三峡库区中低产土壤重金属含量及其与小麦吸收的关系

三峡库区中低产土壤的Hg,As,Cr,Pb,Cu五个重金属含量（除渝北区外），均在国家土壤环境质量标准内，属自然背景值一级标准。Cd和Zn高于全国土壤中的平均含量和背景值含量，属二级标准。土壤的重金属含量与土壤母质类型，pH值，阳离子交换量，有机质，无定形铁和物理性粘粒有关，同时存在一定的地域分布。重庆近郊的土壤所有重金属含量相对较高。土壤重金属的可给态或有效性含量极低，锌和铜不是过量，而是不足。小麦籽粒中As,Cr,Pb,Zn,Cu含量低于国家食品对重金属限量标准和小麦籽粒背景值标准，Hg,Cd含量高于国家规定标准。籽粒中的Cu,Zn含量是小麦茎叶中的2.0-2.2倍，而茎叶中的Hg,Pb,As,Cr,Cd含量明显高于籽粒。     

江苏天目湖表层沉积物中多环芳烃污染特征与来源

区别于长江三角洲地区众多的大型天然浅水湖泊,江苏天目湖是一个较深的水库型湖泊,也是重要的城乡生活及工农业水源地之一。为了解天目湖表层沉积物中多环芳烃（PAHs）污染状况, 2006年在天目湖全湖采集7个点位的表层沉积物样品,利用GC/MS分析了16种优控PAHs。结果表明：天目湖表层沉积物中16种优控PAHs总量介于28750~71393 ng/g（干重）,平均值为45852 ng/g;在空间分布上,北部受污染程度高于南部,主要是北部旅游业快速发展导致污染物排放的影响;沉积物中总有机碳含量与PAHs总量呈显著相关;利用特征化合物指数对PAHs的来源进行判别,指示天目湖表层沉积物中PAHs的主要来源是木材、煤的不完全燃烧。与不同地区水体沉积物PAHs含量对比表明,天目湖PAHs污染处于一个低至中等程度。基于沉积物中多环芳烃的环境质量标准,仅有1个样点芴浓度超过风险效应低值,但远小于毒性风险效应中值,因此沉积物中多环芳烃的生态风险较小。然而天目湖表层沉积物中的PAHs的污染程度已超过南水北调东线所经过的南四湖,而且天目湖湖水较深,湖水交换周期比较长,其PAHs污染应引起重视,需制定切实措施保护江苏“最后一泓净水”。     

1961～2010年金沙江流域降水时空演变特征

基于金沙江流域1961~2010年逐日降水资料,对流域长时间尺度降水要素和多个典型降水日数进行分析,研究金沙江流域降水的时空演变特征。结果表明:1961~2010年,金沙江流域年降水量呈一定的增加趋势,但未通过显著性检验,汛期雨量变化趋势不明显,逐月降水除9月和12月外其他月份均呈微弱增加趋势。小雨等级和中雨等级的降水日数空间变化趋势相似,呈中上游地区微弱增加、下游地区微弱减少趋势,大雨及以上等级的降水日数则以微弱增加为主,仅在源区、德格一带呈不明显减少趋势。年无雨日数和年连续无雨日数呈比较明显的中上游地区减少、下游增加趋势,特别是年无雨日数在昭觉、昭通、会泽等区域增加趋势显著,年连续有雨日数则呈全流域减少,在下游小部分地区显著减少。研究还表明金沙江流域下游地区无雨日数及连续无雨日数特别在2000s偏多,而年连续有雨日数则在2000s明显偏少,表明近年来流域下游地区发生干旱事件的可能性增加。     

Heavy metals in fish (Solea vulgaris, Anguilla anguilla and Liza aurata) from salt marshes on the southern Atlantic coast of Spain

