Atmospheric Mercury Pollution in Beijing

Abstract

The atmospheric mercury pollution in Beijing is a serious problem. Atmospheric mercury has three sources: natural emission, anthropogenic emission and previously deposited mercury reemission or recycling, composing elemental mercury, divalent mercury and particulate-phase mercury. Many studies showed that mercury in Beijing’s air was higher than the general level of mercury concentration in the atmosphere. Mercury emission sources were discussed. Industrial emissions, coal burning, vehicle exhaust emissions and waste incineration were thought to be the main sources of atmospheric mercury pollution in Beijing. And also meteorology has an effect on atmospheric mercury concentration in Beijing. Measures have been taken to control the emission of mercury into the air in recent years.     

Formation of PBDD/F from flame-retarded plastic materials under thermal stress

Thermal treatment of plastics flame retarded with brominated compounds often lead to the formation of PBDD/F, especially if polybrominated diphenyl ethers are used. By the presence of antimony(III) oxide, water and some other metals, the amounts of PBDD/F increase. Even during the production and recycling processes of plastics, PBDD/F can be found in considerable amounts. By the use of flame retardants, which are not direct precursors of PBDD/F, the amounts can significantly be decreased. An incomplete and uncontrolled incineration, occurring in fire accidents in private residences, can form high amounts of PBDD/F, which can endanger the environment and persons in contact with fire residues. Complete and controlled incineration of bromine-containing compounds as usually conducted in municipal waste incinerators, however, show no raised risk. An overview about the formation of PBDD/F primarily during combustion and also during production and recycling processes of flame-retarded plastic materials is given in this paper.     

Mercury pollution in Wuchuan mercury mining area,Guizhou, Southwestern China: The impacts from large scale and artisanal mercury mining

To evaluate the environmental impacts from large scale mercury mining (LSMM) and artisanal mercury mining (AMM), total mercury (THg) and methyl mercury (MeHg) were determined in mine waste, ambient air, stream water and soil samples collected from Wuchuan mercury (Hg) mining area, Guizhou, Southwestern China. Mine wastes from both LSMM and AMM contained high THg concentrations, which are important Hg contamination sources to the local environment. Total gaseous mercury (TGM) concentrations in the ambient air near AMM furnaces were highly elevated, which indicated that AMM retorting is a major source of Hg emission. THg concentrations in the stream water varied from 43 to 2100 ng/L, where the elevated values were mainly found in the vicinity of AMM and mine waste heaps of LSMM. Surface soils were seriously contaminated with Hg, and land using types and organic matter played an important role in accumulation and transportation of Hg in soil. The results indicated heavy Hg contaminations in the study area, which were resulted from both LSMM and AMM. The areas impacted by LSMM were concentrated in the historical mining and smelting facilities, while Hg pollution resulted from AMM can be distributed anywhere in the Hg mining area.     

国外废旧家用电子电器回收再利用研究

随着废旧家用电子电器数量和种类的增加及其产生的环境污染问题，废旧家用电子电器的处理处置、回收再利用引起世界各国的广泛关注。本文阐述了一些工业发达国家在废旧家用电子电器回收再利用方面所采取的措施、取得的成功经验和未来发展趋势。     

无锡市能源消费、碳排放与经济增长关系分析

经济增长对资源消耗存在很大的依赖性,研究能源消费、碳排放与经济增长关系,可为经济增长方式转变和低碳城市建设提供重要科学依据。基于IPCC国家温室气体排放清单指南中的方法估算了无锡市能源消费碳排放,并建立“脱钩”模型探讨能源消费、碳排放与经济增长之间的关系。结果表明：（1）2000~2010年,无锡市碳排放从84335万t增加到2 52804万t,总量不断增加,但趋势有所减缓,且各县市碳排放特征差异显著;（2）无锡市碳排放与经济增长整体处于弱脱钩状态,且脱钩状态有不断增强的趋势,市区经济发展已不依赖于能源消费,朝着环境友好方向发展,江阴和宜兴节能减排压力仍然很大;（3）优化产业结构、调整工业结构和提高能源利用效率是改善无锡市能源消费、碳排放和经济增长关系的有效途径,各县市根据具体情况,侧重点有所不同     

