滤袋数目对翼形上进风袋式除尘器内流场影响的数值模拟研究

针对实际运行过程中,袋式除尘器滤袋使用寿命短,压力损失过大的问题,本文以翼形上进风袋式除尘器为研究对象,采用CFD(computational fluid dynamics)技术模拟分析不同滤袋数(分别为92、88、84、80、76和72)时袋式除尘器内气流分布和压力损失规律。主要考察了流量分配系数、最大流量不均幅值、气流迹线、滤袋表面速度分布与压降等指标。结果表明,滤袋数为76个时,气流分布最为均匀,各滤袋负载均衡;相同过滤速度下,装置的压降随滤袋数目的增加而上升,即压降大小顺序为9288847672;与72个滤袋相比,76个滤袋的可用过滤面积更大。综合考虑,袋式除尘器的最优滤袋数目为76个。模拟结果为袋式除尘器的设计和优化提供了依据。     

基于故障树分析法袋式除尘器滤袋失效的研究与应用

在分析影响袋式除尘器滤袋失效因素的基础上,应用故障树分析法(fault tree analysis,FTA)对袋式除尘器滤袋的失效进行研究。以某袋式除尘器为例,建立该袋式除尘器滤袋失效的故障树,并结合其运行及废弃滤袋的调查情况,分析影响其滤袋失效的主要因素。结果表明,该袋式除尘器滤袋失效的主要影响因素为清灰压力峰值分布的不均匀(清灰不彻底)所导致的运行阻力过高。在此基础上,利用计算流体动力学(CFD)方法建立该袋式除尘器清灰数值计算模型,模拟其清灰时滤袋表面的压力峰值分布,发现该布袋除尘器滤袋底部表面的清灰压力峰值较低,无法达到正常清灰的要求,从而验证了故障树分析的正确性。以数值模拟为指导,改进该袋式除尘器的清灰结构,改善其清灰效果。     

旋风-滤袋复合除尘器的数值模拟分析

为了分析旋风-滤袋复合除尘器的内部流场,借助流体分析软件Fluent对旋风-滤袋复合除尘器的运行机理进行了数值模拟分析。结果显示,除尘器总体上达到了除尘设计目的,但在气流分配上存在不足,容易对部分滤袋造成过度冲刷,影响滤袋使用寿命。通过加装导流元件的方式可以有效改善气流分布不均的情况。     

基于流固耦合的滤袋振动的数值模拟

滤袋是决定袋式除尘器除尘效率的关键元件,由于是柔性的悬挂结构,相邻的滤袋在气流作用下可能会发生相互碰撞,引起严重的破袋事故。针对该问题采用流固耦合方法,对袋式除尘器流场引起柔性滤袋的振动进行了数值模拟。分别以3个大小不同的进口风速模拟了滤袋的振动规律,得到了滤袋底部一点的位移图和轨迹图,结果表明,进口速度越大,滤袋的位移越大。所以有效地控制进口风速和提高内部气流速度的均匀性,可以减少滤袋的破袋事故,对节约更换滤袋的费用,有很大的经济效益。     

基于ASMM模型对不同袋长袋式除尘器气固两相流的模拟

为了提高袋式除尘器内部流场的均匀性,延长滤袋的使用寿命以及降低能耗,以某环保公司下进风袋式除尘器为几何模型,采用简化的欧拉模型-代数滑移混合模型(algebraic slip mixture model,ASMM)模拟了3种袋长分别为6、8和10 m的袋式除尘器处理粒径为1、2.5、5、10和20μm颗粒时其内的气固两相流动。对比分析了不同袋长除尘器内速度云图、颗粒相体积份额以及压力损失等,结果表明:随着滤袋长度的增加,除尘器内部流场的均匀性提高;袋式除尘器对5种不同粒径颗粒都具有一定的去除能力,滤袋长度为8 m时受到的二次扬尘影响较小;滤料及粉尘层厚度为2 mm时,袋式除尘器的压力损失随着滤袋长度的增加而增加,颗粒粒径对除尘器压力损失的影响较小;通过对比袋长为8 m时除尘器模拟压降与实验结果,验证了模拟结果的可靠性。因此,除尘器的最优袋长为8 m,模拟结果为袋式除尘器的设计和优化提供了理论依据。     

袋式除尘器喷管喷吹口径优化

喷管喷吹均匀是为了使同一排滤袋清灰力度均匀。针对袋式除尘器喷管喷吹气流均匀性的问题,国内外学者对各喷嘴出口气流质量流量的均匀性十分关注。采用流体力学fluent软件对喷管内流场进行模拟,提出了同一排滤袋清灰强弱分布受到各喷嘴出口气流的动量通量分布的影响,而不是质量流量的看法。对引射空间流场进行模拟,验证了这一看法。结果表明,为了达到喷管喷吹均匀,应使各喷嘴出口气流动量通量分布均匀。采用动量通量修正和重复迭代的方法对喷管喷吹口径进行优化设计,获得了较好的动量通量均匀性。     

