Review of Pesticide Retention Processes Occurring in Buffer Strips Receiving Agricultural Runoff1

Arora, Kapil, Steven K. Mickelson, Matthew J. Helmers, and James L. Baker, 2010. Review of Pesticide Retention Processes Occurring in Buffer Strips Receiving Agricultural Runoff. Journal of the American Water Resources Association (JAWRA) 46(3):618-647. DOI: 10.1111/j.1752-1688.2010.00438.x Abstract: Review of the published results shows that the retention of the two pesticide carrier phases (runoff volume and sediment mass) influences pesticide mass transport through buffer strips. Data averaged across different studies showed that the buffer strips retained 45% of runoff volume (ranging between 0 and 100%) and 76% of sediment mass (ranging between 2 and 100%). Sorption (soil sorption coefficient, K_oc) is one key pesticide property affecting its transport with the two carrier phases through buffer strips. Data from different studies for pesticide mass retention for weakly (K_oc < 100), moderately (100 < K_oc < 1,000), and strongly sorbed pesticides (K_oc > 1,000) averaged (with ranges) 61 (0-100), 63 (0-100), and 76 (53-100) %, respectively. Because there are more data for runoff volume and sediment mass retention, the average retentions of both carrier phases were used to calculate that the buffer strips would retain 45% of weakly to moderately sorbed and 70% of strongly sorbed pesticides on an average basis. As pesticide mass retention presented is only an average across several studies with different experimental setups, the application of these results to actual field conditions should be carefully examined.     

Impact of Vegetative Cover on Runoff and Soil Erosion at Hillslope Scale in Lanjaron, Spain

Soil loss and surface runoff patterns over a four-year period (1997–2000) were studied in erosion plots from three hillslopes under different vegetative covers (Rosmarinus officinalis, Triticum aestivum and natural-spontaneous vegetation) in Lanjaron (Alpujarras) on the south flank of the Sierra Nevada of southeast Spain. The erosion plots were located on the hillslopes at 35.5% incline, at 1,480 m in altitude and with 41.8 m² (21 m×1.9 m) in area. The vegetative covers were tested for effectiveness in controlling the surface runoff and soil loss production. The highest runoff and erosion values, ranging from 114.1 to 1.7 mmyr^–1 and from 14,564.3 to 6.6 kgha^–1yr^–1, respectively, over the entire study period, were measured under the Triticum aestivum. In the Rosmarinus officinalis, runoff ranged from 7.9 to 1.3 mmyr^–1 and erosion from 156.4 to 2.3 kgha^–1yr^–1, while on the hillslope under natural-spontaneous vegetation, runoff ranged from 4.4 to 0.9 mmyr^–1 and erosion from 322.3 to 2.2 kgha^–1yr^–1. According to the results the vegetative covers of Rosmarinus officinalis and natural-spontaneous vegetation reduced the soil losses by 99 and 98%, with respect to the Triticum aestivum, and the runoff losses by 94 and 96%, respectively. Also, the Rosmarinus officinalis and natural-spontaneous plants influenced infiltration by intercepting much of the rainfall water respect to the Triticum aestivum. Monitoring allowed more direct linkages to be made between management practices and their impacts on runoff and soil erosion, thereby enabling to identify problems and take appropriate preventive measures to improve the management practices.     

Exposure Times to the Spring Atrazine Flush Along a Stream-Reservoir System1

Stoeckel, James A., Jade Morris, Elizabeth Ames, David C. Glover, Michael J. Vanni, William Renwick, and María J. González, 2012. Exposure Times to the Spring Atrazine Flush Along a Stream-Reservoir System. Journal of the American Water Resources Association (JAWRA) 48(3): 616-634. DOI: 10.1111/j.1752-1688.2011.00633.x Abstract: We used enzyme-linked immunosorbent assay to examine reservoir-mediated shifts in spring to fall exposure of aquatic organisms to the spring atrazine pulse over four years in a Midwestern stream-reservoir system. Peak atrazine concentrations in the major inflowing stream exceeded 10 μg/l in all four years. The reservoir had a beneficial effect in two of four years by diluting atrazine below the 10 μg/l threshold. However, during the other two years, exposure times above 10 μg/l were approximately doubled in the reservoir compared to the major inflowing stream. Thresholds of 3 and 5 μg/l were exceeded during all four years in the reservoir. The uplake and downlake reservoir sites were four to five times more likely to exceed these thresholds and aquatic organisms were subjected to longer exposure times above these thresholds compared to the inflowing stream. Release of elevated atrazine concentrations from the reservoir extended exposure times in the outflowing stream. This effect was most pronounced just below the dam. Aquatic organisms upstream of the reservoir were most likely to experience acute exposures whereas organisms within and immediately downstream of the reservoir were more likely to experience chronic exposures. The ubiquity of reservoirs and the annual spring herbicide flush highlight the importance of considering the presence and relative location of reservoirs when assessing risk to aquatic communities as well as locations of drinking water intakes.     

