An assessment of energy recovery methods applicable to domestic refuse disposal

Any recycled material for re-use must be competitive in both quality and cost when compared with virgin raw materials. In the case of domestic refuse these two constraints mean that direct recycling for materials re-use is very restricted and indirect uses are sought instead. One major area of indirect recycling is energy recovery. This paper presents economic analyses performed on a net energy output basis for incineration for both heat and electrical energy production and also for gas production by pyrolysis. Acid hydrolysis of refuse for the production of ethyl alcohol or protein is also presented and analysed in detail since by this means finite oil reserves are conserved. An economic case is made for further work in this area as it is shown to be the only refuse recycling process with the potential to accomplish both refuse disposal and energy recovery at costs substantially less than straight incineration.     

Industrial metabolism of PVC in China: A dynamic material flow analysis

In China, the rapid development of the polyvinylchloride (PVC) industry will inevitably lead to various environmental problems. This paper studies the PVC metabolism further by (1) constructing dynamic models based on material flow analysis (MFA), (2) introducing calculation on detailed lifetime distribution of different types of products and recycling, and (3) obtaining the performances of waste emissions and accumulation as a function of raw material input and time. Based on system evolution theory and population development models, the developing trend of the PVC industry is studied, and annual consumptions in future years are predicted. The annual emission and accumulation after metabolism can be calculated by tracking the amount of raw material input, existing form and process flow for a single year (2003), as well as over a longer period (from 1958 to 2048) in China. Analysis indicates that over 0.6 billion tons of PVC waste will have accumulated in the environment by the end of 2050. In this scenario analysis, the effects of product structure, lifetime distribution, mechanical recycling, chemical recycling and incineration on waste output are all taken into consideration. The product metabolism process can be decelerated by changing these factors appropriately. However, mechanical recycling and chemical recycling are the most effective solutions.     

Life cycle assessment of waste paper management: The importance of technology data and system boundaries in assessing recycling and incineration

The significance of technical data, as well as the significance of system boundary choices, when modelling the environmental impact from recycling and incineration of waste paper has been studied by a life cycle assessment focusing on global warming potentials. The consequence of choosing a specific set of data for the reprocessing technology, the virgin paper manufacturing technology and the incineration technology, as well as the importance of the recycling rate was studied. Furthermore, the system was expanded to include forestry and to include fossil fuel energy substitution from saved biomass, in order to study the importance of the system boundary choices. For recycling, the choice of virgin paper manufacturing data is most important, but the results show that also the impacts from the reprocessing technologies fluctuate greatly. For the overall results the choice of the technology data is of importance when comparing recycling including virgin paper substitution with incineration including energy substitution. Combining an environmentally high or low performing recycling technology with an environmentally high or low performing incineration technology can give quite different results. The modelling showed that recycling of paper, from a life cycle point of view, is environmentally equal or better than incineration with energy recovery only when the recycling technology is at a high environmental performance level. However, the modelling also showed that expanding the system to include substitution of fossil fuel energy by production of energy from the saved biomass associated with recycling will give a completely different result. In this case recycling is always more beneficial than incineration, thus increased recycling is desirable. Expanding the system to include forestry was shown to have a minor effect on the results. As assessments are often performed with a set choice of data and a set recycling rate, it is questionable how useful the results from this kind of LCA are for a policy maker. The high significance of the system boundary choices stresses the importance of scientific discussion on how to best address system analysis of recycling, for paper and other recyclable materials.     

Life cycle assessment of waste paper management: The importance of technology data and system boundaries in assessing recycling and incineration

