蔗糖厂洗布水的生化处理试验研究

分别采用水解 -二段生物接触氧化以及二段生物接触氧化两种工艺 ,通过接种高效蔗糖降解菌对蔗糖厂洗布水的生化处理进行试验研究 ,结果表明 :填料采用煤渣较好 ;加适量的氮源和磷源能提高生化处理效果 ;两种工艺处理都能使废水达标排放 ,但从经济角度考虑认为水解 -二段接触氧化工艺较优。     

超临界水氧化有机废水动力学分析

根据推流式超临界水氧化 (SCWO)反应器处理有机废水的动力学方程式 ,结合近年来超临界水氧化降解各种有机废水的实验研究情况 ,对超临界水氧化有机废水的反应动力学影响因素进行了综合分析 ,同时指出了该技术在有机废水处理中的应用优势和存在问题。     

水中有机污染物超声强化氧化技术研究进展

超声波技术在化学、环境、制药以及生物等领域有着广阔的应用前景。在降解水中难降解有机污染物方面 ,超声强化氧化技术有一定优势 ,降解效果显著 ,符合绿色环保技术的要求。超声强化氧化技术主要可分为超声空化技术、超声强化化学 (催化 )氧化技术、超声强化电化学 (催化 )氧化技术、超声强化光化学 (催化 )氧化技术、超声 生物降解等几大类 ,本文对各类技术的优缺点进行了评述。     

Fenton氧化与生化组合技术处理油田采油废水的研究

采用Fenton氧化与生化组合技术处理生物难降解的采油废水的研究结果表明 ,Fenton氧化技术不但对采油废水中有机质有较好的去除率 ,而且大大地改善了废水的可生化性 ,在H2 O2 的投加浓度和Fe2 + 与H2 O2 的摩尔比分别为10mmol/L和 0 .1的条件下 ,经过 30min氧化后可使废水BOD值由原来的 5mg/L上升至 4 0mg/L ;同时随着氧化时间的延长 ,废水中残余的有机物分子量逐渐降低。 30min氧化后的废水经过生物处理 ,其出水COD值为 10 2mg/L ,可以满足国家综合污水外排标准 ,经济分析结果表明 ,该技术处理采油废水的运行成本为 1 4 7元 /t。这一技术在解决石油行业采油废水的外排达标方面具有很好的应用前景。     

中央空调净化系统的改进措施

介绍了室内空气净化技术及其特点。针对中央空调系统的特点，提出了将活性炭吸附技术、TiO2光催化技术与静电除尘技术结合的静电活性炭-TiO2光催化复合技术，这一组合技术可能成为今后空调系统空气净化系统重要的改进措施。     

中央空调净化系统的改进措施

介绍了室内空气净化技术及其特点.针对中央空调系统的特点,提出了将活性炭吸附技术、TiO2光催化技术与静电除尘技术结合的静电活性炭-TiO2光催化复合技术,这一组合技术可能成为今后空调系统空气净化系统重要的改进措施.     

Destruction of diphenylarsine chloride (CLARK I) with activated ozone

The new technology of Plasmazon® uses the extremely strong oxidation of radicals to break up the compocunds of organic connections, e.g. chemical warfare agents like Clark I. In making a comparison of oxidation to normal ozone, the factor of the Plasmazon® -technology is available up to 10³. The investigation in an experimental test shows that it is possible to destroy the warfare agent character of Clark I. As the possibility of a large-lot application this technology is the method of choice for other chemical or biological warfare agents.     

Advanced oxidation processes for the treatment of olive-oil mills wastewater

In this work, the treatment of an actual industrial waste with three advanced oxidation processes (AOP) has been studied: conductive-diamond electrooxidation (CDEO), ozonation and Fenton oxidation. The wastewater comes from olive-oil mills (OMW) and contains a COD of nearly 3000 mg dm(-3). CDEO allowed achieving the complete mineralization of the waste with high current efficiencies. Likewise, both ozonation and Fenton oxidation were able to treat the wastes, but they obtained very different results in terms of efficiency and mineralization. The accumulation of oxidation-refractory compounds as final products excludes the use of ozonation and Fenton oxidation as a sole treatment technology. This confirms that besides the hydroxyl-radical mediated oxidation, CDEO combines other important oxidation processes such as the direct electro-oxidation on the diamond surface and the oxidation mediated by other electrochemically formed compounds generated on this electrode.     

A Field Demonstration of the UV/Oxidation Technology to Treat Ground Water Contaminated with VOCs

This paper presents the Geld evaluation results of the ultraviolet radiation (UV)/oxidation technology developed by Ultrox International, Santa Ana, California. The Geld evaluation was performed at the Lorentz Barrel and Drum (LB&D) site in San Jose, California, under the Superfund Innovative Technology Evaluation program in February and March of 1989.

The UV/oxidation technology uses UV radiation, ozone, and hydrogen peroxide to oxidize organic contaminants present in water. At the LB&D site, this technology was evaluated in treating ground water contaminated with volatile organic compounds (VOCs). The Ultrox system achieved VOC removals greater than 90 percent. Most VOCs were removed through chemical oxidation. However, for a few VOCs, such as 1, 1, 1-trichloroethane and 1, 1-dichloroethane, stripping also contributed toward removal. The treated ground water met the applicable discharge standards for discharge into a local waterway at 95 percent confidence level. There were no harmful air emissions to the atmosphere from the Ultrox system, which is equipped with an off-gas treatment unit.     

