To Dredge or Not

The streams, rivers, freshwater lakes, and coastal and open ocean waters of the world have been used for centuries for the disposal of municipal and industrial wastes. During the twentieth century, the range and quantities of waste materials discharged to the world's fresh and salt waters have grown progressively, increasing the potential ecological and human health impacts. The types and quantities of organic and inorganic wastes reaching the surface waters and associated sediments have increased in proportion to a region's or nation's population and industrial growth. Many of the contaminaants deliberately or inadvertently discharged to waterways are hydrophobic, are not biodegradable, or are highly resistant to degradation resulting in the accumulation of organic and inorganic substances in the waters, bottom, and suspended sediments of impacted waterways. Because of their persistence, these compounds and trace metals bioaccumulate and bioconcentreate in the aquatic organisms that occupy the affected waterway. Because many of the discharged waste materials are relatively insoluble and readily sorb to particles, the bottom and suspended sediments will commonly have higher contaminant concentrations than the associated overlying waters. Concentrations will normally decrease downstream of the contaminant source areas due to inputs and dilution by sediments and waters from cleaner tributaries. Although the sediments will normally have the higher concentrations, considerable quantities of contaminants may be found in the aqueous phase requiring not only removal of the solids, but treatment of the associated water as well. This is particularly the case when the water to solids recovered during dredging may approach 10:1. Many of the persistent contaminants impacting a nation's waterways are readily sorbed to the finer‐grained, organic rich sediments. Reaches of rivers and streams, or areas amenable to deposition of organic rich clays and silts, result in the creation of “hot spots” of contamination, localized areas where higher contaminant concentrations are found. It is these “hot spots” that are at the center of a debate over whether to dredge or leave the contaminated sediments undisturbed to allow natural attenuation to work. It is well recognized that dredging is not able to remove all of the contaminated sediments; some portion of the resuspended sediments created during the dredgirg will be dispersed downstream. The issue is whether to physically removeportions of the mass of contaminants impacting waterwa‐ys or rely on natural attenuation. Environmental dredging is expensive and many argue not worth the effort because of the lack of effective technologies that will prevent redistribution of the material resuspended as apart oJthe dredging process and management of associated water. Opponents of dredging cite natural attenuation and burial by cleaner sediments as eflective mechanisms to reduce the concentration of contaminants. Dredgingproponents argue the contaminant sources and accumulated hot spots must be removed in order to accelerate ecological recovery of the impacted waterway as well as reduce impacts to the environment and to public heulth. During thc next several years, decisions will be made by the U.S. Environmental Protection Agemy (USEPA) on whether to dredge major and minor waterways involving millions of cubic yards of contaminatedsedinaents requiring expenditures of hundreds of millions oj‐dollars by the responsible parties. © 2000 John Wiley & Sons, Innc.     

Role of iron chemistry in controlling the release of pollutants from resuspended sediments

Aquatic sediments often contain a large number of chemical contaminants that are potential pollutants. It is often presumed that such contaminants are released to the water column during sediment resuspension and, in there, adversely impact aquatic life and other beneficial uses of the water. However, extensive laboratory and field studies of about 100 contaminated sediments from across the United States that specifically addressed this type of release showed that of about 30 common heavy metals, organic compounds, and other potential pollutants, only manganese II and ammonia were released to then remain in the water column after sediment resuspension. These results indicated that the chemistry of aqueous iron controls the availability of many contaminants in resuspended sediment. The formation of ferric hydroxide during sediment suspension into the water column, as a result of the reaction between ferrous iron in the sediments and dissolved oxygen in the water column, leads to rapid scavenging of many contaminants in the Fe(OH)₃ precipitate. The scavenged contaminants are redeposited in the sediments. This article reviews the role of the aqueous chemistry of iron as it relates to controlling the release of potential pollutants from resuspended sediments. © 2005 Wiley Periodicals, Inc.     

