Quantifying uncertainty in LCA-modelling of waste management systems

Uncertainty analysis in LCA studies has been subject to major progress over the last years. In the context of waste management, various methods have been implemented but a systematic method for uncertainty analysis of waste-LCA studies is lacking. The objective of this paper is (1) to present the sources of uncertainty specifically inherent to waste-LCA studies, (2) to select and apply several methods for uncertainty analysis and (3) to develop a general framework for quantitative uncertainty assessment of LCA of waste management systems. The suggested method is a sequence of four steps combining the selected methods: (Step 1) a sensitivity analysis evaluating the sensitivities of the results with respect to the input uncertainties, (Step 2) an uncertainty propagation providing appropriate tools for representing uncertainties and calculating the overall uncertainty of the model results, (Step 3) an uncertainty contribution analysis quantifying the contribution of each parameter uncertainty to the final uncertainty and (Step 4) as a new approach, a combined sensitivity analysis providing a visualisation of the shift in the ranking of different options due to variations of selected key parameters. This tiered approach optimises the resources available to LCA practitioners by only propagating the most influential uncertainties.     

Evaluation of environmental impacts from municipal solid waste management in the municipality of Aarhus, Denmark (EASEWASTE).

A new computer based life cycle assessment model (EASEWASTE) was used to evaluate a municipal solid waste system with the purpose of identifying environmental benefits and disadvantages by anaerobic digestion of source-separated household waste and incineration. The most important processes that were included in the study are optical sorting and pre-treatment, anaerobic digestion with heat and power recovery, incineration with heat and power recovery, use of digested biomass on arable soils and finally, an estimated surplus consumption of plastic in order to achieve a higher quality and quantity of organic waste to the biogas plant. Results showed that there were no significant differences in most of the assessed environmental impacts for the two scenarios. However, the use of digested biomass may cause a potential toxicity impact on human health due to the heavy metal content of the organic waste. A sensitivity analysis showed that the results are sensitive to the energy recovery efficiencies, to the extra plastic consumption for waste bags and to the content of heavy metals in the waste. A model such as EASEWASTE is very suitable for evaluating the overall environmental consequences of different waste management strategies and technologies, and can be used for most waste material fractions existing in household waste.     

Environmental assessment of waste incineration in a life-cycle-perspective (EASEWASTE).

A model for life-cycle assessment of waste incinerators is described and applied to a case study for illustrative purposes. As life-cycle thinking becomes more integrated into waste management, quantitative tools for assessing waste management technologies are needed. The presented model is a module in the life-cycle assessment model EASEWASTE. The module accounts for all uses of materials and energy and credits the incinerator for electricity and heat recovered. The energy recovered is defined by the user as a percentage of the energy produced, calculated on the lower heating value of the wet waste incinerated. Emissions are either process-specific (related to the amount of waste incinerated) or input-specific (related to the composition of the waste incinerated), while mass transfer to solid outputs are governed by transfer coefficients specified by the user. The waste input is defined by 48 material fractions and their chemical composition. The model was used to quantify the environmental performance of the incineration plant in Aarhus, Denmark before and after its upgrading in terms of improved flue gas cleaning and energy recovery. It demonstrated its usefulness in identifying the various processes and substances that contributed to environmental loadings as well as to environmental savings. The model was instrumental in demonstrating the importance of the energy recovery system not only for electricity but also heat from the incinerator.     

Environmental assessment of solid waste systems and technologies: EASEWASTE.

A new model has been developed for evaluating the overall resource consumption and environmental impacts of municipal solid waste management systems by the use of life cycle assessment. The model is named EASEWASTE (Environmental Assessment of Solid Waste Systems and Technologies) and is able to compare different waste management strategies, waste treatment methods and waste process technologies. The potential environmental impacts can be traced back to the most important processes and waste fractions that contribute to the relevant impacts. A model like EASEWASTE can be used by waste planners to optimize current waste management systems with respect to environmental achievements and by authorities to set guidelines and regulations and to evaluate different strategies for handling of waste. The waste hierarchy has for decades been governing waste management but the ranking of handling approaches may not always be the most environmentally friendly. The EASEWASTE model can identify the most environmentally sustainable solution, which may differ among waste materials and regions and can add valuable information about environmental achievements from each process in a solid waste management system.     

