OPTICAL CHARACTERISTICS OF NEW ZEALAND RIVERS IN RELATION TO FLOW1

ABSTRACT: Six years (1989–1994) of data from New Zealand's National Rivers Water Quality Network were used to characterize the optical water quality regime of river waters as regards: visual clarity (black disc visibility), turbidity, and light-absorbing aquatic humic material (referred to as ‘yellow substance,’ measured as light absorption at 440 nm). Quantitative relationships between optical water quality variables and flow in rivers are well-described by power law expressions. Visual clarity usually decreases strongly with increasing flow in individual rivers. There is a strong, inverse relationship between turbidity and visibility, but, because of differences between sites, turbidity is not a good general predictor of visual clarity (the attribute of real interest) in rivers. Yellow substance tends to increase with increasing flow, probably because during rainstorms, soil water high in yellow-colored humic material, rather than rain water or ground water, dominates discharge. Therefore, rivers are typically clear and low in humic matter at low flow, and turbid and yellow-colored at high flow.     

OFFSITE MEASUREMENT OF THE VISUAL CLARITY OF WATERS1

ABSTRACT: The black disk method for measuring visual water clarity in situ is becoming established as a simple but robust method for optically characterizing natural waters. However, in spite of its virtues, the method is limited by a practical visibility minimum of around 0.1 m and the requirement for direct access to the water body at a point where there is adequate lighting for the visual observations. A method has been devised for measuring black disk clarity off-site on samples of waters, diluted if necessary, and contained in a trough constructed of galvanized steel. In 23 streams, rivers, and lakes of diverse optical and physical character, measurements of visual clarity of water samples contained in troughs agreed closely with in situ measurements and correlated well (inversely) with the beam attenuation coefficient measured by transmissometer. Therefore, at sites where in situ measurement is difficult, visual clarity of waters can be measured offsite on a water sample. Furthermore, the visibility of samples diluted with tap water of known clarity was predictable from a simple balance on light attenuation. This means that useful visual clarity measurements on very turbid waters and effluents can be made in a trough containing volumetrically diluted samples, so extending application of the black disk method to very low visual ranges.     

OPTICAL IMPACTS AND SOURCES OF SUSPENDED SOLIDS IN ONONDAGA CREEK,U.S.A.1

ABSTRACT: The degradation of the optical aesthetics in the mouth of Onondaga Creek, New York, that occurs during high flow periods as a result of the influx of large quantities of suspended solids, is documented. Features of the degradation include very low clarity (Secchi disc minimum of approximately 0.1 m) and a brown ‘muddy’ appearance. The reduced clarity is mostly a result of increased light scattering. Loading and concentration profiles obtained for an approximately 35 km interval above the creek mouth over a wide range of flow indicates most of the suspended solids received during runoff events is resuspended stream sediment and eroded bank material. Application of microscopy-based individual particle analysis techniques indicates that the origin of most of these deposits and much of the suspended solids during runoff events is point source inputs, termed ‘mud boils,’ located approximately 32 km upstream of the creek mouth.     