In Situ Solidification (ISS) of River Sediments: Pilot Demonstration and Discussion of ISS as a Remedial Alternative to Dredging and Capping

In situ solidification (ISS) is a proven technology for remediation of upland site soils, but has not been thoroughly demonstrated for use in impacted underwater sediments. This article describes the first successful use of ISS techniques to solidify underwater sediments containing manufactured gas plant non‐aqueous‐phase liquid (NAPL). The techniques consisted of mixing cementitious grout with the sediments in situ to create a monolith that immobilized the contaminants, significantly decreased the hydraulic conductivity, and also vastly decreased contaminant leaching potential of the sediments. The success of this pilot demonstration project suggests that ISS may be a viable alternative for: sites requiring deep dredging; large volume projects on urban waterways where staging and amending areas are limited; sites with NAPL impacts that cannot be controlled during dredging; and sites where eventual NAPL breakthrough is anticipated if reactive caps are employed. The potential economic, environmental, and operational benefits of this technology will be discussed. This article focuses on the primary objectives of the pilot demonstration: to meet quantitative performance criteria for strength and hydraulic conductivity; to assess the leach performance of the solidified sediments; and to satisfy water quality parameters for turbidity, pH, and sheen. Approach/activities: The pilot study utilized a customized marine platform (modular floats, tug boats, etc.) and full‐scale ISS equipment (auger rig, silos, etc.) and varied operational parameters to provide a range of data to assist in evaluating the feasibility and efficacy of the technology for use in similar environments and in planning future ISS projects on the water. Water quality controls and monitoring were implemented during the operation, and the study documented and evaluated the environmental disruption (short‐term impacts) and costs of the application of the ISS process to contaminated aquatic sediments. ©2016 Wiley Periodicals, Inc.     

Concepts for sediment restoration on the palos verdes shelf,California

This article summarizes a study conducted by the U.S. Army Engineer Waterways Experiment Station to develop technical information and to evaluate the engineering feasibility of restoration alternatives for DDT-and PCB-contaminated sediments on the Palos Verdes shelf and slope near Los Angeles, California. The study evaluated the nonremoval alternative of in-place capping of contaminated sediments on the shelf and slope; removal of contaminated sediments using conventional and specialized dredging equipment and deep ocean mining equipment; treatment of contaminated sediments; and disposal of contaminated sediments in confined (diked) disposal facilities (CDFs), contained aquatic disposal (CAD) sites, upland landfills, and deep ocean basin sites. Cost estimates of the various alternatives were also prepared. This article concludes that restoration of the contaminated sediments is technically feasible. Sediments on the shelf and slope can be removed using available dredging technologies for deep water environments. In-place capping, CAD, and CDF alternatives are technically feasible. The deep ocean basin disposal alternative is not feasible from the technical or regulatory standpoint. The treatment alternative is not feasible from the implementability and economic standpoint.     

Ecotoxicological assessment and evaluation of a pine bark biosorbent treatment of five landfill leachates

When selecting a landfill leachate treatment method the contaminant composition of the leachate should be considered in order to obtain the most cost-effective treatment option. In this study the filter material pine bark was evaluated as a treatment for five landfill leachates originating from different cells of the same landfill in Sweden. The objective of the study was to determine the uptake, or release, of metals and dissolved organic carbon (DOC) during a leaching test using the pine bark filter material with the five different landfill leachates. Furthermore the change of toxicity after treatment was studied using a battery of aquatic bioassays assessing luminescent bacteria (Vibrio fischeri) acute toxicity (30-min Microtox®), immobility of the crustacean Daphnia magna, growth inhibition of the algae Pseudokirchneriella subcapitata and the aquatic plant Lemna minor; and genotoxicity with the bacterial Umu-C assay. The results from the toxicity tests and the chemical analysis were analyzed in a Principal Component Analysis and the toxicity of the samples before and after treatment was evaluated in a toxicity classification. The pine bark filter material reduced the concentrations of metal contaminants from the landfill leachates in the study, with some exceptions for Cu and Cd. The Zn uptake of the filter was high for heavily contaminated leachates (≥73%), although some desorption of zinc occurred in less contaminated waters. Some of the leachates may require further treatment due to discharge into a natural recipient in order to reduce the risk of possible biological effects. The difference in pH changes between the different leachates was probably due to variations in buffering capacity, affected by physicochemical properties of the leachate. The greatest desorption of phenol during filtration occurred in leachates with high conductivity or elevated levels of metals or salts. Generally, the toxicity classification of the leachates implies that although filter treatment with pine bark removes metal contaminants from the leachates effectively, it does not alter leachate toxicity noticeably. The leachates with the highest conductivity, pH and metal concentrations are most strongly correlated with an increased toxic response in the score plots of both untreated and treated leachates. This is in line with the toxicity classification of the leachate samples. The results from this study highlight the importance of evaluating treatment efficiency from the perspective of potential recipient effects, rather than in terms of residual concentrations of individual contaminants when treating waters with a complex contamination matrix, such as landfill leachates.     