脉冲袋式除尘器喷吹管内压缩气流喷吹均匀性的数值模拟

运用计算流体力学(CFD)的方法,对大型脉冲袋式除尘器清灰时喷吹管内压缩气流喷吹的均匀性进行了数值模拟研究。在对传统等直径喷嘴的喷吹管出口的平均质量流量、流量偏差和喷嘴内气流的速度场进行分析的基础上发现,通过改变喷嘴直径和形状可以提高喷吹管系统的清灰均匀性。其中,采用锥形变径喷嘴时,喷吹管喷出的压缩气流的流量偏差降到2%以内,喷嘴内气流合速度方向与径向夹角几乎为零,到达滤袋的速度明显增大,极大改善了喷吹管喷吹气流的均匀性,有效提高滤袋的清灰强度,为袋式除尘器清灰系统的优化设计提供了依据。     

下进风内滤式袋式除尘器流场的模拟与优化

为优化袋式除尘器内部流场、提高除尘效率,以实验室规模的下进风内滤式袋式除尘器为原型,利用计算流体动力学(CFD)技术模拟其内流场并进行优化(将进口管改为渐扩型进口管、进口处增设多孔板、滤袋进口处增设3块导流挡板),再现颗粒相运动轨迹,采用均方根值法及流量分配系数法对流场均匀性校验。结果显示:优化后进口射流和灰斗处的涡流消失,内部流场均匀性得到改善,其均方根为0.095,颗粒相在滤袋中分布均匀。     

袋式除尘器入口烟道流场数值模拟与优化设计

采用计算流体动力学(CFD)方法,对某热电厂350 MW机组袋式除尘器入口烟道及除尘器内部的气流流场分布进行了数值模拟实验研究。识别了原烟道设计结构存在的问题,分析了造成各除尘器单元流量分配不均匀和除尘器喇叭口进口断面速度分布不均匀的原因,并提出了改变进口烟道形状,在入口烟道布置导流板的优化方案。经过模拟仿真对比,优化后并联的5个除尘器单元流量分配不均匀性得到明显改善,最大流量偏差由10.79%减小至-2.29%,且5个喇叭口进口断面速度相对均方根值均不大于0.25,满足技术规范要求。     

低能耗脉冲喷吹袋式除尘器的三维数值模拟及工程应用

以袋式除尘器装置为研究对象,考虑射流偏移,建立了脉冲喷吹清洁的三维CFD数值模型,并进行实验验证;对喷嘴与文丘里管优化设计,修改数值模型,研究了低能耗下的脉冲喷吹清灰效果;在将改进的喷嘴与文丘里管进行工程应用的过程中,研究了其对大气粉尘排放的影响。结果表明,建立的三维CFD模型展现出了高瞬态行为和可压缩效应,即在射流中表现出涡流环与冲击单元现象。与孔喷嘴相比,改进后的喷嘴设计对射流偏移进行了调整,并且使滤袋内脉冲压力增加了5.1%～13.3%,提升了清灰效果。对比喉部直径为85 mm的文丘里管,无文丘里管的设计使得射流不易进入滤袋中,导致滤袋内脉冲压力降低了41.4%～46.3%,引起清灰效果的下降;减小文丘里管喉部直径,可以减少回流,提升滤袋内脉冲压力,改善清灰效果。对比原始装置,安装了改进喷嘴与文丘里管的袋式除尘器能明显降低大气粉尘排放,以上研究结果可为脉冲喷吹清灰除尘器的优化设计提供参考。     

Chloroaromatic pollutants in mussels incubated in two finnish watercourses polluted by industry

Concentrations of different chlorinated compounds were measured in mussels incubated in two polluted watercourses, a river (the River Kymijoki) and a lake (Lake Vanaja) for four weeks in summer 1995. The sum concentrations of polychlorinated phenols (PCP) and biphenyls (PCB) were both about 1 μg/g lipid weight (lw) in Lake Vanaja mussels, while in the River Kymijoki mussels PCPs were non-detectable and PCBs were measured 120 ng/g lIw. The concentrations of toxic polychlorinated dibenzo-p-dioxin (PCDD) and dibenzofuran (PCDF) congeners ranged between <17 and 370 pg/g Iw in Lake Vanaja mussels and between <38 and 11,000 pg/g lw in the River Kymijoki mussels. Polychlorinated diphenyl ethers (PCDE) were detected in the mussels incubated in the River Kymijoki (0.4–1.1 ng/g Iw), but not in those incubated in Lake Vanaja. Polychlorinated phenoxyanisoles (PCPA) were measured 33 ng/g lw and polychlorinated phenoxyphenols (PCPP) 300 ng/g lw in the mussels incubated in the River Kymijoki. PCPAs were also detected in reference samples, which were sediment and pike from the River Kymijoki and Baltic salmon, seal and white-tailed sea eagle.     

