Reprocessing of metallurgical slag into materials for the building industry

Several methods of reprocessing metallurgical (blast furnace) slag into materials for the building industry, based on melting aggregates with submerged combustion, were developed and tested. The first method involves melting hot slag with some additives directly in a slag ladle with a submerged gas-air burner, with the objective of producing stabilized slag or glass-ceramic. The second method involves direct draining of melted slag from a ladle into the slag receiver, with subsequent control of the slag draining into the converter where special charging materials are added to the melt, with the objective of producing glass-ceramic. A third method involves melting cold slag with some additives inside a melting converter with submerged gas-air burners, with the objective of producing glass-ceramic fillers for use in road construction. Specific to the melting process is the use of a gas-air mixture with direct combustion inside the melt. This feature provides melt bubbling to help achieve maximum heat transfer from combustion products to the melt, improve mixing (and therefore homogeneity of the melt), and increases the rate of chemical reactions. The experimental data for different aspects of the proposed methods are presented. The reprocessed blast-furnace slag in the form of granules can be used as fillers for concretes, asphalts, and as additives in the production of cement, bricks and other building materials. As well, reprocessed blast-furnace slag can be poured into forms for the production of glass-ceramic tiles.     

国外建材产业发展循环经济简况

第二次世界大战之后,特别是从20世纪50年代开始,欧洲各国、日本及美国等国家以住宅建设为主的建筑产业化快速发展,极大地激活并快速推进了建材生产的产业化发展。但是,建材产业的迅猛发展又带来了两个十分突出的问题：一是极大地消耗了煤炭、电力、石灰石、土地等不可再生资源;二是产生大量的废气、废料、废渣、废水,对大气环境和自然环境造成严重的污染。为了应对日益严重的资源危机与环境危机,从20世纪70年代,开始发展以“减量化、再利用、再循环”为核心的循环经济,发达国家建材产业纷纷引入循环经济理念,在“减量化、再利用、资源化”方面取得显著成效。     

建筑材料再循环利用价值研究

绿色建筑材料及产品的再循环利用价值的确定似乎是一件比较简单的事情,但在绿色建筑评估体系中来具体确定其再循环价值却是非常困难的.对建筑评价体系中的建筑材料再循环价值进行初步研究和计算,该计算过程考虑了建筑材料选择、建筑结构、建筑施工、建筑拆除技术以及回收频率等,因其计算结果含有能量因素,可作为建筑材料再循环价值的计算方法.     

Raw material potential of recyclable materials for fiber composites: a review study

The aim of this study is to investigate waste streams as a source of recyclable raw material for fiber composite production. Globally, vast volumes of waste are produced daily that are not recycled effectively. In this work, three different raw material sources are examined; industrial, construction and municipal solid waste streams. All three sources produce wastes that are currently underutilized. Usage areas for the waste material include use as a reinforcing fiber, as part of the plastic matrix or as a filler. The industrial sector produces more homogenous waste, while waste from municipalities is mixed. Irregular material flow, the varying condition of the waste and different pretreatments used pose difficulties for recycling. Furthermore, some materials are industry-specific and may be produced in only certain areas. Despite these difficulties, huge amount of potentially useful exploitable waste is available and using different waste streams as a part of wood-plastic composite production can reduce waste volumes disposed to landfill.     

Reuse of textile effluent treatment plant sludge in building materials

This study examines the potential reuse of textile effluent treatment plant (ETP) sludge in building materials. The physico-chemical and engineering properties of a composite textile sludge sample from the southern part of India have been studied. The tests were conducted as per Bureau of Indian Standards (BIS) specification codes to evaluate the suitability of the sludge for structural and non-structural application by partial replacement of up to 30% of cement. The cement-sludge samples failed to meet the required strength for structural applications. The strength and other properties met the Bureau of Indian Standards for non-structural materials such as flooring tiles, solid and pavement blocks, and bricks. Results generally meet most ASTM standards for non-structural materials, except that the sludge-amended bricks do not meet the Grade NW brick standard. It is concluded that the substitution of textile ETP sludge for cement, up to a maximum of 30%, may be possible in the manufacturing of non-structural building materials. Detailed leachability and economic feasibility studies need to be carried out as the next step of research.     

