兰州市空气污染物的变化规律与特征

论述了兰州市 1 993～ 1 996年间 ,室内外空气污染物 ,特别是一些非常规监测指标 ,如 PM1 0 、PM2 .5～ 1 0 和 PM2 .5 的污染规律和分布特征。结果表明兰州市仍以尘污染为主 ,PM1 0 在 TSP中平均占 3 3 %左右 ,而 PM2 .5 占了 PM1 0 的大部分     

An air quality balance index estimating the total amount of air pollutants at ground level

A new index named Air Quality Balance Index (AQBI), which is able to characterise the amount of pollution level in a selected area, is proposed. This index is a function of the ratios between pollutant concentration values and their standards; it aims at identifying all situations in which there is a possible environmental risk even when several pollutants are below their limit values but air quality is reduced. AQBI is evaluated by using a high-resolution three-dimensional dispersion model: the air concentration for each substance is computed starting from detailed emissions sources: point, line and area emissions hourly modulated. This model is driven with accurate meteorological data from ground stations and remote sensing systems providing vertical profiles of temperature and wind; these data are integrated with wind and temperature profiles at higher altitudes obtained by a Local Area Model. The outputs of the dispersion model are compared with pollutant concentrations provided by measuring stations, in order to recalibrate emission data. A three-dimensional high resolution grid of AQBI data is evaluated for an industrial area close to Alessandria (Northern Italy), assessing air quality and environmental conditions. Performance of AQBI is compared with the Air Quality Index (AQI) developed by the U.S. Environmental Protection Agency. AQBI, computed taking into account all pollutants, is able to point out situations not evidenced by AQI, based on a preset limited number of substances; therefore, AQBI is a good tool for evaluating the air quality either in urban and in industrial areas. The AQBI values at ground level, in selected points, are in agreement with in situ observations.     

Inventory of emissions of primary air pollutants in the city of Kocaeli, Turkey

This study aims to obtain a reliable inventory of the emission rates of the principal air pollutants including PM, SO2, NOx) and CO in Kocaeli, Turkey. In the first stage, the pollutant sources classified as point, area and line sources are determined in the area. Then the annual emission rates of the pollutants released from these sources are estimated by the emission factors given by USEPA and CORINAIR. Results show that the annual emission rates for PM, SO2, NOx) and CO are 2195 tons, 5342 tons, 14632 tons and 23095 tons, respectively. On the other hand, the pollutant group with the highest contribution to total emission rate is determined as the point sources for NOx, which is responsible for 73% of total NOx emission, while it is the area sources for PM, SO2 and CO with the contribution percentages of 75, 76 and 69, respectively.     

Persistent organic pollutants in European background air: derivation of temporal and latitudinal trends

Data are presented for polynuclear aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), polybrominated diphenyls ethers (PBDEs) and selected organochlorine compounds (OCs) in passive air samplers (PAS) along a rural/remote latitudinal transect from southern UK to northern Norway during 2002-2004. This study is part of an ongoing campaign, using semi-permeable membrane devices (SPMDs) as PAS over two year intervals since 1994. Data for PCBs, selected OCs and PBDEs are compared with that from previous campaigns. Absolute sequestered amounts of selected PCB congeners have decreased in a first order fashion between 1994-2004, with an average atmospheric clearance rate of 4.1 +/- 0.6 years and continue to fractionate with latitude. HCB has also declined between 1998-2004, with a clearance rate of 6 +/- 2.4 years. Data on DDT and its breakdown products indicate little fresh release in Europe. Comparison of PBDEs in 2000-02 and 2002-04 indicates site differences, generally with increases at UK sites and decreases in Norway. BDE-28, 47 and 49 decreased with increasing latitude (p < 0.04), while the other congeners did not show any significant latitudinal dependence. Transect data are presented for PAHs the first time. Three- and 4-ringed compounds dominated the mixture present in the SPMD. The PAH composition of the SPMDs at site 3 was compared to the average composition taken by active sampling at the same site. SPMD performance for sampling PAHs leaves many uncertainties, but they can be successfully used to semiquantitatively detect PAHs in the atmosphere. Fluorene and phenanthrene increased with latitude (p > 0.05), while 1-methylphenanthere, fluoranthene, benzo[b]fluoranthene and indeno[123-cd]pyrene decreased. Results are discussed in terms of sources, long-range atmospheric transport, global fractionation and clearance processes.     

