Environmental occurrences, behavior, fate, and ecological effects of nanomaterials: an introduction to the special series

The release of engineered nanomaterials (ENMs) into the biosphere will increase as industries find new and useful ways to utilize these materials. Scientists and engineers are beginning to assess the material properties that determine the fate, transport, and effects of ENMs; however, the potential impacts of released ENMs on organisms, ecosystems, and human health remain largely unknown. This special collection of four review papers and four technical papers identifies many key and emerging knowledge gaps regarding the interactions between nanomaterials and ecosystems. These critical knowledge gaps include the form, route, and mass of nanomaterials entering the environment; the transformations and ultimate fate of nanomaterials in the environment; the transport, distribution, and bioavailability of nanomaterials in environmental media; and the organismal responses to nanomaterial exposure and effects of nanomaterial inputs, on ecological communities and biogeochemical processes at relevant environmental concentrations and forms. This introductory section summarizes the state of knowledge and emerging areas of research needs identified within the special collection. Despite recent progress in understanding the transport, transformations, and fate of ENMs in model environments and organisms, there remains a large need for fundamental information regarding releases, distribution, transformations and persistence, and bioavailability of nanomaterials. Moreover, fate, transport, bioaccumulation, and ecological impacts research is needed using environmentally relevant concentrations and forms of ENMs in real field materials and with a broader range of organisms.     

The role of atmospheric transformations in determining environmental impacts of carbonaceous nanoparticles

In studies that have explored the potential environmental impacts of manufactured nanomaterials, the atmosphere has largely been viewed as an inert setting that acts merely as a route for inhalation exposure. Manufactured nanomaterials will enter the atmosphere during production, use, and disposal, and rather than simply being transported, airborne nanoparticles are in fact subject to physical and chemical transformations that could modify their fate, transport, bioavailability, and toxicity once they deposit to aqueous and terrestrial ecosystems. The objective of this paper is to review the factors affecting carbonaceous nanomaterials' behavior in the environment and to show that atmospheric transformations, often overlooked, have the potential to alter nanoparticles' physical and chemical properties and thus influence their environmental fate and impact. Atmospheric processing of naturally occurring and incidental nanoparticles takes place through coagulation, condensation, and oxidation; these phenomena are expected to affect manufactured nanoparticles as well. It is likely that carbonaceous nanomaterials in the atmosphere will be oxidized, effectively functionalizing them. By influencing size, shape, and surface chemistry, atmospheric transformations have the potential to affect a variety of nanoparticle-environment interactions, including solubility, interaction with natural surfactants, deposition to porous media, and ecotoxicity. Potential directions for future research are suggested to address the current lack of information surrounding atmospheric transformations of engineered nanomaterials.     

An ecological perspective on nanomaterial impacts in the environment

Growing concerns over the potential for unintended, adverse consequences of engineered nanoparticles (ENPs) in the environment have generated new research initiatives focused on understanding the ecological effects of ENPs. Almost nothing is currently known about the fate and transport of ENPs in environmental waters, soils, and sediments or about the biological impacts of ENPs in natural environments, and the bulk of modern nanotoxicogical research is focused on highly controlled laboratory studies with single species in simple media. In this paper, we provide an ecological perspective on the current state of knowledge regarding the likely environmental impacts of nanomaterials and propose a strategy for making rapid progress in new research in ecological nanoscience.     

