Landfill leachate affects metabolic responses of Zea mays L. seedlings

With an increasing focus on phyto-remediation options for landfill leachate, it is important to understand the responses of plant systems to landfill leachate stress. It is especially important to study the tolerant mechanisms of plant systems. We investigated several physiological changes of Zea mays L. (maize) in response to landfill leachate. Specifically, we investigated growth, chlorophyll content, lipid peroxidation, protein oxidation and activities of antioxidant enzymes. The results indicate that landfill leachate affected the growth and chlorophyll level of maize seedlings. Furthermore, landfill leachate elevated the levels of lipid peroxidation and protein oxidation in leaf tissues in a time-dependent manner, accompanied by the changes in antioxidant status. The physiological responses varied as a function of leachate concentration, and the growth inhibition, chlorophyll content inhibition and oxidative stress occurred after the exposure of higher concentrations of leachate. Higher concentrations of landfill leachate contained higher levels of pollutants. Our results indicate that landfill leachate affected the metabolic responses of plant systems. The risk of pollution occurred mainly in samples of higher concentration. Therefore, the critical aspect of phyto-remediation for landfill leachate is controlling its concentration. In doing so, plant systems may be able to tolerate the environmental stress of landfill leachate.     

Formulation of a landfill pollution potential index to compare pollution potential of uncontrolled landfills

Generally speaking, landfilling is one of the prominent methods of waste disposal around the globe, but some under-developed and developing countries still continue to practice uncontrolled open dumping of waste. These uncontrolled landfills pose a relatively high threat to the various elements of the environment in comparison with the conventional engineered landfills that are used in many developed countries. However, some closed, un-engineered landfills do exist in developing countries. This paper presents a novel approach to compare the pollution potential of uncontrolled landfills using an index. The landfill pollution potential index (LPPI) has been developed using the Delphi technique and is an aggregation of six pollution indices that have already been developed for the quantification of different environmental elements. The LPPI is an increasing scale index, in which a higher index value indicates a higher pollution threat. The LPPI of a landfill in Delhi was calculated and the high LPPI value indicates that the respective landfill poses a significant threat to the environment. The LPPI can be used as an aid to diagnose a landfill's pollution potential relative to other landfills and therefore also to rank remediation investments.     

丹阳北庄生活垃圾填埋场地下水污染分析

建立了针对生活垃圾填埋场地下水污染问题的数学预测模型,以丹阳北庄生活垃圾填埋场工程为例,预测和分析了北庄生活垃圾填埋场渗滤液对地下水的污染。     

Construction and evaluation of simulated pilot scale landfill lysimeter in Bangladesh

This research concentrates the design, construction and evaluation of simulated pilot scale landfill lysimeter at KUET campus, Khulna, Bangladesh. Both the aerobic and anaerobic conditions having a base liner and two different types of cap liner were simulated. After the design of a reference cell, the construction of landfill lysimeter was started in January 2008 and completed in July 2008. In all construction process locally available civil construction materials were used. The municipal solid waste (MSW) of 2800–2985 kg having the total volume of 2.80 m³ (height 1.6 m) and moisture content of 65% was deposited in each lysimeter by applying required compaction energy. In contrast, both the composition in terms of methane (CH₄), carbon dioxide (CO₂) and oxygen (O₂) as well as the flow rate of landfill gas (LFG) generated from MSW in landfill lysimeter were measured and varied significantly in relation to the variation of lysimeter operational condition. Moreover, anaerobic lysimeter-C shows the highest composition of LFG in compare to the anaerobic lysimeter-B due to the providing of lower compaction of cap liner in anaerobic lysimeter-C. Here, it is interesting to note that in absence of compacted clay liner (CCL) and hence percolation of rainwater that facilitates rapid degradation of MSW in aerobic lysimeter-A has resulted in the highest settlement than that of anaerobic landfill lysimeter-B and C. Moreover, in case of anaerobic lysimeter-B and C, the leachate generation was lower than that of aerobic lysimeter-A due to the providing of cap liner in anaerobic lysimeter-B and C, played an important role to reduce the percolation of rainwater. The study also reveals that the leachate pollution index (LPI) has decreased in relation to the increasing of elapsed period as well as the LPI for collection system of aerobic lysimeter-A was higher than that of the collection system of anaerobic lysimeter-B and C. Finally, it can be depicted that LPI for lysimeter was significantly high and proper treatment will be necessary before discharging the lysimeter leachate into the water bodies.     

