DEVELOPMENT OF A FRACTURED MEDIUM FLOW MODEL FOR A WASTE SITE1

ABSTRACT: A three‐dimensional fractured medium flow model was developed for the Bear Creek Valley (BCV) S‐3 site of the Oak Ridge Reservation (ORR) using SWIFT III. The numerical modeling for this site focused on a conceptual model established through the analysis of heterogeneous geologic units and matrix fracture properties of the subsurface in the BCV area. The SWIFT III modeling analysis was based on the previous modeling studies that used MODFLOW and MODPATH. A rigorous calibration was obtained first by comparing simulated results with the existing data on ground water levels and then by comparing pumping test results with the simulated ground water levels. A satisfactory agreement between observed and simulated results was obtained. The calibrated model was used to determine sustained yield from a ground water interceptor trench. Different withdrawal rates were used to simulate the performance of the trench for the sustained withdrawal of ground water.     

WATER QUALITY AND MACROINVERTEBRATE POPULATIONS BEFORE AND AFTER A HAZARDOUS WASTE CLEANUP1

ABSTRACT: Water samples and macroinvertebrates were collected from Finley Creek, Indiana, both before and two years after the cleanup of a nearby hazardous waste site. Water quality constituents were compared between years. Below the disposal site higher concentrations of constituents were found before and after the cleanup. However, two years after the cleanup, an improvement of water quality was observed. Total dissolved solids decreased by 52% and macroinvertebrate taxa increased by 44%.     

ENVIRONMENTAL IMPACT EVALUATION OF HAZARDOUS WASTE DISPOSAL IN LAND1

Since the publication of Rachel Carson's Silent Spring in 1962 there has been a rapidly growing public concern over widespread contamination of the environment with hazardous wastes. In recent years scientific findings on the ecological effects of various hazardous substances have posed several important questions. What exactly are hazardous wastes? Can these substances be disposed of in a technically feasible, economical, and safe way with assurance that they have been permanently eliminated from the ecosystem? What compositional alterations or movements of the hazardous wastes occur in water, soil, or air systems? What effect will these wastes have on the water, soil, or air systems? What effect will these wastes have on the water, soil, or air properties? Consequently, a University of Louisville study has developed a relevant definition of hazardous wastes for the Environmental Engineering profession together with priority of concern rating systems to delineate the degree of environmental impact imposed on a total ecosystem by a hazardous waste and the feasibility of disposing of hazardous substances at specific landfill sites. It is felt that refinements of the priority of concern rating systems offered here may provide a sound basis from which procedural decisions may be structured to establish future national hazardous waste disposal sites.     

GROUND AND SURFACE WATER QUALITY IMPACTS OF NORTH CAROLINA SANITARY LANDFILLS1

ABSTRACT: Ground and surface water quality monitoring data from 71 municipal sanitary landfills in North Carolina were analyzed to determine the nature and extent of current contamination problems and identify any common characteristics associated with this contamination. A total of 322 surface and 411 ground water quality records were analyzed using the SAS data system. Almost all the landfill records included inorganic and heavy metal analyses while approximately half of the records also included organic analyses by CC/MS. Our analysis indicates that landfills are having measurable impacts on ground and surface water quality, but these impacts may not be as severe as is commonly assumed. Statistically significant increases were detected in the average concentrations in ground water and downstream surface water samples when compared to upstream surface water samples. The largest percentage increases were observed for zinc, turbidity, total organic carbon, conductivity, total dissolved solids, and lead. Violations of ground water quality standards for heavy metals and hazardous organic compounds were detected at 53 percent of the landfills where adequate data existed. The moat common heavy metal violations were for lead (18 percent), chromium (18 percent), zinc (6 percent), cadmium (6 percent), and arsenic (6 percent) (percentage of landfills violating shown in parenthesis). The organic compounds that appear to pose the greatest threat to ground water are the chlorinated solvents (8 percent), petroleum derived hydrocarbons (8 percent), and pesticides (5 percent). A comparison of monitoring data from sanitary landfills and secondary wastewater treatment plants suggests that the concentrations of heavy metal and organic pollutants discharged to surface waters from these two sources are similar.     