Comparisons were made of metal concentrations in water and sediment with those in the muscle and livers of three species of fish caught in four seawater reservoirs (two in the Odiel estuary and two in the Bay of Cádiz). The concentrations of a large number of metals in the water, sediment and fish were higher in the Odiel reservoirs than in those in Cádiz. We found high metal-enrichment factors in the livers as compared to muscle (over 100 for Fe and Cu and around 5 for Zn, Ni, Cd and Pb). The three fish species showed differences in metal content. For example, eels accumulated more metals in muscle and grey mullet in the liver. The metal levels found in muscle in the three species were below the legal limits for human consumption, although Cu in the liver was above the limit in the three species taken from the Odiel reservoirs, and Zn levels in liver were over the maximum in eels from one of the Odiel marshes. Significant correlations (p<0.05) were obtained for the levels of numerous metals in water, sediment and fish.     

The impact of global change on economic values of water for Public Irrigation Schemes at the São Francisco River Basin in Brazil

Economic values of water for the main Public Irrigation Schemes in the sub-middle region of the São Francisco River Basin, in northeastern Brazil, are determined in this study using an integration of a global agro-economic land and water use (MAgPIE) with a local economic model (Positive Mathematical Programming). As in the latter, the water values depend on the crops grown, and as Brazilian agriculture is strongly influenced by the global market, we used a regionalized version of the global model adapted to the region in order to simulate the crop land use, which is in turn determined by changes in global demand, trade barriers, and climate. The allocation of sugarcane and fruit crops projected with climate change by the global model, showed an impact on the average yields and on the water costs in the main schemes resulting in changes in the water values locally. The economic values for all schemes in the baseline year were higher than the water prices established for agricultural use in the basin. In the future, these water values will be higher in all the schemes. The highest water values currently and in the future were identified in municipalities with a significant proportion of area growing irrigated sugarcane. Being aware of current water values of each user in a baseline year and in a projected future under global climate and socioeconomic changes, decision makers should improve water allocation policies at local scale, in order to avoid conflicts and unsustainable development in the future.     

长江河口九段沙上沙湿地芦苇与土壤之间营养元素的灰色关联分析

为探明生长季不同时期芦苇湿地生态系统植物与土壤之间营养元素的关系,利用灰色关联分析方法,对长江河口九段沙上沙芦苇湿地的芦苇营养元素吸收量与土壤营养元素含量之间的关联度进行了研究。结果表明：芦苇主要从0～15 cm土壤吸取N元素,从15～40 cm土壤获取P、K元素,而从40～60 cm土壤吸收N、P、K元素量都较少。芦苇-土壤之间营养元素关联度排序为：4月为N＞K＞P;5月为P＞K＞N,6～8月为K＞P＞N;9～11月为N＞K＞P;12月为P＞N＞K。同一营养元素不同时期芦苇-土壤之间关联度也存在差异,芦苇与土壤营养元素N、P、K元素关联最密切时期分别出现在9、12与6月,均与上层土壤营养元素关联最密切。9、12与6月分别为芦苇-土壤之间N、P、K元素迁移、转化与循环的活跃时期,上层土壤是其活动相对重要的场所。芦苇生长过程中吸收土壤营养元素均存在时空差异,不同时期芦苇对不同深度土壤的营养元素吸收强度也不尽相同。芦苇地下部分不同部位与土壤中营养元素种类的关联度排序相同,而芦苇地上部分的排序则不同。     