Evaluating biotoxicity variations of landfill leachate as penetrating through the soil column

Recent studies of leachate-induced ecotoxicity have focused on crude samples, while little attention has been given to changes in biotoxicity resulting from the environmental behavior of landfill leachate. Therefore, we set up a soil column to simulate the underground penetration of leachate into the soil layer, define the rules of migration and transformation of leachate pollutants, and determine the variation in toxicity of landfill leachate during penetration. The results demonstrated that: (1) landfill leachate inhibited the growth and chlorophyll levels, elevated the levels of lipid peroxidation and protein oxidation, and stimulated the antioxidant enzyme activities of barley seedlings. The effects generally displayed a peak value at 12–24 cm, slowly declined at 36–48 cm, and then rapidly decreased with penetrating distance in the column. (2) Statistical correlation analysis of the properties of leachate and the observed biotoxic effects revealed that COD, conductivity and heavy metals (esp. Ni, Mn, Cd) were positively correlated with variations in biotoxicity. (3) The microbial activity of outflowing leachate sampled from the 48 cm port was significantly higher than the activity from succedent ports, and the types of contaminants increased in the leachate outflowing from the same port, implying that microbial behaviors near the 48 cm port could be used to partially evaluate variations in the composition and biotoxicity of landfill leachate. Taken together, the above results illustrate the polluting characteristics of landfill leachate when penetrating a soil column and provide guidance for pollution control and risk assessment of landfill leachate.     

Emissions of C&D refuse in landfills: A European case

A field study was developed in a new landfill for refuse from construction and demolition (C&D) material recovery plants of small size (4 Ha.) in Europe, with the aim of evaluating the liquid and gas emissions in this type of facility at a large scale. It included characterization of the materials, monitoring leachate and gas quantity and composition. Besides thermometers, piezometers and sampling ports were placed in several points within the waste. This paper presents the data obtained for five years of the landfill life. The materials disposed were mainly made up of wood and concrete, similar to other C&D debris sites, but the amount of gypsum drywall (below 3% of the waste) was significantly smaller than other available studies, where percentages above 20% had been reported. Leachate contained typical C&D pollutants, such as different inorganic ions and metals, some of which exceeded other values reported in the literature (conductivity, ammonium, lead and arsenic). The small net precipitation in the area and the leachate recirculation into the landfill surface help explain these higher concentrations, thus highlighting the impact of liquid to solid (L/S) ratio on leachate characteristics. In contrast to previous studies, neither odor nuisances nor significant landfill gas over the surface were detected. However, gas samples taken from the landfill inside revealed sulfate reducing and methanogenic activity.     

Size fractionation of organic matter and heavy metals in raw and treated leachate

This study characterized the organic matter and heavy metals in the leachate from two typical municipal solid waste (MSW) sanitary landfills in China, the recently established (3-year-old) Liulitun landfill and the mature (11-year-old) Beishenshu landfill, using a size fractionation procedure. The organic matter of all raw and treated leachate samples primarily existed in a truly-dissolved fraction with an apparent molecular weight (AMW) of <1 kDa, and its percentage decreased with an increase in overall AMW. The leachate from the newer landfill had a higher percentage of truly-dissolved organic matter. After anaerobic treatment, this leachate had a similar size fraction of organic matter to that seen for the raw leachate of the mature landfill. Biochemical processes had different removal efficiencies for various types of AMW organic matter, and the concentration of moderate AMW organic matter appeared to increase throughout these processes. Most of the heavy metals existed in a colloidal fraction (AMW >1 kDa and particle size <0.45 μm). The behaviors of different species of heavy metals had large variations. The size fractions of heavy metal species were significantly affected by treatment processes and landfill age, except for Zn. The concentration ratio of heavy metals to organic matter was maximal in the colloidal fraction and showed an inverse change to that seen for organic matter concentration changes caused by biochemical processes. Consequently, the pollution levels of heavy metals were substantially increased by treatment processes, although their concentrations decreased.     

The performance of Electro-Fenton oxidation in the removal of coliform bacteria from landfill leachate

Leachate pollution is one of the main problems in landfilling. Researchers have yet to find an effective solution to this problem. The technology that can be used may differ based on the type of leachate produced. Coliform bacteria were recently reported as one of the most problematic pollutants in semi-aerobic (stabilized) leachate. In the present study, the performance of the Electro-Fenton process in removing coliform from leachate was investigated. The study focused on two types of leachate: Palau Borung landfill leachate with low Coliform content (200 MPN/100 m/L) and Ampang Jajar landfill leachate with high coliform content (>24 × 10⁴ MPN/100 m/L). Optimal conditions for the Electro-Fenton treatment process were applied on both types of leachate. Then, the coliform was examined before and after treatment using the Most Probable Number (MPN) technique. Accordingly, 100% removal of coliform was obtained at low initial coliform content, whereas 99.9% removal was obtained at high initial coliform content. The study revealed that Electro-Fenton is an efficient process in removing high concentrations of pathogenic microorganisms from stabilized leachate.     