IRRIGATION METHODS AND TRANSPORT OF IMAZAMETHABENZ‐METHYL TO GROUND WATER: GREENFIELDS BENCH,MONTANA1

ABSTRACT: A series of gravel terraces support a shallow aquifer that is the sole source of drinking water for three public water supplies and more than 400 private wells on the Greenfields Bench in west‐central Montana. Farming practices on the Greenfields Bench include irrigation of malting barley and the yearly application of herbicides for the control of weeds. The most commonly used herbicide (imazamethabenz‐methyl, U.S. trade name Assert®) has been found in the ground water on the Greenfields Bench. An experiment was conducted in 2000 and 2001 to characterize the transport of Assert and its acid metabolite to ground water under three irrigation methods: flood, wheel line sprinkler, and center pivot sprinkler. Results show that Assert concentrations in ground water are controlled by hydraulic loading rates of each irrigation method, Assert persistence in soil, hydraulic characteristics of the aquifer, and adsorption/desorption of Assert onto clay particles and organic matter.     

ADSORPTION OF PHOSPHATE BY RIVER PARTICULATE MATTER1

ABSTRACT: The adsorption of phosphate on particulate matter from the Illinois and Spoon Rivers was investigated. Adsoprtion reached equilibrium after 5 to 6 days and adsorption isotherms were linear for both constant and varying amounts of particulate matter. Adsorption was maximum at pH 8.3 – 8.4 and minimum at 6.0. Rates of adsorption were influenced by the equilibrium concentration of phosphate-P and were essentially the same for the Illinois and Spoon Rivers. However, the quantity of phosphate-P adsorbed per unit weight of particulate matter differed for the two streams with that in the Illinois River exhibiting an adsorption capacity 7 times that of the Spoon River.     

WATER AND WASTE WATER IN IMPERIAL ROME1

ABSTRACT: Rome is noted for its water and waste water systems which were constructed during ancient times. This paper is a discussion of the impact these systems had on living conditions in the imperial city. Rome's water system provided a constant supply to centrally located areas in contrast to modern systems which deliver water on demand to individual connections. For both water and waste water systems, access points were generally outside the household. Because of this lack of individual connections, Romans were forced to spend much of their time outside their tenements in the baths, latrines, arenas, streets, and shops of the imperial city.     

EFFECTS OF TOPOGRAPHY AND SOIL PROPERTIES ON RECHARGE AT TWO SITES IN AN AGRICULTURAL FIELD1

ABSTRACT: Field experiments were conducted from 1992 to 1995 to estimate ground water recharge rates at two sites located within a 2.7‐hectare agricultural field. The field lies in a sand plain setting in central Minnesota and is cropped continuously in field corn. The sites are located at a topographically high (upland) site and a topographically low (lowland) site in an effort to quantify the effects of depression focusing of recharge. Three site‐specific methods were used to estimate recharge rates: well hydrograph analysis, chlorofluorocarbon age dating, and an unsaturated zone water balance. All three recharge methods indicated that recharge rates at the lowland site (annual average of all methods of 29 cm) exceeded those at the upland site (annual average of 18 cm). On an annual basis, estimates by the individual methods ranged from 12 to 44 percent of precipitation at the upland site and from 21 to 83 percent at the lowland site. The difference in recharge rates between the sites is primarily attributed to depression focusing of surface water runon at the lowland site. However, two other factors were also important: the presence of thin lamellae at the upland site, and coarser textured soils below a depth of 1.5 m at the lowland site.     

