MODELING LIGHT ATTENUATION,SECCHI DISK,AND EFFECTS OF TRIPTON IN SENACA RIVER,NEW YORK,USA1

The development, testing, and application of a probabilistic model framework for the light attenuation coefficient for downwelling irradiance (K_d) and Secchi disc transparency (SD) that resolves the effects of several light attenuating constituents, including phytoplankton and nonliving particles (tripton), is documented. The model is consistent with optical theory, partitioning the magnitudes of the light attenuating processes of absorption and scattering according to the contributions of attenuating constituents as simple summations. The probabilistic framework accommodates variations in the character and concentrations of these constituents and ambient conditions during measurements, and recognizes a linear relationship between the magnitudes of absorption and scattering by tripton. The model is tested and applied for a 21 km reach of the Seneca River, New York, that features optical gradients caused by an intervening hypereutrophic lake and dam, and a severe infestation of the exotic zebra mussel. The model is applied to resolve the roles of phytoplankton and tripton in regulating measured longitudinal patterns of SD along the study reach of the river and increases in SD since the zebra mussel invasion, and to predict decreases in K_d since the invasion.     

CAUSES OF UGHT AVI'ENUATION IN TAMPA BAY AND CHARLOTTE HARBOR,SOUTHWESTERN FLORIDA1

ABSTRACT: Vertical attenuation of photosynthetically active radiation (PAR) in clear waters of central Florida theoretically can vary almost 50 percent during a sunny summer day as a result of changing solar elevation. We used a simple formula to partially adjust the attenuation coefficient in Tampa Bay and Charlotte Harbor for changing solar elevation of the direct beam and then used multiple regression analysis to estimate the relative contribution of different water properties or constituents to the adjusted attenuation coefficient, k_adj. Color, on an average, was responsible for 18 percent of k_adj, chlorophyll a for 21 percent, nonchiorophyll suspended matter for 55 percent, and seawater for the remaining 6 percent. In both estuaries, k_adj increased with decreasing salinity as a result of freshwater runoff adding color, suspended matter, and nutrients. Nutrients affected attenuation by stimulating phytoplankton growth and increasing concentrations of chlorophyll a. Reduced nutrient loading to upper Tampa Bay (Hilisborough Bay) in the early to mid-1980's appears to have decreased concentrations of chlorophyll a, increased water clarity, and increased seagrass recolonization. Assuming other attenuating substances remained unchanged, the decrease in the average concentration of chlorophyll a from 30 to 15 μg L_?1 would correspond to an increase in the depth of light penetration necessary for seagrass survival (>10 percent incident light) from 1.0 to 1.5 m, which, on a relatively flat sea bed (slope of 2 m/km), would increase the area potentially available for seagram recolonization by 0.25 km²/km of shoreline.     

ASPECTS OF THE UNDERWATER LIGHT FIELD OF EIGHT CENTRAL NEW YORK LAKES1

ABSTRACT: The underwater light field of eight central New York lakes, which represent a wide range of trophic state, was characterized through paired measurements of Sechi disc transparency (SD, m) and diffuse light attenuation (K_d, m^?1). A total of 90 paired measurements are included in the data base. Substantial variability in the K_d SD product with time within individual systems, and amongst systems, was observed, which indicates differences in the relative contributions of absorption and scattering to attenuation. More than 50 percent of the temporal variability in K_d was attributable to attendant variations in chlorophyll a (C, mg m^?3) in only two of the lakes. Estimates of the adsorption (a, m^?1) and scattering (b, m^?1) coefficients based on paired K_d and SD measurements compared well with more precise determinations available for one of the lakes. Determinations of a and b for the eight lakes, from SD and K_d measurements, indicated great system-specificity and temporal variability in these characteristics. The temporal variability in relative contributions of a and b to K_d is consistent with covariation of different attenuating components and the lack of correlation between C and K_d in most of the study lakes.     