IMPACT ASSESSMENT MODEL FOR CLEAR WATER FISHES EXPOSED TO EXCESSIVELY CLOUDY WATER1

ABSTRACT: A new type of empirical model described here enables real time assessment of impacts caused by excessive water cloudiness as a function of (a) reduced visual clarity (excessive cloudiness) and (b) duration of exposure to cloudy conditions, in fisheries or fish life stages adapted to life in clear water ecosystems. This model takes the familiar form used in earlier suspended sediment dose effect models where z is severity of ill effect (SEV), x is duration of exposure (h), y is black disk sighting range (y BD, m)—a measure of water clarity, a is the intercept, and b and c are slope coefficients. As calibrated in this study the model is Severity of ill effect is ranked on a 15‐step scale that ranges from 0 to 14, where zero represents nil effect and 14 represents 100 percent mortality. This model, based on peer consultation and limited meta analysis of peer reviewed reports, accomplishes the following: (a) identifies the threshold of the onset of ill effects among clear water fishes; (b) postulates the rate at which serious ill effects are likely to escalate as a function of reduced visual clarity and persistence; (c) provides a context (the “visual clarity” matrix, with its cell coordinates) to share and compare information about impacts as a function of visual clarity “climate” (d) demonstrates changes in predator prey interactions at exposures greater than and less than the threshold of direct ill effects; (e) calibrates trout reactive distance (cm) as function of water clarity in the form where y represents reactive distance (cm) and x represents visual clarity (black disk sighting range, cm), and where a and b are intercept and slope respectively, such that (f) identifies black disk sighting range, in meters, and its reciprocal, beam attenuation, as preferred monitoring variables; and (g) provides two additional optical quality variables (Secchi disk extinction distance and turbidity) which, suitably calibrated as they have been in this study, expand the range of monitoring options in situations in which the preferred technology—beam attenuation equipment or black disk sighting equipment—is unavailable or impractical to use. This new model demonstrates the efficacy of peer collaboration and defines new research horizons for its refinement.     

CAUSES OF UGHT AVI'ENUATION IN TAMPA BAY AND CHARLOTTE HARBOR,SOUTHWESTERN FLORIDA1

ABSTRACT: Vertical attenuation of photosynthetically active radiation (PAR) in clear waters of central Florida theoretically can vary almost 50 percent during a sunny summer day as a result of changing solar elevation. We used a simple formula to partially adjust the attenuation coefficient in Tampa Bay and Charlotte Harbor for changing solar elevation of the direct beam and then used multiple regression analysis to estimate the relative contribution of different water properties or constituents to the adjusted attenuation coefficient, k_adj. Color, on an average, was responsible for 18 percent of k_adj, chlorophyll a for 21 percent, nonchiorophyll suspended matter for 55 percent, and seawater for the remaining 6 percent. In both estuaries, k_adj increased with decreasing salinity as a result of freshwater runoff adding color, suspended matter, and nutrients. Nutrients affected attenuation by stimulating phytoplankton growth and increasing concentrations of chlorophyll a. Reduced nutrient loading to upper Tampa Bay (Hilisborough Bay) in the early to mid-1980's appears to have decreased concentrations of chlorophyll a, increased water clarity, and increased seagrass recolonization. Assuming other attenuating substances remained unchanged, the decrease in the average concentration of chlorophyll a from 30 to 15 μg L_?1 would correspond to an increase in the depth of light penetration necessary for seagrass survival (>10 percent incident light) from 1.0 to 1.5 m, which, on a relatively flat sea bed (slope of 2 m/km), would increase the area potentially available for seagram recolonization by 0.25 km²/km of shoreline.     

Monitored and Modeled Correlations of Sediment and Nutrients with Chesapeake Bay Water Clarity

This article analyzes the correlations of the observed and modeled light attenuation coefficient, Kd, with in situ total suspended solids (TSS) and chlorophyll‐a concentrations in Chesapeake Bay (CB) tidal waters, and with sediment and nutrient loads from the Chesapeake watershed. Light attenuation is closely related to in situ TSS and chlorophyll‐a concentrations, however, the strength of the correlation differs among the CB segments. There are distinct differences between saline and tidal fresh segments in the main Bay, but less distinction among saline and tidal fresh segments in the tidal tributaries. The correlation between Kd with sediment and nutrient loads is complicated by the lag times of TSS and the chlorophyll‐a responses to reductions in nutrient and sediment loads from the watershed, and also due to the diverse load sources. Three sets of model sensitivity scenarios were performed with: (1) differential sediment and nutrient loads; (2) selective sediment source types; and (3) geographically isolated inputs. The model results yield similar findings as those based on observed data and provide information regarding the effect of sediment on specific water bodies. Based on the model results a method was developed to determine sediment and nutrient load reductions needed to achieve the water clarity standards of the CB segments.     