The Environmental Pollution Perception of Residents in Coal Mining Areas: A Case Study in the Hancheng Mine Area, Shaanxi Province, China

The environmental behavior of the residents depends on their perception of environmental pollution. Hence, it is important for scientific and policy experts to research on the impact of the environmental pollution perception of local residents. Owing to the richness of natural resources, Hancheng coal mine areas are abound in heavy industries, and environmental pollution is serious and typical in this area, thus, the residents are anxious about their health. Using questionnaires, this paper surveys the perception of residents living in the coal mine area. The influential factors of environmental perception were analyzed by the Rank Sum Test. The results were: (1) the majority of the residents in the coal mine area are not satisfied with their living environment. The perception order of pollution severity is: air pollution?>?noise pollution?>?sanitation?>?water pollution. The residents think that pollution is mainly caused by coal processing. Hence, coal mining is not the main reason of the pollution in the coal mine area. (2) Age and length of residence have significant positive effects on perceptions of air, water, and noise pollutions; whereas education has a significant negative effect on perceptions of water and noise pollutions, as well as sanitation. This phenomenon can be explained by the various cultural groups having varied perceptions on the environmental pollution. In addition, proximity to mine has significant negative effect on perceptions of water and noise pollution. In conclusion, the paper discusses the effects of demographical and social factors on the perception of environmental pollution and gives suggestions on the planning and management of the environment.     

Building a model of commitment to the natural environment to predict ecological behavior and willingness to sacrifice

We examined the connection between individuals’ relationships with the natural environment and their environmental behaviors with a focus on commitment to the environment, defined as psychological attachment and long-term orientation to the natural world. Commitment is theorized to emerge from structural interdependence with the environment and to lead to pro-environmental behaviors. Close relationships research has identified three key antecedents to commitment (satisfaction, alternatives, and investments). We developed environment-specific measures of these constructs, and factor analysis verified three distinct factors. A path analysis revealed that satisfaction with the environment and investments in the environment, but not alternatives to the environment, predicted commitment to the environment. Moreover, commitment mediated the effects of satisfaction and investments on general ecological behavior and willingness to sacrifice for the environment. In regression analyses, commitment predicted general ecological behavior and willingness to sacrifice for the environment, even when controlling for ecological worldview, inclusion of nature in the self, connectedness to nature, and environmental identity. Individuals who are satisfied with and invested in the natural world are likely to be committed to the environment and act with the well-being of the environment in mind.     

Sorption, mobility, and transformation of estrogenic hormones in natural soil

Potent estrogenic hormones are consistently detected in the environment at low concentration, yet these chemicals are strongly sorbed to soil and are labile. The objective of this research was to improve the understanding of the processes of sorption, mobility, and transformation for estrogens in natural soils, and their interaction. Equilibrium and kinetic batch sorption experiments, and a long-term column study were used to study the fate and transport of 17beta-estradiol and its primary metabolite, estrone, in natural soil. Kinetic and equilibrium batch experiments were done using radiolabeled 17beta-estradiol and estrone. At the concentrations used, it appeared that equilibrium sorption for both estrogens was achieved between 5 and 24 h, and that the equilibrium sorption isotherms were linear. The log K(oc) values for 17beta-estradiol (2.94) and estrone (2.99) were consistent with previously reported values. Additionally, it was found that there was rate-limited sorption for both 17beta-estradiol (0.178 h(-1)) and estrone (0.210 h(-1)). An approximately 42 h long, steady-flow, saturated column experiment was used to study the transport of radiolabeled 17beta-estradiol, which was applied in a 5.00 mg L(-1) solution pulse for 44 pore volumes. 17beta-estradiol and estrone were the predominant compounds detected in the effluent. The effluent breakthrough curves were asymmetric and the transport modeling indicated that sorption was rate-limited. Sorption rates and distributions of the estrogens were in agreement between column and batch experiments. This research can provide a better link between the laboratory results and observations in the natural environment.     