中国灾害性对流天气日数的时空变化特征

采用1961~2016年中国2 481站的冰雹、大风、雷暴和闪电日数数据,利用多种数理统计方法,分析了中国4种灾害性对流天气日数时空分布特征、周期变化规律和气候突变特征。结果表明：（1）在时间上,中国4种灾害性对流天气日数呈减少趋势,且冰雹和雷暴日数具有“先增 后减”的分段变化特征。中国冰雹、大风、雷暴和闪电日数分别具有3~5 a、2~3 a、1~2 a和1~4 a左右的振荡周期,且冰雹和雷暴日数分别于2002和1992年发生突变。（2）在空间上,青藏高原 四川西部地区是冰雹、大风和雷暴日数的高值分布区。同时长江以南地区也是雷暴日数的高值分布区。华南及其同纬度的西南地区是闪电日数的高值分布区。（3）在趋势上,中国冰雹日数主要在青藏高原地区呈减少趋势。大风日数变化趋势呈东部减少 中部不变 西部增减镶嵌的空间格局。雷暴日数在西藏、华北、重庆、浙江和黑龙江西北部呈增加趋势。中国闪电日数变化趋势在长江以南地区减少明显。（4）在波动上,中国冰雹日数在东南地区波动较大,大风日数在胡焕庸线以东波动较大。中国雷暴日数波动特征呈西北高 东南低的空间格局,闪电日数除在新疆北部和华南地区波动动较小外,其它地区波动相对较大。     

贵州省城市污泥重金属组成特征与农用风险评价

分别选取了贵州省7个主要城市的10个典型污水处理厂脱水污泥样品进行检测,统计了2009~2012年污泥中重金属Cu、Zn、Pb、Cd、Ni、Cr、As、Hg的含量。结果表明,城市污泥中重金属含量受到各地区工矿业发展的影响,部分重金属在某一污水处理厂出现了远大于其它地区的极值,具有明显的地域特征。2009~2012年贵州省城市污泥重金属的变化表现为As、Hg呈升高趋势,其它重金属变化趋势不明显,As、Hg升高可能是因为贵州省近年来燃煤消耗量增加,烟气排放污染所致。对污泥重金属的农用风险评价显示,贵阳中部（S2）、黔西地区(S9)污泥农用重金属的生态风险较高,不推荐直接施用,其它各地区污泥农用风险较低,可以进行农用,建议各污水处理厂应根据本地区污泥重金属特征制定合理的污泥处置措施     

近50年长江中下游地区日照时数的时空特征及其影响因素

利用1961～2010年长江中下游地区93个站日照、降水、云量和风速资料,采用气候倾向率、突变检测和相关分析等方法,研究了长江中下游地区年、季、月日照时数的时空特征及其成因。结果表明,长江中下游地区年、季、月日照时数空间分布均呈东北多西南少的分布形式,夏季最多,其次为秋、春与冬季。近50 a长江中下游地区年日照时数普遍显著减少,区域平均减幅为682 h/10a,多于同期全国平均减幅,明显的年代际转折发生在20世纪80年代初期。年日照时数异常偏多出现在1963年和1971年,但未出现过异常偏少年。各季的日照时数也都是负趋势,夏、秋、冬3季减少显著,夏季减少最多也最明显,其次依次是冬季、秋季和春季。近30 a年及夏、秋、冬 3季日照时数减幅缩小,春季则转为以147 h/10a的速率在增加。除湖北中南部、湖南北部、江西北部、安徽北部和浙江东南部年日照时数在20世纪80年代有明显突变外,其他站点的年日照时数没有明显的突变。长江以北地区年日照时数减少与降水量增加和平均风速减少有密切关系,而在长江以南地区低云量的增加作用也非常重要     

Polybrominated diphenyl ethers in domestic indoor dust from Canada, New Zealand, United Kingdom and United States

Because of the similarities in European and North American dietary exposure, it has been suggested that the order of magnitude higher body burdens in North Americans may be due to international variations in exposure via ingestion of indoor dust. Furthermore, ingestion of indoor dust has been suggested as a possible source of PBDEs in the blood serum of New Zealanders. Hence, polybrominated diphenyl ethers (PBDEs) were measured in domestic indoor dust from: Amarillo/Austin, Texas, US; Birmingham, UK; Toronto, Canada; and Wellington, New Zealand. Concentrations of BDE 209 in two UK samples were - at 520,000 and 100,000 ng g(-1) - the highest ever recorded in a domestic (or office) indoor dust sample. Median concentrations in ng g(-1) were: in Canada 620 and 560 for Sigmatri-hexa-BDEs and BDE 209 respectively; in New Zealand 96, BDE 209 not determined; in the UK 59 and 2,800; and in the US 1600 and 1300. With respect to BDE 209, concentrations were in the order: UK approximately US>Canada. For Sigmatri-hexa-BDEs, the order of concentrations was US approximately Canada>New Zealand approximately UK. Combined with principal component analysis of congener patterns, this suggests that, while North American dusts are contaminated by both Deca- and Penta-BDE commercial formulations, UK dusts are contaminated predominantly by Deca-BDE. The Octa-BDE formulation appears of minimal importance in accordance with available market demand figures. Despite the commercial formulations of PBDEs never having been manufactured in, nor imported into New Zealand, their presence in dusts from that country suggests international trade in PBDE-containing goods is an important pathway effecting their global distribution.     