Comparison of Indexes for Prioritizing Placement of Water Quality Buffers in Agricultural Watersheds1

Dosskey, Michael G. and Zeyuan Qiu, 2011. Comparison of Indexes for Prioritizing Placement of Water Quality Buffers in Agricultural Watersheds. Journal of the American Water Resources Association (JAWRA) 47(4):662‐671. DOI: 10.1111/j.1752‐1688.2011.00532.x Abstract: Five physically based, spatially distributed, empirical indexes were compared for the degree to which they identified the same or different locations in watersheds where vegetative buffers would function better for reducing agricultural nonpoint source pollution. All five indexes were calculated on a 10 m × 10 m digital elevation grid on agricultural land in the 144‐km² Neshanic River watershed in New Jersey. The indexes included the topography‐based Wetness Index (WI) and Topographic Index (TI) and three soil survey‐based indexes (sediment trapping efficiency [STE], water trapping efficiency [WTE], and groundwater interaction [GI]). Results showed that each index associated higher pollution risk and mitigation potential to a different part of the landscape. The WI and TI identified swales and riparian areas where runoff converges, whereas STE and WTE identified upland sites. The STE and WTE lack the fine scale of slope resolution and the accounting for convergent runoff patterns that can be important for properly locating buffers in some watersheds. The GI index indicates the existence of a shallow water table but the correspondence with WI‐ and TI‐identified sites was only modest. For watersheds where pollutant loading is generated by both saturation‐excess (emphasized by TI and WI) and infiltration‐excess processes (emphasized by STE and WTE), the indexes could be complementary. However, techniques would be needed for properly apportioning priority among sites identified by each index.     

Techniques to Reduce the Impact of Asulam Drift from Helicopter Sprayers on Native Vegetation

Asulam is often applied from the air to control bracken. This herbicide affects other ferns and spray drift could affect their survival. This paper discusses the use of bioassays to assess drift (a) spatially around a single bracken patch, (b) downwind from sprayed areas, and (c) spatially in undulating terrain and with different vegetation cover types. The aims were to develop policies to protect sensitive habitats. It is suggested that “no-spray” buffer zones in excess of 160–180 m are needed to minimise risk. Protection of rare ferns from overstorey vegetation or from steep slopes did not occur. Although less drift was found upwind there was significant damage at the end of the helicopter runs because of errors in switching the sprayer on and off.     

Publicly-provided information in environmental management: incorporating groundwater quality goals into herbicide treatment recommendations

Use of publicly-provided information to promote environmental quality has received somewhat less attention in the environmental management literature than use of other environmental policy tools based on economic incentives such as emissions taxes, subsidies and marketable permits. Yet publicly-provided information may have potential as an environmental policy tool, especially in managing problems of agricultural pollution, due in large part to the existing capability of public information agencies associated with the agricultural research community. Information provided by these agencies is known to be an important factor in decision making in agriculture and may have potential for influencing decisions that relate directly to preserving the integrity of environmental resources. Moreover, this potential may have particular relevance for protecting groundwater quality from agricultural production since the results of contamination are often at least partially internal to the farm decision maker. This paper develops an empirical model to formulate publicly-provided herbicide treatment recommendations designed to protect both the quality of groundwater and the income of farmers. An economic and statistical model of a crop-pest system is used in conjunction with a groundwater loading model to derive the trade-off relationship between producer income and movement of herbicide material through the root zone. The trade-off relationship can provide the basis for formulating herbicide treatment recommendations and can also shed light on appropriate groundwater quality goals.     