Environmental impact assessment of leachate recirculation in landfill of municipal solid waste by comparing with evaporation and discharge (EASEWASTE)

In some arid regions where landfill produces minimal amount of leachate, leachate recirculation is suggested as a cost-effective option. However, its long-term impacts to environment remain disputed. For the purpose of revealing the environmental impacts of leachate recirculation in landfill, four scenarios were modeled using EASEWASTE, comparing the strategies of leachate recirculation (with or without gas management), evaporation and discharge. In the current situation (Scenario A), a total of 280 t of waste was generated and then transported to a conventional landfill for disposal. A number of contaminants derived from waste can be stored in the landfill for long periods, with 11.69 person equivalent (PE) for stored ecotoxicity in water and 29.62 PE for stored ecotoxicity in soil, considered as potential risks of releasing to the environment someday. Meanwhile, impacts to ecotoxicity and human toxicity in surface water, and those to groundwater, present relatively low levels. In Scenario B, leachate evaporation in a collecting pool has minimal impacts on surface water. However, this strategy significantly impacts groundwater (1055.16 PE) because of the potential infiltration of leachate, with major contaminants of As, ammonia, and Cd. A number of ions, such as Cl^?, Mg²⁺, and Ca²⁺, may also contaminate groundwater. In Scenario C, the direct discharge of leachate to surface water may result in acidification (2.71 PE) and nutrient enrichment (2.88 PE), primarily attributed to soluble ammonia in leachate and the depositional ammonia from biogas. Moreover, the direct discharge of leachate may also result in ecotoxicity and human toxicity via water contaminated by heavy metals in leachate, with 3.96 PE and 11.64 PE respectively. The results also show that landfill gas is the main contributor to global warming and photochemical ozone formation due to methane emission. In Scenario D, landfill gas flaring was thus be modeled and proven to be efficient for reducing impacts by approximately 90% in most categories, like global warming, photochemical ozone formation, acidification, nutrient enrichment, ecotoxicity, and human toxicity. Therefore, leachate recirculation is considered a cost-effective and environmentally viable solution for the current situation, and landfill gas treatment is urgently required. These results can provide important evidence for leachate and gas management of landfill in arid regions.     

Modelling of environmental impacts of solid waste landfilling within the life-cycle analysis program EASEWASTE

A new computer-based life-cycle assessment model (EASEWASTE) has been developed to evaluate resource and environmental consequences of solid waste management systems. This paper describes the landfilling sub-model used in the life-cycle assessment program EASEWASTE, and examines some of the implications of this sub-model. All quantities and concentrations of leachate and landfill gas can be modified by the user in order to bring them in agreement with the actual landfill that is assessed by the model. All emissions, except the generation of landfill gas, are process specific. The landfill gas generation is calculated on the basis of organic matter in the landfilled waste. A landfill assessment example is provided. For this example, the normalised environmental effects of landfill gas on global warming and photochemical smog are much greater than the environmental effects for landfill leachate or for landfill construction. A sensitivity analysis for this example indicates that the overall environmental impact is sensitive to the gas collection efficiency and the use of the gas, but not to the amount of leachate generated, or the amount of soil or liner material used in construction. The landfill model can be used for evaluating different technologies with different liners, gas and leachate collection efficiencies, and to compare the environmental consequences of landfilling with alternative waste treatment options such as incineration or anaerobic digestion.     

Modelling of environmental impacts from biological treatment of organic municipal waste in EASEWASTE

The waste-LCA model EASEWASTE quantifies potential environmental effects from biological treatment of organic waste, based on mass and energy flows, emissions to air, water, soil and groundwater as well as effects from upstream and downstream processes. Default technologies for composting, anaerobic digestion and combinations hereof are available in the model, but the user can change all key parameters in the biological treatment module so that specific local plants and processes can be modelled. EASEWASTE is one of the newest waste LCA models and the biological treatment module was built partly on features of earlier waste-LCA models, but offers additional facilities, more flexibility, transparency and user-friendliness. The paper presents the main features of the module and provides some examples illustrating the capability of the model in environmentally assessing and discriminating the environmental performance of alternative biological treatment technologies in relation to their mass flows, energy consumption, gaseous emissions, biogas recovery and compost/digestate utilization.     