The significance of technical data, as well as the significance of system boundary choices, when modelling the environmental impact from recycling and incineration of waste paper has been studied by a life cycle assessment focusing on global warming potentials. The consequence of choosing a specific set of data for the reprocessing technology, the virgin paper manufacturing technology and the incineration technology, as well as the importance of the recycling rate was studied. Furthermore, the system was expanded to include forestry and to include fossil fuel energy substitution from saved biomass, in order to study the importance of the system boundary choices. For recycling, the choice of virgin paper manufacturing data is most important, but the results show that also the impacts from the reprocessing technologies fluctuate greatly. For the overall results the choice of the technology data is of importance when comparing recycling including virgin paper substitution with incineration including energy substitution. Combining an environmentally high or low performing recycling technology with an environmentally high or low performing incineration technology can give quite different results. The modelling showed that recycling of paper, from a life cycle point of view, is environmentally equal or better than incineration with energy recovery only when the recycling technology is at a high environmental performance level. However, the modelling also showed that expanding the system to include substitution of fossil fuel energy by production of energy from the saved biomass associated with recycling will give a completely different result. In this case recycling is always more beneficial than incineration, thus increased recycling is desirable. Expanding the system to include forestry was shown to have a minor effect on the results. As assessments are often performed with a set choice of data and a set recycling rate, it is questionable how useful the results from this kind of LCA are for a policy maker. The high significance of the system boundary choices stresses the importance of scientific discussion on how to best address system analysis of recycling, for paper and other recyclable materials.     

The influence of adhesives on recycling

The finiteness of many resources made it necessary to think about how to save them by developing resource-saving technologies, e.g. to recycle materials. To execute the idea of recycling, it is necessary to think about a material recycling of the used products when designing them. This means that all additives of the process have to be designed in the way they do not disturb the later material recycling. Today, adhesives play a decisive role in the production of almost every good, especially for mass-produced articles and therefore it is important to choose adhesives that do not disturb the recycling of the primary materials. In recycling processes which take place at high temperatures (e.g. glass or metal recycling), the influence of the adhesives usually formed by organic polymers can be ignored. In the field of low temperature recycling technologies, the question whether an adhesive is recycling-friendly or not can only be answered by knowing its application and the recycling process. If the recycling processes are known, it is easy to chose suitable adhesives. For plastic and paper recycling, there are a lot of adhesives today that fulfill the requirements of recyclers. In order to simplify recycling for the future, adhesives with “switches enclosed” are being developed which will allow us to disbond system components into separate parts after use for reuse or material recycling.     

Incorporation of recycling flows into economy-wide material flow accounting and analysis: A case study for the Czech Republic

Economy-wide material flow accounting and analysis (EW-MFA) is considered a convenient tool for monitoring the vast range of issues related to the consumption of materials. As an increase in recycling is considered a crucial way of decreasing environmental pressures from this consumption, it makes sense to develop an indicator based on EW-MFA which would incorporate recycling flows. A prominent example of such an indicator is the cyclical use rate, which was developed by the Japanese Fundamental Plan for Establishing a Sound Material-Cycle Society.We calculated this indicator for the Czech Republic for 2002–2011 and proved that it can also be calculated for countries other than Japan, even though we encountered some unclear methodological issues related to specific features of the Czech waste management system. We further developed two modifications of the indicator taking into consideration that one purpose of the cyclical use rate is to express the ratio of consumption of secondary (recycled) materials and primary raw materials. We discussed these modifications and showed that overall cyclical use rate in the Czech Republic lags behind Japan both in terms of absolute value and trend development, although the indicator is higher for biomass in the Czech Republic. We also showed that this unfavorable evaluation is in contradiction with some classic waste indicators, such as treatment of waste by main treatment methods which is favorably evaluated in the Czech Republic. We concluded that it would be advisable to analyze measures for increasing recycling rates introduced by Japan and assess their possible transposition into the Czech Republic's institutional and legal framework for waste management.     

Air emissions from pavement layers composed of varying rates of reclaimed asphalt

An experimental study of road building and recycling of used pavement has been conducted within the framework of a Life Cycle Analysis. Four equivalent asphalt concretes made with different recycling rates have been investigated during road construction. Airborne emissions, pollutant release over time and odor production related to asphalt laying have all been determined and compared among the various recycling rates. All of the results (VOC, PAH and odors), expressed in terms of concentrations and fluxes, exhibit quite monotonic variations with respect to the recycling rate. These results, however, did not reveal the same trend as a function of the recycling rate (increases or decreases), depending on the selected target parameter (VOC or PAH). Indicators have been proposed for a discussion of results that take into account: (i) raw material emissions with respect to the reference defined in the case of pavement without reclaimed asphalt; and (ii) emissions in each case from all material production sources.     

