循环冷却水浓缩倍率对凝汽器管路的腐蚀和结垢趋势

利用水质判断指数来预测不同循环冷却水浓缩倍率下水的结垢趋势,确定形成最佳碳酸钙保护膜所对应的浓缩倍率,以达到最经济的防止循环冷却水系统腐蚀和结垢的目的.     

承德热电厂循环冷却水化学处理的研究

采用ＹＪ系列水质稳定剂处理承德热电厂循环水，阻垢和缓蚀作用显著，有效地阻了该厂凝结品铜管的结垢和系统设备的腐蚀 。     

利用除盐设备的再生废液防止灰管结垢

宝鸡发电厂于1982年7月在水处理室与灰浆池之间铺设了一条陶瓷管道,将化学除盐设备酸(HCl)、碱(NaOH)再生废液及冲洗水排入灰浆池,与灰水混合后,经冲灰管排往灰场。经过七年来的运行实践,证明采用这一技术措施可消除除盐设备再生废液对水体环境的酸碱污染。对防止冲灰管结垢,减少冲灰管维护费用等效果显著。现     

电磁阻垢技术在火电厂大型循环水系统中的适用性研究

通过电磁阻垢技术在火电厂大型循环水系统中的应用情况进行研究分析,发现火电厂大型循环冷却水系统单独采用电磁阻垢处理方式和传统化学加药处理方式相比尚有欠缺,电厂在选择电磁阻垢处理方式进行循环水系统处理时应持谨慎态度,应用前应进行考证和试验。对于已采用电磁阻垢处理方式的电厂应加强循环水水质监督和机组热力参数监督,一旦发生异常情况,应立即恢复化学加药处理或进行两种方式的联合处理。     

新型清洗剂YJ—701在承德热电厂凝汽器化学清洗中的应用

1前言在循环水的水质稳定研究中，常常会遇到阻垢效果不明显或有些系统根本不采取阻垢措施的情况。有时循环水的硬度较高，从而导致冷却水系统中的热交换设备表面结垢。由于垢层比金属的导热性差（见表1），从而不同程度地影响设备的传热效率，造成能源浪费；有些设备由于结垢严重而造成局部温度过热引起爆裂、爆炸的事故。造成生产停顿带来经济损失。因此，对热交换设备的积垢必须定期进行清洗以保证生产系统的正常运行。清洗方法可分为物理清洗及化学清洗。前者是指凭藉某些器具如毛刷、胶球、刮管器等在机械力或压缩空气、水力的作用下除…     

湿法烟气脱硫系统GGH腐蚀和结垢对策研究

湿法烟气脱硫系统GGH的运行存在着腐蚀和结垢、堵塞的现象.分析了湿法脱硫系统GGH在运行过程中腐蚀、结垢的原因,从运行、维护等方面提出来减轻GGH腐蚀、结垢的策略.     

亚临界锅炉的化学清洗

针对灞桥热电厂300MW超临界机组的特点、安装进度及环保要求,制定了相应的化学清洗方案并进行了炉前热力系统和锅炉本体除油清洗,以及中高压给水系统和炉本体的EDTA清洗。实践表明,灞桥热电厂化学清洗范围、清洗工艺和清洗系统的设计是合理的。     

火电机组热力系统EDTA化学清洗

对火电机组EDTA化学清洗过程中的清洗范围、清洗工艺、控制参数和清洗效果等进行了介绍,并结合工程实际提出了EDTA清洗过程中易出现的问题,为化学清洗工作提供了一定的防范措施.     

基于Excel和VBA的汽轮机排汽焓求解

热力性能测试和计算是火电机组热经济性分析的基础,其中排汽焓的确定不容忽视。在分析比较目前各种在线和离线计算方法的基础上,介绍了利用Excel的矩阵函数,配合少量VBA代码,快速求解汽轮机排汽焓的具体方法。该方法以汽轮机及回热系统能量平衡为基础,遵循GB 8117-1987要求并参考ASME PTC6-1996规范。实例计算表明,该方法编程简单,计算快速,可满足汽轮机热力性能试验报告等的需要。     