EFFECT OF “WHITING” ON OPTICAL PROPERTIES AND TURBIDITY IN OWASCO LAKE,NEW YORK1

ABSTRACT: The effects “whiting” (CaCO₃ precipitate) had on the optical properties and turbidity of the epilimnion of Owasco Lake, New York, were studied during the summer of 1985. Turbidity was partitioned according to “whiting” and non-“whiting” components utilizing a simple acidification procedure. Diffuse light attenuation was partitioned according to the attenuating processes of absorption and scattering. “Whiting” was present most of the summer. Two major “whiting” events occurred that caused major increases in turbidity and the attenuation of light. “Whiting” was the principle regulator of turbidity during the study; it caused increases in light attenuation by increasing light scattering. “Whiting” events can easily be mistaken by the public for phytoplankton blooms.     

WATER COLUMN LIGHT ATTENUATION IN DANSHUEI RIVER ESTUARY,TAIWAN1

ABSTRACT: The penetration of sunlight into the water column plays a critical role in the aquatic ecosystem. This study investigates light attenuation through the water column of the Danshuei River estuary and explores the models for quantifying it. The measurement of photosynthetically active radiation (PAR) indicates that the conventional exponential attenuation of light with depth is a very good model. A light attenuation coefficient may be derived from the PAR measurements at each location. The simpler measurements of Secchi depth (SD) provide an approximate estimate of the attenuation coefficients through an inverse linear relationship. The results also reveal that the amount and kinds of materials, which are either dissolved or suspended in the water, control light attenuation through the water column. However, the linear regression with such a model results in very poor correlation, and a relatively large constant term for the Danshuei River estuary. The regression with salinity yields a good correlation, indicating that the fraction of sea water might be a good parameter for estimating light attenuation coefficient for practical application in the Danshuei River estuary.     

A SIMPLE TECHNIQUE FOR ESTIMATING ABSORPTION AND SCATTERING COEFFICIENTS1

ABSTRACT: Results from five different test systems, which include a wide range of optical conditions, indicate credible estimates of the values of the absorption and scattering coefficients can be calculated from paired measurements of Secchi disc transparency and the diffuse attenuation coefficient. The diagnostic utility of the estimates in identifying components and processes that regulate light penetration is demonstrated for three different cases. The simple estimation technique is valuable in the analysis of existing data bases that lack comprehensive optical information to develop and evaluate alternate models for light penetration and to establish the experimental needs of future field programs to support lake management efforts.     

SPATIAL DELINEATION OF BIOTIC AND ABIOTIC GRADIENTS IN A RURAL NEW YORK RESERVOIR1

ABSTRACT: The spatial changes in abiotic and biotic variables from riverine to lacustrine areas characterized by the river-lake concept of reservoir function was applied to the Tomhannock Reservoir, Rensselaer County, New York. To identify these longitudinal gradients, a two-year investigation (May 1991 to October 1992) was conducted to measure primary productivity, nutrient concentrations, chlorophyll α and phytoplankton biomass at three locations in the 705-ha water supply reservoir. Emphasis was placed on the measurement of primary production using the carbon-14 artificial incubator (photosynthetron) technique. The average annual production in 1992 was 247.3 gm^?2 245 d^?1, ranging from 52 to 2677 mg C m^?2. Mean alpha^B (assimilation efficiency), P^Bm (assimilation number), and I_k (saturation irradiance) were 4.40 mg C mgChl^?1 E^?1 m^?2, 3.82 mg C mgChl^?1 h^?1, and 236.5 μE m^?2 s^?1, respectively. Neither seasonal nor spatial variability of these photosynethetic parameters were observed. Except for Secchi depth, distinct longitudinal zones from river inflow to darn were not statistically demonstrated in the Tomhannock Reservoir. Mean extinction coefficient, chlorophyll α and total phosphorus concentrations decreased; Secchi transparency and phytoplankton biomass increased; while primary productivity and dissolved inorganic nitrogen concentration remained the same from headwater to darn. These baseline data will be used to assess the future effectiveness of best management practices (BMPs) recently instituted on selected watershed farmland in an attempt to reduce the detrimental impact of agricultural activities on drinking water quality.     