Trends in background levels of persistent organic pollutants at Kosetice observatory, Czech Republic.1) Part I. Ambient air and wet deposition 1996-2005

Kosetice observatory is a facility of the Czech Hydrometeorological Institute, which is a part of the European Monitoring and Evaluation Programme (EMEP) network. Persistent organic pollutants (POPs: PCBs, DDTs, HCHs, PAHs) have been monitored in all environmental matrices using the integrated monitoring approach. Generally, the atmospheric levels of POPs in this Central European background station (mean values: 0.115 ng m(-3) for SigmaPCBs, 0.040 ng m(-3) for SigmaDDTs, 0.077 ng m(-3) for SigmaHCHs, and 17 ng m(-3) for SigmaPAHs) are significantly higher than those in other EMEP stations localized mostly in Northern and Western Europe. Long-term trends of POP concentrations in the ambient air and wet deposition are presented in this article and they show a slow decline in the last decade for most of the investigated compounds. Temporally increased levels of certain chemicals were associated with some local climatic (floods) or socio-economic (fuel prices) factors.     

Methods used for estimating fugitive emission rates of air pollutants and their application in China

This paper presents a series of methods for measuring and estimating fugitive emission rates, which have been widely applied in environmental impact assessment and establishing national emission standard and health protection zone (buffer zone) standards in China.     

Variation in spatial pattern of criteria air pollutants before and during initial rain of monsoon

Spatial patterns of various criteria air pollutants,like SO₂, NO₂, O₃, and TSP were studied atShahdara National Ambient Air Quality Monitoring stationin Delhi (India) in July 1999. The minimum pollutantconcentrations were observed during morning hours,whereas the highest concentrations were found during thelate night hours, which seem to be related with thevehicular emission. Pre-monsoon daily ambient airquality spatial pattern was compared with the spatialpattern during initial and subsequent rain shower ofmonsoon. These spatial patterns were found to beessentially the same before and during rain, however asignificant decrease in SO₂, NO₂ and TSPconcentrations (40-45%) was observed after initial andsubsequent rains of the monsoon, demonstrating theimportance of rainfall in the scavenging of thesecriteria air pollutants.     

Novel integrative passive samplers for the long-term monitoring of semivolatile organic air pollutants

Two types of passive sampler were developed for the long-term monitoring of semivolatile organic compounds (SOCs) in air. They consist of poly(dimethylsiloxane) (PDMS)-coated stir bars (type A) or silicone tubing (type B), acting as a solid receiving medium, enclosed in a heat-sealed low-density polyethylene (LDPE) membrane. These samplers combine the advantages of integrative passive sampling with those of analysing accumulated analytes by thermodesorption-GC-MS, whilst avoiding the use of solvents and expensive sample preparation and cleanup steps. The performance of these samplers was investigated for the integrative sampling of SOCs, including alpha- and gamma-hexachlorocyclohexanes, hexachlorobenzene, 2,4,4'-trichlorobiphenyl, 2,2',5,5'-tetrachlorobiphenyl and fluoranthene, in laboratory exposure experiments under controlled conditions. For both types of sampler, the uptake of all the analytes investigated was linear over an exposure period of 15 days. The sampling rates calculated ranged from 70 to 320 ml h(-1) (sampler A) and 630 to 4300 ml h(-1) (sampler B). The passive samplers are able to detect low time-weighted average air concentrations in the pg m(-3) range. The small, robust and inexpensive sampling devices were tested successfully for the long-term air monitoring of semivolatile organic pollutants in a polluted area over an exposure period of up to 28 days.     

