涡凹气浮(CAF)系统在处理石化废水中的应用

介绍了先进的污水处理系统——涡凹气浮系统,其工作原理与技术参数及在克拉玛依处理石化废水的工程实例。实际运行效果表明该系统具有占地少、投资与能源省,操作和管理简单,处理效果好等特点。在石油石化领域推广可收到较好的效果。     

~puvalisation废水生态净化床系统在分散型废水处理中的应用效果

Epuvalisation生态净化床处理技术是一种主要针对分散型废水的新型污水处理技术,较人工湿地或生物塘等传统生态处理技术有着显著的优势,具有更高的净化效率、更好的灵活性、更低的运行维护成本及产生附有价值的副产品如蔬菜、花卉以及植物饲料或肥料等。无论是开路还是闭路系统,作为对废水进行深度（二级或三级）处理的技术,Epuvalisation废水生态处理系统对废水中的氮、磷以及像大肠杆菌、链球菌等生活污水的一些指示性污染物都具有良好的去除效果,处理后的废水可以用作农业灌溉或直接排放至地表水体中而无需担忧造成二次污染或引起地表水体的富营养化的问题。     

复合人工湿地处理稠油废水研究

针对新疆油田稠油废水的水质特点,结合克拉玛依地区戈壁、荒漠地自然环境特征,研究建立油田废水人工湿地处理技术模式,设计"复合流人工湿地—兼(好)氧组合生物塘—生态滤池"(WPF)复合人工湿地系统,介绍WPF系统的工艺流程、结构设计,并进行了经济评估。     

实现基准排水量达标的炼油企业污水处理与回用工程实践

根据符合GB31570—2015《石油炼制工业污染物排放标准》中基准排水量要求的某石油炼制企业的废水处理与循环利用工程设置和实际运行数据,文章以酸性水汽提处理、电脱盐废水预处理、催化剂再生烟气脱硫废水处理等炼油企业点源废水分质处理工艺,全厂污水深度处理与回用和循环利用工 程为主要研究对象,系统研究了石油炼制主要产排废水分质处理与循环利用的工程实践对炼油企业节水减排的贡献。     

炼油废水回用处理工艺与控制系统

通过分析炼油废水的特点及其在水中存在的形式,根据炼油废水回用水处理法,结合庆阳石化炼油废水处理系统,介绍了庆阳石化炼油废水采用物化处理+生化处理+回用处理工艺过程及系统组成。     

螯合树脂在电镀含镍废水处理中的应用实例

采用离子交换工艺对电镀废水原有处理系统出水进行树脂过滤吸附后,能够稳定达到《电镀废水排放标准》(GB 21900—2008)中表3的要求.该工艺运行稳定可靠,可为同行业类似废水处理提供工程经验.     

大港油田氧化塘生物处理采油废水

大港油田采用氧化塘生物处理技术对采油废水进行处理,经过五年的运行实践表明,处理效果显著,去除率逐年提高,运行稳定。COD、石油类、SS去除率2000年至2004年分别由43%、51%、-14%提高到77%、98%、26%。氧化塘生物处理技术投资少、运行费用低,处理成本小于0.2元/m3。     

酿造废水处理的优化工艺组合

酿造废水属于高浓度有机废水，要将其处理达到排放标准，必须经过多种处理工艺的组合才能办到。通过物化处理、生化处理的实验室研究，我们得出了资源化和净化相结合的优化工艺组合，使酿酒废水的排放达到规定的排放标准，且运行费用和收益基本持平，解决了环保工程与经济效益间的矛盾。     

短程膜工艺处理尾矿干堆渗滤液的应用实例

结合广西壮族自治区某尾矿库区干堆渗滤液污水深度处理工程实例,介绍了短程膜工艺及其在处理重金属废水工程上的应用。运行结果表明,短程膜工艺对总铜、锌、砷、铅、镉具有优异的去除效果,出水水质符合《铅锌工业污染物排放标准》(GB25466-2010)表3要求。与传统重金属污水处理工艺相比,短程膜工艺具有处理流程短、成本低、能耗少、处理效果好、稳定可靠的优势,且能方便接入现有的废水生物处理系统,是选矿、冶炼行业重金属废水的理想处理工艺,对现有污水处理系统提标改造具有重要意义。     