How to evaluate raw material supply risks—an overview

Some strategic raw materials do have an extremely unsecure supply situation. Several working groups around the world have made criticality assessments for metallic raw materials to analyze the driving impact factors for this instability. However, the influences on raw material availability are manifold and therefore criticality assessment methods are very heterogeneous. Here we give an overview about the differences and similarities of supply risk evaluation in 15 criticality assessment methods. We take the example of Indium, which has been rated in 60% of these criticality studies, and show which data base is used for supply risk evaluation. Our results show a lack of consensus about which indicators give reliable information for raw material supply risk and how these indicators should be aggregated. We anticipate our essay to be a starting point for more justified indicator selection and weighting in criticality assessments.     

Exergy losses during recycling and the resource efficiency of product systems

Recycling materials have always some degree of contamination. The presence of contaminations in the recycling streams causes a shift in the original composition of the materials to recycle. As a consequence, their quality may decrease with each recycling step. Additionally, lower quality resources are produced from resource streams that had initially a higher quality. These quality losses cannot be measured by mass balances, as the quality degradation cannot be translated by mass measures alone. To account all losses caused by recycling contaminations, all downstream recycling processes required to bring the materials back to the resource cycles must be included. This article describes a method to calculate the exergy content and exergy losses of metal solutions during recovery and recycling. The losses attributed to recycling, namely the material losses, the contamination losses with other metals, and the consequent need for dilution can be used as indicators of the quality loss of materials and of the efficiency of resource use in product systems. Therefore, exergy is proposed here as a measure of the efficiency of resources use.     

The recycling of rare earths from waste tricolor phosphors in fluorescent lamps: A review of processes and technologies

Rare earths have become the most important strategic resources, widely used as functional materials in industry and many other aspects of life due to its optical, electrical, and magnetic characteristics. As a consequence, a considerable number of wastes containing rare earths such as abandoned fluorescent lamps are generated and lost. Considering the scarcity in availability and supply of certain raw materials, waste tricolor phosphors are viewed as potential resources that can be mined in urban areas for their reutilization as rare earths. A number of studies in this area have been carried out all over the world.The purpose of this paper is to review the current status of recycling technologies of rare earths from waste tricolor phosphors in fluorescent lamps. The main characteristics of the tricolor phosphors were introduced, and also a detail review of the typical single recycling and reusing technologies with regard to waste tricolor phosphors was carried out in present paper. After that, several combined recycling processes and technologies were evaluated. Based on the review, the prospects of recycling technologies were suggested.     

Evaluation of life cycle inventory data for recycling systems

This paper reviews databases on material recycling (primary as well as secondary production) used in life cycle assessments (LCA) of waste management systems. A total of 366 datasets, from 1980 to 2010 and covering 14 materials, were collected from databases and reports. Totals for CO₂-equivalent emissions were compared to illustrate variations in the data. It was hypothesised that emissions from material production and the recycling industry had decreased over time due to increasing regulation, energy costs and process optimisation, but the reported datasets did not reveal such a general trend. Data representing the same processes varied considerably between databases, and proper background information was hard to obtain, which in turn made it difficult to explain the large differences observed. Those differences between the highest and lowest estimated CO₂ emissions (equivalents) from the primary production of newsprint, HDPE and glass were 238%, 443% and 452%, respectively. For steel and aluminium the differences were 1761% and 235%, respectively. There is a severe lack of data for some recycled materials; for example, only one dataset existed for secondary cardboard. The study shows that the choice of dataset used to represent the environmental load of a material recycling process and credited emissions from the avoided production of virgin materials is crucial for the outcome of an LCA on waste management. Great care and a high degree of transparency are mandatory, but advice on which datasets to use could not be determined from the study. However, from the gathered data, recycling in general showed lower emission of CO₂ per kg material than primary production, so the recycling of materials (considered in this study) is thus beneficial in most cases.     