WATER QUALITY AND SOURCE OF FRESHWATER DISCHARGE TO THE CALOOSAHATCHEE ESTUARY,FLORIDA1

ABSTRACT: The Caloosahatchee River has two major sources of freshwater one from its watershed and the other via an artificial connection to Lake Okeechobee. The contribution of each source to the freshwater discharge reaching the downstream estuary varies and either may dominate. Routine monitoring data were analyzed to determine the effects of total river discharge and source of discharge (river basin, lake) on water quality in the downstream estuary. Parameters examined were: color, total suspended solids, light attenuation, chlorophyll a, and total and dissolved inorganic nitrogen and phosphorus. In general, the concentrations of color, and total and dissolved inorganic nitrogen increased, and total suspended solids decreased, as total discharge increased. When the river basin was the major source, the concentrations of nutrients (excepting ammonia) and color in the estuary were relatively higher than when the lake was the major source. Light attenuation was greater when the river basin dominated freshwater discharge to the estuary. The analysis indicates that water quality in the downstream estuary changes as a function of both total discharge and source of discharge. Relative to discharge from the river basin, releases from Lake Okeechobee do not detectably increase concentrations of nutrients, color, or TSS in the estuary.     

Resolution and Analysis of Spatial Variations and Patterns in an Urban Lake with Rapid Profiling Instrumentation

Rapid response vertical profiling instrumentation was used to document spatial variability and patterns in a small urban lake, Onondaga Lake, associated with multiple drivers. Paired profiles of temperature, specific conductance (SC), turbidity (T_n), fluorometric chlorophyll a (Chl_f), and nitrate nitrogen (NO₃^?) were collected at >30 fixed locations (a “gridding”) weekly, over the spring to fall interval of several years. These gridding data are analyzed (1) to characterize phytoplankton (Chl_f) patchiness in the lake's upper waters, (2) to establish the representativeness of a single long‐term site for monitoring lake‐wide conditions, and (3) to resolve spatial patterns of multiple tracers imparted by buoyancy effects of inflows. Multiple buoyancy signatures were resolved, including overflows from less dense inflows, and interflows to metalimnetic depths and underflows to the bottom from the plunging of more dense inputs. Three different metrics had utility as tracers in depicting the buoyancy signatures as follows: (1) SC, for salinity‐enriched tributaries and the more dilute river that receives the lake's outflow, (2) T_n, for the tributaries during runoff events, and (3) NO₃^?, for the effluent of a domestic waste treatment facility and from the addition of NO₃^? solution to control methyl mercury. The plunging inflow phenomenon, which frequently prevailed, has important management implications.     

Toward Reversal of Eutrophic Conditions in a Subtropical Estuary: Water Quality and Seagrass Response to Nitrogen Loading Reductions in Tampa Bay, Florida, USA

Coastal waters have been significantly influenced by increased inputs of nutrients that have accompanied population growth in adjacent drainage basins. In Tampa Bay, Florida, USA, the population has quadrupled since 1950. By the late 1970s, eutrophic conditions including phytoplankton and macroalgal blooms and seagrass losses were evident. The focus of improving Tampa Bay is centered on obtaining sufficient water quality necessary for restoring seagrass habitat, estimated to have been 16,400 ha in 1950 but reduced to 8800 ha by 1982. To address these problems, targets for nutrient load reductions along with seagrass restoration goals were developed and actions were implemented to reach adopted targets. Empirical regression models were developed to determine relationships between chlorophyll a concentrations and light attenuation adequate for sustainable seagrass growth. Additional empirical relationships between nitrogen loading and chlorophyll a concentrations were developed to determine how Tampa Bay responds to changes in loads. Data show that when nitrogen load reduction and chlorophyll a targets are met, seagrass cover increases. After nitrogen load reductions and maintenance of chlorophyll a at target levels, seagrass acreage has increased 25% since 1982, although more than 5000 ha of seagrass still require recovery. The cooperation of scientists, managers, and decision makers participating in the Tampa Bay Estuary Program’s Nitrogen Management Strategy allows the Tampa Bay estuary to continue to show progress towards reversing many of the problems that once plagued its waters. These results also highlight the importance of a multi-entity watershed management process in maintaining progress towards science-based natural resource goals.     