Application of simulation models to the diagnosis of MSW landfills: an example

Among the landfill simulation programs being developed by several research groups around the world as tools for the management of sanitary landfills is MODUELO, whose second version, MODUELO 2, has been presented elsewhere. It reproduces the operational history of the landfill and its hydrologic and biodegradation processes, allowing the estimation of the flow and pollutants emitted in the leachate and the generated landfill gas over time. This program has been used for a diagnosis study of an existing European MSW landfill. The construction and calibration of the facility's hydrologic model, based on the available data, allowed the detection and quantification of two sources increasing the flows reaching the leachate collection system: a small portion (6-7%) of the runoff over the landfill surface and the contribution of water coming from external hillsides of the same watershed that represent a total surface area of around 20ha. The contrast of the leachate quality (COD, BOD, NH(4)-N and TKN) simulation results and measured data showed the potential of these models for the assessment of other significant aspects in landfill operation such as the potential harnessing of the landfill gas. Nonetheless, in this case as in many others, the accuracy of the simulation results was limited by the scant quality of the available data, which highlights the need for implementing continuous monitoring and characterizing protocols to take advantage of these programs as a tool for landfill optimization.     

Trends in the use of Fenton,electro-Fenton and photo-Fenton for the treatment of landfill leachate

Advanced oxidation processes (AOPs) such as Fenton, electro-Fenton and photo-Fenton have been applied effectively to remove refractory organics from landfill leachate. The Fenton reaction is based on the addition of hydrogen peroxide to the wastewater or leachate in the presence of ferrous salt as a catalyst. The use of this technique has proved to be one of the best compromises for landfill leachate treatment because of its environmental and economical advantages. Fenton process has been used successfully to mineralize wide range of organic constituents present in landfill leachate particularly those recalcitrant to biological degradation. The present study reviews the use of Fenton and related processes in terms of their increased application to landfill leachate. The effects of various operating parameters and their optimum ranges for maximum COD and color removal are reviewed with the conclusion that the Fenton and related processes are effective and competitive with other technologies for degradation of both raw and pre-treated landfill leachate.     

Application of a contaminant mass balance method at an old landfill to assess the impact on water resources

Old and unlined landfill sites pose a risk to groundwater and surface water resources. While landfill leachate plumes in sandy aquifers have been studied, landfills in clay till settings and their impact on receiving water bodies are not well understood. In addition, methods for quantitatively linking soil and groundwater contamination to surface water pollution are required. This paper presents a method which provides an estimate of the contaminant mass discharge, using a combination of a historical investigation and contaminant mass balance approach. The method works at the screening level and could be part of a risk assessment. The study site was Risby Landfill, an old unlined landfill located in a clay till setting on central Zealand, Denmark. The contaminant mass discharge was determined for three common leachate indicators: chloride, dissolved organic carbon and ammonium. For instance, the mass discharge of chloride from the landfill was 9.4 ton/year and the mass discharge of chloride to the deep limestone aquifer was 1.4 ton/year. This resulted in elevated concentrations of leachate indicators (chloride, dissolved organic carbon and ammonium) in the groundwater. The mass discharge of chloride to the small Risby Stream down gradient of the landfill was approximately 31 kg/year. The contaminant mass balance method worked well for chloride and dissolved organic carbon, but the uncertainties were elevated for ammonium due to substantial spatial variability in the source composition and attenuation processes in the underlying clay till.     

Stochastic modelling of landfill leachate and biogas production incorporating waste heterogeneity. Model formulation and uncertainty analysis

A mathematical model simulating the hydrological and biochemical processes occurring in landfilled waste is presented and demonstrated. The model combines biochemical and hydrological models into an integrated representation of the landfill environment. Waste decomposition is modelled using traditional biochemical waste decomposition pathways combined with a simplified methodology for representing the rate of decomposition. Water flow through the waste is represented using a statistical velocity model capable of representing the effects of waste heterogeneity on leachate flow through the waste. Given the limitations in data capture from landfill sites, significant emphasis is placed on improving parameter identification and reducing parameter requirements. A sensitivity analysis is performed, highlighting the model's response to changes in input variables. A model test run is also presented, demonstrating the model capabilities. A parameter perturbation model sensitivity analysis was also performed. This has been able to show that although the model is sensitive to certain key parameters, its overall intuitive response provides a good basis for making reasonable predictions of the future state of the landfill system. Finally, due to the high uncertainty associated with landfill data, a tool for handling input data uncertainty is incorporated in the model's structure. It is concluded that the model can be used as a reasonable tool for modelling landfill processes and that further work should be undertaken to assess the model's performance.     