焦化废水脱氮处理技术进展

评述了焦化废水脱氮处理方法,包括蒸氨法、折点加氯法、吸附法、催化湿式氧化法、烟道气治理法及生物法,介绍了传统处理方法的改进措施及其适用情况,并对生物脱氮领域最新研究理论及工艺发展方向进行了介绍。     

我国表面活性剂LAS废水的处理技术进展

概述了我国表面活性剂LAS废水处理中的常用方法 ,以LAS的最终去向将处理方法分为破坏性和非破坏性两大类 ,对各类方法的应用现状及发展方向进行了分析和评价 ,认为应从回收和彻底氧化分解两种途径处理该类废水。     

微电解-催化氧化-A/O法处理苯硫酚废水

采用微电解—催化氧化—A／O工艺处理苯硫酚生产废水，结果表明，该工艺对CODcr、石油类、挥发酚、苯、甲苯各项污染物指标均有较好的去除效果，整个工艺运行稳定。只要控制好各个处理环节，出水水质能达到国家一级排放标准。     

硫化氢吸收净化技术研究进展

综合评述了硫化氢气体的吸收净化方法及特点。净化方法分为干法和湿法两大类。大部分干法脱硫剂均不能再生 ,硫容量相对较低 ,主要适于气体精细脱硫。吸收净化工艺能适应较高负荷的脱硫要求 ,应用面广 ,其中尤以吸收氧化法较突出。指出吸收氧化法中的铁基工艺尽管在工艺控制方面还有一定难度 ,但仍可作为一种有较大发展前途的方法。     

Use of electrochemical technology to increase the quality of the effluents of bio-oxidation processes. A case studied

In this work, it has been studied the use of conductive-diamond electrochemical oxidation (CDEO) as a refining technology to assure the quality of the effluents of door manufacturing processes (DMP). To do this, the raw effluents of these factories have been treated by a combination of physicochemical, biological and CDEO treatments. CDEO was found to be a feasible alternative to the refinement of a wooden DMP waste. It can successfully decrease the organic load of the effluents of the biological oxidation with low energy requirements. In addition, in case of incidents in the biological process, CDEO can treat successfully the effluents of the coagulation process. The effluents of the biological treatment have also been treated by CDEO in order to check the possible use of electrochemical technology to increase the biodegradability of the effluents and their possible recycle to the biological treatment. Unfortunately, electrochemical technology was found to be not adequate to increase the biodegradability of the effluents of a biological treatment. The hard oxidation conditions generated during CDEO do not lead to the accumulation of intermediates but to the almost direct formation of carbon dioxide. Lowering the current density or changing the electrodes can not enhance the biodegradability of the effluents of an electrochemical cell.     

臭氧高级氧化技术在废水处理中的应用

综述了近年来迅速发展的臭氧高级氧化技术，包括臭氧氧化技术、臭氧／过氧化氢、臭氧／紫外辐射、臭氧与活性炭协同作用等技术，介绍了各种高级氧化技术的基本原理及在废水处理中的应用，并对其特点进行了评述。     

Cold plasma technology: advanced and sustainable approach for wastewater treatment

Environmental Science and Pollution Research - Cold plasma has been a potent energy-efficient and eco-friendly advanced oxidation technology which has gained attention in recent decades as a...     

MnO2催化Fenton试剂降解苯酚废水

实验对MnO2催化Fenton试剂氧化高浓度苯酚废水的动力学特性和去除效果进行了研究。结果表明,MnO2可以提高Fenton试剂体系对苯酚的降解率以及COD的去除率;Fenton试剂以及MnO2催化Fenton试剂氧化苯酚废水体系中苯酚的降解都符合拟一级动力学模型。在MnO2催化Fenton试剂氧化体系中,苯酚的降解速率常数有明显提高,反应活化能也有所降低,说明MnO2的加入可以使反应容易进行。废水降解前后紫外可见吸收光谱和红外谱图表明,Fenton试剂法将苯酚可能降解为羧酸、烯烃等有机物中间体。     

浅谈ANAMMOX反应的启动研究

厌氧氨氧化（ANAMMOX）是一种新型的生物脱氮技术,在废水处理方面具有良好的应用前景。但由于厌氧氨氧化细菌生长缓慢,倍增时间长达11d,因此,厌氧氨氧化反应器的启动成为众多学者的研究对象。文中概述了近年来的学者们在研究厌氧氨氧化启动时,以选择不同反应器、接种不同污泥和采用不同方法,富集培养的过程及经验。同时通过分析启动过程中各种氮的变化情况,来进一步理解启动过程。     

光化学氧化技术去除水中有机污染物的试验研究

以自来水为试验对象，对紫外－臭氧和紫外－二氧化钛两种光化学氧化技术对水中微量有机污染物的去除进行了试验研究，结果表明两种工艺的UVA（紫外吸光度）去除率均达到80％以上，对氯仿的去除也均能达到国家饮用水标准。在此基础上，自制了一种催化剂膜，并取得了预期的处理效果，有望在新型净水技术及设备的研制和开发上得到应用。     

Destruction of Volatile Organic Compounds Using Catalytic Oxidation

Catalytic oxidation is an air pollution control technique in which volatile organic compounds (VOCs) and vapor-phase air toxics in an air emission stream are oxidized with the help of a catalyst Design of catalytic systems for control of point source emissions is based on stream-specific characteristics and desired control efficiency. This paper discusses the key emission stream characteristics and VOC characteristics that affect the applicability of catalytic oxidation. The application of catalytic oxidation technology to four types of air emission sources is discussed: (1) groundwater stripping operations; (2) graphic arts facilities; (3) flexographic printing plants; and (4) latex monomer production. The characteristics of each of these emissions are discussed along with the catalytic technology used to control these emissions.