Cost‐Effective Sediment Dredge Disposal Options for Small Craft Harbors in Canada

Sediment dredge disposal options were reviewed to improve cost‐effectiveness and environmental safety for dredging of coastal sediments at the Department of Fisheries and Oceans Small Craft Harbours (DFO‐SCH) program in Canada. Historically, contaminated dredge sediments exceeding federal guidelines were disposed of in nearby landfills. Recent federal regulatory changes in sediment quality guidelines adopted by provincial regulators in Canada has resulted in updates to guidelines for disposal of contaminated solids in landfills. Updates now require specific and general disposal options for contaminated dredge material destined for land‐based disposal, resulting in more expensive disposal in containment cells (if contaminated sediments exceed federal guidelines). However, as part of this study, a leachate testing method was applied to contaminated sediments to simulate migration of potential contaminants in groundwater. Using this approach, leachate quality was compared to federal freshwater criteria and drinking water quality guidelines for compliance with new regulations. Leachate testing performed on the highest sediment contaminant concentrations triggered less than 2 percent potable water exceedances, meaning that most dredge spoils could be disposed of in privately owned or provincially operated landfill sites, providing less expensive disposal options compared to containment cell disposal. Current dredge disposal practices were reviewed at 35 harbor sites across Nova Scotia and their limitations identified in a gap analysis. Improved site management was developed following this review and consultation with interested marine stakeholders. New disposal options and chemical analyses were proposed, along with improvements to cost efficiencies for management of dredged marine sediments in Atlantic Canada. © 2013 Wiley Periodicals, Inc.     

Total Lead and Stable Lead Isotopes in Stockholm Sediments

Lead (Pb) in the environment is derived from both naturaland anthropogenic sources. The aim of this study is to estimate the isotopic signature of anthropogenic Pb in sediments from a highly contaminated area (Stockholm), to discuss the influence of different sources on this signature, and to suggest natural Pb background concentrations. Also distribution patterns and differences between different water areas in Stockholm have been studied, both by total Pb and stable Pb isotopes. In 1993, sediment samples were collected at 24 stations in the Stockholm area and analysed for total Pb, zirconium (Zr), scandium (Sc) and stable Pb isotopes (^{204, 206-208}Pb). Total Pb data show that the Stockholm sediments are severely contaminated by Pb. The contamination seems to be rather local since the small lakes surrounding the central parts of Stockholm are much less effected than the central parts. Stockholm is clearly influenced by anthropogenic and natural sources, but in some of the small lakes also by Pb in zircons from the geological basement. The anthropogenic Pb in Stockholm has typical ²⁰⁷Pb/²⁰⁶Pb ratios of 0.85–0.89 and ²⁰⁸Pb/²⁰⁴Pb ratios of 36–38, which are distinct from natural sources. Pb/Sc ratios suggest that the natural background Pb concentration is 10–20 mg kg^-1 d.w.     