Toxicological evaluation of the chemical oxidation methods for landfill stabilization

As the stabilization criteria for landfill sites, only chemical criteria for the leachate discharges from the landfill sites have been used in Japan and many other countries. Recently, chemical oxidation has been developed as a method for the early-stabilization of landfills. However, by-products that are difficult to detect by chemical analysis can be produced by this method. Therefore, toxicity tests are useful tools for detecting the changes of leachate quality after application of this method. The heat source in the A landfill was analyzed by organic position inquiry technology, and ozone-treated leachate was sprayed back to the heat source in the landfill. Toxicity changes of the leachate after the spray were monitored using Microtoxtrade mark, ToxScreen-II, and DaphTox tests. The hardly-degradable organic matter was efficiently removed and toxicities of the leachate in the heat source decreased after the application. These toxicity results were significantly related to chemical oxygen demand (COD) changes. Thus, it was concluded that the toxicity tests were effective for monitoring the leachate quality after applying the chemical oxidation method for landfill stabilization, and its incorporation to establish the criteria for early-stabilization of landfill sites needs to be considered.     

Leachate recirculation in a landfill: some insights obtained from the development of a simple 1-D model

The re-introduction of leachate back into the waste can play an important part in landfill management. It can encourage biodegradation by raising the water content and transporting bacteria, nutrients and waste products. It also enables leachate to be stored within the body of the landfill, for example to help minimise temporal variations in the load on a leachate treatment plant. It is helpful for a landfill operator to be able to estimate the rate at which the landfill can accept leachate (the maximum infiltration or injection rate), the storage capacity of the landfill and the leachate retention time. This paper discusses some of the insights obtained from the development and application of a simple conceptual model of leachate recirculation that can be used to estimate key parameter values on the basis of the hydraulic properties of the waste. The model is described, partly validated against a more rigorous numerical analysis, and then used to interpret data obtained from field tests on a real site. The shortcomings of the model in its current form are discussed, and suggestions are made as to how these might be addressed in the context of developing the model as a design tool.     

Nitrogen management in landfill leachate: Application of SHARON,ANAMMOX and combined SHARON–ANAMMOX process

In today’s context of waste management, landfilling of Municipal Solid Waste (MSW) is considered to be one of the standard practices worldwide. Leachate generated from municipal landfills has become a great threat to the surroundings as it contains high concentration of organics, ammonia and other toxic pollutants. Emphasis has to be placed on the removal of ammonia nitrogen in particular, derived from the nitrogen content of the MSW and it is a long term pollution problem in landfills which determines when the landfill can be considered stable. Several biological processes are available for the removal of ammonia but novel processes such as the Single Reactor System for High Activity Ammonia Removal over Nitrite (SHARON) and Anaerobic Ammonium Oxidation (ANAMMOX) process have great potential and several advantages over conventional processes. The combined SHARON–ANAMMOX process for municipal landfill leachate treatment is a new, innovative and significant approach that requires more research to identify and solve critical issues. This review addresses the operational parameters, microbiology, biochemistry and application of both the processes to remove ammonia from leachate.     

Consequences of raising the height of a landfill in a water-deficient climate

A large-scale field experiment has been carried out at the Coastal Park landfill which serves the City of Cape Town, South Africa. The landfill is unlined, and the City Council was under pressure from the central Government to cap and close the existing landfill and to establish an extension to the landfill with a lining to prevent the escape of leachate into the ground water. Measuring cells, installed to measure the rate of leachate flow from the landfill had shown that over a period of 9 years, from 1987 to 1995, leachate flow had averaged only 2% of rainfall. It therefore appeared possible, by increasing the moisture absorption capacity of the landfill, i.e., by increasing its height, to stop the leachate flow completely. If this could be achieved, there would be no need for a lining, and the raising would considerably extend the life of the landfill.The paper describes the experiment and its results, including the effects of the raising on leachate flow, settlement, leachate quality and the potential for polluting ground water, and the landfill’s water balance.     