EFFECT OF “WHITING” ON OPTICAL PROPERTIES AND TURBIDITY IN OWASCO LAKE,NEW YORK1

ABSTRACT: The effects “whiting” (CaCO₃ precipitate) had on the optical properties and turbidity of the epilimnion of Owasco Lake, New York, were studied during the summer of 1985. Turbidity was partitioned according to “whiting” and non-“whiting” components utilizing a simple acidification procedure. Diffuse light attenuation was partitioned according to the attenuating processes of absorption and scattering. “Whiting” was present most of the summer. Two major “whiting” events occurred that caused major increases in turbidity and the attenuation of light. “Whiting” was the principle regulator of turbidity during the study; it caused increases in light attenuation by increasing light scattering. “Whiting” events can easily be mistaken by the public for phytoplankton blooms.     

ESTIMATING TMDL BACKGROUND SUSPENDED SEDIMENT LOADING TO GREAT LAKES TRIBUTARIES FROM EXISTING DATA1

ABSTRACT: The total maximum daily load (TMDL) for suspended sediment is the maximum quantity of suspended sediment that can enter a waterway without affecting the beneficial uses of the waterway. It is calculated as the sum of permissible allotments of point sources of suspended sediment, permissible allotments of nonpoint sources of suspended sediment, background (natural) loading of suspended sediment, and a margin of safety. The goal of this project was to develop methods for estimating background levels of sediment loads in tributaries of the Great Lakes. Such quantification is key to determining permissible TMDL in waters that do not meet water quality standards under the Clean Water Act of 1972. Suspended sediment loading for 46 rivers was estimated from data collected at U.S. Geological Survey (USGS) gages. Land use and physiographic attributes were estimated for these gaged basins with a geographic information system (GIS). Basin attributes and sediment yield data are the basis for examining two approaches to estimating background suspended sediment loads. One method, based upon envelope curves of sediment yield and drainage area, will be shown to have considerable merit. A second method, based upon correlation of sediment yield to various basin attributes such as drainage area and land use, will be shown to be fraught with difficulties.     

SUSPENSOIDS IN NEW YORK CITY'S DRINKING WATER RESERVOIRS: TURBIDITY APPORTIONMENT1

ABSTRACT: The technique of i ndividual p article a nalysis conducted by s canning electron microscopy interfaced with a utomated X ‐ray microanalysis (IPA/SAX) was used to characterize suspended particulate matter in New York City's drinking water reservoirs and their tributaries. The study covered a two year period and involved analyses of more than 300 samples. The particle cross sectional area per unit volume (PAV), or area concentration, was measured to account for the observed turbidity, a representation of light scattering property of the studied medium. A simple linear model with a nearly zero intercept was able to explain more than 85 percent of the variation in the measured turbidity. Moreover, the particle assemblage was categorized into generic particle types with distinctive geochemical or geological origins. Thus, PAV compositions in terms of particle types could be apportioned into turbidity components based on the model. Inorganic tripton, dominated by aluminosilicate (clay) and silicate of nonbiological nature, was found to be the major turbidity causing constituent in most cases. With the exception of one reservoir where organic detritus was significant, the predicted inorganic particle turbidity agreed with the measured turbidity within experimental error.     

RUNOFF EVENT IMPACTS ON A WATER SUPPLY RESERVOIR: SUSPENDED SEDIMENT LOADING, TURBID PLUME BEHAVIOR, AND SEDIMENT DEPOSITION1

Abstract: The impacts of runoff events on external suspended solids loading to Schoharie Reservoir, New York, and patterns of light scattering and sediment deposition in this reservoir are assessed. The assessment is based on monitoring of suspended solids concentrations in the reservoir's primary tributary, detailed vertical profiles of optical backscattering (a surrogate measure of light scattering) in the reservoir water column, and analysis of sediment trap collections, over a seven-month interval of high runoff. These impacts are reported to be tightly temporally coupled and strongly positively related to the magnitude of runoff events. The primary tributary entered the reservoir as a plunging inflow during runoff events, causing conspicuous subsurface peaks in light scattering, with vertical patterns that varied strongly for different events. Deposition quantified by near-bottom trap deployments is reported to be more representative than results from metalimnetic deployments that were generally within, rather than below, the turbid layers. Direct inputs of sediment, transported by density currents, are found to drive deposition, rather than resuspension/redeposition. More than 50 percent of the reported deposition occurred in less than 15 percent of the study period, associated with the four largest runoff events.     