可用作原料的固体废物进口可行性评价指标体系探索研究

合理利用境外的可用作原料的固体废物,可以弥补我国国内资源的相对不足,但固体废物固有的废物属性仍不可避免地会带来一定的环境负面影响。建立可用作原料的固体废物进口可行性评价体系,对于在合理利用境外废物资源的同时,保护和改善环境具有重要意义。本文论述了我国建立可用作原料的固体废物进口可行性评价体系的理论和原则,并根据影响可用作原料的固体废物进口可行性评价的因素分析,构建了可用作原料的固体废物进口可行性评价指标体系框架。     

电解金属锰工艺清洁生产初探

以国内某金属锰龙头企业为例,从工艺流程、设备选型、原材料与能源、尾渣回收、中水回用等方面来分析,提出清洁生产的建议与措施,以期为电解金属锰的工艺改进提供科学的依据,对电解锰行业清洁生产具有指导意义。     

A normative strategy for sustainable resource choice and recycling

A normative strategy is proposed for resource choice and recycling to meet the criterion of sustainability, defined as near constancy of natural resources. In this strategy resource choice should be fitted to the fate of products and product wastes, with geochemically scarce virtually non-renewable resources being reserved for uses that allow for nearly 100% recycling and negligible loss of irretrievable material and material deterioration. Sustainable recycling is argued to be strongly dependent on product design that slows loss of quality by products and materials. Recycling processes should aim at quality conservation by cascading. Non-product and recycling outputs should match with required inputs into the economy. Finally technologies should be employed that prevent the build-up of contaminants in products. Examples are given of the ways in which elements of this normative strategy may be implemented. Internalisation of currently external costs will strongly favour the proposed strategy.     

Amounts of non-fibrous components in recovered paper

Paper and board recycling is now a central issue in papermaking. Understanding of material flows, as a part of the total production chain, as well as, fibrous and non-fibrous component flows needs further clarification. These flows are studied at a European level, with special focus on Germany and Sweden. Non-fibrous components are discussed in terms of a material which hampers the processing of paper and board. Resource-efficiency improvements, in conjunction with economic benefits, are sought and recycling has been able to fulfil both of these. The main drivers to maximize the use of recovered paper in paper and board manufacturing, have been improved over the last decades. These drivers are cost, environmental image and good technical properties to be used as raw material.The increased recycling rate has reduced the quality of the collected paper, produced recycled paper, and replaced virgin pulp. Also, recycling as a process, like deinking, produces large amounts of waste material that has challenges to find proper utilization. These problem areas are addressed in this paper, too.One focus area in the analysis of statistical information is an estimation of the share of non-fibrous components and fibre volumes of paper in Europe (EU) for the year 2010.     

Evaluation of recycling efforts of aircraft companies in Wichita

The number of manufactured aircraft has been continuously increasing worldwide because of the high demand for airline transportation. During manufacturing, many advanced materials and devices are used to build various sizes and shapes of aircraft. However, most of these materials and devices require considerable energy and labor to produce, so reusing these at any life stage of the aircraft offers many economic and environmental benefits, and is considered lucrative and environmentally responsible. Several recyclable materials—composites, metals and alloys, wires, wood, paper, plastics, electronics, and avionics—emerge as waste streams during the manufacturing of aircraft. Many aircraft companies have been recycling these materials to remanufacture aircraft parts or other products for more sustainable production. In the present study, we evaluated the recycling efforts of local aircraft companies in Wichita, KS. These efforts were considered in terms of recycling efficiency/rate and environmental benefits. These included cradle-to-gate (CTG) life-cycle inventory analysis of the materials, carbon dioxide emissions, virgin material replacement with recycled materials, and natural resources usage. Our findings show that there exists a significant potential for contributions to sustainability as well as environmental and health benefits in the region from recycling by aircraft manufacturing plants.     

