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石油烃污染地下水原位修复技术研究进展 总被引:15,自引:2,他引:15
概述了石油烃污染地下水原位修复技术的进展,包括原位化学氧化、原位电动修复、渗透反应格栅、冲洗、土壤气抽出、地下水曝气、生物修复,并对今后的研究发展趋势进行了展望。 相似文献
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以重庆市某铅污染场地为研究对象,选用多种稳定化药剂对土壤开展稳定化修复技术研究,着重探讨了不同单一药剂与复配药剂对土壤铅浸出浓度的影响。实验结果表明:磷酸二氢钠(MSP)、磷酸氢二钠、磷酸钠和石灰4种无机药剂中MSP的稳定化修复效果最佳,且磷酸盐类的稳定化修复效果整体上优于石灰;MSP与少量有机药剂腐殖酸复配施用的稳定化修复效果优于单独施加MSP;在MSP投加比(与土壤的质量比)为5%、腐殖酸投加比为2%、养护时间为7 d的最优工艺条件下,土壤中铅的浸出浓度由41.70 mg/L降至0.16 mg/L,低于《生活垃圾填埋场污染控制标准》(GB 16889—2008)中规定的0.25 mg/L浓度限值。 相似文献
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植物修复石油污染土壤的研究进展 总被引:4,自引:0,他引:4
石油污染土壤的植物修复技术以其处理成本低、无二次污染、自然美观等特点,正逐步成为未来石油污染治理研究的一个重要方向。文章综述了植物修复石油污染土壤的研究进展,阐述了植物修复的机理、影响因素、转基因植物的应用及与其他技术的联用,并探讨了植物修复石油污染土壤研究中存在的问题。 相似文献
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In situ chemical oxidation (ISCO) with permanganate has been widely used for soil and groundwater treatment in the saturated zone. Due to the challenges associated with achieving effective distribution and retention in the unsaturated zone, there is a great interest in developing alternative injection technologies that increase the success of vadose‐zone treatment. The subject site is an active dry cleaner located in Topeka, Kansas. A relatively small area of residual contamination adjacent to the active facility building has been identified as the source of a large sitewide groundwater contamination plume with off‐site receptors. The Kansas Department of Health and Environment (KDHE) currently manages site remedial efforts and chose to pilot‐test ISCO with permanganate for the reduction of perchloroethene (PCE) soil concentrations within the source area. KDHE subsequently contracted Burns & McDonnell to design and implement an ISCO pilot test. A treatability study was performed by Carus Corporation to determine permanganate‐soil‐oxidant‐demand (PSOD) and the required oxidant dosing for the site. The pilot‐test design included an ISCO injection approach that consisted of injecting aqueous sodium permanganate using direct‐push technology with a sealed borehole. During the pilot test, approximately 12,500 pounds of sodium permanganate were injected at a concentration of approximately 3 percent (by weight) using the methods described above. Confirmation soil sampling conducted after the injection event indicated PCE reductions ranging from approximately 79 to more than 99 percent. A follow‐up treatment, consisting of the injection of an additional 6,200 pounds of sodium permanganate, was implemented to address residual soil impacts remaining in the soil source zone. Confirmation soil sampling conducted after the treatment indicated a PCE reduction of greater than 90 percent at the most heavily impacted sample location and additional reductions in four of the six samples collected. © 2009 Wiley Periodicals, Inc. 相似文献
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With the successful implementation of in situ chemical oxidation (ISCO) programs to remediate contaminated soil and groundwater aquifers worldwide, ISCO has become established as a traditional remediation technique. On the basis of historical success, expanded ISCO practices are now routinely applied to increasingly difficult geologic environments, including formerly problem locations such as those containing nonaqueous‐phase liquid, fractured bedrock, low‐conductivity media, and highly layered and/or heterogeneous aquifers. Effective delivery of amendment, however, remains the single most important aspect of successful remediation, particularly given the range of potentially applicable delivery methods and site complexities. Selecting the most appropriate technique for any specific site depends upon a clear understanding of the variety of site constraints, including factors such as site conditions, underlying geology, contaminant distribution, technology limitations, and other project‐specific factors. Because the injection program is often the largest cost associated with implementation of an ISCO project, it is critical to develop a cost‐effective injection method for each site. Constant head injection provides a cost‐effective alternative for sites with low‐conductivity lithology(ies). Constant head injection employs a continuous low‐pressure application method to deliver ISCO agents over a long period of time. This synergistic method complements the existing site conditions and heterogeneity, working with the natural conditions, rather than trying to overcome or destroy the site geology using highly aggressive delivery techniques. © 2014 Wiley Periodicals, Inc. 相似文献
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The effects of in situ chemical oxidation (ISCO) on biological processes, as reported in the literature, were researched to determine if coupling ISCO with in situ bioremediation could be achieved in field and laboratory experiments. Literature was compiled concerning the effect of ISCO on microbial communities following addition of a chemical oxidant at a range of concentrations designed to treat a variety of subsurface contaminants. The results indicate that although microbial communities may potentially be adversely affected by chemical oxidation in the short term, a rebound of microbial biomass and/or bioremediation activity can be expected. Successfully coupling ISCO with bioremediation in field applications may be a cost‐effective method of achieving risk‐based site remediation goals. © 2006 Wiley Periodicals, Inc. 相似文献