基于农户兼业视角的农业废弃物资源循环利用意愿及其影响因素比较

基于农户兼业视角,利用湖北省农村地区的微观调查数据,运用Logistic回归模型比较了不同兼业类型农户农业废弃物资源循环利用意愿及其影响因素。研究结果显示：（1）大部分农户具有农业废弃物资源循环利用意愿,其中纯农户和一兼农户的利用意愿相当,且高出二兼农户;（2）农户对农业废弃物资源价值的感知是影响不同兼业类型农户利用意愿的共同因素,农户感知农业废弃物资源的价值越高,其利用意愿也越强;（3）影响不同兼业类型农户利用意愿的因素有明显差异,性别对农户尤其是二兼农户的利用意愿有显著的正向作用;年龄对纯农户和二兼农户利用意愿的影响均为负,尤其是对纯农户影响更大;土地经营规模对农户尤其是一兼农户的利用意愿有显著的正向影响;对获取经济收益的感知正向作用于一兼农户和二兼农户的利用意愿,尤其是对一兼农户有更大程度影响;对纯农户而言,对自身经济条件的感知也显著影响其利用意愿     

Environmental mercury contamination in China: sources and impacts

This review article focused on the current status of mercury (Hg) contamination in different ecological compartments in China, and their possible environmental and health impacts, focusing on some major cities. Mercury emission from non-ferrous metals smelting (especially zinc smelting), coal combustion and miscellaneous activities (of which battery and fluorescent lamp production and cement production are the largest), contributed about 45%, 38% and 17%, respectively, to the total Hg emission based on the data of 1999. Mercury contamination is widespread in different ecological compartments such as atmosphere, soil and water. There is evidence showing bioaccumulation and biomagnification of Hg in aquatic food chains, with higher concentrations detected in carnivorous fish. In terms of human exposure to Hg, fish consumption is the major exposure pathway for residents living in coastal cities such as Hong Kong, but inhalation may be another major source, affecting human health in areas with severe atmospheric Hg, such as Guiyang City (Guizhou Province). The first case study indicated that after closure of the acetic acid plant 20 years at Songyuan City (Jilin Province), 16.7% of residents' hair still contained Hg concentration in excess of 1 mg/kg (the reference dosage value, RfD set by USEPA). The second case study indicated that the male residents of Hong Kong who consumed more than four or more meals of fish per week tended to contain higher Hg in their hair, which was linked to their subfertility. There is also increasing evidence showing that skin disorders and autism in Hong Kong children are related to their high Hg body loadings (hair, blood and urine), through prenatal methyl Hg exposure. There seems to be an urgent need to identify the sources of Hg, speciation and concentrations in different ecological compartments, which may lead to high body loadings in human beings. Adverse health effects of residents living in places with a higher background level of Hg, due to long-term exposure to chronic levels of Hg through oral intake should not be overlooked.     

基于卫星夜间灯光数据的中国分省碳排放时空模拟

中国能源统计数据"横向不可比,纵向不可加"现象依然突出,尤其是分省能源消费统计千差万别,给分省碳排放评估带来了较大困难,如何利用卫星遥感数据科学合理地估算中国分省碳排放是当前亟须研究的问题。本文运用DMSP/OLS全球稳定夜间灯光数据,在通过相互校正、年内融合和年际间校正等系列处理得到中国分省稳定夜间灯光数据的基础上,首先分别构建中国分省稳定夜间灯光亮度DN值与人均碳排放和单位面积碳排放之间的时空地理加权回归模型,两个模型整体效果均较好,拟合优度分别高达96.74%和99.24%;其次运用稳定夜间灯光亮度DN值对分省人均碳排放和单位面积碳排放进行时空模拟;最后运用人口规模和土地面积对分省碳排放进行估算。估算结果显示:(1)整体来看,2000—2013年年均碳排放模拟值与实际值6.3349×109t较为接近,两个模型的相对误差均在0.5%以内。(2)分年度来看,所有年份的相对误差均在5%以内,2006年分省加总碳排放模拟值与实际碳排放6.2036×109t最为接近,绝对误差和相对误差均较小,两个模型模拟值的相对误差均为0.04%。(3)分省域来看,2000—2013年年均碳排放模拟值与实际碳排放均非常接近,除海南和宁夏外,其余28个省区市的相对误差均在1%以内。(4)分年度分省域来看,以2013年为例,40%省份的相对误差在2%以内,70%省份的相对误差在5%以内。从整体、分年度、分省域、分年度分省域的估算结果来看,基于稳定夜间灯光数据的中国分省碳排放时空模拟效果良好。因此,运用卫星夜间灯光数据可以较为准确地对中国分省碳排放进行估算和预测,为卫星遥感影像数据服务分省碳排放监测和评估提供一种补充性参考。     