Evaluating Cover Crops (Sudex,Sunn Hemp,Oats) for Use as Vegetative Filters to Control Sediment and Nutrient Loading From Agricultural Runoff in a Hawaiian Watershed1

Abstract: A study was conducted to determine the effects of three land covers (sunn hemp –Crotalaria juncea, sudex, a sorghum‐sudangrass hybrid –Sorghum bicolor x S. bicolor var. sudanese, and common oats –Avena sativa) planted as vegetative filter strips on the reduction of sediment and nutrient loading of surface runoff within the Kaika‐Waialua watershed on the island of Oahu, Hawaii. Runoff samples were collected and analyzed for total suspended solids (TSS), total dissolved solids (TDS), phosphorous, and three forms of nitrogen (nitrate, ammonium, total nitrogen). Study results show that during seven out of 10 runoff events, the three cover crop treatments significantly reduced TSS as compared to the fallow treatment. Average removal efficiencies were 85, 77, and 73% for oats, sunn hemp, and sudex, respectively, as compared to the fallow treatment. Nutrient concentrations were low with phosphorous concentrations, lower than 1 (μg/ml) for all treatments, and total nitrogen (TN) concentrations below 7 (μg/ml) except in the sunn hemp treatment, where TN concentrations were less than 10 (μg/ml). Results of analysis of TDS showed that the cover crop treatments did not decrease dissolved solids concentrations in comparison with the fallow treatment. Analysis of nutrient concentrations in runoff samples did not detect any significant decreases in phosphorous, nitrogen, ammonium, or TN concentrations in comparison to the fallow treatment. However, a significant increase in TN concentrations in the sunn hemp treatment was detected and showed the nitrogen fixing capacity of sunn hemp. No treatment effects on runoff volume were detected, and runoff volumes were directly correlated with rainfall amounts showing no crops significantly impacted soil infiltration rates. These results were attributed to extremely low soil hydraulic conductivities (0.0001‐7 cm/day at the soil surface, 15 and 30 cm below the soil surface). This study showed that cover crops planted as vegetative filters can effectively reduce sediment loads coming from idle and fallow fields on moderately steep volcanically derived highly weathered soils.     

GROUND WATER QUALITY IMPLICATIONS OF SOIL CONSERVATION MEASURES: AN ECONOMIC PERSPECTWE1

ABSTRACT: An evaluation of the intermedia movement of pesticides applied under various land management systems already in place, or to be implemented, under the Conservation Reserve and Conservation Compliance programs is presented. The simulation modeling approach followed in this analysis consists of a mathematical programming model and leaching/surface runoff, Pesticide Root Zone Model (PRZM) models. Special care was taken to ensure that the physical model was sensitive to the chemical characteristics of individual pesticides and the important physical changes brought about by different agricultural practices. Results show that, although these programs as now planned, increase farm income and achieve soil conservation goals, they may adversely affect ground water quality. Also, depending on soil and location characteristics, there are tradeoffs between surface and ground water quality implications. Hence, if these programs are to address water quality problems, the recommended practices must be evaluated for their impact on water quality, particularly in potentially vulnerable areas.     

DISSIPATION OF 2,4-D DMA AND BEE FROM WATER,MUD, AND FISH AT LAKE SEMINOLE,GEORGIA1

ABSTRACT: Four 10-ha plots in dense watermilfoil beds of Lake Seminole, Georgia, were each treated with either 2,4-D DMA or 2,4-D BEE at rates of 22.5 and 45 kg a.e./ha. Both formulations were shown to be rapidly converted to the 2,4-D acid form, with no detection of 2,4-D DMA or 2,4-D BEE in the water within less than 24 hours after treatment. The maximum detected 2,4-D concentrations in the high rate 2,4-D DMA and 2,4-D BEE plots were 3.6 and 0.68 mg/, respectively. However, all but seven samples at a 2,4-D BEE plot showed nondetectable herbicide levels by day 7, with all water samples showing nondetectable levels by day 13. Dimethylnitrosamine and 2,4-dichlorophenol, potentially toxic transformation products of the herbicide formulations, were at nondetectable levels in all water samples. Sediment samples showed no significant net accumulation of 2,4-D, 2,4-D BEE, or 2,4-dichlorophenol during the summer monitoring; dimethylnitrosamine remained at nondetectable levels. There was no accumulation of 2,4-D in fish collected from the two plots treated with 2,4-D DMA. Four of 24 game fish from the 2,4-D BEE treatment plots contained low levels of 2,4-D in muscle tissue, with a maximum value of 0.29 μg/g. In contrast, 18 of 20 gizzard shad collected from these plots through day 13 contained detectable 2,4-D in the muscle, with a maximum concentration of 6.9 μg/g. All fish collected after day 13 contained nondetectable levels of 2,4-D. Small decreases in dissolved oxygen and pH, associated with the complete watermilfoil control in all plots, had returned to normal summer values by day 28.