重庆市“禁磷”绩效评估

国内外研究表明，水体中的磷16％左右来自使用含磷洗涤用品。为保护三峡水库水环境,防止库区水体富营养化，重庆市政府决定，从2003年１月１日起，在全市范围内禁止销售和使用含磷洗涤用品。含磷洗衣粉的磷含量平均为4%，无磷洗衣粉的磷含量平均为0.013%，“禁磷”后洗衣粉的磷削减率平均为99.7%。监测结果表明，“禁磷”前后主城区城市污水排放口总磷浓度平均降幅为15.12%、中等城市为18.36％、县城为33.66％；禁磷前，城市居民洗衣粉磷排放量占城市污水总磷的13.77％，禁磷后只占0.05％；禁磷前，农村居民洗衣粉磷排放量占农村生活污水总磷排放量的30.53％，禁磷后只占0.01％。按城市综合污水总磷浓度变化计算（考虑到城市公建商贸行业的洗涤剂用量），则禁磷后城镇削减磷排放量1 056.2 t/a；农村居民按洗衣粉实际使用量计算，入河生活污水削减磷1 203.8 t/a；城镇和农村共削减总磷排放量2 260 t/a，占重庆市磷污染负荷总量的6.0％。     

Comparative studies on the concentration of rare earth elements and heavy metals in the atmospheric particulate matter in Beijing, China, and in Delft, The Netherlands

Atmospheric particulate matter (APM) was collected at three sampling sites in Beijing, China, from February to June 1998. The concentrations of rare earth elements (REE) and cobalt (Co), zinc (Zn), copper (Cu), cadmium (Cd) and lead (Pb) in the APM were determined by inductively coupled plasma mass spectrometry (ICP-MS). The results obtained in Beijing, China, were compared to that obtained in Delft, the Netherlands, in 1997. The influence of coal combustion was considered. The results demonstrated that the content of APM, the concentrations of REE and Co, Zn, Cd, Pb in the APM in Beijing, China, were higher than that in Delft, the Netherlands. From the ratios of La to Ce, and La to Sm, which may be used as tracers for the origin of the REE, it is concluded that the origins of REE in China differ from those in the Netherlands.     

岷江径流变化特征及其对青藏高原气候变化的响应

依据1961~2003年水文气象资料,运用Mann Kendall检验和线性倾向估计方法进行了岷江年径流、青藏高原年气温与年降水长期变化特征分析及其变化趋势显著性检验,利用Pearson相关分析研究了岷江径流变化与青藏高原气温和降水间的相关性。结果表明：(1)在青藏高原年平均气温显著升高而年降水略有增加但不显著的气候环境下,岷江径流量总体呈减少的变化趋势,年变化率分别为上游紫坪铺站-2619 0 m3/s、下游高场站-6538 5m3/s,其中紫坪铺站径流减少趋势十分显著,通过了5%显著水平的信度检验;从季节变化上看,岷江径流减少主要发生在夏季和秋季,而以春季变化最少;从时间变化特性看,在60~80年代,岷江年径流呈现出年代际的周期性波动变化。(2)岷江径流随青藏高原平均气温的升高而减小;青藏高原降水与岷江径流间的相关性在上下游及季节上则表现不同,与春季径流的相关性最强,与上游紫坪铺站径流具有弱负相关性,而与下游高场站径流具有显著的正相关性;同时,岷江径流变化对青藏高原气温和降水变化在时间响应上还表现出季节上的滞后性。     