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Surfactants and cosolvents are useful for enhancing the apparent solubility of dense nonaqueous‐phase liquid (DNAPL) compounds during surfactant‐enhanced aquifer remediation (SEAR). In situ chemical oxidation (ISCO) with permanganate, persulfate, and catalyzed hydrogen peroxide has proven to be a cost‐effective and viable remediation technology for the treatment of a wide range of organic contaminants. Coupling compatible remedial technologies either concurrently or sequentially in a treatment train is an emerging concept for more effective cleanup of DNAPL‐contaminated sites. Surfactants are effective for DNAPL mass removal but not useful for dissolved plume treatment. ISCO is effective for plume control and treatment but can be less effective in areas where large masses of DNAPL are present. Therefore, coupling SEAR with ISCO is a logical next step for source‐zone treatment. This article provides a critical review of peer‐reviewed scientific literature, nonreviewed professional journals, and conference proceedings where surfactants/cosolvents and oxidants have been utilized, either concurrently or sequentially, for DNAPL mass removal. © 2010 Wiley Periodicals, Inc. 相似文献
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In situ chemical oxidation (ISCO) typically delivers oxidant solutions into the subsurface for contaminant destruction. Contaminants available to the oxidants, however, are limited by the mass transfer of hydrophobic contaminants into the aqueous phase. ISCO treatments therefore often leave sites with temporarily clean groundwater which is subject to contaminant rebound when sorbed and free phase contaminants leach back into the aqueous phase. Surfactant Enhanced In situ Chemical Oxidation (S‐ISCO®) uses a combined oxidant‐surfactant solution to provide optimized contaminant delivery to the oxidants for destruction via desorption and emulsification of the contaminants by the surfactants. This article provides an overview of S‐ISCO technology, followed by an implementation case study at a coal tar contaminated site in Queens, New York. Included are data points from the site which demonstrate how S‐ISCO delivers desorbed contaminants without uncontrolled contaminant mobilization, as desorbed and emulsified contaminants are immediately available to the simultaneously injected oxidant for reaction. ©2016 Wiley Periodicals, Inc. 相似文献
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Timothy J. Pac James Baldock Brendan Brodie Jennifer Byrd Beatriz Gil Kevin A. Morris Denice Nelson Jaydeep Parikh Paulo Santos Miguel Singer Alan Thomas 《补救:环境净化治理成本、技术与工艺杂志》2019,29(2):75-91
This paper compiles a detailed set of in situ chemical oxidation (ISCO) lessons learned pertaining to design, execution, and safety based on global experiences over the last 20 years. While the benefits of a “correct” application are known (e.g., cost effectiveness, speed, permanence of treatment), history also provides examples of a variety of “incorrect” applications. These provide an opportunity to highlight recurring themes that resulted in failures. ISCO is, and will continue to provide, an important remedial tool for site remediation, particularly as a component of a multifaceted approach for addressing large and complex sites. Future success, however, requires an objective understanding of both the benefits and the limitations of the technology. The ability to learn from the mistakes of the past provides an opportunity to eliminate, or at least minimize, them in the future. Over the last 25 years of ISCO application, process understanding and knowledge have improved and evolved. This paper combines a thorough discussion of lessons learned through decades of ISCO implementation throughout all aspects of ISCO projects with an analysis of changes to the ISCO remediation market. By discussing the interplay of these two themes and providing recommendations from collective lessons learned, we hope to improve the future of safe, cost‐effective, and successful applications of ISCO. 相似文献
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Jurgen H. Exner 《补救:环境净化治理成本、技术与工艺杂志》1995,5(3):1-18
Contamination of soil and sediment by pollutants represents a major environmental challenge. Remediation of soil during the original Superfund years consisted primarily of dig and haul, capping, or containment. The 1986 amendments to CERCLA—SARA—provided the incentive for treatment and permanent remedies during site remediation. Thermal treatment, which routinely achieves the low cleanup criteria required by RCRA land-ban regulations, became one of the major technologies used for cleanup under the concept of ARAR. As the remediation industry matured and recognized specific market niches in soil remediation, a number of new technologies emerged. Thermal desorption, bioremediation, soil vapor extraction, soil washing, and soil extraction are being used on sites at which the technology offers advantages over incineration. In addition, a continuing stream of emerging technologies is being presented that requires careful evaluation relative to existing cleanup methods. Each of these technologies offers a range of options for achieving appropriate cleanup criteria, application to different soil matrices, cost, time of remediation, and public acceptability. Balancing cleanup criteria defined by regulation or risk assessment with technology cost and capability affords the opportunity to solve these problems with appropriate balance of cost and protection of human health and the environment. 相似文献
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Analytical techniques for designing of in situ chemical oxidation (ISCO) to treat organics in soil and groundwater are emerging. There are several issues that need to be resolved prior to adopting a standard analytical technique. Some of the more salient issues are discussed. In addition, currently practiced analytical techniques for estimating the oxidant demand for the oxidants permanganate and persulfate are provided. In the absence of analytical measurements, rules of thumb can be used with caution to estimate the overall oxidant demand. © 2003 Wiley Periodicals, Inc. 相似文献
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综述了物理修复、化学修复、微生物修复及联合修复等几种主要的1,2,4-三氯苯(1,2,4-TCB)环境污染修复技术的研究进展。阐述了各种修复方法的反应原理、修复条件和效果,对比了各种修复方法的优缺点。提出今后的研究方向:解决物理吸附法修复1,2,4-TCB污染后的吸附剂的后续处理问题;优化化学降解1,2,4-TCB的工艺条件,避免二次污染,进行现场试验,实现工程应用;分离、培育1,2,4-TCB的优势降解菌种;深入研究联合修复技术的降解机理,实现1,2,4-TCB的高效、彻底降解。 相似文献