WATER QUALITY AND SOURCE OF FRESHWATER DISCHARGE TO THE CALOOSAHATCHEE ESTUARY,FLORIDA1

ABSTRACT: The Caloosahatchee River has two major sources of freshwater one from its watershed and the other via an artificial connection to Lake Okeechobee. The contribution of each source to the freshwater discharge reaching the downstream estuary varies and either may dominate. Routine monitoring data were analyzed to determine the effects of total river discharge and source of discharge (river basin, lake) on water quality in the downstream estuary. Parameters examined were: color, total suspended solids, light attenuation, chlorophyll a, and total and dissolved inorganic nitrogen and phosphorus. In general, the concentrations of color, and total and dissolved inorganic nitrogen increased, and total suspended solids decreased, as total discharge increased. When the river basin was the major source, the concentrations of nutrients (excepting ammonia) and color in the estuary were relatively higher than when the lake was the major source. Light attenuation was greater when the river basin dominated freshwater discharge to the estuary. The analysis indicates that water quality in the downstream estuary changes as a function of both total discharge and source of discharge. Relative to discharge from the river basin, releases from Lake Okeechobee do not detectably increase concentrations of nutrients, color, or TSS in the estuary.     

Investigating public preferences for managing Lake Champlain using a choice experiment

The Lake Champlain Basin in Vermont and New York, USA and Quebec, Canada includes a large lake and watershed with complex management issues. A transboundary comprehensive management plan prepared for the lake includes 11 goals across many issue areas. We developed a choice experiment to examine public preferences for alternative Lake Champlain management scenarios across these issue areas. Five ecosystem attributes (water clarity-algae blooms, public beach closures, land use change, fish consumption advisories and the spread of water chestnut, an invasive plant) were varied across three levels and arrayed into paired comparisons following an orthogonal fractional factorial design. Two thousand questionnaires were distributed to basin residents, each including nine paired comparisons that required trading off two, three or four attributes. Completed surveys yielded 6541 responses which were analyzed using binary logistic regression. The results showed that although water clarity and beach closures were important, safe fish consumption was the strongest predictor of choice. Land use pattern and water chestnut distribution were weaker but also significant predictors, with respondents preferring less land development and preservation of the agricultural landscape. Current management efforts in the Lake Champlain Basin are heavily weighted toward improving water clarity by reducing phosphorus pollution. Our results suggest that safe fish consumption warrants additional management attention. Because choice experiments provide information that is much richer than the simple categorical judgments more commonly used in surveys, they can provide managers with information about tradeoffs that could be used to enhance public support and maximize the social benefits of an ecosystem management program.     

Climate Change Impacts and Uncertainties on Spring Flooding of Lake Champlain and the Richelieu River

The source of the Richelieu River is Lake Champlain, located between the states of New York, Vermont, and Québec. In 2011, the lake and the Richelieu River reached historical flood levels, raising questions about the influence of climate change on the watershed. The objectives of this work are to model the hydrology of the watershed, construct a reservoir model for the lake and to analyze flooding trends using climate simulations. The basin was modeled using the HSAMI lumped conceptual model from Hydro‐Québec with a semi‐distributed approach in order to estimate the inflows into Lake Champlain. The discharge at the Richelieu River was computed by using a mass balance equation between the inputs and outputs of Lake Champlain. Future trends were estimated over the 2041‐2070 and 2071‐2100 periods using a large number of outputs from general circulation models and regional climate models downscaled with constant scaling and daily translation methods. While there is a certain amount of uncertainty as to future trends, there is a decreasing tendency in the magnitude of the mean spring flood. A flood frequency analysis showed most climate projections indicate the severity of most extreme spring floods may be reduced over the two future periods although results are subject to a much larger uncertainty than for the mean spring flood. On the other hand, results indicate summer‐fall extreme events such as caused by hurricane Irene in August 2011 may become more frequent in the future.     