Estimation of daily sunshine duration using support vector machines

Although sunshine duration (SD) is one of the most frequently measured meteorological parameters, there is a lack of measurements in some parts of the world. Hence, it should be estimated accurately for areas where no reliable measurement is possible. The main objective of this study is to evaluate the potential of support vector machine (SVM) approach for estimating daily SD. For this purpose, three different kernels of SVM, such as linear, polynomial, and radial basis function (RBF), were used. Different combinations of five related meteorological parameters, namely cloud cover, maximum temperature (T_max), minimum temperature (T_min), relative humidity (RH), and wind speed (WS), and one astronomic parameter, day length, were considered as the inputs of the models, and the output was obtained as daily SD. Simulated values of the models were compared with ground measured values, and concluded that the usage of the SVM-RBF estimator with combination of all input attributes produced the best results. The coefficient of determination, root mean square error, and mean absolute error were found to be 0.8435, 1.5105 h, and 1.0771 h, respectively, for the pooled four-year daily data set of 14 stations in Turkey. It was also deduced that accuracy increased as the number of attributes increased and the major contribution to this came from RH as compared with T_max, T_min, and WS. This study has shown that the SVM methodology can be a good alternative for conventional and artificial neural network methods for estimating daily SD.     

Three-dimensional numerical simulation of water quality and sediment-associated processes with application to a Mississippi Delta lake

A three-dimensional water quality model was developed for simulating temporal and spatial variations of phytoplankton, nutrients, and dissolved oxygen in freshwater bodies. Effects of suspended and bed sediment on the water quality processes were simulated. A formula was generated from field measurements to calculate the light attenuation coefficient by considering the effects of suspended sediment and chlorophyll. The processes of adsorption–desorption of nutrients by sediment were described using the Langmuir Equation. The release rates of nutrients from the bed were calculated based on the concentration gradient across the water–sediment interface and other variables including pH, temperature and dissolved oxygen concentration.The model was calibrated and validated by applying it to simulate the concentrations of chlorophyll and nutrients in a natural oxbow lake in Mississippi Delta. The simulated time series of phytoplankton (as chlorophyll) and nutrient concentrations were generally in agreement with field observations. Sensitivity analyses were conducted to demonstrate the impacts of varying suspended sediment concentration on lake chlorophyll levels.     

Relationship between liquid depth and the acoustic generation of hydrogen: design aspect for large cavitational reactors with special focus on the role of the wave attenuation

Understanding the effect of the liquid depth (z) on the acoustic generation of hydrogen is highly required for designing large-scale sonoreactors for hydrogen production because acoustic cavitation is the central event that initiates sonochemical reactions. In this paper, we present a computational analysis of the liquid-depth effect on the generation of H₂ from a reactive acoustic bubble trapped in water irradiated with an attenuating sinusoidal ultrasound wave. The computations were made for different operating conditions of frequency (355–1000 kHz), acoustic intensity (1–5 W/cm²), and liquid temperature (10–30°C). The contribution of the acoustic wave attenuation on the overall effect of depth was appreciated for the different conditions. It was found that the acoustic generation of hydrogen diminished hardly with increasing depth up to z = 8 m, and the depth effect was strongly operating parameter-dependent. The sound wave attenuation played a crucial role in quenching H₂ yield, particularly at higher z. The reduction of the H₂ yield with depth was more pronounced at higher frequency (1000 kHz) and lower temperature (10°C) and acoustic intensity (1 W/cm²). The attenuation of the sound wave may contribute up to 100% in the overall reductive effect of depth toward H₂ production rate. This parameter could be imperatively included when studying all aspects of underwater acoustic cavitation.     