东营污水处理厂生态塘工艺的应用

东营污水处理厂采用污水处理与利用相结合的生态塘处理工艺,主要由高效厌氧塘、曝气塘、曝气养鱼塘、养鱼塘、藕塘、芦苇塘等组成。经过应用分析以及10个月的数据统计可以看出:在东营市这样土地资源丰富的地区采用生态塘工艺处理城市污水,具有基建费用低、运行费用省、维护管理方便、处理效果比较稳定的优点。     

序批式活性污泥法在炼油化工废水处理中的应用

炼油化工废水处理的传统处理工艺中存在一定的弊端。为此,玉门炼油化工总厂对其废水处理设施进行了改建和扩建,其生物处理系统采用了序批式活性污泥法处理工艺。经过 3年运行的结果表明:该系统运行效果良好,处理后的水质可达到《GB8978-1996》(石化)一级排放标准的要求;化学需氧量(COD)和生化需氧量(BOD)分别降低78.6%和91.2%,硫化物去除率为98.2%,挥发酚去除率为99.6%。而且该反应器具有较强的耐冲击负荷能力,进水中COD在600 mg/L以下且有大幅度波动时,该系统仍可稳定地运行,处理后的水可达标排放。     

炼化污水“零排放”技术现状与发展趋势

在节能降耗、节水减排已成为国策的背景下,炼化污水集中处理达标排放的末端治理已经不能满足炼化行业发展,炼化污水"零排放"的实施将是大势所趋。在实施炼化污水"零排放"过程中,应深化开展水系统优化、技术创新集成等工作,将节能、节水、减排有机结合,突破制约污水"零排放"的技术瓶颈,并将技术成熟化、管理制度化,形成完整的炼化污水"零排放"技术体系,促进我国炼化企业的可持续发展。     

Volatile organic compound emissions from wastewater treatment plants in Taiwan: legal regulations and costs of control

This study assessed volatile organic compound (VOC) emission characteristics from wastewater treatment plants (WWTPs) in five Taiwanese industrial districts engaged in numerous manufacturing processes, including petrochemical, science-based industry (primarily semiconductors, photo-electronics, electronic products and biological technology), as well as multiple manufacturing processes (primarily pharmaceuticals and paint manufacturing). The most aqueous hydrocarbons dissolved in the wastewater of Taiwanese WWTPs were acetone, acrylonitrile, methylene chloride, and chloroform for the petrochemical districts; acetone, chloroform, and toluene for the science-based districts; and chlorinated and aromatic hydrocarbons for the multiple industrial districts. The aqueous pollutants in the united WWTPs were closely related to the characteristics of the manufacturing plants in the districts. To effectively prevent VOC emissions from the primary treatment section of petrochemical WWTPs, the updated regulations governing VOC emissions were issued by the Taiwanese Environmental Protection Administration in September 2005, legally mandating a seal cover system incorporating venting and air purification equipment. Cost analysis indicates that incinerators with regenerative heat recovery are optimal for treating high VOC concentrations, exceeding 10,000ppm as CH(4), from the oil separation basins. However, the emission concentrations, ranging from 100 to 1000ppm as CH(4) from the other primary treatment facilities and bio-treatment stages, should be collected and then injected into the biological oxidation basins via existing or new blowers. The additional capital and operating costs required to treat the VOC emissions of 1000ppm as CH(4) from primary treatment facilities are less than US$0.1 for perm(3) wastewater treatment capacity.     

Use of cattails in treating wastewater from a Pb/Zn mine

This article describes the use of a combined treatment system, which includes an aquatic treatment pond withTypha latifolia Linn. (Typhaceae) as the dominant species and a stabilization pond, to treat the wastewater from a Pn/Zn mine at Shaoguan, Guangdong Province, China. In 1983, it was noted thatT. latifolia bloomed in areas affected by the wastewater emitted from the mine, hence a combined purification system was subsequently built. The influent contained high levels of total suspended solids (4635 mg/liter), chemical oxygen demand (14.5 mg/liter) as well as Pb (1.6 mg/liter) and Zn (1.9 mg/liter). The results of the effluent after treatment showed that the total suspended solids, chemical oxygen demand, Pb, and Zn had been reduced by 99%, 55%, 95%, and 80% respectively. The results of plant tissue analysis indicled thatT. latifolia assimilated significant amounts of Pb and Zn, especially in the root portion. During 1986 several species of algae and fish were present in the pond, usually with a higher density in areas containing lower metal concentrations in the water. Paper was presented in part at the conference “The Use of Constructed Wetlands in Water Pollution Control” held 24–28 September 1990, Cambridge, UK.     