IDENTIFICATION OF DISSOLVED-CONSTITUENT SOURCES IN MINE-SITE GROUND WATER USING BATCH MIXING1

ABSTRACT: Batch-mixing experiments were used to help identify lithologic and mineralogic sources of increased concentrations of dissolved solids in water affected by surface coal mining in northwestern Colorado. Ten overburden core samples were analyzed for mineral composition and mixed with distilled water for 90 days until mineral-water equilibrium was reached. Between one day and 90 days after initial contact, specific conductance in the sample mixtures had a median increase of 306 percent. Dissolved-solids concentrations ranged from 200 to 8,700 mg/L in water samples extracted from the mixtures after 90 days. Mass. balance simulations were conducted using the geochemical models BALANCE and WATEQF to quantify mineral-water interactions occurring in five selected sample mixtures and in water collected from a spring at a reclaimed mine site. The spring water is affected by mineral-water interactions occurring in all of the lithologic units comprising the overburden. Results of the simulations indicate that oxidation of pyrite, dissolution of dolomite, gypsum, and epsomite, and cation-exchange reactions are the primary mineral-water interactions occurring in the overburden. Three lithologic units in the overburden (a coal, a sandstone, and a shale) probably contribute most of the dissolved solids to the spring water. Water sample extracts from mixtures using core from these three units accounted for 85 percent of the total dissolved solids in the 10 sample extracts. Other lithologic units in the overburden probably contribute smaller quantities of dissolved solids to the spring water.     

URBANIZATION IMPACT ON WATER QUALITY DURING A FLOOD IN SMALL WATERSHEDS1

ABSTRACT: The impact of various urban land uses on water flow and quality in streams is being studied by monitoring small streams in the Milwaukee urban area. This paper compares the responses of an urban watershed and an agricultural watershed to an autumn rainfall of 2.2 cm. Flow from the urban basin showed a substantially greater response to the rain than that from the rural. Dilution, resulting from the greater quantities of surface runoff in the urban watershed, caused lower concentrations of sodium, chloride, calcium, magnesium, bicarbonate and total dissolved solids in the urban stream. The total quantity of these materials removed per unit drainage area of the urban basin was much greater, however. Road salt was still among the dominant dissolved materials in the urban water chemistry seven months after the last road salting. Sodium was apparently being released from adsorption by clays in the urban basin. Suspended sediment concentrations and total loads were higher in the urban stream.     

SOLIDS DISTRIBUTION IN LAKE CHAPALA,MEXICO1

ABSTRACT: Lake Chapala is the largest natural water body in Mexico and also one of the most important shallow lakes in Latin America. For the past several years it has suffered various environmental problems such as the upstream overuse of water, contamination, and sedimentation. For the past 10 years the lake has had less than 50 percent of its historical water level over the past century. No criteria are reported in the literature that establish a water storage volume that will guarantee water quality conditions necessary for the survival of the lake. After determining the behavior of total solids concentrations in relation to the variations in the lake's depth, we proposed a minimum water column height of 5.0 m, representing a storage volume of about 5,000 Mm³. This volume would result in the recommended water quality standards for total dissolved solids. Calculated distribution maps show that the total solids concentration in the lake has increased since the end of the 1970s. The solids are primarily concentrated in the eastern part of the lake, as a consequence of the high solids discharged from the Lerma River, its main tributary.     

LAKE CHAMPLAIN BASIN NONPOINT SOURCE PHOSPHORUS ASSESSMENT1

ABSTRACT: Existing land use data were used to estimate nonpoint source phosphorus loads to Lake Champlain (Vermont/New York/Quebec) in a loading function model that combined P concentration coefficients with regional hydrologic data. The estimates were verified against monitored loading data, then used to assess the relative magnitudes of contributions from major land uses and regions of the Lake Champlain Basin. The Basin is comprised of 62 percent forest, 28 percent agricultural land, 3 percent urban land, and 7 percent water. The best-fit model estimated an annual total P load of 457 mt/year, which did not differ significantly from the 458 metric tons/year measured for an average hydrologic year, and accurately predicted loads from major tributaries. Agriculture contributes 66 percent of the annual nonpoint source P load to Lake Champlain; urban and forest land contribute 18 percent and 16 percent, respectively. Because agricultural land contributes most nonpoint source P to Lake Champlain, load reduction effort must deal with agricultural sources. However, because the urban 3 percent of the basin contributes 18 percent of the estimated load, high load reduction efficiencies might be achieved by addressing urban sources. This assessment clearly demonstrated the relationship between land use and P loads in the Lake Champlain Basin, a prerequisite for policy-makers to endorse a P management strategy requiring changes in land use and management.     