Deterioration of Jerusalem limestone from air pollutants; field observations and laboratory simulation

Samples of Jerusalem limestones were exposed to high levels of common air pollutants (SO₂, NO) in the presence and absence of hydrocarbon, water vapor and ultra-violet light. After exposure, the outer layers were shaved off and analyzed for sulfate and nitrate. The results revealed that even after one day of exposure significant concentrations of CaSO₄ and Ca(NO₃)₂ could be detected in the external 40 m layers. Sulfate formation was found to relate very strongly to relative humidity with nearly undetectable production at humidities below 10%. Nitrate formation was found to relate to UV light and to a limited extent to the presence of hydrocarbon but was unchanged at different humidities. Surface samples were taken from different sites of the old city wall and were also analyzed for the same substances. The data showed that the concentrations of especially CaSO₄, and to a limited extend Ca(NO₃)₂, measured at various points along the city walls were higher than the expected values extrapolated from laboratory simulations. The elevated pollution content may be explained in part due to the deposition of transported ions, especially sulfate, onto the stone surface. It was concluded that although air pollution may not cause any structural damage in the foreseeable future it definitely deteriorates the fine details of the ancient monument.     

Use of real-time sensors to characterise human exposures to combustion related pollutants

Concentrations of black carbon and nitrogen dioxide have been collected concurrently using a MicrAeth AE-51 and an Aeroqual GSS NO(2) sensor. Forty five sampling events with a duration spanning between 16 and 22 hours have collected 10,800 5 min data in Birmingham (UK) from July to October 2011. The high temporal resolution database allowed identification of peak exposures and which activities contributed the most to these peaks, such as cooking and commuting. Personal exposure concentrations for non-occupationally exposed subjects ranged between 0.01 and 50 μg m(-3) for BC with average values of 1.3 ± 2.2 μg m(-3) (AM ± SD). Nitrogen dioxide exposure concentrations were in the range 相似文献   

Phthalate levels in Norwegian indoor air related to particle size fraction

Phthalates are found in numerous consumer products, including interior materials like polyvinyl chloride (PVC). Several studies have identified phthalates in indoor air. A recent case-control study demonstrated associations between allergic symptoms in children and the concentration of phthalates in dust collected from their homes. Here we have analyzed the content of selected phthalates in particulate matter (PM): PM(10) and PM(2.5) filter samples collected in 14 different indoor environments. The results showed the presence of the phthalates di-n-butyl phthalate (DBP), butyl benzyl phthalate (BBP), dicyclohexyl phthalate (DCHP) and diethyl hexyl phthalate (DEHP) in the samples. The dominating phthalate in both PM(10) and PM(2.5) samples from all locations was DBP. More than a 10-fold variation in the mean concentration of total phthalates between sampling sites was observed. The highest levels of total phthalates were detected in one children's room, one kindergarten, in two primary schools, and in a computer room. The relative contribution of total phthalates in PM(10) and PM(2.5) was 1.1 +/- 0.3% for both size fractions. The contribution of total phthalates in PM(2.5) to total phthalates in PM(10) ranged from 23-81%, suggesting different sources. Of the phthalates that were analyzed in the PM material, DBP was found to be the major phthalate in rubber from car tyres. However, our analyses indicate that tyre wear was of minor importance for indoor levels of both DBP as well as total phthalates. Overall, these results support the notion that inhalation of indoor PM contributes to the total phthalate exposure.     

Influence of aerosol spectrum and air pollutants on fog formation in urban environment of megacity Delhi, India