Composition and Toxicity of Residual Bunker C Fuel Oil in Intertidal Sediments After 30 Years

In 1970, approximately 2000 m³ of Bunker C crude oil impacted 300 km of Nova Scotia’s coastline following the grounding of the tanker Arrow. Only 10% of the contaminated coast was subjected to cleanup, the remainder was left to cleanse naturally. To determine the long-term environmental impact of residual oil from this spill event, samples of sediment and interstitial water were recovered in 1993, 1997 and 2000 from a sheltered lagoon in Black Duck Cove. This heavily oiled site was intentionally left to recover on its own. Visual observations and chemical analysis confirmed that substantial quantities of the weathered cargo oil were still present within the sediments at this site. However, direct observations of benthic invertebrate abundance suggest that natural processes have reduced the impacts of the residual oil. To confirm this hypothesis, sediment and interstitial water samples from Black Duck Cove were assessed with a comprehensive set of biotests and chemical assays.Residual oil in the sediments had limited effect on hepatic CYP1A protein levels and mixed function oxygenase (MFO) induction in winter flounder (Pleuronectes americanus). No toxicity was detected with the Microtox solid phase test (Vibrio fischeri). Significant sediment toxicity was detected by the amphipod survival test (Eohaustorius estuarius) in four out of the eight contaminated sediments. Interstitial water samples were deemed non-toxic by the Microtox 100% test (Vibrio fischeri) and the echinoid fertilization test (Lytechinus pictus). Sediment elutriates were also found to be non-toxic in the grass shrimp embryo-larval toxicity (GSELTOX) test (Palaemonetes pugio).Recovery at this contaminated site is attributed to natural processes that mediated biodegradation and physical removal of oil from the sediments. In support of the latter mechanism, mineralization experiments showed that all test sediments had the capacity for hexadecane, octacosane and naphthalene degradation, while chemical analysis confirmed that the Bunker C oil from the Arrow had undergone substantial biodegradation.     

Sediment–Water Interactions in an Eroded and Heavy Metal Contaminated Peatland Catchment,Southern Pennines,UK

Atmospherically deposited lead in the upper layer of the heavily eroded peatlands of the Peak District, southern Pennines, UK, reaches concentrations in excess of 1,000 mg kg⁻¹. Erosion of the upper peat layer in this region is releasing lead, associated with eroded peat particles, into the fluvial system. Understanding the process mechanisms that control dissolved lead concentrations in contaminated peatland streams is vital for understanding lead cycling and transport in peatland streams. Many headwater streams of the southern Pennines recharge drinking water reservoirs. Measurements in the Upper North Grain (UNG) study catchment show that mean sediment-associated and dissolved lead concentrations are 102 ± 39.4 mg kg⁻¹ and 5.73 ± 2.16 μg l⁻¹, respectively. Experimental evidence demonstrates that lead can desorb from suspended sediments, composed of contaminated peat, into stream waters. In-stream processing could therefore account for the elevated dissolved lead concentrations in the fluvial system of UNG.     

Sand Cap Placement and Cap Thickness Monitoring: A Case Study at a Confined Disposal Facility

Thin sediment capping is a commonly used technique to prevent mobilization of contaminants from sediments into the environment. A 70‐m‐deep subaqueous confined disposal facility (CDF, 350,000 m²) at Malmøykalven, Oslofjord, which received dredged contaminated sediments from Oslo Harbor, was capped with 148,900 m³ of sand in 2009. This research serves as a case study regarding some of the key considerations involved with the cap placement and monitoring of the cap layer. Uncertainty is included in all the cap thickness monitoring methods and a combined use of them provided a better understanding of the cap coverage and structure at the site. An open water disposal model (STFATE) was used to simulate the behavior of the barge‐released cap material. The modeling results were consistent with field observations regarding the material spread, and the results provided insight into the relatively high material losses calculated. Better knowledge obtained of material settling resulted in cap properties and cap monitoring methods that are useful when planning similar operations. ©2015 Wiley Periodicals, Inc.     