Polybrominated diphenyl ether in the East Asian environment: a critical review

Polybrominated diphenyl ethers (PBDEs) have been extensively used as flame retardants in consumer goods. Sufficient evidence shows that PBDEs have been rapidly accumulating in the environment worldwide. In Asia, deca-bromodiphenyl ether has been produced and used in large quantities, while penta-BDE has largely ceased in the mid-1990s. This paper summarizes and critically reviews the status of PBDE pollution in East Asia, with emphases on the comparisons with Europe and North America and the interpretation of the differences. In general, the concentrations of PBDEs in atmosphere, sludge, human and biological samples of East Asia are comparable to or lower than those in Europe and North America. However, in the sediments of waters near densely populated and heavily industrialized areas, PBDE levels are among the highest ever reported in the literature. In Japan and China, concentrations of PBDEs in sediment cores showed an increasing trend for the past 20-30 years. Also, PBDEs levels in human breast milk in Japan increased about 10-fold in the past 20 years. The presence of PBDEs in fur seal has increased about 150-fold in 1994 than that in 1972. Regional and inter-continental transport cannot be confirmed due to insufficient information. However, the detection of a number of PBDE congeners in a pristine lake on the Qinghai-Tibet Plateau may be an evidence of their long-range transport.     

乌江流域梯级水库入出库河流中总汞和甲基汞的时空分布

2006年1~12月，每月采集乌江流域梯级水库入出库河流水样，用两次金汞齐-冷原子荧光光谱法和蒸馏-乙基化结合GC CVAFS法测定了水中总汞和甲基汞的浓度。结果表明：（1）入出库河流中总汞年均加权浓度分别为317和 2.34 ng/L，甲基汞为014和 0.18 ng/L。（2）不同水库入出库河流中总汞和甲基汞的时空分布特征不同，位于上游第一级的普定和洪家渡水库入库河流中总汞有明显的季节变化趋势，且显著低于出库河流；而甲基汞的季节变化在出库河流中较为明显，而且库龄大的普定、东风、乌江渡水库出库河流中甲基汞浓度显著高于入库河流。（3）相关分析发现水库入库河流中总汞、甲基汞浓度主要受悬浮颗粒物的影响，而与水量间的相关性因水库所处位置的不同而有差异，上游的普定和洪家渡水库中呈显著正相关，其它水库中呈负相关。     

不同生态经济类型区生态农业模式与技术研究

开展区域生态农业建设，是推进农业结构战略性调整，加速农业由资源数量型向技术效益型转化，实现农业可持续发展的必然选择。根据湖南省近10年生态农业研究成果与实践经验，针对全省不同生态经济类型区的自然资源特点和社会经济发展水平，系统研究阐明了山地“林-药-果”、丘陵“草-粮-牧”、岗地“果-粮-猪”、平湖“粮-经-牧-渔”、水域“水生经济作物-水禽-水产”共生、蓄洪垸“林-草-牧-渔”、庭园“猪-沼-果”、城郊(或旅游区)“农业观光园”等区域生态农业实用模式的建设重点与技术要点，并实例分析了推广应用上述高效生态农业模式所产生的经济、生态与社会效益。     

青藏高原四季降水变化特征分析

利用青藏高原87个地面气象台站41年（1960～2000年）的月降水资料,并在Arcgis 9.0中通过Kriging插值方法对少数站点的缺测值进行了插补,用线性回归方法研究了高原四季降水量的变化趋势及区域上的差异。为了保证本研究的完整性,对高原年降水也做了相应分析。结果表明：（1）高原冬春两季降水量呈显著增加趋势。冬季雅鲁藏布江下游、春季高原东北部为降水减少区,高原其他区域均表现为增加;夏秋两季降水量基本保持不变,但夏季高原中部和川西降水减少,高原南部和北部降水表现为增加;秋季高原中部、南部降水增加,川西降水减少。（2）高原年降水呈显著增加趋势。在区域上高原南部大致以东经102度为界,该线以东降水减少,以西降水增加,且降水增加区域表现出随纬度的增加而递减的特征。高原中部、北部的年降水基本保持不变或微弱增加。     