建材产业发展循环经济的任务目标与措施

从多方面论述了建材产业发展循环经济的任务、目标、技术路线及措施。指出在循环经济之业链中,建材产业将成为资源减量化、再利用、再循环途径最多和潜力最大的产业之一,建材产业发展循环经济,既可实现自身的可持续发展,又可促进和带动其他行业循环经济的发展。     

A novel method for preparing phosphorus building gypsum (PBG)-based building materials with low water/gypsum ratios

Journal of Material Cycles and Waste Management - It is necessary to consider the dual problems of poor performance and low production efficiency that stem from the highly utilised water/gypsum...     

Matt waste from glass separated collection: an eco-sustainable addition for new building materials

Matt waste (MW), a by-product of purification processes of cullet derived from separated glass waste collection, has been studied as filler for self-compacting concrete and as an addition for newly blended cement. Properties of self-compacting concrete compared to reference samples are reported. They include characteristics at the fresh and hardened states, and the compressive strength and porosity of mortar samples that were formulated with increasing amounts of MW to be used as cement replacement (up to 50wt.%). The effects of matt waste are discussed with respect to the mechanical and microstructural characteristics of the resulting new materials.     

Recycling of low-silicate iron tailings in the production of lightweight building materials

Journal of Material Cycles and Waste Management - A feasible process for preparing lightweight building materials from the low-silicate iron tailings was developed. Various proportions of...     

The building materials decree: an example of a Dutch regulation based on the potential impact of materials on the environment

Some 20 years ago Dutch society became very aware of the problem of the increasing production of waste materials and of the need to find solutions. Technical solutions had to be developed and introduced into society. Due to the discovery of many soil pollution problems and other environmental calamities, people asked for clear criteria on which proper and safe solutions could be based. Therefore a large number of environmental aspects had to be taken into account in the developing field of environmental policy. The Dutch building materials decree is one of the steps on the road towards a sustainable society. The decree is based on the soil protection act and the surface water protection act. The decree gives quality criteria for the application and re-use of stony materials and earth used as building materials. No difference is made between primary materials, secondary materials and waste materials. The decree is applicable in case these materials are used in constructions where they are in contact with rain, surface water and ground water (e.g. in embankments, road building, outside walls of buildings, foundations and roofs). For implementation of the decree in the construction industry it was necessary to develop standards, methods for testing and certification schemes. In order to guarantee independent testing and judgement, laboratories had to meet quality standards put forward in an accreditation scheme. Although this legislation does not cover all environmental aspects, it has proved to be an important element in judging the environmental quality of construction materials in a direct or indirect way, and a contribution to the management of waste materials. The question of clear and fair criteria was easily put forward. Answering this question, however, turned out to be a complex task in which a great number of aspects had to be considered and a great many tools had to be developed, checked and thoroughly discussed. In some cases practical choices had to be made in order to prevent an unclear situation continuing too long. After an introduction period of three years, the decree came into full operation on 1 July 1999.     

Flue gas desulfurization gypsum and coal fly ash as basic components of prefabricated building materials

The manufacture of prefabricated building materials containing binding products such as ettringite (6CaO·Al₂O₃·3SO₃·32H₂O) and calcium silicate hydrate (CSH) can give, in addition to other well-defined industrial activities, the opportunity of using wastes and by-products as raw materials, thus contributing to further saving of natural resources and protection of the environment.Two ternary mixtures, composed by 40% flue gas desulfurization (FGD) gypsum or natural gypsum (as a reference material), 35% calcium hydroxide and 25% coal fly ash, were submitted to laboratory hydrothermal treatments carried out within time and temperature ranges of 2 h–7 days and 55–85 °C, respectively. The formation of (i) ettringite, by hydration of calcium sulfate given by FGD or natural gypsum, alumina of fly ash and part of calcium hydroxide, and (ii) CSH, by hydration of silica contained in fly ash and residual lime, was observed within both the reacting systems. For the FGD gypsum-based mixture, the conversion toward ettringite and CSH was highest at 70 °C and increased with curing time. Some discrepancies in the hydration behavior between the mixtures were ascribed to differences in mineralogical composition between natural and FGD gypsum.     