Effects of Acid Rain on Competitive Releases of Cd, Cu, and Zn from Two Natural Soils and Two Contaminated Soils in Hunan, China

Leaching experiments of rebuilt soil columns with two simulated acid rain solutions (pH 4.6–3.8) were conducted for two natural soils and two artificial contaminated soils from Hunan, south-central China, to study effects of acid rain on competitive releases of soil Cd, Cu, and Zn. Distilled water was used in comparison. The results showed that the total releases were Zn>Cu>Cd for the natural soils and Cd>Zn≫Cu for the contaminated soils, which reflected sensitivity of these metals to acid rain. Leached with different acid rain, about 26–76% of external Cd and 11–68% external Zn were released, but more than 99% of external Cu was adsorbed by the soils, and therefore Cu had a different sorption and desorption pattern from Cd and Zn. Metal releases were obviously correlated with releases of TOC in the leachates, which could be described as an exponential equation. Compared with the natural soils, acid rain not only led to changes in total metal contents, but also in metal fraction distributions in the contaminated soils. More acidified soils had a lower sorption capacity to metals, mostly related to soil properties such as pH, organic matter, soil particles, adsorbed SO₄ ²⁻, exchangeable Al³⁺ and H⁺, and contents of Fe₂O₃ and Al₂O₃.     

Effect of Sediment Humic Substances on Sorption of Selected Endocrine Disruptors

Characterizing sorption processes is essential to understand the environmental distribution and toxicity potential of endocrine disruptors in terrestrial and aquatic systems. The sorption behaviors of three endocrine disruptors (bisphenol A (BPA), 17β-estradiol (E2), and 17α-ethynylestradiol (EE2)) on sediments were investigated using batch techniques. Samples were taken from some representative reaches in several major Chinese rivers. More attention has been paid to the effect of sediment organic components on the sorption of BPA, E2, and EE2. The results show that the sediment organic carbon-normalized partition coefficients (K _oc (sed)) for three endocrine disruptors are in the order of EE2 > E2 > BPA, which corresponds to the octanol-water partitioning coefficients (logK _ow) of the compounds. Moreover, the K _oc values for humic substances (K _oc (hs)) are comparable with the K _oc (sed) values and highly dependent on the physico-chemical properties of humic substances in sediments. The UV absorptivity at 272 nm (A ₂₇₂), which suggests the abundance of aromatic rings in humic substance structure, correlates well with the K _oc (hs) values. In addition, the infrared spectra of the humic substances extracted from sediments show four strong bands centered at 3,400 cm⁻¹, 1,625 cm⁻¹, 1,390 cm⁻¹, and 1,025 cm⁻¹. The K _oc (hs) values have a positive linear relation with the peak area ratio for peak at 1,025 cm⁻¹ and a negative linear relation with the peak area ratio between peaks at 1,625 cm⁻¹ and 1,025 cm⁻¹. Hence, the hydrogen bonds play a critical role to the sorption of selected endocrine disruptors.     

Chlorinated Hydrocarbon–Contaminated Site Investigation With Optimized 3D‐CSIA Approach

An optimized “Three‐Dimensional Compound Specific Isotope Analysis (3D‐CSIA)'' investigation was conducted at a chlorinated hydrocarbon–contaminated site in order to (1) determine if multiple onsite sources of groundwater contamination existed and (2) demonstrate the cost‐effectiveness of applying isotope fingerprinting at such a complex contaminated site. Previous groundwater investigations identified chlorinated hydrocarbons at levels that significantly exceed drinking‐water standards but failed to determine the source(s) of contamination due to the lack of vadose‐zone contamination and the absence of groundwater contaminants in shallow portions of the surficial aquifer. To better understand the contaminant source(s), groundwater samples were taken and tested for both the presence of chlorinated hydrocarbons and their isotopic signatures of ¹³C/¹²C, ³⁷Cl/³⁵Cl, and ²H/¹H. A site investigation with an optimized 3D‐CSIA approach revealed multiple chlorinated hydrocarbon releases from different sources, which was also cost‐effective considering the new lines of evidence of target contaminants obtained with the 3D‐CSIA approach instead of any traditional fingerprinting approaches. In addition, the 3D‐CSIA results inferred in situ bioremediation of chlorinated hydrocarbons would be feasible at the site. © 2013 Wiley Periodicals, Inc.     