Solidification/stabilization of landfill leachate concentrate using different aggregate materials

The application of reverse osmosis for the treatment of landfill leachate is becoming widespread in Turkey as well as in Europe. A major drawback of this process is the production of concentrate, which could be as much as 30% of the feed stream, and high concentrations of salts and contaminants. The reverse osmosis concentrate is disposed of by using several methods including re-infiltration, drying, incineration and solidification/stabilization. In this study, solidification/stabilization (S/S) technology was studied for the treatment of reverse osmosis concentrate produced from landfill leachate. In order to benefit from its capability to absorb heavy metals, ammonia and some other pollutants, zeolite and different aggregate materials were used in solidification experiments. Main pollutants in the leachate concentrate, TOC, DOC, TDS and ammonia were successfully solidified and approximately 1% of TOC, DOC, TDS and ammonia remained in the eluate water. The results indicated that the landfill disposal limits could be attained by solidification/stabilization process.     

Modelling of environmental impacts of solid waste landfilling within the life-cycle analysis program EASEWASTE

A new computer-based life-cycle assessment model (EASEWASTE) has been developed to evaluate resource and environmental consequences of solid waste management systems. This paper describes the landfilling sub-model used in the life-cycle assessment program EASEWASTE, and examines some of the implications of this sub-model. All quantities and concentrations of leachate and landfill gas can be modified by the user in order to bring them in agreement with the actual landfill that is assessed by the model. All emissions, except the generation of landfill gas, are process specific. The landfill gas generation is calculated on the basis of organic matter in the landfilled waste. A landfill assessment example is provided. For this example, the normalised environmental effects of landfill gas on global warming and photochemical smog are much greater than the environmental effects for landfill leachate or for landfill construction. A sensitivity analysis for this example indicates that the overall environmental impact is sensitive to the gas collection efficiency and the use of the gas, but not to the amount of leachate generated, or the amount of soil or liner material used in construction. The landfill model can be used for evaluating different technologies with different liners, gas and leachate collection efficiencies, and to compare the environmental consequences of landfilling with alternative waste treatment options such as incineration or anaerobic digestion.     

Rehabilitation of El Yahoudia dumping site, Tunisia

As in all developing countries, cities in Tunisia face serious problems of environmental pollution caused mainly by the inadequate and inefficient final disposal of their generated solid wastes. The Tunisian government launched a development program including the construction of landfills in the main cities and the closure of the contaminated sites issued from solid wastes landrising practice. The project of the Henchir El Yahoudia landfill restoration is the first experience in this programme. It has been suggested to convert the site to a green park and to implement an ornamental plant nursery. The whole surface of the landfill is approximately 100 ha from which 30 ha have been already transformed to an urban recreational area and the remaining 70 ha have to be characterized for the project extension. A field investigation by boring was conducted in order to define the geological and the hydrogeological conditions, the vertical and horizontal wastes layer extension, content and degree of decomposition and the composition and quantities of leachate and landfill gas. Representative samples of waste, soil, groundwater and leachate were collected for laboratory analyses. Several of these borings were converted to piezometers to define the flow regime in the site. The results showed that the biogas (CH4, H2S, and CO2), leachate and waste, distribution in the site is mainly affected by the temporal variation of the site operating method. The underlying fissured clay layer facilitated leachate infiltration into the groundwater where high BOD, COD and nitrogen concentrations were registered.     

Design considerations of constructed wetlands to reduce landfill leachate contamination in tropical regions

In tropical regions, landfill leachate contamination at municipal solid waste disposal sites is a critical issue because of the large volume of highly contaminated leachate formed during the rainy season. We evaluated the efficacy of constructed wetlands (CWs) with the ability to reduce the water volume and pollutant levels to reduce leachate contamination compared to the most commonly used treatment system, stabilization ponds, based on parameters obtained in a field experiment in Thailand. The simulation indicated that CWs had a higher potential to reduce the water volume than stabilization ponds over the course of a year. Scenario evaluations under varying initial water depths, system depths, and area sizes indicated that the CWs could reduce the treatment area to prevent overflow and leachate pollution. In addition, the CWs were estimated to reduce the leachate amount and pollution by 83–100% and 92–99%, respectively. When there is limited land available, deeper CWs can be used to sustainably prevent contamination from leachate overflow. Effectively designed CW systems may be valuable for both reducing the required area and the contamination; therefore, CWs are a promising option for sustainable landfill leachate treatment systems in developing tropical regions.