USE OF SOIL MOISTURE PROBES TO ESTIMATE GROUND WATER RECHARGE AT AN OIL SPILL SITE1

Soil moisture data collected using an automated data logging system were used to estimate ground water recharge at a crude oil spill research site near Bemidji, Minnesota. Three different soil moisture probes were tested in the laboratory as well as the field conditions of limited power supply and extreme weather typical of northern Minnesota: a self‐contained reflectometer probe, and two time domain reflectometry (TDR) probes, 30 and 50 cm long. Recharge was estimated using an unsaturated zone water balance method. Recharge estimates for 1999 using the laboratory calibrations were 13 to 30 percent greater than estimates based on the factory calibrations. Recharge indicated by the self‐contained probes was 170 percent to 210 percent greater than the estimates for the TDR probes regardless of calibration method. Results indicate that the anomalously large recharge estimates for the self‐contained probes are not the result of inaccurate measurements of volumetric moisture content, but result from the presence of crude oil, or borehole leakage. Of the probes tested, the 50 cm long TDR probe yielded recharge estimates that compared most favorably to estimates based on a method utilizing water table fluctuations. Recharge rates for this probe represented 24 to 27 percent of 1999 precipitation. Recharge based on the 30 cm long horizontal TDR probes was 29 to 37 percent of 1999 precipitation. By comparison, recharge based on the water table fluctuation method represented about 29 percent of precipitation.     

STORM AND SEASONAL DISTRIBUTIONS OF FECAL COLIFORMS AND CRYPTOSPORIDIUM IN A SPRING1

ABSTRACT: The transmission of disease in ground water is a topic of great concern to government agencies, ground water specialists, and the general public. The purpose of this study was to compare the temporal variability in storm flow of fecal coliform bacteria densities and Cryptosporidium parvum oocyst densities in agriculturally impacted karst ground water. Cryptosporidium parvum oocyst densities ranged from 0 to 1,050 oocysts/1, and mean storm densities ranged from 3.5 to 156.8 oocysts/1. Fecal coliform densities ranged from less than 1 CFU/100ml to more than 40,000 CFU/100ml, and geometric mean storm densities ranged from 1.7 CFU/100ml to more than 7,000 CFU/100ml. Fecal coliform densities correlated well with flow during storms, but Cryptosporidium oocyst densities exhibited a great deal of sample to sample variability and were not correlated with flow. Fecal coliform densities did not correlate positively with Cryptosporidium oocyst densities. Fecal coliform densities were greatest at storm peaks, when sediment loads were also greatest. Multiple transport mechanisms for fecal coliform bacteria and C. parvum oocysts may necessitate various agricultural land management and livestock health maintenance practices to control movement of pathogens to karst ground water.     

POTENTIAL IMPACT OF EARTHEN WASTE STORAGE STRUCTURES ON WATER RESOURCES IN IOWA1

ABSTRACT: Earthen waste storage structures (EWSS) associated with large confined (concentrated) animal feeding operations (CAFOs) were evaluated for their potential to impact water resources in Iowa. A representative sample of 34 EWSS from a digital database of 439 lagoons and basins permitted between 1987 and 1994 was analyzed. Eighteen percent (6 of 34) directly overlie alluvial aquifers that are used widely for potable water supply. Ninety‐four percent (29 of 31) were constructed below the water table based on EWSS depth data. At 65 percent of EWSS (22 of 34), 50 percent or more of the manure‐spreading area (MSA) has a water‐table depth less than 1.6 m. At 74 percent of EWSS (25 of 34), 90 percent or more of the MSA contains soil with vertical K exceeding 25.4 mm/hr. Seventy‐one percent (24 of 34) occur where 10 percent or less of the MSA is frequently flooded. No significant differences were found among leakage rates due to aquifer vulnerability class or surficial material. However, at least 50 percent of EWSS (14 of 28) leaked at rates significantly greater than 1.6 mm/d under the new construction standard. The estimated 5,000 unregulated CAFOs may have a greater potential to impact water resources in Iowa.     

PERMEABILITY OF AIR AND IMMISCIBLE ORGANIC LIQUIDS IN POROUS MEDIA1

ABSTRACT: The conductivity of air, mineral oil (relative viscosity 77), and a light nontoxic oil (relative viscosity 4.7) was measured in three porous media: a sand, loamy sand, and a silt loam. The measurements were made over a range of water contents for each porous medium. Small volumes of air were present as well as significant amounts of water during most of the oil conductivity measurements. The results were compared to two methods for calculating conductivities of immiscible fluids in water-wet porous media. A new equation that accounts for swelling and for the gas slippage effect in very small pores was formulated for use with these methods The observed conductivities, spanning seven orders of magnitude, agree reasonably well with calculated values. Only three soil parameters are required to calculate the conductivities: (1) the saturated conductivity of water, (2) the saturated conductivity of the immiscible fluid of interest, and (3) a pore size index value that is obtained from an estimate from the water release curve of the porous material. Remediation of organic liquid spills is briefly discussed to illustrate the practical applications of gas phase conductivities, as well as those for immiscible organic liquid phases. It is concluded that, in light of spatial variation under field conditions, the method presented for calculating values of three-phase conductivities will be useful in the management of immiscible organic liquid spills and leaks.     