Effects of Light Zenith Angle Variation on Spectral Responses of a Water Body’s Environmental Quality

The effect of light source zenith angle (θ_z) variation on the spectral reflectance measurement from sediment-laden water was studied in the laboratory using a spectroradiometer. Light source zenith angle in addition to sediment characteristics and concentration play a dominant role in affecting the reflectance characteristics of a suspension. With an increase in θ_z values, an increase in spectral reflectance is observed. The spectral reflectance characteristics of a water body also increase with the sediment concentration for all soil types and at all wavelengths. Empirical relationships between the spectral reflectance, suspended sediment concentration, and the light source zenith angle have been developed. Such a remote sensing technique for monitoring the concentration of the suspended sediment and their characteristics is a useful tool for economical estimation of a large water body’s quality related parameters vis-a-vis its environmental quality.Retd. Professor of Environmental Engineering & Pollution Control, Presently Residing at Makkhan Kutir, Bhargava Lane, Devpura, Haridwar-249401, India.Former Ph.D. student.     

Quality and Quantity of Suspended Particles in Rivers: Continent-Scale Patterns in the United States

Suspended solids or sediments can be pollutants in rivers, but they are also an important component of lotic food webs. Suspended sediment data for rivers were obtained from a United States–wide water quality database for 622 stations. Data for particulate nitrogen, suspended carbon, discharge, watershed area, land use, and population were also used. Stations were classified by United States Environmental Protection Agency ecoregions to assess relationships between terrestrial habitats and the quality and quantity of total suspended solids (TSS). Results indicate that nephelometric determinations of mean turbidity can be used to estimate mean suspended sediment values to within an order of magnitude (r² = 0.89). Water quality is often considered impaired above 80 mg TSS L^–1, and 35% of the stations examined during this study had mean values exceeding this level. Forested systems had substantially lower TSS and somewhat higher carbon-to-nitrogen ratios of suspended materials. The correlation between TSS and discharge was moderately well described by an exponential relationship, with the power of the exponent indicating potential acute sediment events in rivers. Mean sediment values and power of the exponent varied significantly with ecoregion, but TSS values were also influenced by land use practices and geomorphological characteristics. Results confirm that, based on current water quality standards, excessive suspended solids impair numerous rivers in the United States.     

MODELING LIGHT ATTENUATION,SECCHI DISK,AND EFFECTS OF TRIPTON IN SENACA RIVER,NEW YORK,USA1

The development, testing, and application of a probabilistic model framework for the light attenuation coefficient for downwelling irradiance (K_d) and Secchi disc transparency (SD) that resolves the effects of several light attenuating constituents, including phytoplankton and nonliving particles (tripton), is documented. The model is consistent with optical theory, partitioning the magnitudes of the light attenuating processes of absorption and scattering according to the contributions of attenuating constituents as simple summations. The probabilistic framework accommodates variations in the character and concentrations of these constituents and ambient conditions during measurements, and recognizes a linear relationship between the magnitudes of absorption and scattering by tripton. The model is tested and applied for a 21 km reach of the Seneca River, New York, that features optical gradients caused by an intervening hypereutrophic lake and dam, and a severe infestation of the exotic zebra mussel. The model is applied to resolve the roles of phytoplankton and tripton in regulating measured longitudinal patterns of SD along the study reach of the river and increases in SD since the zebra mussel invasion, and to predict decreases in K_d since the invasion.     