Urban areas are facing increasing fog frequencies that may result due to increased air pollution emanating from variety of sources. The increased pollution levels may lead to the atmospheric reactions resulting into the formation of secondary pollutants that may also lead to increased aerosol number concentrations (ANC) in the atmosphere. This could cause enhanced water aerosols in the presence of favourable meteorological conditions and high relative humidity. This study deals with the atmospheric pollution and visibility during winter season of megacity Delhi in order to assess the relationship between the two specifically during fog episodes. Thus, this study analyses the levels of air pollutants, aerosol spectrum and meteorological conditions during one week each in the winter season of the years 2004 and 2006 in order to have an improved understanding of their role in fog formation in mega-city Delhi. More than 300 h of measurements which included episodes of dense, thick and moderate fogs of about 25 h, were studied. The measurements cover most of the accumulation mode and greater size spectrum of aerosols. Thus, the analysis is performed for the entire period, specifically, before the fog sets up, during and afterwards. In general, the relatively small variations in number concentration show larger variations in visibility prior and post dense fog formation than during dense fog episodes. Preliminary analysis of monthly averaged RSPM (Respirable Suspended particulate Matter or PM(10)) concentration values for four winter months for a period of 6 years (1996-2001) and visibility did not show a good correlation with total occurrences of fog. However, daily averaged RSPM concentration showed a good correlation with the occurrences of thick fog. Diurnal variation of Sulfur-dioxide and Nitrogen dioxide were found to have inverse relationship with visibility during fog which may be due to formation of secondary pollutants such as sulfate and to a lesser extent nitrates. Amongst, the daily averaged concentrations of all the criteria pollutants, RSPM was found to be best correlated with the fog in comparison to other pollutants.     

Spatial variability of air pollutants in the city of Taranto, Italy and its potential impact on exposure assessment

Epidemiological studies typically use monitored air pollution data from a single station or as averaged data from several stations to estimate population exposure. In industrialized urban areas, this approach may present critical issues due to the spatial complexities of air pollutants which are emitted by different sources. This study focused on the city of Taranto, which is one of the most highly industrialized cities in southern Italy. Epidemiological studies have revealed several critical situations in this area, in terms of mortality excess and short-term health effects of air pollution. The aims of this paper are to study the variability of air pollutants in the city of Taranto and to interpret the results in relation to the applicability of the data in assessing population exposure. Meteorological and pollution data (SO2, NO2, PM10), measured simultaneously and continuously during the period 2006–2010 in five air quality stations, were analyzed. Relative and absolute spatial concentration variations were investigated by means of statistical indexes. Results show significant differences among stations. The highest correlation between stations was observed for PM10 concentrations, while critical values were found for NO2. The worst values were observed for the SO2 series. The high values of 90th percentile of differences between pairs of monitoring sites for the three pollutants index suggest that mean concentrations differ by large amounts from site to site. The overall analysis supports the hypothesis that various parts of the city are differently affected by the different emission sources, depending on meteorological conditions. In particular, analysis revealed that the influence of the industrial site may be primarily identified with the series of SO2 data which exhibit higher mean concentration values and positive correlations with wind intensity when the monitoring station is downwind from the industrial site. Results suggest evaluating the population exposure to air pollutants in industrialized cities by taking into account the possible zones of influence of different emission sources. More research is needed to identify an indicator, which ought to be a synthesis of several pollutants, and take into account the meteorological variables.     

Public perceptions of air quality and quality of life in urban and suburban areas of London

A comparative study was undertaken at two different sites (one urban, one suburban) in Greater London in order to examine whether there was a relationship between publicly available air quality data and the public's perception of air quality. Perceptions of air quality and its role as a potential quality of life indicator was also investigated. A total of 200 people were interviewed in Wood Green and Wimbledon in 1999 and air quality data were obtained simultaneously from the nearest appropriate monitoring station. The study has enabled a comparison between the public's perception of air quality and the actual monitored concentration values. The survey results reveal how seriously the public regards air pollution from road traffic in terms of their quality of life and identifies the attitudes of the public to nuisance from road traffic. The results reveal that the public's perception of air quality is not a reliable indicator of the actual levels of air pollution in their area. The results also revealed that air pollution issues generated as a result of road traffic are of high importance in terms of people's quality of life when compared to other aspects of their quality of life. The study revealed that residents in the urban area (Wood Green) were more disturbed by road traffic than residents in the suburban area (Wimbledon). Out of all the disturbances listed, it was found that residents were more disturbed by vehicle-derived fumes, dust and dirt than other aspects of road traffic related nuisance. The TELETEXT/CEEFAX service on air quality was little used by the public as a means of obtaining information on air pollution.     