Fate of pesticides in combined paddy rice-fish pond farming systems in northern Vietnam

During the last decades, high population growth and export-oriented economics in Vietnam have led to a tremendous intensification of rice production, which in turn has significantly increased the amount of pesticides applied in rice cropping systems. Since pesticides are toxic by design, there is a natural concern on the impact of their presence in the environment on human health and environmental quality. The present study was designed to examine the water regime and fate of pesticides (fenitrothion, dimethoate) during two consecutive rice crop seasons in combined paddy rice-fish pond farming systems in northern Vietnam. Major results revealed that 5 and 41% (dimethoate), and 1 and 17% (fenitrothion) of the applied mass of pesticides were lost from the paddy field to the adjacent fish pond during spring and summer crop seasons, respectively. The decrease of pesticide concentration in paddy surface water was very rapid with dissipation half-life values of 0.3 to 0.8 and 0.2 d for dimethoate and fenitrothion, respectively. Key factors controlling the transport of pesticides were water solubility and paddy water management parameters, such as hydraulic residence time and water holding period. Risk assessment indicates that the exposure to toxic levels of pesticides for aquaculture (, ) is significant, at least shortly after pesticide application.     

Dynamic modeling of chemical fate and transport in multimedia environments at watershed scale-II: trichloroethylene test case

A multimedia environmental fate model was developed to study the temporal dynamics and spatial distribution of a chemical pollutant at watershed scale. The theoretical considerations and implementation of the model were described in the accompanying paper (Part I). This paper presents the result of a test simulation on the transport of trichloroethylene (TCE) in the Connecticut River Basin. The simulation results were reported as time series of concentrations and inter-media transport fluxes in the compartments of atmosphere, plant, soil, surface water, and sediment. Predicted concentrations from the test simulation were compared with published field data or predictions by validated models. The temporal trends in TCE predictions were evaluated by comparing the simulation results with monthly TCE concentrations in various environmental compartments and monthly fluxes of inter-media transport processes. Results indicated that the simulation results were in reasonable agreement with reported data in the literature. The results also revealed that the mass transport of TCE from the atmosphere compartment to soil and surface water was a major route of TCE dispersion in the environment.     

高含硫天然气钻井环境风险评价及防范措施

天然气钻井作业由于地下情况复杂隐藏着多种不安全因素,存在着较大的环境风险。要真正减少钻井施工现场的安全事故,必须充分了解影响钻井施工安全的风险源,评估风险的危害性的大小及范围,通过抓好安全生产管理,对风险进行控制,达到安全生产施工的目标。文章分析了天然气钻井中可能出现的环境风险因素,提出预防或减缓事故的对策和措施,为钻井行业提供安全可靠的参考。     

Land classification used to select abandoned hazardous waste study sites

The biological effects of hazardous substances in the environment are influenced by climate, physiography, and biota. These factors interact to determine the transport and fate of chemicals, but are difficult to model accurately except for small areas with a large data base. The requirement for a large data base may be reduced locally if the regional influences of these factors were predetermined from existing data. Knowledge of the regional factors would also relax the restriction to considering only small areas. This paper advocates consideration of regional characteristics of the environment in the early stages of waste management strategy development. It presents as an example a procedure for selecting study sites from candidate-abandoned hazardous waste dumpsites in the southeastern United States. It uses small-scale maps of low resolution from the National Atlas to delineate the boundaries and to determine the environmental characteristics that prevail over units of land within the region. A computer map-overlay and graphic approach is used to facilitate the grouping of land types. Abandoned hazardous waste dumpsites found within land types that best represent the region are surveyed for selecting a study site. It is expected that environmental impact data obtained from a representative site would be useful for predicting impact potentials in similar remotely located areas within the same general region.     

ENVIRONMENTAL CONCERN: CONCEPTUAL DEFINITIONS, MEASUREMENT METHODS, AND RESEARCH FINDINGS

A serious threat to human beings and their environment is the continuous and accelerating overuse and destruction of natural resources. Bearing this in mind, it is unfortunate that efforts to permanently change people's environmentally destructive behaviour through interventions has typically not been met with success. A necessary condition may be an increase in environmental concern and knowledge about the effects and consequences of the ongoing environmental deterioration for future generations. Studies are reviewed that have attempted to show (1) correlations between determinants, such as socio-demographic and/or psychological factors, and environmental concern, and (2) an impact of environmental concern on environmentally responsible behaviour. In general, correlations with background factors are weak. Factors affecting behaviour appear to be knowledge, internal locus of control (positive control beliefs), personal responsibility, and perceived threats to personal health. The need for further research that attempts to specify the process leading to environmentally responsible behaviour is highlighted. A new framework is presented which integrates some of the previous research.     