The Input and Transmission of Fallout Radionuclides Through Redó, a High Mountain Lake in the Spanish Pyrenees

Fallout radionuclides have increasing value as tracers of pathways for pollutant transport through catchment/lake systems, in addition to their more traditional role in dating sediment records. The objectivesof this study, carried out within the EU MOLAR project, were tomeasure atmospheric fluxes of fallout ²¹⁰Pb, ¹³⁷Cs and ⁷Be at Redó, to establish mass balances for theseradionuclides, and test and validate models of pollutant transport through the lake and its catchment. This was achieved by comparing measured fluxes and concentrations in the water column with theoretical estimates using simple compartment models. Several interesting points emerged. Differences betweensoil core and rainwater measurements suggest that Saharan dust may be an important source of fallout ²¹⁰Pb. Fluxes throughthe water column had a clear seasonal trend reflecting winter icecover. Significant concentrations of ¹³⁷Cs are still presentin the water column, due to continued inputs from the catchment and/or remobilisation from the bottom sediments.     

Potential Remobilization of Toxic Anions during Reduction of Arsenated and Chromated Schwertmannite by the Dissimilatory Fe(III)-Reducing Bacterium Acidiphilium cryptum JF-5

Schwertmannite, an iron(III)-oxyhydroxysulfate formed in acidic mining-impacted stream or lake waters often contaminated with toxic elements like arsenate or chromate, is able to incorporate high amounts of these oxyanions. Detoxification of the water might be achieved if precipitated arsenated or chromated schwertmannite is fixed in the sediment. However, under reduced conditions, reductive dissolution of iron oxides mediated by the activity of Fe(III)-reducing bacteria might mobilize arsenate and chromate again. In this study, the reduction of synthesized arsenated or chromated schwertmannite by the acidophilic Fe(III)-reducer Acidiphilium cryptum JF-5, isolated from an acidic mining-impacted sediment, was investigated. In TSB medium at pH 2.7 with glucose as electron donor, A. cryptum JF-5 reduced about 10% of the total Fe(III) present in pure synthetic schwertmannite but only 5% of Fe(III) present in arsenated schwertmannite. In contrast to sulfate that was released during the reductive dissolution of pure schwertmannite, arsenate was not released during the reduction of arsenated schwertmannite probably due to the high surface complexation constant of arsenate and Fe(III). In medium containing chromated schwertmannite, no Fe(II) was formed, and no glucose was consumed indicating that chromate might have been toxic to cells of A. cryptum JF-5. Both As(V) or Cr(VI) could not be utilized as electron acceptor by A. cryptum JF-5. A comparison between autoclaved (121 °C for 20 min) and non-autoclaved schwertmannite samples demonstrated that nearly 100%of the bound sulfate was released during heating, and FTIR spectra indicated a transformation of schwertmannite to goethite. This structural change was not observed with autoclaved arsenated or chromated schwertmannite. These results suggest that the mobility of arsenate and chromate is not enhanced by the activity of acidophilic Fe(III)-reducing bacteria in mining-impacted sediments. In contrast, the presence of bound arsenate and chromate seemed to stabilize schwertmannite against reductive dissolution and its further transformation to goethite that is an ongoing process in those sediments.     