粉煤灰中活性CaO在高pH值条件下的溶出特性

测定了粉煤灰在不同初始pH值条件下Ca2 +随时间的变化。结果表明 :当pH >12 .5时 ,粉煤灰中活性CaO的溶出量明显降低。提出将化学除盐设备阴床再生的废碱液引入输灰管 ,将使输灰管道结垢有所缓解。     

Distribution of Cd,Ck, Pb and Zn in Soil and Vegetation Compartments in Stands of Five Boreal Tree Species in N.E. Sweden

Concentrations and total quantity of cadmium (Cd), cupper (Cu),lead (Pb) and zink (Zn) were determined in biomass and soil compartments in a replicated tree species experiment with 27-yr-old stands growing on former farmland in N.E. Sweden. Sequentialextractions of soil samples were performed in order to estimate the exchangeable and an organically bound fraction of each element. The tree species included were Picea abies (L.)H. Karst., Pinus sylvestris L., Pinus contorta Dougl., Larix sibirica Ledeb., and Betula pendula Roth.Tree species influenced the rate of removal of Cu, Pb and Zn incase of stemwood harvesting, and of Cd, Cu and Zn in the case ofwhole-tree harvesting. B. pendula and P. abies had higher quantities and average concentrations of Zn in the biomass. For all species, >50% of the Zn in the stems was found in the bark. P. abies and L. sibirica had higher quantities of Cu in the biomass than the other species.P. abies and P. contorta had high quantities of Cd inthe biomass in relation to the other species. Branches and stembark contained high concentrations of Cd and Pb in relation to foliage and stemwood. Dead branches had especially high concentrations of Pb. The high accumulation rate of Zn in thebiomass of B. pendula was related to a low exchangeable amount of Zn in the A horizon. In the superficial centimeters ofthe A horizon, a depletion similar to that found for Zn was detected for Cu, whereas for Cd and Pb, no correlations were found between quantities of elements in the trees and element pools in the soil.     

Starch-plastic materials—Preparation,physical properties,and biodegradability (a review of recent USDA research)

Recent starch-plastic research at the National Center for Agricultural Utilization Research is reviewed and related worldwide efforts are noted. Properties of starch that influence its formulation and performance in plastics are discussed. Methods are given for preparation of starch-poly(methyl acrylate) graft copolymer, starch-poly(ethylene-co-acrylic acid), and starch-poly(ethylene-co-acrylic acid)-polyethylene plastics. Their physical properties are discussed, as is degradability by enzymes or amylolytic organisms from soil, ponds, and streams.The mention of firm names or trade products does not imply that they are endorsed or recommended by the U.S. Department of Agriculture over other firms or similar products not mentioned.     

Application of Cellulose Microfibrils in Polymer Nanocomposites

Cellulose microfibrils obtained by the acid hydrolysis of cellulose fibers were added at low concentrations (2–10% w/w) to polymer gels and films as reinforcing agents. Significant changes in mechanical properties, especially maximum load and tensile strength, were obtained for fibrils derived from several cellulosic sources, including cotton, softwood, and bacterial cellulose. For extruded starch plastics, the addition of cotton-derived microfibrils at 10.3% (w/w) concentration increased Young’s modulus by 5-fold relative to a control sample with no cellulose reinforcement. Preliminary data suggests that shear alignment significantly improves tensile strength. Addition of microfibrils does not always change mechanical properties in a predictable direction. Whereas tensile strength and modulus were shown to increase during addition of microfibrils to an extruded starch thermoplastic and a cast latex film, these parameters decreased when microfibrils were added to a starch–pectin blend, implying that complex interactions are involved in the application of these reinforcing agents.     