Economic transition and environmental sustainability: effects of economic restructuring on air pollution in the Russian Federation

Economic liberalization in former socialist countries may have various implications for their environmental sustainability. Positive effects of this process are potentially associated with improved efficiency, investments into cleaner technologies, responsiveness to environmentally aware markets, and ending subsidies to heavy industries. On the other hand, market liberalization may result in weaker environmental controls, economic instabilities distracting attention from environmental issues, and increasing orientation towards profit-making leading to more intensive exploitation of natural resources. In addition, trade liberalization may result in shifts towards more pollution and resource-intensive industries. This article seeks to quantify effects of economic restructuring in Russia on air pollution from productive economic sectors in the 1990s. Air pollution in Russia had significantly declined in 1991-1999, however, this decline was largely due to economic decline, as the overall pollution intensity of the economy had decreased only slightly. The factors that affected the pollution intensity are: (1) a decrease in the combined share of industrial and transport activities in the economy and (2) changing pollution intensities of the industrial and transport sectors. The pollution intensity of the Russian industry had remained relatively stable during the 1990s. This was the result of the two opposite and mutually canceling trends: (a) increasing shares of pollution-intensive branches such as metal smelting and oil production vs. less pollution intensive manufacturing and (b) decline in pollution intensities within the industrial branches. The article proposes a methodology by which the contribution of both factors to the overall pollution intensity of the industrial sector can be quantified. The pollution intensity of the Russian transport sector appears to have declined in the first half of the 1990s and increased in the second half. The most recent trend can be explained by a rising proportion of private motorcars used for transportation of people and goods instead of traditional rail and other public transport. The findings of the paper demonstrate that shifts towards more pollution-, resource- and energy-intensive industries as a result of economic liberalization emerges as a significant negative factor of the process of economic transition threatening sustainability of emerging market economies. A research agenda to further investigate these impacts is proposed.     

New perspectives in ecotoxicology

The task of regulating potentially harmful chemicals in the environment is presently hindered by the lack of appropriate concepts and methods for evaluating the effects of anthropogenic chemicals on ecosystems. Toxicity tests at the molecular and physiological levels have been used successfully as indicators of adverse effects on test organisms and have been extrapolated to humans to establish a basis for risk assessment. However, laboratory measurements of effects upon individuals do not translate readily into potential effects upon natural populations, in part because natural populations interact with other populations and with the physical environment. Even more difficult to assess are the deleterious impacts of anthropogenic chemicals on ecosystems, because of effects on species interactions, diversity, nutrient cycling, productivity, climatic changes, and other processes.Effects on ecosystems resulting from chemical stresses are outside the realm of classical toxicology, and an ecosystem-level perspective is essential for the consideration of such effects; but the science that deals with ecosystem-level effects,ecotoxicology, is still developing. This article synthesizes the topics discussed at a workshop on ecotoxicology held by the Ecosystems Research Center at Cornell University. Topics covered include: the regulatory framework in which ecotoxicological research must be applied; ecosystem modification of toxicant fate and transport; how ecosystem composition, structure, and function are influenced by chemicals; methods currently available for predicting the effects of chemicals at the ecosystem level; and recommendations on research needs to enhance the state of the science of ecotoxicology.     

天然气勘探开发项目综合环境影响评价指标体系研究

针对目前天然气勘探开发项目环境影响评价不够系统的局限性,运用系统的思想观点和思维方法提出了天然气勘探开发项目综合环境影响评价指标体系.该评价体系把综合环境影响评价分为政策法规环境影响、自然生态环境影响、资源能源环境影响、经济环境影响、社会环境影响和科技环境影响等六大环境影响进行评价.借鉴环境影响评价的相关研究成果,分别为上述六大环境影响评价设计了具体的评价因子和评价指标.     