Multivariate statistical characterization of water quality in Lake Lanier, Georgia, USA

Watershed monitoring programs depend on water quality characterization data collected for many parameters, at many times and places, and with limited resources. Our objective is to present a strategy that reduces the measured parameters, locations, and frequency without compromising the quality of the monitoring program. One year of twice-monthly (growing season) and monthly (dormant season) water quality data collected from 17 lake and 10 tributary sites are used in conjunction with multivariate statistical techniques to improve the utility of collected data by identifying key parameters and monitoring locations. Factor analysis shows that tributary water quality data consists of three components-stormwater runoff, municipal and industrial discharges, and ground water-which can be distinguished using total suspended solids, total dissolved solids, and alkalinity plus soluble reactive P, respectively. Lake water quality characterization is more ambiguous than tributary water quality characterization, but factor analysis indicates that anoxia associated with lake stratification is the largest source of lake water quality variation, followed by nutrient abundance, and finally by biomass abundance. Cluster analysis suggests that tributary and lake monitoring stations can be consolidated. Reducing the number of parameters and stations frees up resources for increased monitoring elsewhere.     

SPRINGFLOW EFFECTS ON CHEMICAL LOADS IN THE SNAKE RWER,SOUTH-CENTRAL IDAHO1

ABSTRACT: The 150-kilometer middle reach of the Snake River (middle Snake) in south-central Idaho receives large quantities of water from springs discharging along the north side of the river from the regional Snake River Plain aquifer. Water-quality samples collected from nine north-side springs in April 1994 indicated that springs in the upstream part of the reach had larger concentrations of dissolved solids, dissolved nitrate, total nitrogen, tritium, and heavy isotopes of hydrogen and oxygen than to springs in the downstream part of the reach. Because the spring chemistry varies in the reach, discharge from the springs resulted in a degradation in water quality in some parts of the middle Snake and improvements in water quality in other parts. Depending on the annual discharge in the Snake River, the contribution from the north-side springs represented 33 to 66 percent of the discharge, 32 to 57 percent of the dissolved solids, 26 to 50 percent of the total nitrogen, and 7 to 14 percent of the total phosphorus transported annually from the middle Snake. Synoptic sampling showed that the north-side springs contributed 84 percent of the discharge and 35, 40, and 10 percent of the dissolved solids, total nitrogen, and total phosphorus load, respectively, to the Snake River during the peak of the irrigation season in 1994.     

Sedimentation basin performance at highway construction sites

Sedimentation basins (SBs) are commonly used during highway construction for erosion and sedimentation pollution control as well as for attenuation of overland storm waters. In order to evaluate the sediment removal capacity of these SBs, four basins were selected for monitoring from a new highway construction that extends I-99 to I-80, in Pennsylvania. Between September 2004 and August 2005, ten sampling trips were conducted during which basin inlet and outlet water samples were obtained. The SB samples were analyzed for pH, color, turbidity, total suspended solids (TSS), volatile suspended solids (VSS), total and dissolved iron, magnesium, manganese, aluminum, calcium, sulfate and phosphate. The data showed peaks in concentrations of TSS, total aluminum, total manganese, total iron and total phosphate that closely correlated to localized rainfall peaks. For certain samples, the concentration of TSS in the outlet was higher than the TSS concentration at the basin inlet, suggesting sediment re-suspension. In general SBs managed high flows during wet weather events, but were not effective in capturing particulates. This paper discusses the need for Best Management Practices (BMPs) for the design of SBs that reflect contemporary concerns for management of particle removal and to control the release of particulate-bound metals. This paper also evaluates the water quality impacts of naturally occurring acidic drainages into SBs, as several acidic seeps with pH in the range of 5-6 and having high dissolved concentrations of metals (Fe, Mn, Mg and Ca), sulfate and phosphate were observed draining into the SBs.     