四氮唑废水处理工艺设计

高浓度、高盐分的四氮唑生产废水通过三效蒸发浓缩,馏出液经铁炭氧微电解和混凝预处理,再采用水解酸化一接触氧化一反应二沉主体组合工艺进行处理。研究了该工艺所需构筑物和设备的设计与选型。该工艺在正常运行条件下,处理后出水pH6～9,COD 302mg／L,BOD5 108mg／L,SS30mg／L,色度36倍,水质达到GB8978--1996（污水综合排放标准》三级标准。     

Bioassessment of silvicultural impacts in streams and wetlands of the Eastern United States

Bioassessment is a useful tool to determine the impact of logging practices on the biological integrity of streams and wetlands. Measuring biota directly has an intuitive appeal for impact assessment, and biota can be superior indicators to physical or chemical characteristics because they can reflect cumulative impacts over time. Logging can affect stream and wetland biota by increasing sedimentation rates, altering hydrologic, thermal, and chemical regimes, and changing the base of food webs. Biotic impacts of logging on streams compared to wetlands probably differ, and in this paper we review some of those differences. In streams, invertebrates, fishes, amphibians, algae, and macrophytes have been used as indicators of logging impacts. In wetlands, bioassessment is just beginning to be used, and plants and birds are the most promising indicator taxa. Various best management practices (BMPs) have been developed to reduce the impacts of logging on stream and wetland biota, and we review quantitative studies that have evaluated the efficacy of some of these techniques in streams and wetlands in the eastern United States. Remarkably few studies that address the overall efficacy of BMPs in limiting biotic changes in streams and wetlands after BMP implementation have been published in scientific journals, although some work exists in reports or is unpublished. We review these works, and compile conclusions about BMP efficacy for biota from this body of research.     

Characterization of air emissions and residual ash from open burning of electronic wastes during simulated rudimentary recycling operations

Air emissions and residual ash samples were collected and analyzed during experiments of open, uncontrolled combustion of electronic waste (e-waste), simulating practices associated with rudimentary e-waste recycling operations. Circuit boards and insulated wires were handled separately to simulate processes associated with metal recovery. The average emissions of polychlorinated dibenzodioxins and dibenzofurans (PCDD/PCDFs) were 92 ng toxic equivalency (TEQ)/kg [n = 2, relative standard deviation (RSD) = 98%] and 11 900 ng TEQ/kg (n = 3, RSD = 50%) of the initial mass of the circuit boards and insulated wire, respectively. The value for the insulated wire is about 100 times higher than that for backyard barrel burning of domestic waste. The emission concentrations of polybrominated dibenzodioxins and dibenzofurans (PBDD/PBDFs) from the combustion of circuit boards were 100 times higher than for their polychlorinated counterparts. Particulate matter (PM) sampling of the fly ash emissions indicated PM emission factors of approximately 15 and 17 g/kg of the initial mass for the circuit boards and insulated wire, respectively. Fly ash samples from both types of e-waste contained considerable amounts of several metallic elements and halogens; lead concentrations were more than 200 times the United States regulatory limits for municipal waste combustors and 20 times those for secondary lead smelters. Leaching tests of the residual bottom ash showed that lead concentrations exceeded U.S. Environmental Protection Agency landfill limits, designating this ash as a hazardous waste.     

Does Soil Acidification Affect Spruce Needle Chemical Composition and Tree Growth?

In 1994, a large survey of soil chemistry was undertaken in thecounty of Värmland in central Sweden (Lundström et al., 1998).The southern part of the county was affected by soilacidification whereas there were no such indications in thenorthern part. To investigate the influence of soil chemistryon the trees at the specific sites, the survey was continued byan analysis of needle chemistry (Norway spruce) which wasundertaken at 150 of the 180 sites, and of tree growth at 65 ofthe 180 sites. Growth was expressed as a ratio between expectedgrowth, estimated with a national, empirical growth model, andthe growth observed in the field. In statistical analyses,using rank correlation, PCA and PLS, there were only weakindications of an influence of soil chemistry on needlechemistry and on tree growth. A moderate correlation betweennitrogen and sulphur in needles was found, which wasinterpreted as an effect of deposition and of processes in thetree canopy. No obvious regional pattern of the growth ratiowas found, in contrast to the clear pattern of soilacidification. The statistical analysis could not with anycertainty point out any of the soil chemistry variables asespecially important for the tree growth ratio.     

