. Prior to 1965, socio-economic growth related to immigration and tourism resulted in considerable pressure on the coastal zone, leading in particular to beach erosion and degradation of beach environmental quality. Between 1965 and 1980, over 20% of the 132 km-long French Riviera was permanently altered through the implantation of yachting harbours and reclamation fill structures, while beach-based recreation had a rather low ranking as a development choice, except in the two major resorts of Cannes and Nice which exhibit a densely urbanized seafront. On this preponderantly bold rocky coast, the mediocre recreational value inherited by many of the beaches from the regional geologic setting, and from development pressures and earlier errors in coastal management, left them vulnerable to appropriation and so-called ‘valorization’ by yachting harbour and estate developers. Over the last decade, artificial shoreline development has virtually ceased, in response to several more or less interrelated factors. These include relative stagnation of socio-economic growth, increasing development and maintenance costs of yachting harbours, saturation of the yachting harbour market as a result of the burgeoning of new, often cheaper, resorts and of reconversion of commercial and shipbuilding ports to leisure ports in the Mediterranean, more stringent legislation, since 1986, on the implantation of residential and major engineering structures on the coastline, pressure for conservation of the cultural and environmental heritage, and greater demand for beach recreational space. This situation has forced a diversification of shore-based activities, as it has been realised that better managed beaches may balance economic aspirations while contributing to enhanced environmental quality and sensible shoreline conservation. This change in strategy has entailed considerable efforts and money on the improvement of coastal water quality, the provision of amenities for beach-goers, and especially the nourishment of eroding beaches and the creation of several artificial beaches. The extent to which beaches will continue to play a role in the sustainable development of French Riviera resorts will depend largely on the capacity of local authorities to maintain environmental quality in the face of inherited and persistent handicaps such as beach erosion.     

Implications of sustainable aquaculture in future technology transfer: The Oceanic Institute experience

SUMMARY

Aquaculture has provided an alternative animal protein source for people for decades. The transfer of improved aquaculture technology has assisted economic growth in less developed countries by such donor countries as the USA, Japan, the European economic communities, Canada and Australia. Donor agencies provided funding for purchasing advanced equipment, professional training, professional consultation, and experts to advise recipient countries. The level of success varied for each project.

The Oceanic Institute (OI) in Hawaii has engaged in aquaculture development in many regions for decades. The successful transfer of finfish fry production technology has been demonstrated recently in Indonesia and Egypt. Past experience provides a foundation for the next generation of technology transfer, involving consideration of socioeconomics.

This paper examines the difficulties encountered in traditional technology transfer, and the need for sustainable aquaculture development in recipient countries.     

Human resilience and environmental degradation: The eco-cultural link in the Sahel

The relationship between human resilience and environmental degradation was studied in the Sahel. The strongest predictors of human resilience were rate of environmental degradation, avoidance, problem solving and locus of control. Compared to pastoralists, agriculturalists were more stressed and marginalized. Women in all groups scored higher on marginalization and stress than men.     

Long-term forest-floor litter dynamics in Canada's boreal forest: Comparison of two model formulations

Litter decomposition is a key component in ecosystem material cycling that determines (i) forest soil carbon (C) and nutrient content, (ii) release of carbon dioxide to the atmosphere, and (iii) generation and mass transfer of dissolved organic carbon from terrestrial to aquatic ecosystems. In this study, we provide simulations of long term forest-floor litter dynamics generated with both (i) an existing forest nutrient cycling and biomass growth model (ForNBM) with a single-pool formulation of forest-floor litter decomposition (Zhu et al., 2003. Ecol. Model. 169, 347-360), and (ii) a revised version of the model produced by substituting the single-pool formulation with a three-pool version of the formulation tested against data from litterbag experiments (FLDM; Zhang et al., 2010. Ecol. Model. 221, 1944-1953). This is done to determine the importance of subdividing the litter mass into categories of rates of decay (i.e., fast, slow, and very slow) on model accuracy. Forest-forest litter dynamics simulated with the two models are subsequently compared against field measurements collected at several northern jack pine (Pinus banksiana) stands along a southwest-northeast oriented transect (climate gradient) associated with the Boreal Forest Transect Case Study in northwest Canada. Initial comparison shows that the single-pool formulation underpredicts residual litter mass when forests are <65 years old, largely due to the improper treatment of the very slow decomposing litter component. This underprediction is resolved when the three-pool formulation is used. From a ecosystems-response point of view, the revised ForNBM (with the three-pool formulation) demonstrates that (i) forest-floor litter initially increases with forest growth and reaches a plateau once the forest matures; (ii) the forest floor stores more litter and C at the southern and warmer sites than at the northern sites; and (iii) in a similar climate regime, the forest floor stores more litter and C at productive than at nutrient-poor sites.     

Supported porphyrins for the photocatalytic degradation of organic contaminants in water: a review

Environmental Chemistry Letters - Porphyrins are differentiated π-conjugated compounds with unique photochemical and redox properties. The tetrapyrrole macrocycle core of porphyrins is...     

联苯菊酯在棉花和土壤中的残留和降解行为研究

为了评价为联苯菊酯在棉花上使用的安全性,于2010—2011年在济南、杭州两地采用田间试验和气相分析方法研究了联苯菊酯在棉叶、棉籽及土壤中的消解动态和最终残留。联苯菊酯在棉叶和土壤中的降解行为均符合一级降解动力学方程,其降解半衰期分别为4.2-6.7、10.6-16.0 d。联苯菊酯在棉籽和土壤中的最终残留质量分数均小于最低检出限0.01 mg.kg-1,低于联苯菊酯在棉花上的最高残留限量（MRL）0.5 mg.kg-1。建议10%联苯菊酯可溶液剂防治棉花蚜虫,用药次数1-2次,使用剂量是9-18 aig.hm-2,在棉花上的安全间隔期14 d。     

氟铃脲在棉花和土壤中的残留与降解行为研究

利用高效液相色谱分析方法,考查氟铃脲在棉叶及土壤上使用后的降解和残留行为,为安全施药提供依据。采用田间试验法研究氟铃脲在棉叶和土壤中的残留消解动态。氟铃脲在棉叶中的消解动态均满足一级降解动力学过程及其降解常数。按照试验要求,氟铃脲在棉籽中的最终残留均未检出,低于日本规定的最大残留限量值（0.05 mg·kg-1）。该分析方法操作简单,精密度、准确度和灵敏度都符合农药残留标准要求,适用于棉花和土壤中的氟铃脲残留测定;建议2%氟铃脲乳油在棉花上防治病害,用药次数1次,使用剂量是22.5～30.0 g·a·i·hm-2,在棉花上的安全间隔期可定为10 d。