Book review

The Pesticide Manual ‐ A World Compendium, 8th Edition, C.R. Worthing, Editor and S.B. Walker, Assistant Editor, British Crop Protection Council, BCPC Publications Sales, Bear Farm, Binfield, Bracknell, Berkshire RG12 5QE, England. 1987, 1100 pp., UK £50; Overseas £56. ISBN 0–948404–01–9.     

Organochlorine compounds in a three-step terrestrial food chain

The concentrations of 15 organochlorine chemicals (PCBs and pesticides) were studied in a Central European oak wood food chain system: Great tit (Parus major), caterpillars (Tortrix viridana, Operophtera brumata, Erannis defoliaria), and oak-leaves (Quercus robur). Juvenile tits receive organochlorines from the mother via egg transfer and, eventually to a greater extent, from the caterpillar food source during nestling period. The concentrations of PCB 153 (2,2′,4,4′,5,5′-hexachlorobiphenyl, the most abundant in this study) was found in leaf material at ca. 1 ng/g, in caterpillars 10 ng/g, and in bird eggs 170 ng/g on an average and on a dry mass basis.     

The chemical stability of formulations of some hydrolyzable insecticides in aqueous mixtures with hydrolysis catalysts

Abstract

The active ingredients in commercial formulations of malathion, oxamyl, carbaryl, diazinon, and chlorpyrifos diluted to “spray tank”; concentrations with buffered distilled or natural water of pH 4–9 were stable for at least 24 hr. Formulations of trichlorfon were not stable at pH 7 or above but disappearance rates were slower than for the pure chemical in homogeneous solution. Cupric ion was observed to be an effective catalyst for the hydrolysis of a variety of pure organophosphorus insecticides but did not catalyze hydrolysis of the active ingredients of the formulations examined. Increasing the dilution of the formulation increased the susceptibility of malathion, oxamyl, and carbaryl to hydrolysis.     

Radionuclides in pinon pine (Pinus edulis) nuts from los alamos national laboratory lands and the dose from consumption

Abstract

One of the dominant tree species growing within and around the eastern portion of Los Alamos National Laboratory (LANL), Los Alamos, NM, lands is the pinon pine (Pinus edulis). Pinon pine is used for firewood, fence posts, and building materials and is a source of nuts for food—the seeds are consumed by a wide variety of animals and are also gathered by people in the area and eaten raw or roasted. This study investigated the (1) concentration of ³H, ¹³⁷Cs, ⁹⁰Sr, ^totU, ²³⁸Pu, ^{239, 240}Pu, and²⁴¹ Am in soils (0‐ to 12‐in. [31 cm] depth underneath the tree), pinon pine shoots (PPS), and pinon pine nuts (PPN) collected from LANL lands and regional background (BG) locations, (2) committed effective dose equivalent (CEDE) from the ingestion of nuts, and (3) soil to PPS to PPN concentration ratios (CRs). Most radionuclides, with the exception of ³H in soils, were not significantly higher (p < 0.10) in soils, PPS, and PPN collected from LANL as compared to BG locations, and concentrations of most radionuclides in PPN from LANL have decreased over time. The maximum net CEDE (the CEDE plus two sigma minus BG) at the most conservative ingestion rate (10 lb [4.5 kg]) was 0.0018 mrem (0.018 μSv); this is far below the International Commission on Radiological Protection (all pathway) permissible dose limit of 100 mrem (1000 μSv). Soil‐to‐nut CRs for most radionuclides were within the range of default values in the literature for common fruits and vegetables.     