Solubility and Potential Mobility of Heavy Metals in Two Contaminated Urban Soils from Stockholm,Sweden

The solubility and potential mobility of heavy metals (Cd, Cu,Hg, Pb and Zn) in two urban soils were studied by sequential andleaching extractions (rainwater). Compared to rural (arable) soils on similar parent material, the urban soils were highlycontaminated with Hg and Pb and to a lesser extent also with Cd,Cu and Zn. Metal concentrations in rainwater leachates were related to sequential extractions and metal levels reported fromStockholm groundwater. Cadmium and Zn in the soils were mainly recovered in easily extractable fractions, whereas Cu and Pb were complex bound. Concentrations of Pb in the residual fractionwere between two- and eightfold those in arable soils, indicatingthat the sequential extraction scheme did not reflect the solidphases affected by anthropogenic inputs. Cadmium and Zn conc. inthe rainwater leachates were within the range detected in Stockholm groundwater, while Cu and Pb conc. were higher, whichsuggests that Cu and Pb released from the surface soil were immobilised in deeper soil layers. In a soil highly contaminatedwith Hg, the Hg conc. in the leachate was above the median concentration, but still 50 times lower than the max concentration found in groundwater, indicating the possibilityof other sources. In conclusion, it proved difficult to quantitatively predict the mobility of metals in soils by sequential extractions.     

Biodegradation of Injection Molded Starch-Poly (3-hydroxybutyrate-co-3-hydroxyvalerate) Blends in a Natural Compost Environment

Injection molded specimens were prepared by blending poly (hydroxybutyrate-co-valerate) (PHBV) with cornstarch. Blended formulations incorporated 30% or 50% starch in the presence or absence of poly-(ethylene oxide) (PEO), which enhances the adherence of starch granules to PHBV. These formulations were evaluated for their biodegradability in natural compost by measuring changes in physical and chemical properties over a period of 125 days. The degradation of plastic material, as evidenced by weight loss and deterioration in tensile properties, correlated with the amount of starch present in the blends (neat PHBV < 30% starch < 50% starch). Incorporation of PEO into starch-PHBV blends had little or no effect on the rate of weight loss. Starch in blends degraded faster than PHBV and it accelerated PHBV degradation. Also, PHBV did not retard starch degradation. After 125 days of exposure to compost, neat PHBV lost 7% of its weight (0.056% weight loss/day), while the PHBV component of a 50% starch blend lost 41% of its weight (0.328% weight loss/day). PHB and PHV moieties within the copolymer degraded at similar rates, regardless of the presence of starch, as determined by ¹H-NMR spectroscopy. GPC analyses revealed that, while the number average molecular weight (Mn) of PHBV in all exposed samples decreased, there was no significant difference in this decrease between neat PHBV as opposed to PHBV blended with starch. SEM showed homogeneously distributed starch granules embedded in a PHBV matrix, typical of a filler material. Starch granules were rapidly depleted during exposure to compost, increasing the surface area of the PHBV matrix.     

Effects of Nitrogen Deposition on Bryophyte Species Composition of Calcareous Grasslands

Regular additions of NH₄NO₃ (35–140 kg N ha⁻¹ yr⁻¹) and (NH₄)₂SO₄ (140 kg N ha⁻¹ yr⁻¹) to a calcareous grassland in northern England over a period of 12 years have resulted in a decline in the frequency of the indigenous bryophyte species and the establishment of non-indigenous calcifuge species, with implications for the structure and composition of this calcareous bryophyte community. The lowest NH₄NO₃ additions of 35 kg N ha⁻¹ yr⁻¹ produced significant declines in frequency of Hypnum cupressiforme, Campylium chrysophyllum, and Calliergon cuspidatum. Significant reductions in frequency at higher NH₄NO₃ application rates were recorded for Pseudoscleropodium purum, Ctenidum molluscum, and Dicranum scoparium. The highest NH₄NO₃ and (NH₄)₂SO₄ additions provided conditions conducive for the establishment of two typical calcifuges – Polytrichum spp. and Campylopus introflexus, respectively. Substrate-surface pH measurements showed a dose-related reduction in pH with increasing NH₄NO₃ deposition rates of 1.6 pH units between the control and highest deposition rate, and a further significant fall in pH, of >1 pH unit, between the NH₄NO₃ and (NH₄)₂SO₄ treatments. These results suggest that indigenous bryophyte composition may be at risk from nitrogen deposition rates of 35 kg N ha⁻¹ yr⁻¹ or less. These effects are of particular concern for rare or endangered species of low frequency.