Changes in Shallow Groundwater Quality Beneath Recently Urbanized Areas in the Memphis,Tennessee Area1

Barlow, Jeannie R.B., James A. Kingsbury, and Richard H. Coupe, 2012. Changes in Shallow Groundwater Quality Beneath Recently Urbanized Areas in the Memphis, Tennessee Area. Journal of the American Water Resources Association (JAWRA) 48(2): 336‐354. DOI: 10.1111/j.1752‐1688.2011.00616.x Abstract: Memphis, the largest city in the state of Tennessee, and its surrounding suburbs depend on a confined aquifer, the Memphis aquifer, for drinking water. Concern over the potential for downward movement of water from an overlying shallow aquifer to the underlying Memphis aquifer provided impetus for monitoring groundwater quality within the shallow aquifer. The occurrence of volatile organic compounds (VOCs), nitrate, and pesticides in samples from the shallow well network indicate a widespread affect on water quality from the overlying urban land use. Total pesticide concentration was generally higher in more recently recharged groundwater indicating that as the proportion of recent water increases, the occurrence of pesticides related to the current urban land use also increases. Groundwater samples with nitrate concentrations greater than 1.5 mg/l and detectable concentrations of the pesticides atrazine and simazine also had higher concentrations of chloroform, a VOC primarily associated with urban land use, than in other samples. The age of the water from these wells indicates that these concentrations are most likely not representative of past agricultural use, but of more recent urban use of these chemicals. Given that the median age of water represented by the shallow well network was 21 years, a lag time likely exists between changes in land use and the occurrence of constituents related to urbanization in shallow groundwater.     

Impacts of Land‐Cover Change on Suspended Sediment Transport in Two Agricultural Watersheds1

Schilling, Keith E., Thomas M. Isenhart, Jason A. Palmer, Calvin F. Wolter, and Jean Spooner, 2011. Impacts of Land‐Cover Change on Suspended Sediment Transport in Two Agricultural Watersheds. Journal of the American Water Resources Association (JAWRA) 47(4):672‐686. DOI: 10.1111/j.1752‐1688.2011.00533.x Abstract: Suspended sediment is a major water quality problem, yet few monitoring studies have been of sufficient scale and duration to assess the effectiveness of land‐use change or conservation practice implementation at a watershed scale. Daily discharge and suspended sediment export from two 5,000‐ha watersheds in central Iowa were monitored over a 10‐year period (water years 1996‐2005). In Walnut Creek watershed, a large portion of land was converted from row crop to native prairie, whereas in Squaw Creek land use remained predominantly row crop agriculture. Suspended sediment loads were similar in both watersheds, exhibiting flashy behavior typical of incised channels. Modeling suggested that expected total soil erosion in Walnut Creek should have been reduced 46% relative to Squaw Creek due to changes in land use, yet measured suspended sediment loads showed no significant differences. Stream mapping indicated that Walnut Creek had three times more eroding streambank lengths than did Squaw Creek suggesting that streambank erosion dominated sediment sources in Walnut Creek and sheet and rill sources dominated sediment sources in Squaw Creek. Our results demonstrate that an accounting of all sources of sediment erosion and delivery is needed to characterize sediment reductions in watershed projects combined with long‐term, intensive monitoring and modeling to account for possible lag times in the manifestation of the benefits of conservation practices on water quality.     

RELATIONSHIPS BETWEEN LAND USES AND RAINWATER QUALITY IN A SOUTHCENTRAL PENNSYLVANIA WATERSHED1

ABSTRACT: Spatial and temporal variability in rainfall concentrations of nutrients, major ions, and herbicides was monitored at 7 locations in or near the Conodoguinet Creek watershed in south-central Pennsylvania from 1991.1993. Results were used to (1) compare precipitation quality in forested, agricultural and urban areas, and (2) assess the practicality of using volunteer citizen monitoring in such a study. As indicated in previous studies, sulfate and nitrogen concentrations in precipitation were linked to sample pH. Concentrations of major ions in precipitation appeared to relate more to regional influences rather than local influences. However, concentrations of herbicides in precipitation may have been influenced by both regional and local use which caused compounds like atrazine, deethylatrazine, propazine, simazine, metolachior, alachlor, ametryn, and prometon to be present in detectable concentrations in rainfall. Seasonality was evident in nitrogen, sulfate, pH, and herbicide data and was suggested in calcium, iron, manganese, magnesium, orthophosphate, and chloride data. Agricultural weed control activities were probably responsible for the seasonal pattern in pesticide data which peaked in May and June. Tropical storm Danielle may have caused the apparent seasonal patterns for the other nine parameters. This storm did not follow the typical west to east movement pattern and consequently produced rainfall of relative high quality. A variety of quality assurance checks indicated that trained volunteer citizen monitors were successful participants in this intensive and extensive scientific study, collecting good quality samples in a timely manner. Without this kind of volunteer help, it is extremely difficult to complete studies that require sampling in response to natural events such as rainfall.     