A Preliminary Laboratory Study of Initial Copper Release from Dredge Residuals

A preliminary laboratory study was conducted to investigate the impact of different residual types and sediment surface roughness on copper contaminant fluxes to the water column. Sediments from Torch Lake, Michigan served as the test samples. These sediments are mining by‐products with elevated Cu levels. Six experiments were run during which the sediments were conditioned to simulate different forms of residuals. During these experiments, the water column above the sediments was circulated via peristaltic pumping or orbital shaking and the total and dissolved Cu levels were monitored periodically for 15 days. Dissolved Cu levels indicated that during the first 48 hr the water column concentrations approached equilibrium for all six cases. Total Cu levels increased with time and did reach equilibrium but were more susceptible to fluctuations in water column suspended solids levels. Analysis of the resulting dissolved Cu data indicated that the resulting water column Cu concentrations differed with sediment surface and residual type. The highest dissolved Cu water column concentrations were observed for a roughened surface with a larger surface area. The lowest water column dissolved Cu levels were observed for the case with sediment slurry placed over clean sand. The dissolved Cu levels in the water column for all six simulated conditions were several orders higher than the USEPA ambient water quality criteria for protection of aquatic life. © 2014 Wiley Periodicals, Inc.*     

Chloroethene dechlorination in acidic groundwater: Implications for combining fenton's treatment with natural attenuation

A sulfuric acid leak in 1988 at a chloroethene‐contaminated groundwater site at the Naval Air Station Pensacola has resulted in a long‐term record of the behavior of chloroethene contaminants at low pH and a unique opportunity to assess the potential impact of source area treatment technologies, which involve acidification of the groundwater environment (e.g., Fenton's‐based in situ chemical oxidation), on downgradient natural attenuation processes. The greater than 75 percent decrease in trichloroethene (TCE) concentrations and the shift in contaminant composition toward predominantly reduced daughter products (dichloroethene [DCE] and vinyl chloride [VC]) that were observed along a 30‐m groundwater flow path characterized by highly acidic conditions (pH = 3.5 ± 0.4) demonstrated that chloroethene reductive dechlorination can continue to be efficient under persistent acidic conditions. The detection of Dehalococcoides‐type bacteria within the sulfuric acid/chloroethene co‐contaminant plume was consistent with biotic chloroethene reductive dechlorination. Microcosm studies conducted with ¹⁴C‐TCE and ¹⁴C‐VC confirmed biotic reductive dechlorination in sediment collected from within the sulfuric acid/chloroethene co‐contaminant plume. Microcosms prepared with sediment from two other locations within the acid plume, however, demonstrated only a limited mineralization to ¹⁴CO₂ and ¹⁴CO, which was attributed to abiotic degradation because no significant differences were observed between experimental and autoclaved control treatments. These results indicated that biotic and abiotic mechanisms contributed to chloroethene attenuation in the acid plume at NAS Pensacola and that remediation techniques involving acidification of the groundwater environment (e.g., Fenton's‐based source area treatment) do not necessarily preclude efficient chloroethene degradation. © 2007 Wiley Periodicals, Inc.     

Use of Large‐Scale Electrokinetic and ZVI Treatment for Chlorinated Solvent Remediation at an Active Industrial Facility

The combination of electrokinetic and zero‐valent iron (ZVI) treatments were used to treat soils contaminated with chlorinated solvents, including dense nonaqueous phase liquid (DNAPL), at an active industrial site in Ohio. The remediation systems were installed in tight clay soils under truck lots and entrances to loading docks without interruption to facility production. The electrokinetic system, called Lasagna^TM, uses a direct current electrical field to mobilize contaminant via electroosmosis and soil heating. The contaminants are intercepted and reduced in situ using treatment zones containing ZVI. In moderately contaminated soils around the Lasagna^TM‐treated source areas, a grid of ZVI filled boreholes were emplaced to passively treat residual contamination in decades instead of centuries. The remediation systems were installed below grade and did not interfere with truck traffic during the installation and three years of operation. The Lasagna^TM systems removed 80 percent of the trichloroethylene (TCE) mass while the passive ZVI borings system has reduced the TCE by 40 percent. The remediation goals have been met and the site is now in monitoring‐only mode as natural attenuation takes over. © 2014 Wiley Periodicals, Inc.