Exploratory Analysis of the Winter Chemistry of Five Lakes on the North Slope of Alaska1

Abstract: Lakes are important water resources on the North Slope of Alaska. Freshwater is required for oilfield production as well as exploration, which occurs largely on ice roads and pads. Since most North Slope lakes are shallow, the quantity and quality of the water under ice at the end of winter are important environmental management issues. Currently, water‐use permits are a function of the presence of overwintering fish populations, and their sensitivity to low oxygen concentrations. Sampling of five North Slope lakes during the winter of 2004‐2005 shed some light on the winter chemistry of four lakes that were used as water supplies and one undisturbed lake. Field analysis was conducted for oxygen, conductivity, pH, and temperature throughout the lake depth, as well as ice thickness and water depth. Water samples were retrieved from the lakes and analyzed for Na, Ca, K, Mg, Fe, dissolved‐organic carbon, and alkalinity in the laboratory. Lake properties, rather than pumping, were the best predictors of oxygen depletion, with the highest dissolved‐oxygen levels maintained in the lake with the lowest concentration of constituents. Volume weighted mean dissolved‐oxygen concentrations ranged from 4 to 94% of saturation in March. Dissolved oxygen and specific conductance data suggested that the lakes began to refresh in May.     

REGION,LANDSCAPE, AND SCALE EFFECTS ON LAKE SUPERIOR TRIBUTARY WATER QUALITY1

ABSTRACT: In 1998 and 1999, third‐order watersheds in high mature forest (HMF) and low mature forest (LMF) classes were selected along gradients of watershed storage within each of two hydrogeomorphic regions in the Lake Superior Basin to evaluate threshold effects of storage on hydrologic regimes and watershed exports. Differences were detected between regions (North and South Shore) for particulates, nutrients, and pH, with all but silica values higher for South Shore streams (p < 0.05). Mature forest effects were detected for turbidity, nutrients, color, and alkalinity, with higher values in the LMF watersheds, that is, watersheds with less that 50 percent mature forest cover. Dissolved N, ammonium, N:P, organic carbon, and color increased, while suspended solids, turbidity, and dissolved P decreased as a function of storage. Few two‐way interactions were detected between region and mature forest or watershed storage, thus threshold based classification schemes could be used to extrapolate effects across regions. Both regional differences in water quality and those associated with watershed attributes were more common for third‐order streams in the western Lake Superior drainage basin as compared with second‐order streams examined in an earlier study. Use of ecoregions alone as a basis for setting regional water quality criteria would have led to misinterpretation of reference condition and assessment of impacts in the Northern Lakes and Forest Ecoregion.     

Assessment of Future Climate Change Impact on Water Quality of Chungju Lake,South Korea,Using WASP Coupled with SWAT

This study is to evaluate the future potential impact of climate change on the water quality of Chungju Lake using the Water Quality Analysis Simulation Program (WASP). The lake has a storage capacity of 2.75 Gm³, maximum water surface of 65.7 km², and forest‐dominant watershed of 6,642 km². The impact on the lake from the watershed was evaluated by the Soil and Water Assessment Tool (SWAT). The WASP and SWAT were calibrated and validated using the monthly water temperatures from 1998 to 2003, lake water quality data (dissolved oxygen, total nitrogen [T‐N], total phosphorus [T‐P], and chlorophyll‐a [chl‐a]) and daily dam inflow, and monthly stream water quality (sediment, T‐N, and T‐P) data. For the future climate change scenario, the MIROC3.2 HiRes A1B was downscaled for 2020s, 2050s, and 2080s using the Change Factor statistical method. The 2080s temperature and precipitation showed an increase of +4.8°C and +34.4%, respectively, based on a 2000 baseline. For the 2080s watershed T‐N and T‐P loads of up to +87.3 and +19.6%, the 2080s lake T‐N and T‐P concentrations were projected to be 4.00 and 0.030 mg/l from 2.60 and 0.016 mg/l in 2000, respectively. The 2080s chl‐a concentration in the epilimnion and the maximum were 13.97 and 52.45 μg/l compared to 8.64 and 33.48 μg/l in 2000, respectively. The results show that the Chungju Lake will change from its mesotrophic state of 2000 to a eutrophic state by T‐P in the 2020s and by chl‐a in the 2080s. Editor's note: This paper is part of a featured series on Korean Hydrology. The series addresses the need for a new paradigm of river and watershed management for Korea due to climate and land use changes.     

