丙二酸二(2-(2,3-二羟基苯甲酰胺)乙基)酯的合成与螯合性能研究

用2,3-二羟基苯甲酸经羟基保护、酰胺化、酯化和去保护4步反应,生成一种新型的四齿丙二酸二(2-(2,3-二羟基苯甲酰胺)乙基)酯配体.采用傅里叶变换红外光谱(FT-IR)、紫外-可见光谱(UV-Vis)、核磁共振氢谱(1H NMR)、核磁共振碳谱(13C NMR)和质谱(MS)对其结构进行了表征.在中性pH值条件下,研究了这种配体对铀酰离子的络合能力.结果表明,丙二酸二(2-(2,3-二羟基苯甲酰胺)乙基)酯配体与铀酰离子的螯合常数为23.2.     

BTP-N_2复合气体配比优化及灭火临界条件研究

为了考察一溴三氟丙烯(简称BTP)与氮气(N2)所形成的复合灭火介质的复合比以及不同复合比下的临界灭火条件,开展了以下工作:首先,基于多组分分压原理,探讨了BTP-N2预混技术的可行性;其次,基于燃烧学和气体运动学理论,提出了BTP与N2复合灭火介质的灭火临界条件预测理论模型;再次,依据卤代烷灭火介质的特点和灭火机理,构建了临界灭火试验平台,对不同BTP和N2复合比下的复合气体灭火介质进行灭火临界条件研究;最后,通过实验结果修正和完善预测理论模型。结论:BTP-N2复合灭火介质的灭火临界条件理论值与实验值吻合性较好,因此该预测模型能很好地对复合卤烃灭火介质的临界灭火条件进行估算,为研究卤烃气体与惰性气体复合灭火介质的灭火机理及研发高效清洁灭火介质奠定了基础。     

PAN dust explosion inhibition mechanisms of NaHCO3 and Al(OH)3

We investigate the PAN dust explosion inhibition behaviors of NaHCO₃ and Al(OH)₃ in a 20 L spherical explosion system and a transparent pipe explosion propagation test system. The results show that, in the standard 20 L spherical explosion system, the highest PAN dust explosion concentration is 500 g/m³, the maximum explosion pressure is 0.661 MPa, and the maximum explosion pressure increase rate is 31.64 MPa/s; adding 50% NaHCO₃ and 60% Al(OH)₃ can totally inhibit PAN dust explosion. In the DN0.15 m transparent pipe explosion propagation test system, for 500 g/m³ PAN dust, the initial explosion flame velocity is 102 m/s, the initial pressure is 0.46 MPa, and the initial temperature is 967 °C; adding 60% NaHCO₃ and 70% Al(OH)₃ can totally inhibit PAN dust explosion flames. Through FTIR and TG analyses, we obtain the explosion products and pyrolysis patterns of the explosion products of PAN dust, NaHCO₃, and Al(OH)₃. On this basis, we also summarize the PAN dust explosion inhibition mechanisms of NaHCO₃ and Al(OH)₃.