Environmental conservation problems in Kuwait

Summary Environmental problems in Kuwait arise from a number of factors: principally climate, population growth, industrialisation, transport and recreation. The impact of these factors on the environment is discussed in the context of growing awareness of the need for conservation of the remaining facets of Kuwait's heritage. The need to move from discussion of these extant environmental problems to effective action is stressed. Both education and the media have a vital role to play in sharpening awareness of problems and their solutions in the short time-scale left for conservation measures.Eric Caulton is Senior Lecturer and Ecologist in the Department of Biological Sciences, Napier Polytechnic of Edinburgh. In April 1987 he visited Kuwait to undertake an environmental Impact Assessment in the south for the consultants involved in planning Al Khiran new town.David Keddie is an urban planning and economic consultant, and Associate with Roger Tym and Partners. He has worked for both the government and private consultants in Kuwait on various occasions since 1982.     

大气环境因素与腐蚀速率的模糊聚类分析

本文针对我国8个典型大气环境试验站的环境因素数据与基础金属腐蚀数据。采用模糊聚类方法对15项环境因素进行分类,探讨各项环境因素之间的相关性。分析结果表明：有4项环境因素对基础金属腐蚀等级的影响性较高。     

National, holistic, watershed-scale approach to understand the sources, transport, and fate of agricultural chemicals

This paper is an introduction to the following series of papers that report on in-depth investigations that have been conducted at five agricultural study areas across the United States in order to gain insights into how environmental processes and agricultural practices interact to determine the transport and fate of agricultural chemicals in the environment. These are the first study areas in an ongoing national study. The study areas were selected, based on the combination of cropping patterns and hydrologic setting, as representative of nationally important agricultural settings to form a basis for extrapolation to unstudied areas. The holistic, watershed-scale study design that involves multiple environmental compartments and that employs both field observations and simulation modeling is presented. This paper introduces the overall study design and presents an overview of the hydrology of the five study areas.     

锦州油田开发建设中的污染影响及控制措施浅析

油田开发建设中潜在危险因素主要有自然灾害、环境腐蚀、误操作、设备缺陷、施工及人为破坏等问题,结合锦州油田开发建设及所处周边环境的实际情况,通过对来自于钻井、修井作业及油气集输系统的油气水渗漏等相关的工艺环节进行风险评价与分析,分析了油田开发建设对大气、生态、土壤、水环境的影响,从工艺、管理等方面提出了具体污染预防控制措施,并分析了建立应急预案的重要性。     

Environmental Effectiveness of Swine Sewage Management: A Multicriteria AHP-Based Model for a Reliable Quick Assessment

Environmental issues related to swine production are still a major concern for the general public and represent a key challenge for the swine industry. The environmental impact of higher livestock concentration is particularly significant where it coincides with weaker policy standards and poor manure management. Effective tools for environmental monitoring of the swine sewage management process become essential for verifying the environmental compatibility of farming facilities and for defining suitable policies aimed at increasing swine production sustainability. This research aims at the development and application of a model for a quick assessment of the environmental effectiveness of the pig farming sewage management process. In order to define the model, multicriteria techniques, and in particular, Saaty’s analytic hierarchy process, were used to develop an iterative process in which the various key factors influencing the process under investigation were analyzed. The model, named EASE (Environmental Assessment of Sewages management Effectiveness), was optimized and applied to the Lake Trasimeno basin (Umbria, Italy), an area of high natural, environmental and aesthetic value. In this context, inadequate disposal of pig sewage represents a potential source of very considerable pollution. The results have demonstrated how the multicriteria model can represent a very effective and adaptable tool also in those decision-making processes aimed at the sustainable management of livestock production.