CHARACTERIZATION OF SURFACE WATER QUALITY ALONG A WATERSHED DISTURBANCE GRADIENT1

ABSTRACT. Characterizing ecological indicators such as water quality is necessary to effectively manage human-dominated systems such as the New Jersey Pinelands. Pinelands surface waters are naturally acidic and low in nutrients and other dissolved substances. Water quality for 14 Pinelands stream sites monitored by the U.S. Geological Survey was characterized in relation to land use. A gradient of increasing pH, specific conductance, and concentration of dissolved calcium, dissolved magnesium, total nitrite + nitrate-nitrogen, total ammonia-nitrogen, and total phosphorus was associated with a watershed disturbance gradient of increasing land use intensity and waste water flow. These two parallel gradients emphasized the significant effect that watershed disturbance can have on natural water chemistry in the Pinelands. The results of this study can be applied to planning and regulatory programs in the Pinelands.     

HYDROLOGIC LANDSCAPES ON THE DELMARVA PENINSULA PART 1: DRAINAGE BASIN TYPE AND BASE-FLOW CHEMISTRY1

ABSTRACT: The relation between landscape characteristics and water chemistry on the Delmarva Peninsula can be determined through a principal-component analysis of basin characteristics. Two basin types were defined by factor scores: (1) well-drained basins, characterized by combinations of a low percentage of forest cover, a low percentage of poorly drained soil, and elevated channel slope; and (2) poorly drained basins, characterized by a combinations of an elevated percentage of forest cover, an elevated percentage of poorly drained soil, and low channel slopes. Results from base-flow sampling of 29 basins during spring 1991 indicate that water chemistry of the two basin types differ significantly. Concentrations of calcium, magnesium, potassium, alkalinity, chloride, and nitrate are elevated in well-drained basins, and specific conductance is elevated. Concentrations of aluminum, dissolved organic carbon, sodium, and silica are elevated in poorly drained basins whereas specific conductance is low. The chemical patterns found in well-drained basins can be attributed to the application of agricultural chemicals, and those in poorly drained basins can be attributed to ground-water flowpaths. These results indicate that basin types determined by a quantitative analysis of basin characteristics can be related statistically to differences in base-flow chemistry, and that the observed statistical differences can be related to major processes that affect water chemistry.     

EVALUATION OF INFLOW TO MIRROR LAKE,NEW HAMPSHIRE1

ABSTRACT: Measured stream discharge plus calculated ground water discharge (total measured runoff) were compared with runoff calculated by the unit-runoff method for the two largest watersheds of Mirror Lake for 1981–1983. Runoff calculated by the unit-runoff method, using Hubbard Brook watershed 3 as the index watershed, was greater than the total measured runoff into Mirror Lake during periods of high flow and slightly less than the total measured runoff into Mirror Lake during periods of low flow. Annual calculated unit runoff was 17 to 37 percent greater than total measured runoff. Differences in monthly runoff are far greater, ranging from 0 to greater than 100 percent. For high flows the calculated unit runoff is about 2 times greater than total measured runoff. For low flows the northwest basin of Mirror Lake has the greatest ground water contribution compared to the other two basins. In contrast, Hubbard Brook watershed 3 has the least ground water contribution.     

Modeling Water Quantity and Sulfate Concentrations in the Devils Lake Watershed Using Coupled SWAT and CE‐QUAL‐W2

Devils Lake is an endorheic lake in the Red River of the North basin in northeastern North Dakota. During the last two decades, the lake water level has risen by nearly 10 m, causing floods that have cost more than 1 billion USD in mitigation measures. Another increase of approximately 1.5 m in the lake water level would cause spillage into the Sheyenne River. To alleviate this potentially catastrophic spillage, two artificial outlets were constructed. However, the artificial drainage of water into the Sheyenne River raises water quality concerns because the Devils Lake water contains significantly higher concentrations of dissolved solids, particularly sulfate. In this study, the Soil and Water Assessment Tool (SWAT) was coupled with the CE‐QUAL‐W2 model to simulate both water balance and sulfate concentrations in the lake. The SWAT model performed well in simulating daily flow in tributaries with E_NS > 0.5 and |PBIAS| < 25%, and reproduced the lake water level with a root mean square error of 0.35 m for the study period from 1995 to 2014. The water temperature and sulfate concentrations simulated by CE‐QUAL‐W2 for the lake are in general agreement with the field observations. The model results show that the operation of the two outlets since August 2005 has lowered the lake level by 0.70 m. Furthermore, the models show pumping water from the two outlets raises sulfate concentrations in the Sheyenne River from ~100 to >500 mg/L. Editor's note : This paper is part of the featured series on SWAT Applications for Emerging Hydrologic and Water Quality Challenges. See the February 2017 issue for the introduction and background to the series.     