PHYTOPLANKTON PRODUCTIVITY AND BIOMASS IN THE CHARLOTTE HARBOR ESTUARINE SYSTEM,FLORIDA1

ABSTRACT: Phytoplankton carbon-14 productivity at a depth of 50 percent of surface light and chlorophyll-α concentrations were measured every other month from November 1985 through September 1986 at 12 stations in the Charlotte Harbor estuarine system. Maximum productivity and chlorophyll-α concentrations occurred during summer or early autumn near the mouths of tidal rivers. Most of the variability in light-normalized productivity and chlorophyll-α could be attributed to two factors derived from Principal Component Analysis of ambient water-quality characteristics. One factor related to seasonal variability and the other to spatial variability. The seasonal factor incorporated the interaction of temperature and nutrients. The spatial factor incorporated the interaction of salinity, nutrients, and water color that resulted from the mixing of freshwater inflow and seawater. Although freshwater inflow increased the availability of nutrients in low salinity (less than 10‰) waters, the highly colored freshwater restricted light penetration and phytoplankton productivity. Maximum productivity and biomass occurred where color associated with the freshwater inflow had been diluted by seawater so that light and nutrients were both available. Concentrations of inorganic nitrogen were often at or below detection limit throughout most of the high salinity (greater than 20‰) waters of the estuary and was probably the most critical nutrient in limiting phytoplankton productivity.     

Kinetic development and evaluation of membrane sequencing batch reactor (MSBR) with mixed cultures photosynthetic bacteria for dairy wastewater treatment

This experimental study was conducted to evaluate a membrane sequencing batch reactor (MSBR) with mixed culture photosynthetic bacteria for dairy wastewater treatment. The study was undertaken in two steps: laboratory and pilot scale experiments. In the first step, kinetics analysis of the MSBR was carried out in a laboratory scale experiment with influent COD concentration of 2500 mg/L. The pilot scale experiment was conducted to investigate the performance of the MSBR and checked the suitability of the kinetics for an engineering design. The kinetic coefficients K_s, k, k_d, Y and μ_m were found to be 174-mg-COD/L, 7.42/d, 0.1383/d, 0.2281/d and 1.69/d, respectively. There were some deviations of COD removal efficiency between the design value and the actual value. From the kinetics estimation, COD effluent from the design was 27 mg/L while the average actual COD effluent from the experiment was 149 mg/L. Due to the different light source condition, the factors relating to light energy (i.e. L_f and IR_%) must be incorporated into engineering design and performance prediction with these kinetic coefficients of the photosynthetic MSBR.     

Environmental Control and Limnological Impacts of a Large Recurrent Spring Bloom in Lake Washington,USA

A series of statistical analyses were used to identify temporal and spatial patterns in the phytoplankton and nutrient dynamics of Lake Washington, an mesotrophic lake in Washington State (USA). These analyses were based on fortnightly or monthly samples of water temperature, Secchi transparency, ammonium (NH₄), nitrate (NO₃), inorganic phosphorus (IP), total nitrogen (TN), total phosphorus (TP), dissolved oxygen (DO), pH and chlorophyll a (chl a) collected during 1995–2000 from 12 stations. Lake Washington has a very consistent and pronounced annual spring diatom bloom which occurs from March to May. During this bloom, epilimnetic chl a concentrations peak on average at 10 μg/L, which is 3 times higher than chl a concentrations typically seen during summer stratified conditions. The spring bloom on average comprised 62% diatoms, 21% chlorophytes and 8% cyanobacteria. During summer stratification, diatoms comprised 26% of the phytoplankton community, chlorophytes 37% and cyanobacteria 25%. Cryptophytes comprised approximately 8% of the community throughout the year. Overall, 6 phytoplankton genera (i.e., Aulacoseira, Fragilaria, Cryptomonas, Asterionella, Stephanodiscus, and Ankistrodesmus) cumulatively accounted for over 50% of the community. These analyses also suggest that the phytoplankton community strongly influences the seasonality of NO₃, IP, DO, pH and water clarity. According to a MANOVA, seasonal fluctuations explained 40% of the total variability for the major parameters, spatial heterogeneity explained 10% of variability, and the seasonal-spatial interaction explained 10% of variability. Distinctive patterns were identified between offshore and inshore sampling stations. The results of our analyses also suggest that spatial variability was substantial, but much smaller than temporal variability.     