The use of 'exotic' framework structures in waste management

The use of porous framework materials in waste management applications has the potential to be a powerful tool in toxic metal remediation. The properties that these materials possess, including high surface area and ion-exchange capacity, are theoretically valuable. Furthermore, the flexibility of many of these frameworks allows the potential for immobilisation of waste materials with the framework of the material, in addition to the traditional capture in the pore structure. However, for either of these routes to be useful for waste management purposes, these structures must also be stable in any proposed storage media. This study examines the stability of a range of porous materials whose frameworks are made out of zinc and arsenic, both considered toxic minesite wastes, when exposed to aqueous media. The three frameworks examined (sodalite analogue Na(6)(H(2)O)(8)(ZnAsO(4))(6), open framework K(3)Zn(4)O(AsO(4))(3).3.5H(2)O, and an ABW type framework NH(4)ZnAsO(4)) all have similar hydrothermal synthetic routes and bulk framework compositions, but differ in counter ion used, pore size and complexity of structure. The phases were examined before and after storage in an aqueous environment, and their crystallinity and leaching were determined. All phases prepared were found to be extremely unstable outside their original synthetic environment, and very soluble when exposed to water, calling into question their practical use in any environment.     

Life cycle modelling of environmental impacts of application of processed organic municipal solid waste on agricultural land (EASEWASTE).

A model capable of quantifying the potential environmental impacts of agricultural application of composted or anaerobically digested source-separated organic municipal solid waste (MSW) is presented. In addition to the direct impacts, the model accounts for savings by avoiding the production and use of commercial fertilizers. The model is part of a larger model, Environmental Assessment of Solid Waste Systems and Technology (EASEWASTE), developed as a decision-support model, focusing on assessment of alternative waste management options. The environmental impacts of the land application of processed organic waste are quantified by emission coefficients referring to the composition of the processed waste and related to specific crop rotation as well as soil type. The model contains several default parameters based on literature data, field experiments and modelling by the agro-ecosystem model, Daisy. All data can be modified by the user allowing application of the model to other situations. A case study including four scenarios was performed to illustrate the use of the model. One tonne of nitrogen in composted and anaerobically digested MSW was applied as fertilizer to loamy and sandy soil at a plant farm in western Denmark. Application of the processed organic waste mainly affected the environmental impact categories global warming (0.4-0.7 PE), acidification (-0.06 (saving)-1.6 PE), nutrient enrichment (-1.0 (saving)-3.1 PE), and toxicity. The main contributors to these categories were nitrous oxide formation (global warming), ammonia volatilization (acidification and nutrient enrichment), nitrate losses (nutrient enrichment and groundwater contamination), and heavy metal input to soil (toxicity potentials). The local agricultural conditions as well as the composition of the processed MSW showed large influence on the environmental impacts. A range of benefits, mainly related to improved soil quality from long-term application of the processed organic waste, could not be generally quantified with respect to the chosen life cycle assessment impact categories and were therefore not included in the model. These effects should be considered in conjunction with the results of the life cycle assessment.     

The challenge of electronic waste (e-waste) management in developing countries

Information and telecommunications technology (ICT) and computer Internet networking has penetrated nearly every aspect of modern life, and is positively affecting human life even in the most remote areas of the developing countries. The rapid growth in ICT has led to an improvement in the capacity of computers but simultaneously to a decrease in the products lifetime as a result of which increasingly large quantities of waste electrical and electronic equipment (e-waste) are generated annually. ICT development in most developing countries, particularly in Africa, depends more on secondhand or refurbished EEEs most of which are imported without confirmatory testing for functionality. As a result large quantities of e-waste are presently being managed in these countries. The challenges facing the developing countries in e-waste management include: an absence of infrastructure for appropriate waste management, an absence of legislation dealing specifically with e-waste, an absence of any framework for end-of-life (EoL) product take-back or implementation of extended producer responsibility (EPR). This study examines these issues as they relate to practices in developing countries with emphasis on the prevailing situation in Nigeria. Effective management of e-waste in the developing countries demands the implementation of EPR, the establishment of product reuse through remanufacturing and the introduction of efficient recycling facilities. The implementation of a global system for the standardization and certification/labelling of secondhand appliances intended for export to developing countries will be required to control the export of electronic recyclables (e-scarp) in the name of secondhand appliances.     

Sustainable waste management in the Indian mining industry.