FIELD MEASUREMENT OF FLOW VELOCITIES,SUSPENDED SOLIDS CONCENTRATIONS,AND TEMPERATURES IN LAKE OKEECHOBEE1

ABSTRACT: This paper presents a field investigation of collecting hydrodynamic and sediment data in Lake Okeechobee with analyses examining mechanisms affecting sediment resuspension in the lake. Lake Okeechobee is a large subtropical lake located in south central Florida. Three‐dimensional flow velocities, suspended solids concentrations (SSC), and temperatures at four locations were measured from January 18 to March 5, 2000. Analyses of these data indicate that wind is the dominant factor in driving flow velocities and therefore transporting suspended solids. Wind direction also affects the SSC, especially in the north central and west littoral areas of the lake. The surface and bottom velocity components frequently flow in opposite directions, forming a stratification of the water column and preventing suspended solids from settling out. This retention of SSC in the water column may have a strong impact on the water quality of Lake Okeechobee. This study provides valuable storm event data and mechanism analyses, which will improve our understanding of the transport of suspended solids, thermal exchanges, and flow patterns within Lake Okeechobee.     

A SEDIMENT RESUSPENSION AND WATER QUALITY MODEL OF LAKE OKEECHOBEE1

ABSTRACT: The influence of sediment resuspension on the water quality of shallow lakes is well documented. However, a search of the literature reveals no deterministic mass-balance eutrophication models that explicitly include resuspension. We modified the Lake Okeechobee water quality model - which uses the Water Analysis Simulation Package (WASP) to simulate algal dynamics and phosphorus, nitrogen, and oxygen cycles - to include inorganic suspend. ed solids and algorithms that: (1) define changes in depth with changes in volume; (2) compute sediment resuspension based on bottom shear stress; (3) compute partition coefficients for ammonia and ortho-phosphorus to solids; and (4) relate light attenuation to solids concentrations. The model calibration and validation were successful with the exception of dissolved inorganic nitrogen species which did not correspond well to observed data in the validation phase. This could be attributed to an inaccurate formulation of algal nitrogen preference and/or the absence of nitrogen fixation in the model. The model correctly predicted that the lake is light-limited from resuspended solids, and algae are primarily nitrogen limited. The model simulation suggested that biological fluxes greatly exceed external loads of dissolved nutrients; and sediment-water interactions of organic nitrogen and phosphorus far exceed external loads. A sensitivity analysis demonstrated that parameters affecting resuspension, settling, sediment nutrient and solids concentrations, mineralization, algal productivity, and algal stoichiometry are factors requiring further study to improve our understanding of the Lake Okeechobee ecosystem.     

Effect of Urmia Lake's drying on groundwater corrosion and scaling potential in the northwest of Iran (Case study: Spring and summer, 2015)

The most common problems in water distribution systems are corrosion and scaling, which cause both economic and customer health problems. The aim of the present study is to report the relationship between Urmia Lake's drying and the corrosion and scaling potential of groundwater used as drinking water during the spring and summer of 2015. Groundwater samples were collected from all of the catchments of the Urmia Lake basin, and the characteristics of the water were used to determine the corrosive and scaling indices using the Langelier Saturation Index and the Ryznar Stability Index. The results showed that the total dissolved solids measurement of the samples collected from the islands of Urmia Lake was higher than the maximum value of the standard level. In addition, the hardness in 36% of the zones was higher than that of the maximum suggested level. The concentration of calcium was lower than that of the standard, but the rest of the parameters were in the standard level range. Also, the results showed that the water of the Urmia Lake basin tends to be very scaling and corrosive. In order to control the corrosion and scaling caused by groundwater drawn from the catchments around Urmia Lake, measures should be taken to prevent Urmia Lake's drying and to manage the groundwater around this area. It is also suggested that a laboratory study regarding the condition of the distribution system be carried out to adjust the effective parameters, such as the pH.