The Euler Number as an Index of Spatial Integrity of Landscapes: Evaluation and Proposed Improvement

The spatial integrity of a habitat or landscape is determined by the occurrence of habitat fragments and of perforations inside them. A landscape is said to have less spatial integrity with increasing numbers of fragments and perforations. The Euler number (ε) is a numerical measure of spatial integrity, based upon the difference |n _f −n _p | between the number of fragments (n _f ) and the number of perforations (n _p ). In this contribution, ε is evaluated, and an improvement is presented as a new index ε*, which is a combination of two metrics (ε _i , ε _d ) based on n _f and n _p . The term ε _i quantifies the intensity of perforation and/or fragmentation. The term ε _d measures the extent to which fragmentation predominates perforation, and vice versa. The intensity and dominance measures are combined into an Euclidean distance measure, generating the new ensemble value ε*, calculated as ε*= (n _f +n _p )⁻¹√[1 +n _f ²]. Use, sensitivity, and application of ε*, ε _i , and ε _d are illustrated using percolation maps. Application of the new metrics by environmental scientists is encouraged because (1) no negative values can be generated with ε*, ε _i , and ε _d ; (2) the range of ε*, ε _i , and ε _d is fixed; (3) process dominance and intensity are both assessed; (4) ε*, ε _i , and ε _d are easy to calculate and to interpret; and (5) ε* is not only based upon |n _f −n _p |, as ε is. Guidelines for practical use by means of a biplot of ε _i and ε _d are given.     

胶州湾水质自动站周边水质及运行效果分析

据2016年胶州湾水质自动监测的数据结果,分析了水质变化趋势,并统计和评价其水质超标情况。结果表明:2016-04—11水质自动站海域溶解氧质量浓度和pH 的日均值均达到二类海水水质标准,达标率为100%;活性磷酸盐年均值为0.023mg/L,无机氮年均值为0.154mg/L,以硝酸盐为主(64.9%);无机氮和活性磷酸盐超标率均为16.7%,而且集中在降雨量较大的8月、9月,营养盐指标超标基本与海泊河的淡水输入有关;叶绿素a质量浓度与溶解氧、pH 和浊度呈显著正相关,浮游植物光合作用对该海域表层海水的水质参数影响较大;自动站监测和人工监测的营养盐在年际变化上呈现较一致的趋势,说明运用水质自动站监测该海域的营养盐变化趋势较为准确。     

NONLINEAR PROGRAMMING IN RIVER BASIN MODELING1

ABSTRACT: This paper explores the use of nonlinear programming in river basin water quality modelling. Applications recently reported in the literature, along with the author's experience with nonlinear programming, are reviewed. Results obtained using nonlinear programming are compared with the results obtained by other researchers using linear and dynamic programming to solve river basin water quality optimization problems. These water quality models have objective functions with continuous first partial derivatives, several inequality and variable bound constraints, and are of the form: minizie Σ^j=n_j=1Y_j(X_j) subject to Σ^j=n_j=1a_ijX_jb_i, i=1,2, …, m c_jX_jd_j, j= 1,2, …, n The variable X_i is the maximum allowable ratio of the BOD (biochemical oxygen demand) of the effluent outflow to the BOD of the wastewater inflow for treatment plant j, in the range c_j to d_j. The a_ijd and b_i are constants in the DO (dissolved oxygen) and BOD constraints. The resuks show, given certain assumptions about the data, that nonlinear programming is a better solution method for these problems than is either linear programming or dynamic programming.     

Possible Utilization of Silica Gel Sludge for the Removal of Phenol from Aqueous Solutions: Laboratory Studies

This paper discusses the adsorption capacity of silica gel sludge for phenol removal from aqueous solution. Kinetic experiments showed that phenol adsorption was completed after 2 h. Adsorption isotherms were measured for phenol from aqueous solution onto silica gel sludge under various pHs and temperatures. Results showed that the adsorption capacities for phenol was increased as pH decreased from 6.5 to 2. Temperature also was found to affect the adsorption isotherm. As temperature increases from 30 to 50°C, the adsorption capacity increases. The adsorption equilibrium of phenol on silica gel sludge was described by the linear Freundlich and Langmuir models. Furthermore, results showed that the isotherm parameters fit both linearized Langmuir and Freundlich adsorption isotherms. The Freundlich and Langmuir parameters at optimum pH was found as K _f=2.89, 1/n=0.23 and K _d=22.0, q _m=7.98, respectively. Whereas, for those at optimum temperature it was observed as K _f=2.87, 1/n=0.16 and K _d=20.93, q _m=7.91, respectively.