WATER BALANCE AT A LOW-LEVEL RADIOACTIVE-WASTE DISPOSAL SITE1

ABSTRACT: The water balance at a low-level radioactive-waste disposal site in northwestern Illinois was studied from July 1982 through June 1984. Continuous data collection allowed estimates to be made for each component of the water-balance equation independent of other components. The average annual precipitation was 948 millimeters. Average annual evapotranspiration was estimated at 637 millimeters, runoff was 160 millimeters, change in water storage in a waste-trench cover was 24 millimeters, and deep percolation was 208 millimeters. The magnitude of the difference between precipitation and all other components (81 millimeters per year) indicates that, in a similar environment, the water-budget method would be useful in estimating evapotranspiration, but questionable for estimation of other components. Precipitation depth and temporal distribution had a very strong effect on all other components of the water-balance equation. Due to the variability of precipitation from year to year, it appears that two years of data are inadequate for characterization of the long-term average water balance at the site.     

COST ANALYSIS OF WATER AND WASTE WATER TREATMENT PROCESSES IN DEVELOPING COUNTRIES1

ABSTRACT: Mathematical modeling techniques are used to develop predictive equations for cost of water and waste water treatment processes in developing countries utilizing socioeconomic, environmental, and technological indicators. Predictive equations are developed for each of the three regions (Africa, Asia, and Latin America) for construction, operation, and maintenance costs of slow sand filter, rapid sand filter, stabilization lagoon, aerated lagoon, activated sludge, and trickling filter. Data analysis indicated that cost of water treatment processes is a function of technological indicator (percentage of imported materials), population, and the design capacity. The variables which gave the best correlation for waste water treatment cost were population, design flow, and the percentage of imported waste water disposal materials.     

ACUTE RESIDUAL TOXICITY OF SEVERAL DISINFECTANTS IN DOMESTIC AND INDUSTRIAL WASTE WATER1

ABSTRACT: This study determined the acute toxicity of waste water disinfected with chlorine, bromine chloride, or ozone. The residual toxicity of effluent dechlorinated with sulfur dioxide was also tested. Toxicity tests were conducted with cyprinid, salmonid, and centrarchid fishes, as well as several species of fresh water macroinvertebrates. Residual chlorine exhibited the greatest toxicity of the disinfectants tested; dechlorination with sulfur dioxide effectively eliminated the toxicity of chlorinated effluent. Residual ozone produced mortality in test animals only under special conditions where subjects were exposed to effluent immediately after it was contacted with ozone, and chlorobrominated effluent was more toxic to salmonids than chlorinated effluent.     