Concentration‐Duration‐Frequency Curves for Stream Turbidity: Possibilities for Assessing Biological Impairment1

Abstract: Siltation and subsequent biological impairment is a national problem prompting state regulatory agencies to develop sediment total maximum daily loads (TMDL) for many streams. To support TMDL targets for reduced sediment yield in disturbed watersheds, a critical need exists for stream assessments to identify threshold concentrations of suspended sediment that impact aquatic biota. Because of the episodic nature of stream sediment transport, thresholds should not only be a function of sediment concentration, but also of duration and dose frequency. Water quality sondes can collect voluminous amounts of turbidity data, a surrogate for suspended sediment, at intervals that can be used to characterize concentration, duration, and frequency of elevated turbidity events. To characterize turbidity sonde data in an ecologically relevant manner, a methodology for concentration‐duration‐frequency (CDF) curves was developed using turbidity doses that relate to different levels of biological impairment. To illustrate this methodology, turbidity CDF curves were generated for two sites on Little Pigeon River in the Great Smoky Mountains National Park, Tennessee, using over 30,000 sonde data measurements per site for a one‐year period. Utilizing a Poisson arrival approach, turbidity spikes were analyzed stochastically by observing the frequency and duration of recorded events over a turbidity level that relates to a biological dose response. An exponential equation was used to fit duration and frequency of a specified turbidity level to generate concentric‐shaped CDF curves, where at specific turbidities longer durations occurred less frequently and conversely shorter durations occurred more frequently. The significance of the equation fit to the data was accomplished with a Kolmogorov‐Smirnov goodness‐of‐fit test. Our findings showed that the CDF curves derived by an exponential function performed reasonable well, with most curves significant at a 95% confidence level. These CDF curves were then used to demonstrate how they could be used to assess biological impairment, and identify future research needs for improved development of sediment TMDLs.     

A SIMPLE TECHNIQUE FOR ESTIMATING ABSORPTION AND SCATTERING COEFFICIENTS1

ABSTRACT: Results from five different test systems, which include a wide range of optical conditions, indicate credible estimates of the values of the absorption and scattering coefficients can be calculated from paired measurements of Secchi disc transparency and the diffuse attenuation coefficient. The diagnostic utility of the estimates in identifying components and processes that regulate light penetration is demonstrated for three different cases. The simple estimation technique is valuable in the analysis of existing data bases that lack comprehensive optical information to develop and evaluate alternate models for light penetration and to establish the experimental needs of future field programs to support lake management efforts.     

OPTICAL HETEROGENEITY IN GREEN BAY1

Differences in light penetration and light attenuating components and processes are documented along 112 km of the major (NE/SW) axis of Green Bay (Lake Michigan) during a three-day cruise (May 25–27, 1982). Measurements included diffuse attenuation of downwelling irradiance (k_d), Secchi disk transparency (SD), phytoplankton pigments (chlorophyll a and phaeophytin), turbidity (T_n), and dissolved color (absorbance). The relative importance of absorption and scattering to attenuation was calculated from paired measurements of k_d and SD. Absorption and scattering coefficients were calculated; value estimates were supported by a strong linear relationship between the scattering coefficient (b) and T_n (b = 0.99 *T_n; r²= 097, n = 12). Light attenuation characteristics, including the extent of light penetration and the magnitudes and relative importance of absorption, scattering and individual attenuating components, were found to be heterogenous in space. This heterogeneity is due to the characteristics and positions of entry of fluvial discharges to the bay as they influence levels of dissolved color (Gelbstoff), phytoplankton standing crop, and inorganic particulates. Identification of key processes regulating light penetration and their potential for response to pollution control measures can aid in the development of a water quality management plan for Green Bay.     

QUALITY STUDY OF GRAYWATER TREATMENT SYSTEMS1

ABSTRACT: A residential single family dwelling was retrofitted to recycle graywater for landscape irrigation and toilet flushing. The objective of this study was to determine improvements in graywater quality by evaluating five simple graywater treatment systems that were easily adapted to the household plumbing. The treatment systems consisted of (1) water hyacinths and sand filtration, (2) water hyacinths, copper ion disinfection, and sand filtration, (3) copper ion disinfection and sand filtration, (4) copper/silver ion disinfection and sand filtration, and (5) 20–μm cartridge filtration. Water quality parameters measured were fecal and total coliform indicator bacteria, nitrates, suspended solids, and turbidity. Reductions in bacterial concentration, suspended solids and turbidity were achieved by all systems tested. Treatment reduced nitrate concentrations to an average of 2.6 mg/liter. Reductions in suspended solids, and turbidity were influenced more by the quality of the graywater entering the treatment system than the efficiency of the systems themselves. The water hyacinths and sand filtration system provided the best graywater quality in terms of the concentrations of fecal indicator bacteria. The system providing the best water quality in regard to average suspended solids after treatment was the water hyacinths, copper ion, and sand filtration system, and the best average turbidity was achieved by the copper/silver ion generating unit with sand filtration. All systems were capable of significant reductions in fecal indicator bacteria, suspended solids, and turbidity; however, additional treatment or disinfection would be necessary to further reduce the level of coliform and fecal coliform bacteria to achieve regulatory standards in the State of Arizona.     