中国资本回报率:考虑碳减排成本的新核算

对资本回报率进行绿色核算既符合当前绿色发展的新理念,同时也是判断我国经济增长可持续性的重要依据。使用超越对数生产函数估算1960—2014年碳排放的影子价格;利用Hall-Jorgenson租金公式测算剔除碳减排成本的中国资本回报率的动态演变趋势。对中国资本回报率重新估算克服了因忽略碳减排成本而导致的高估,估算结果更加科学可靠。研究结果:(1)中国碳排放的影子价格由1960年的56.34元/t上升到2011年的1651.69/t,根据影子价格计算的碳减排成本占GDP总量的份额年均为31%。(2)不考虑碳减排成本和税收因素的基础资本回报率变动趋势可以划分为三个阶段。1952-1983年为第一阶段,资本回报率在波动中由高位逐步回落。1984—2010年是第二个阶段,基础资本回报率保持平稳。2011年以来是第三个阶段,这一阶段中国的资本回报率呈台阶式下降趋势,特别是2012—2014年,税后的资本回报率已经难以抵补企业投资的机会成本。(3)考虑碳减排成本将导致资本回报率平均下降约12%。其中1960—1975年资本回报率呈下降趋势。1976—2008年资本回报率基本保持稳定,资本回报率平均值为15.2%。2009年以后,资本回报率则表现出逐年下降的趋势,2014年的估算值甚至降为-1%。本文仅考虑了碳减排成本,如果再考虑诸如二氧化硫等废气排放、废水与固废排放的成本后,绿色资本回报率的估算值将更低。建议:在当前的经济形势下,应实施激励企业技术创新以及减税(尤其是生产税)政策遏制资本回报率下降的趋势。另外,需要采取分阶段递增的环境规制政策,逐步实现企业环境外部成本的内部化。     

Long-term emissions of hexabromocyclododecane as a chemical of concern in products in China

There has been ever-increasing international interest in investigating the long-term emissions of chemicals in products (CiPs) throughout their entire life cycle in the anthroposphere. Hexabromocyclododecane (HBCDD) is a contemporary example of special interest due to the recent listing of this hazardous flame retardant in the Stockholm Convention and the consequent need for parties to take appropriate measures to eliminate this compound. Here, we conducted a scenario-based dynamic substance flow analysis, coupled with interval linear programming, to forecast the future HBCDD emissions in China in order to assist with the implementation of the Stockholm Convention in this current world's predominant HBCDD manufacturing and consuming country. Our results indicate that, under a business-as-usual scenario, the cumulative HBCDD production will amount to 238,000 tonnes before its phase-out, 79% of which will be consumed in domestic market, accumulate as stocks in flame-retarded polystyrene insulation boards, and ultimately end up in demolition waste. While the production is scheduled to end in ca. 2021, emissions of HBCDD would continue until after 2100. For the entire simulation period 2000–2100, 44% of total cumulative emissions will arise from the industrial manufacture of HBCDD-associated end-products, whereas 49% will come from the end-of-life disposals of HBCDD-containing waste. The most effective end-of-life disposal option for minimizing emissions we found was, a pre-demolition screening combined with complete incineration. Our study warns of the huge challenges that China would face in its eliminating HBCDD contamination in the following decades, and provides an effective methodology for a wider range of countries to recognize and tackle their long-term emission problems of hazardous CiPs.     