WASTE WATER REUSE IN PHOENIX-HOW VIABLE IS IT?1

ABSTRACT: The Phoenix metropolitan area has a unique combination of circumstances which makes it one of the prime areas in the Nation for waste water reuse. Overriding all of these conditions is the long-term inadequacy of the existing water supplies. The Salt River Valley has a ground water overdraft of about 700,000 acre feet per year. To help alleviate this situation, the Corps of Engineers in conjunction with the MAG 208 is looking at ways to reuse a projected 2020 waste water flow of 340,000 acre feet per year. Reuse options identified include ground water recharge, agricultural irrigation, turf irrigation, recreational lakes, fish and wildlife habitats, and industrial cooling. These look nice on paper but before they can be implemented, some hard questions have to be answered, such as: How acceptable are local treatment plants when 15 years ago there was a major push to eliminate local plants; is the Phoenix area ready for reuse in urban areas; what are people willing to pay for water; who benefits if a city goes to ground water recharge; how much agriculture will be left in the area by 2020? These and other questions must be resolved if reuse is to become a viable option in water resource planning in the Phoenix area. Summary. Large scale reuse of waste water conforms with the national goal of better resource management through recycling. The Phoenix metropolitan area has a unique combination of circumstances which makes it one of the prime areas in the nation for waste water reuse. Some of the most notable conditions are: the existence of a large and rapidly growing urban area which is in the process of planning for future waste water management systems; the existence of agricultural areas which are projected to be farmed well into the future, and the existence of constructed and planned major recreational systems such as Indian Bend Wash which can use recycled waste water; the existence of extensive depleted ground water aquifers; the need for a dependable source for the cooling of the Palo Verde Nuclear reactors; and finally, overriding all of this, the long-term inadequacy of the existing water supplies. Given this, one would expect to find total reuse within the Phoenix metropolitan area. Reuse is taking place with irrigation and nuclear power cooling to the west but there is no long term plan which looks at the Valley as a whole and considers waste water as part of the Valley's water resources. The Corps 208 plan is looking at waste water in this manner but initial analysis shows that although reuse is technically feasible there are many financial, social, institutional, and political questions still to be answered. These include: determining the value of existing diminishing water sources and what people are willing to pay for the next source of water; are people willing to identify priority uses of water for the area so that water of varying quality is put to its highest and best use; will the present institutional boundaries remain to create water-rich and water-poor areas; and will legislation be forthcoming to simplify the complex surface and ground water laws that presently exist? The Corps 208 study will not be able to answer these questions, but the goal at the moment is to identify feasible reuse systems along with decisions the public, owners, agencies, and politicians must make to select and implement them. If some sort of logical process is not developed and public awareness not increased, the chance for a long-term plan to utilize waste water as a major element in the Phoenix area water resource picture, may be missed.     

DETERMINING THE SOURCE OF STREAM CONTAMINATION IN A KARST‐WATER SYSTEM,SOUTHWEST VIRGINIA,USA1

ABSTRACT: Karst terrane provides a linkage between surface water and ground water regimes by means of caves, sinkholes and swallets, and sinking streams, and facilitates the inter‐watershed transfer of water and contaminants through these subsurface systems. The goal of this study was to develop procedures to identify the sources of degradation of a creek situated in a complex karst‐water system. The study approach consisted of using dye tracing technique to determine subsurface flow paths through the karst system, a water‐sampling network to identify and characterize pollution sources within the surface watershed and subsurface flow regime, and evaluation of analytical data for several water quality parameters. The results of this study provide an interesting perspective of water and contaminant movement in karst‐water systems and pinpoint the sources of stream contamination for a case study site in southwest Virginia where two springs supply water to a contaminated freshwater stream.     

MUNICIPAL RESPONSES TO VOLATILE ORGANIC COMPOUNDS IN WISCONSIN GROUND WATER1

ABSTRACT: Contamination of ground water supplies with volatile organic compounds is a new and significant problem. Municipalities and their community water systems are often the first to discover ground water contamination because of the monitoring programs they are required to carry out. When contamination exceeds standards, some action is required. The responses of Wisconsin municipalities to volatile organic compounds that exceed standards in their ground water sources is described. Actions to protect human health are prompt, but the survey results indicate plumes of contaminated ground water are usually not treated. They may continue to migrate and contaminate other private and public wells.     

ARSENIC POISONING IN BANGLADESH: A GEOGRAPHIC ANALYSIS1

ABSTRACT: Drinking of arsenic‐contaminated tubewell water has become a serious health threat in Bangladesh. Arsenic contaminated tubewells are believed to be responsible for poisoning nearly two‐thirds of this country's population. If proper actions are not taken immediately, many people in Bangladesh will die from arsenic poisoning in just a few years. Causes and consequences of arsenic poisoning, the extent of area affected by it, and local knowledge and beliefs about the arsenic problem — including solutions and international responses to the problem — are analyzed. Although no one knows precisely how the arsenic is released into the ground water, several contradictory theories exist to account for its release. Initial symptoms of the poisoning consist of a dryness and throat constriction, difficulty in swallowing, and acute epigastric pain. Long‐term exposure leads to skin, lung, or bladder cancer. Both government and nongovernmental organizations (NGOs) in Bangladesh, foreign governments, and international agencies are now involved in mitigating the effects of the arsenic poisoning, as well as developing cost‐effective remedial measures that are affordable by the rural people.