Grass‐Shrub Riparian Buffer Removal of Sediment,Phosphorus, and Nitrogen From Simulated Runoff1

Abstract: Riparian buffer forests and vegetative filter strips are widely recommended for improving surface water quality, but grass‐shrub riparian buffer system (RBSs) are less well studied. The objective of this study was to assess the influence of buffer width and vegetation type on the key processes and overall reductions of total suspended solids (TSS), phosphorus (P), and nitrogen (N) from simulated runoff passed through established (7‐year old) RBSs. Nine 1‐m RBS plots, with three replicates of three vegetation types (all natural selection grasses, two‐segment buffer with native grasses and plum shrub, and two‐segment buffer with natural selection grasses and plum shrub) and widths ranging from 8.3 to 16.1 m, received simulated runoff having 4,433 mg/l TSS from on‐site soil, 1.6 mg/l total P, and 20 mg/l total N. Flow‐weighted samples were collected by using Runoff Sampling System (ROSS) units. The buffers were very efficient in removal of sediments, N, and P, with removal efficiencies strongly linked to infiltration. Mass and concentration reductions averaged 99.7% and 97.9% for TSS, 91.8% and 42.9% for total P, and 92.1% and 44.4% for total N. Infiltration alone could account for >75% of TSS removal, >90% of total P removal, and >90% of total N removal. Vegetation type induced significant differences in removal of TSS, total P, and total N. These results demonstrate that adequately designed and implemented grass‐shrub buffers with widths of only 8 m provide for water quality improvement, particularly if adequate infiltration is achieved.     

POTENTIAL FOR REDUCING NITROGEN POLLUTION THROUGH IMPROVED AGRONOMIC PRACTICES1

ABSTRACT: According to the 1990 National Water Quality Inventory nutrient runoff from agriculture is one of the largest contributors to watershed contamination. Nutrient balance studies suggest that many farmers use more fertilizer than necessary because of insufficient crediting for nutrients coming from manure and legumes. Using data from the USDA's 1990 Farm Costs and Returns Survey, we found that farmers raising only conventional crops spend between $470 to $624 million more per year on fertilizer than necessary. This accounts for a range of 24 percent to 32 percent of total annual nitrogen (N) purchases. The excess N amounts to between 2.5 to 3.3 billion pounds N and has considerable water pollution potential. Farmers and the fertilizer industry have responded positively to highly focused research and education programs which support improved crediting of these nutrients.     

Effect of Watershed Subdivision and Filter Width on SWAT Simulation of a Coastal Plain Watershed1

Cho, Jaepil, Richard R. Lowrance, David D. Bosch, Timothy C. Strickland, Younggu Her, and George Vellidis, 2010. Effect of Watershed Subdivision and Filter Width on SWAT Simulation of a Coastal Plain Watershed. Journal of the American Water Resources Association (JAWRA) 46(3):586-602. DOI: 10.1111/j.1752-1688.2010.00436.x Abstract: The Soil and Water Assessment Tool (SWAT) does not fully simulate riparian buffers, but has a simple filter function that is responsive to filter strip width (FILTERW). The objectives of this study were to (1) evaluate SWAT hydrology and water quality response to changes in watershed subdivision levels and different FILTERW configurations and (2) provide guidance for selecting appropriate watershed subdivision for model runs that include the riparian buffer feature through the FILTERW parameter. Watershed subdivision level is controlled by the critical source area (CSA) which defines the minimum drainage area required to form the origin of a stream. SWAT was calibrated on a 15.7 km² subdrainage within the Little River Experimental Watershed, Georgia. The calibrated parameter set was applied to 32 watershed configurations consisting of four FILTERW representations for each of eight CSA levels. Streamflow predictions were stable regardless of watershed subdivision and FILTERW configuration. Predicted sediment and nutrient loads from upland areas decreased as CSA increased when spatial variations of riparian buffers are considered. Sediment and nutrient yield at the watershed outlet was responsive to different combinations of CSA and FILTERW depending on selected in-stream processes. CSA ranges which provide stable sediment and nutrient yields at the watershed outlet was suggested for avoiding significant modifications in selected parameter set.     

MODELING URBAN NONPOINT SOURCE POLLUTION WITH A GEOGRAPHIC INFORMATION SYSTEM1

ABSTRACT: A geographic information system (GIS) was a useful aid in the assessment of urban nonpoint source pollution and the development of a pollution control strategy. The GIS was used for data integration and display, and to provide data for a nonpoint source model. An empirical nonpoint source loading model driven by land use was used to estimate pollutant loadings of priority pollutants. Pollutant loadings were estimated at fine spatial resolution and aggregated to storm sewer drainage basins (sewersheds). Eleven sewersheds were generated from digital versions of sewer maps. The pollutant loadings of individual land use polygons, derived as the units of analysis from street blocks, were aggregated to get total pollutant loadings within each sewershed. Based on the model output, a critical sewershed was located. Pollutant loadings at major sewer junctions within the critical sewershed were estimated to develop a mitigation strategy. Two approaches based on the installation of wet ponds were investigated - a regional approach using one large wet pond at the major sewer outfall and a multisite approach using a number of smaller sites for each major sewer junction. Cost analyses showed that the regional approach would be more cost effective, though it would provide less pollution control.