LONG-TERM PATTERNS OF WATER QUALITY IN A MANAGED WATERSHED IN OREGON: 1. SUSPENDED SEDIMENT1

The cumulative effects of forest management activities on water quality at a downstream point were monitored from 1972-1980 during development of a watershed for timber resources. Suspended sediment concentration and turbidity were measured at two hydrologic stations which bracketed a 10-km reach of the Middle Santiam River in the Western Cascades of Oregon as it flowed through an 8000-ha block of intensively managed forest land. Slope failures often accompany road building and harvesting in steep forested watersheds and pose the most serious threat to water quality. Although 180 km of road were constructed and 3400 ha of old-growth forests were harvested from slopes averaging over 60 percent, long-term changes in sediment yields remained undetectable during the period of measurement. The geologic characteristics of the basin and the road construction and maintenance techniques as prescribed by Oregon's forest practice regulations helped to minimize the occurrence of slope failures so that long-term changes in suspended sediment export rates did not occur. Throughout the nine-year measurement period, seven slope failures which added sediment directly to streams produced measurable short-term responses at the downstream sampling location, but these erosion events were too small and too infrequent to produce long-term changes in sediment yield from the watershed.     

Estimation of Suspended‐Sediment Concentration From Total Suspended Solids and Turbidity Data for Kentucky, 1978‐19951

Williamson, Tanja N. and Charles G. Crawford, 2011. Estimation of Suspended‐Sediment Concentration From Total Suspended Solids and Turbidity Data for Kentucky, 1978‐1995. Journal of the American Water Resources Association (JAWRA) 47(4):739‐749. DOI: 10.1111/j.1752‐1688.2011.00538.x Abstract: Suspended sediment is a constituent of water quality that is monitored because of concerns about accelerated erosion, nonpoint contamination of water resources, and degradation of aquatic environments. In order to quantify the relationship among different sediment parameters for Kentucky streams, long‐term records were obtained from the National Water Information System of the U.S. Geological Survey. Suspended‐sediment concentration (SSC), the parameter traditionally measured and reported by the U.S. Geological Survey, was statistically compared to turbidity and total suspended solids (TSS), two parameters that are considered surrogate data. A linear regression of log‐transformed observations was used to estimate SSC from TSS; 72% of TSS observations were less than coincident SSC observations; however, the estimated SSC values were almost as likely to be overestimated as underestimated. The SSC‐turbidity relationship also used log‐transformed observations, but required a nonlinear, breakpoint regression that separated turbidity observations ≤6 nephelometric turbidity units. The slope for these low turbidity values was not significantly different than zero, indicating that low turbidity observations provide no real information about SSC; in the case of the Kentucky sediment record, this accounts for 30% of the turbidity observations.     

SUSPENDED SEDIMENT PRODUCTION FROM FORESTED WATERSHEDS ON OAHU,HAWAII1

Suspended sediment from forested and agricultural watersheds was sampled over a five-year period on the island of Oahu. A variety of storm conditions were sampled, giving a measure of the extreme variability in suspended sediment production. Total annual suspended sediment from all watersheds sampled ranged from 8400 kg/km² to 617,000 kg/km². Normally, about 90 percent of the total suspended sediment was produced during less than 2 percent of the time. Suspended sediment concentrations rapidly increased during rising stream flow resulting from rain storms. Time to peak of less than two hours is common, with a similarly rapid return to prestorm conditions. The data presented indicate the great variability of suspended sediment yields, making establishment of effective standards difficult.