Real time remote monitoring of air pollutants and their online transmission to the web using internet protocol

Recent advances in both information and sensor technologies have enabled the development of Real Time Remote Monitoring (RTRM) capabilities for environmental management. An online and real time remote monitoring system for air pollution has been designed and installed at a traffic police station at Punjagutta in Hyderabad, India. The system is optimized using electrochemical sensors and a real time particulate matter analyzer. The system also monitors meteorological parameters such as temperature, humidity, rainfall, barometric pressure, wind speed and wind direction. The system periodically monitors both pollution and meteorological parameters at pre- programmed intervals of hr during peak periods and 1 hr during non peak periods of the day and continuously uploads to a predestinated web site (www.appcb.org/home.htm) using File Transfer Protocol. The web site renders a quick, simple and graphical display of air pollution levels and meteorological parameters and their significance to humans. The present paper highlights design considerations of a pollution monitoring system, system hardware and software requirements and practical limitations and future directions for real time remote monitoring of air pollution.     

Occupational and indoor air exposure to persistent organic pollutants: a review of passive sampling techniques and needs

Exposure to persistent organic pollutants (POPs) and related compounds such as PCBs, brominated flame retardants, organochlorine pesticides and PAHs is regarded as an important environmental risk factor for humans. Recently concerns about POPs resulted in the international protocol called the Stockholm Convention on POPs. Air quality standards (indoor, outdoor and occupational) for PAHs and other POPs will also be applied in the EU in the future. This will bring requirements for monitoring, to check for compliance and to reduce human exposures to POPs. This can occur from point sources and in various microenvironments, indoors, outdoors and in workplaces. Monitoring can be undertaken either by an active (pumped) method or using a passive (diffusive) air sampling (PAS) device. To date, PAS for POPs have mainly been used as integrating (long-term) samplers for ambient (outdoor) air. However, there are several reasons to develop PAS for monitoring of POPs in occupational and indoor environments. We discuss the potential advantages, limitations and developments needed, so that PAS can be used reliably and routinely indoors and in occupational settings for POPs.     

Air pollutants and the characterization of the organic content of aerosol particles in a mixed industrial/semi-rural area in central Italy

Both regulated and unregulated air pollutants were detected during an intensive seasonal sampling campaign in a mixed industrial/semi-rural area on the outskirts of Rome, Italy, at two sites located opposite a hospital waste incinerator, downwind according to the direction of the prevailing local winds. Concentrations of pollutants were significantly lower than in urban atmospheres. The composition of particulate organic material indicated a heavy biogenic impact, accompanied by a lower contribution from petroleum-related processes. Both PAH and nitro-PAH group compositions of particulates were used to assess the nature and relative importance of sources. Both sites showed that different and diffuse sources contributed to local pollution with a significant contribution from traffic, proving that the hospital waste incinerator was not the main pollution source in this area. Among unregulated compounds, a series of positional isomers of nitro-PAHs and other organic compounds associated with particulate matter were investigated. In particular, 1- and 3-nitrophenanthrene identification was carried out, and they proved to be the most abundant nitro-PAHs.     

Migration of pollutants in groundwater. II. adsorbable pollutants and numerical dispersion reduction

We discuss here the partial differential equations governing the migration of a decomposing pollutant adsorbing according to a Langmuir isotherm and undergoing 2-dimensional flow in a saturated aquifer. The equation governing the mass transfer of the pollutant to the surfaces within the aquifer are solved in closed form, permitting the use of larger values of the time increment t in the numerical integration of the dispersion-advection equation governing the behavior of the dissolved pollutant. In this numerical integration transverse numerical dispersion is eliminated by using conformal coordinates (velocity potential and stream function), and longitudinal numerical dispersion is very substantially reduced by use of an asymmetrical 4-point formula to represent the advection term. Some representative results are given as contour maps. The mass transfer rate coefficient is estimated as the least positive eigenvalue of a diffusion problem.