Adaptive capacity determinants in developed states: examples from the Nordic countries and Russia

Adaptive capacity in a community context has so far mainly been studied in developing countries as well as indigenous communities in the industrialised world. This article adds to that literature through reviewing studies undertaken in the Nordic countries and Russia, highlighting the ways in which general determinants of adaptive capacity play out in Northern, industrialised contexts. The paper illustrates that the determinants of adaptive capacity in industrialised states exhibit systematic differences from mixed subsistence-cash based communities such as those found in Arctic Canada. We discuss in particular the importance of economic resources in a market-based system, technological competition, and infrastructure, in determining adaptive capacity of natural resource-dependent communities in the Nordic countries and Russia. The paper also illustrates differences in adaptive capacity within the case study region, including between peripheral and central locations with regard to economic resources and diversification possibilities, and between Nordic and Russian cases with regard to infrastructure and technology access. The findings indicate that understanding of determinants of adaptive capacity in resource-dependent communities would benefit from both further contextualisation and broad comparison, across different types of political and administrative systems.     

Accumulation of Chernobyl-derived 137Cs in bottom sediments of some Finnish lakes

The amount and vertical distribution of Chernobyl-derived 137Cs in the bottom sediments of some Finnish lakes were studied. Sediment and surface water samples were taken in 2000 and 2003 from 12 stations in nine lakes and the results were compared with those obtained in corresponding surveys carried out in 1969, 1978, 1988 and 1990. Each of the five deposition categories of Chernobyl fallout in Finland were represented. The depth profiles of 137Cs in the sediments showed considerable variety in the lakes studied. The peak values varied between 1.5 and 46 kBq kg(-1) dry wt. The size and shape of the peak did not always correlate with the amount of deposition in the area, but on the other hand, reflected differences in sedimentation processes in different lakes. In some of the lakes the peak still occurred in the uppermost (0-2 cm) sediment layer, but in an extreme case the peak occurred at a depth of 22-23 cm corresponding to a sedimentation rate of 16 mm year(-1) during the 14 years after the Chernobyl accident. The total amounts of 137Cs in sediments varied from 15 to 170 kBq m(-2) at the sampling stations studied. Since 1990, the amounts have continued to increase slightly in two lakes, but started to decrease in the other lakes. In most of the lakes, the total amounts of 137Cs in sediments were about 1.5-2 times higher than in local deposition. In two lakes, the ratio was below 1, but in one case 3.2. Compared with the total amounts of 137Cs at the same stations in the late 1960s and 1970s, the values were now at their highest, at about 60-fold. The most important factors affecting 137Cs values in sediments were the local amount of deposition and the type of the lake and the sediment, but in addition, there were a number of other factors to be considered.     

苏南经济快速发展区土壤有效态镉含量影响因素及分布特征

研究了农田土壤有效态镉含量的影响因素及分布特征。结果表明：① 土壤有效态Cd含量总体较高,平均值为0.092 mg/kg,最大值高达0.354 mg/kg,且土壤Cd的平均活化率高达53%,Cd是该区主要的重金属污染物之一;②土壤表层有效态Cd含量与全Cd含量呈极显著正相关,回归分析表明该区农田土壤有效态Cd含量主要受全Cd含量的影响;③在不同经济功能区,有效态Cd和土壤Cd的活化率均以化工区为高,在不同地貌区,二者均以中部平原区最高,中部平原区Cd的活化率显著高于北部洼区;④在土壤剖面上,土壤有效态Cd含量和土壤Cd的活化率均以表层为高,表明土壤Cd的环境风险主要集中在表层20 cm。