Twenty years of PET bottle to bottle recycling—An overview

Polyethylene terephthalate (PET) has become the most favourable packaging material world-wide for beverages. The reason for this development is the excellent material properties of the PET material, especially its unbreakability and the very low weight of the bottles compared to glass bottles of the same filling volume. Nowadays, PET bottles are used for softdrinks, mineral water, energy drinks, ice teas as well as for more sensitive beverages like beer, wine and juices. For a long time, however, a bottle-to-bottle recycling of post-consumer PET packaging materials was not possible, because of the lack of knowledge about contamination of packaging polymers during first use or recollection. In addition, the decontamination efficiencies of recycling processes were in most cases unknown. During the last 20 years, PET recollection as well as recycling processes made a huge progress. Today, sophisticated decontamination processes, so-called super-clean recycling processes, are available for PET, which are able to decontaminate post-consumer contaminants to concentration levels of virgin PET materials. In the 1991, the first food contact approval of post-consumer PET in direct food contact applications has been given for post-consumer recycled PET in the USA. Now, 20 years after the first food approval of a PET super-clean recycling process, this article gives an overview over the world-wide progress of the bottle-to-bottle recycling of PET beverage bottles, e.g. the recollection amount of post-consumer PET bottles and the super-clean recycling technologies.     

Two Measured Parameters Correlated to Participation Rates in Curbside Recycling Schemes in the UK

Local authorities in the United Kingdom are currently changing their approach towards recycling as they attempt to meet legislative targets. An important part of this drive is the provision of an effective curbside recycling service and it is vital to understand the parameters that influence the performance of the system offered. In this article, three primary datasets, collected from over 1400 households each, are examined for parameters correlated to participation rates. Two measured parameters were found that are not commonly identified in previous studies of curbside recycling schemes, and they are shown to merit further investigation as useful tools for planning purposes. One is the number of types of material collected; participation rates are greater for schemes collecting more materials. The second is the number of households situated on the same road; the lower the number, the higher the participation rate. In both cases, evidence of the measured correlation is presented, justifying their usefulness for planning. The multiple underlying factors causing the correlations are not identified here, but suggestions are made for further studies.     

Impediments to refractory recycling decision-making

This paper focuses on organizational impediments to the successful implementation of industrial recycling programs. Even if a technologically viable and mutually beneficial solution were to exist, there are a number of organizational impediments that make it unlikely to succeed unless the benefits are very large and apparent. These impediments stem from the difficulty in identifying potential partners and involving the appropriate individuals within the firms that understand the technical requirements, value the strategic benefits and are receptive towards establishing the industrial recycling relationship. This dilemma applies to many industrial recycling opportunities, but solutions do exist. One way to avoid some of these obstacles is to use a middleman, or broker, who can play several crucial roles to establish the relationship. This paper describes the impediments and key broker roles, and provides a case study dealing with refractory recycling. It provides a case study that documents a recycling relationship between an aluminum-manufacturing firm that produces a large volume of spent refractories and a regional portland cement producer that is using the spent refractories as an alternative raw material source. This paper also provides a thorough literature search in the area of refractory recycling. Finally, the case study provides an opportunity for analysis and reflection on the implications of these findings to industrial firms, industrial societies and governmental agencies that seek to encourage successful recycling operations.     

Recycling and consumption in Germany and Japan: a case of toilet paper

This paper compares the recycling attitudes of consumers in Germany and Japan, based on our nationwide questionnaires. We analyzed consumption behavior as well as recycling behavior in narrow sense, because it is important to study the former to see how the supply of recycled materials is balanced with the demand, particularly in Japan which exports little recycled materials. Toilet paper was adopted as a specific good for study, because consumers have options of buying virgin products and recycled products. It was found that German households pay for waste collection specifically and have higher recycling rates than Japanese households. On the other hand, similar figures in German and Japanese consumers were observed with regard to consumption of recycled products. Their purchasing criteria and preference on virgin and recycled products of toilet paper were examined by self-report and blind test with 2×2 experimental design for toilet paper (German versus Japanese, virgin versus recycled). Blind test showed that people prefer domestic and virgin products in both countries. Half of respondents rating virgin products guessed that the products contained recycled material. For Japanese, the material of the sample toilet paper, made from virgin pulp, seems to be a more determining factor than the nationality of products, i.e. made in Japan. On the other hand, for Germans, the domestic nature seems to be a more dominant factor than the material, i.e. made from virgin material. Canonical discriminant analysis in conjunction with logistic regression based on self-reporting data detected the characters ‘multiplied’, ‘appearance’ and ‘brand’ as major factors making the difference in preference between the two countries. The possible reasons causing the similarity and dissimilarity between the two countries are discussed with reference to the background history.