Degradation and sorption of imidacloprid in dissimilar surface and subsurface soils

Degradation and sorption/desorption are important processes affecting the leaching of pesticides through soil. This research characterized the degradation and sorption of imidacloprid (1-[(6-chloro-3-pyridinyl)-methyl]-N-nitro-2-imidazolidinimine) in Drummer (silty clay loam) and Exeter (sandy loam) surface soils and their corresponding subsurface soils using sequential extraction methods over 400 days. By the end of the incubation, approximately 55% of imidacloprid applied at a rate of 1.0 mg kg^?1 degraded in the Exeter sandy loam surface and subsurface soils, compared to 40% of applied imidacloprid within 300 days in Drummer surface and subsurface soils. At the 0.1 mg kg^?1 application rate, dissipation was slower for all four soils. Water-extractable imidacloprid in Exeter surface soil decreased from 98% of applied at day 1 to > 70% of the imidacloprid remaining after 400 d, as compared to 55% in the Drummer surface soil at day 1 and 12% at day 400. These data suggest that imidacloprid was bioavailable to degrading soil microorganisms and sorption/desorption was not the limiting factor for biodegradation. In subsurface soils > 40% of ¹⁴C-benzoic acid was mineralized over 21 days, demonstrating an active microbial community. In contrast, cumulative ¹⁴CO₂ was less than 1.5% of applied ¹⁴C-imidacloprid in all soils over 400 d. Qualitative differences in the microbial communities appear to limit the degradation of imidacloprid in the subsurface soils.     

Biochemical interaction of six op delayed neurotoxicants with several neurotargets

Abstract

Five organophosphorous insecticides: Leptophos, EPN, Cyano‐fenphos, trichloronate and salithion proved to cause irreversible ataxia not only to chicken but also to mice and sheep. TOCP was included as a reference. Cyanofenphos blocked the catecholamine B‐receptor binding activity with ³H‐norepinephrine at a level similar to that of the specific inhibitor propranolol in the mouse heart preparation. In the lamb heart preparation, the B‐receptor was more sensitive to Leptophos, salithion and TOCP than to propranolol. The six compounds and their oxons were screened for their in‐vitro inhibition to monamine oxidase (MAO), acetyl cholinesterase (AChE) and neurotoxic esterase (NTE) in the brain of either mouse, lamb or chicken. It is believed that their AChE inhibition stands for their acute toxicity, while NTE inhibition is responsible for their paralytic ataxia.     

土壤中砷的化学平衡

本文比较详细地综述了砷的化学特性,环境背景值及来源和循环,土壤中砷的三大化学平衡即沉淀溶解平衡,氧化还原平衡,吸附解吸平衡,以及微生物对砷的转化。     

Elemental uptake by edible herbs and lettuce (Latuca sativa)

The total concentration of toxic elements (aluminum, cadmium, chromium and lead) and selected macro and micro elements (iron, manganese, copper and zinc) are reported in six leafy edible vegetation species, namely lettuce, spinach, cabbage, chards and green and red types of Amaranth herbs. Although spinach and chards had greater than 125 mv of iron, both the amaranthus herbs recorded > than 320 μ g g^{? 1} dry weight. In both the spinach and chard species, the Mn and Zn levels were appreciable recording > 225 μ g g^{? 1} and 150 μ g g^{? 1} dry weight, respectively. Aluminum concentrations were (in μ g g^{? 1} dry weight) lettuce (10), cabbage (11), spinach (167), chards (65), amaranthus green (293) and amaranthus red (233). All the micro and macro elements and the toxic elements (Ni, Cr, Cd and Pb) elements analyzed, were below the recommended maximum permitted levels (RMI) in vegetables. Further the elemental uptake and distribution of the nine elements, at three growth stages of the lettuce plant grown on soil bed under controlled conditions are detailed. In the soil, except for iron (16%), greater than 33% of the other cations were in exchangeable form. Generally in the lettuce plant, roots retained much of the iron (> 224 μ g g^{? 1}) and aluminum (> 360 μ g g^{? 1}), while leaves had less than 200 μ g g^{? 1} of iron and 165 μ g g^{? 1} of Al. Although the concentrations of elements marginally decreased with growth, the lettuce leaves had significant amounts of Mn (30 μ g g^{? 1}), Zn (50 μ g g^{? 1}) and Cu (3.6 μ g g^{? 1}). Some presence of lead in leaves (2.0 μ g g^{? 1}) was noticed, but all the toxic and other elements analyzed were well below the RMI values for the vegetables.     

The dissipation of nonlyphenol in stream and pond water under simulated field conditions

Abstract

The dissipation of 1.0 ppm nonylphenol in stream and pond water, incubated in flasks at 16°C under simulated field conditions up to 44 days indicated that the half‐life was 2.5 days if the flasks were open, and 16 days if they were closed. A transformed product was detected in the closed flasks.

Translocation of nonylphenol in water occurred when treated water samples were incubated in the presence of sediment. After 10 days, nonylphenol was detected only in the sediment, but not in water (detection limit = 10 ppb). About 80% of the nonylphenol was degraded in 71 days, but no degradation occurred if the water and the sediment were autoclaved prior to incubation.