One of the important sectors that contribute to the national economy is the mining sector. During the mining of minerals and ores, waste materials in the form of overburden are generated. As these are not useful to the mine owners, they may be inappropriately disposed of into the environment, posing serious threat to the environment in the form of land degradation, water and air pollution. The present paper discusses the existing status of waste generation, its characteristics and the disposal methods being adopted in India. Impacts associated with waste disposal practices together with preventive measures for waste disposal are also discussed. Finally, strategies for improvements in existing waste management and for incorporating the same in the overall development plan for the mines are suggested.     

The applicability of Fourier transform infrared (FT-IR) spectroscopy in waste management

State and stability or reactivity of waste materials are important properties that must be determined to obtain information about the future behavior and the emission potential of the materials. Different chemical and biological parameters are used to describe the stage of organic matter in waste materials. Fourier transform infrared spectroscopy provides information about the chemistry of waste materials in a general way. Several indicator bands that are referred to functional groups represent components or metabolic products. Their presence and intensity or their absence shed light on the phase of degradation or stabilization. The rapid assessment of the stage of organic matter decomposition is a very important field of application. Therefore, infrared spectroscopy is an appropriate tool for process and quality control, for the assessment of abandoned landfills and for checking of the successful landfill remediation. A wide range of applications are presented in this study for different waste materials. Progressing stages of a typical yard/kitchen waste composting process are shown. The fate of anaerobically "stabilized" leftovers in a subsequent liquid aerobic process is revealed by spectroscopic characteristics. A compost that underwent the biological stabilization process is distinguished from a "substrate" that comprises immature biogenic waste mixed with mineral compounds. Infrared spectra of freeze-dried leachate from untreated and aerated landfill material prove the effect of the aerobic treatment during 10 weeks in laboratory-scale experiments.     

The use of chemical composition data in waste management planning--a case study

As the waste industry continues to move from a disposal-based system to one based on a combination of recovery options, the need for information on the composition of waste increases and this is reflected by the amount of information on the physical composition of municipal solid wastes that is now available. However, there is far less information on the chemical composition of municipal solid waste. The results from a number of chemical surveys from Europe are compared and show a reasonable degree of agreement, but several problems were identified with the data. Chemical and physical compositional data are combined in a case study example to investigate the flow of key potential pollutants in an integrated solid waste management system that uses materials recycling, composting, incineration and landfilling. This case study has shown that an integrated waste management strategy diverts lead and cadmium away from composting and recycling to incineration, which effectively isolates these elements from the environment through efficient capture of the pollutants followed by secure landfilling or recycling of the residues. However, further work is needed to determine the distribution of mercury in incineration residues and its fate when the residues are landfilled.     

Electronic waste (e-waste): material flows and management practices in Nigeria

The growth in electrical and electronic equipment (EEE) production and consumption has been exponential in the last two decades. This has been as a result of the rapid changes in equipment features and capabilities, decrease in prices, and the growth in internet use. This creates a large volume of waste stream of obsolete electrical and electronic devices (e-waste) in developed countries. There is high level of trans-boundary movement of these devices as secondhand electronic equipment into developing countries in an attempt to bridge the 'digital divide'. The past decade has witnessed a phenomenal advancement in information and communication technology (ICT) in Nigeria, most of which rely on imported secondhand devices. This paper attempts to review the material flow of secondhand/scrap electronic devices into Nigeria, the current management practices for e-waste and the environmental and health implications of such low-end management practices. Establishment of formal recycling facilities, introduction of legislation dealing specifically with e-waste and the confirmation of the functionality of secondhand EEE prior to importation are some of the options available to the government in dealing with this difficult issue.     

Development drivers for waste management.

This paper identifies six broad groups of drivers for development in waste management. Public health led to the emergence of formalized waste collection systems in the nineteenth century, and remains a key driver in developing countries. Environmental protection came to the forefront in the 1970s, with an initial focus on eliminating uncontrolled disposal, followed by the systematic increasing of technical standards. Today, developing countries seem still to be struggling with these first steps; while climate change is also emerging as a key driver. The resource value of waste, which allows people to make a living from discarded materials, was an important driver historically, and remains so in developing countries today. A current trend in developed countries is closing the loop, moving from the concept of 'end-of-pipe' waste management towards a more holistic resource management. Two underpinning groups of drivers are institutional and responsibility issues, and public awareness. There is no, one single driver for development in waste management: the balance between these six groups of drivers has varied over time, and will vary between countries depending on local circumstances, and between stakeholders depending on their perspective. The next appropriate steps towards developing a sustainable, integrated waste management system will also vary in each local situation.