污水深度处理及回收利用的可行性分析

大庆炼化公司从单一化工污水深度处理及回收利用发展为炼油、化工、生活污水统一处理和回用于循环水,既充分利用了现有污水处理场的处理余量,同时由于生活污水中含有比例适当的微生物需要的营养物质,对炼油和化工污水起到补充和稀释作用。这种处理方法既降低了工业污水对污水处理场的冲击,又起到了稳定水质的作用。     

Total site: wastewater minimization: Wastewater reuse and regeneration reuse

Analysis of technological wastewater streams in a refinery and petrochemical complex was carried out. Wastewater flowrates, temperatures, pH and pollutant contents were measured. Regarding the characteristics of the individual waters, possible connections between water outflows from the processes or process units and potential water consumers were determined. Possibilities to reduce the flowrate of technological wastewater with wastewater reuse or preliminary regeneration and reuse were found. The consumption of fresh water could be lowered by 11.2 m³/h, reducing the treatment system load and prolonging its residence time by 7%. The payback period for the changes proposed in the petrochemical plants is 6 months with annual savings of US$27 630. The payback period for the changes proposed in the refinery is 11 days with annual savings of US$15 500.     

Particulates, not plants, dominate nitrogen processing in a septage-treating aerated pond system

In pond and wetland systems for wastewater treatment, plants are often thought to enhance the removal of ammonium and nitrogen through the activities of root-associated bacteria. In this study, we examined the role of plant roots in an aerated pond system with floating plants designed to treat high-strength septage wastewater. We performed both laboratory and full-scale experiments to test the effect of different plant root to septage ratios on nitrification and denitrification, and measured the abundances of nitrifying bacteria associated with roots and septage particulates. Root-associated nitrifying bacteria did not play a significant role in ammonium and total nitrogen removal. Investigations of nitrifier populations showed that only 10% were associated with water hyacinth [Eichhornia crassipes (Mart.) Solms] roots (at standard facility plant densities equivalent to 2.2 wet g roots L(-1) septage); instead, nitrifiers were found almost entirely (90%) associated with suspended septage particulates. The role of root-associated nitrifiers in nitrification was examined in laboratory batch experiments where high plant root concentrations (7.4 wet g L(-1), representing a 38% net increase in total nitrifier populations over plant-free controls) yielded a corresponding increase (55%) in the non-substrate-limited nitrification rate (V(max)). However, within the full-scale septage-treating pond system, nitrification and denitrification rates remained unchanged when plant root concentrations were increased to 7.1 g roots L(-1) (achieved by increasing the surface area available for plants while maintaining the same tank volume). Under normal facility operating conditions, nitrification was limited by ammonium concentration, not nitrifier availability. Maximizing plant root concentrations was found to be an inefficient mechanism for increasing nitrification in organic particulate-rich wastewaters such as septage.     

炼化浓盐水处理与资源化工艺探讨＊

炼化污水深度处理回用是各炼化企业节水减排的主要措施之一。炼化企业反渗透(简称RO)污水脱盐回用装置在运行中暴露出末端高含盐污水的处置难题,影响了污水回用生产的连续运行。文章阐述近年来炼化企业高含盐污水处置现状、存在问题、国内外处理技术及发展趋势,在此基础上针对炼化企业特点,提出以热法、膜法为核心技术的浓盐水处理工艺耦合方案,为炼化企业解决污水回用瓶颈技术难题、实施污水"零排放"与发展循环经济提供借鉴与参考。     

石油化工系统污泥处理研究

石油化工系统污水处理产生的污泥同城市污水处理产生的污泥有一定区别,针对兰州石化公司炼油化工污泥其固有的组分特点,并通过转筒离心机、板框压缩机、带式压滤机、真空过滤机等不同机械脱水方式的比较,提出了这类污泥在处理和处置时应注意的问题及几点建议。