Development of composites using residue from laminated packaging with discarded foundry sand

Journal of Material Cycles and Waste Management - In recent years, the use of residue for the production of new composite materials has gained prominence as it enables reuse of materials and...     

Development of composite materials by mechanochemical treatment of post-consumer plastic waste

Improvement of mechanical properties of recycled mixed plastic waste is one of the fundamental goals in any recycling process. However, polymer immiscibility makes the development of any effective reprocessing method difficult. In this work, a polymer milling process with liquid CO2 was applied to polymeric mixed waste, obtaining a powder material which was successfully utilized as a matrix for a new composite material. Developed materials have interesting mechanical properties and material performance can easily be improved. Investigations on selected mixtures of PP and PE clearly showed evidence of chemical compatibilization.     

Circular economy for durable products and materials: the recycling of plastic building products in Germany—status quo,potentials and recommendations

Journal of Material Cycles and Waste Management - The construction sector is the second largest area for the application for plastics. Due to the long life times of construction products, the...     

Development of a testing method for asbestos fibers in treated materials of asbestos containing wastes by transmission electron microscopy

Appropriate treatment of asbestos-containing wastes is a significant problem. In Japan, the inertization of asbestos-containing wastes based on new treatment processes approved by the Minister of the Environment is promoted. A highly sensitive method for testing asbestos fibers in inertized materials is required so that these processes can be approved. We developed a method in which fibers from milled treated materials are extracted in water by shaking, and are counted and identified by transmission electron microscopy. Evaluation of this method by using asbestos standards and simulated slag samples confirmed that the quantitation limits are a few million fibers per gram and a few μg/g in a sample of 50 mg per filter. We used this method to assay asbestos fibers in slag samples produced by high-temperature melting of asbestos-containing wastes. Fiber concentrations were below the quantitation limit in all samples, and total fiber concentrations were determined as 47–170 × 10^?6 f/g. Because the evaluation of treated materials by TEM is difficult owing to the limited amount of sample observable, this testing method should be used in conjunction with bulk analytical methods for sure evaluation of treated materials.     

Recycling of rubble from building demolition for low-shrinkage concretes

In this project concrete mixtures were prepared that were characterized by low ductility due to desiccation by using debris from building demolition, which after a suitable treatment was used as aggregate for partial replacement of natural aggregates. The recycled aggregate used came from a recycling plant, in which rubble from building demolition was selected, crushed, cleaned, sieved, and graded. Such aggregates are known to be more porous as indicated by the Saturated Surface Dry (SSD) moisture content. The recycled concrete used as aggregates were added to the concrete mixture in order to study their influence on the fresh and hardened concrete properties. They were added either after water pre-soaking or in dry condition, in order to evaluate the influence of moisture in aggregates on the performance of concrete containing recycled aggregate. In particular, the effect of internal curing, due to the use of such aggregates, was studied. Concrete behavior due to desiccation under dehydration was studied by means of both drying shrinkage test and German angle test, through which shrinkage under the restrained condition of early age concrete can be evaluated.     

水污染分析校准用汞溶液的研制

研制了水污染分析校准用汞溶液。采用原子荧光光谱法对样品进行了均匀性和稳定性检验,对样品的量值进行了验证并进行了不确定度评定。检验结果表明:汞溶液均匀性良好,室温条件下可稳定36个月以上;样品的标准值为100 mg/L,扩展不确定度为2 mg/L。样品量值与美国AccuStandard公司同种标准物质具有一致性。可用于水中汞检测的测定标准、质量控制、分析方法研究以及实验室能力验证等方面。