Tracking chemicals in products around the world: introduction of a dynamic substance flow analysis model and application to PCBs

Dynamically tracking flows and stocks of problematic chemicals in products (CiPs) in the global anthroposphere is essential to understanding their environmental fates and risks. The complex behavior of CiPs during production, use and waste disposal makes this a challenging task. Here we introduce and describe a dynamic substance flow model, named Chemicals in Products - Comprehensive Anthropospheric Fate Estimation (CiP-CAFE), which facilitates the quantification of time-variant flows and stocks of CiPs within and between seven interconnected world regions and the generation of global scale emission estimates. We applied CiP-CAFE to polychlorinated biphenyls (PCBs), first to evaluate its ability to reproduce previously reported global-scale atmospheric emission inventories and second to illustrate its potential applications and merits. CiP-CAFE quantifies the pathways of PCBs during production, use and waste disposal stages, thereby deducing the temporal evolution of in-use and waste stocks and identifying their long-term final sinks. Time-variant estimates of PCB emissions into air, water and soil can be attributed to different processes and be fed directly into a global fate and transport model. By capturing the international movement of PCBs as technical chemicals, and in products and waste, CiP-CAFE reveals that the extent of global dispersal caused by humans is larger than that occurring in the natural environment. Sensitivity analysis indicates that the model output is most sensitive to the PCB production volume and the lifetime of PCB-containing products, suggesting that a shortening of that lifetime is key to reducing future PCB emissions.     

Application of active disassembly to extend profitable remanufacturing in small electrical and electronic products

Alternative production approaches are required because of conventional manufacturing's adverse environmental impacts. Remanufacturing returns used products to at least original performance specification from customers' perspectives and gives the resultant products warranties at least equal to that of new equivalents. Remanufacturing is relatively novel in research terms compared to conventional manufacture and recycling but often is more profitable than both. It would help manufacturers address competitive, environmental and legislative pressures by enabling them to meet pressing waste legislation while producing high-quality, lower cost products with less environmentally damaging end-of-life (EoL) and manufacturing modes. Remanufacturing is highly profitable in large, complex mechanical and electromechanical products but with conventional manufacturing and design modes not so in smaller products; particularly fast moving ones. However, effective waste management is urgently required for such products because waste electrical and electronic equipment constitutes the fastest growing EU waste stream and a large percentage of products being produced by major developing economies such as China are of this type. Active disassembly (AD) enables product non-destructive, self-disassembly at EoL and was invented to facilitate a step-change improvement in recycling. This research investigated the use of AD to extend profitable remanufacturing into small EoL electrical and electronic products.     

Time trends of polybrominated diphenyl ethers in East China Seas: Response to the booming of PBDE pollution industry in China

The East China Seas (ECSs) are the receptors of the land-based persistent organic pollutants (POPs), such as polybrominated diphenyl ethers (PBDEs) mainly from China through atmospheric deposition driven by the East Asian winter monsoon and fluvial discharge (e.g., Yangtze River and Yellow River), making the offshore sediments to be a good proxy to reconstruct history of those pollutants in China. In this work, four well-placed sediment cores were extracted from the mud areas in the ECSs, and the ²¹⁰Pb-dated cores were analyzed to yield historical concentration profiles of PBDEs in the area. The results showed that there was a persistent increase from 1970s and almost no clear sign in the decline of PBDEs until recently in China. More importantly, there was a faster increase of PBDEs from 1990s in China; while this period was just shown as gradually leveling off or even declining trends in developed countries. The persistently increasing trend of PBDEs in China since 1990s could be largely due to the booming of the manufacturing industry and unexpectedly transfer of PBDE pollution from developed countries to China. Besides, the relative high concentrations and fluxes of PBDEs in the core from coastal ECS located near a well-known electrical/electronic waste (e-waste) recycling area suggests an important contribution of PBDE emissions from recycling centers of e-waste in China. Although efforts in environmental monitoring of PBDE contamination have been substantially increased over the last decade, China is still lagging behind in terms of nationwide regulation of PBDE usage and treatment of disposal PBDE-containing products.     

三峡水库汞活化效应对鱼汞含量影响的预测

报道了三峡库区长江干流江段鱼体汞元素的含量范围为０．０４￣０．４２ｍｇ／ｋｇ（湿重）,高于长江水系鱼体汞含量水平。分析了三峡库区鱼体汞含量高的原因,指出三峡库区毗邻武陵山高汞背景区,主要受汞矿开发、高汞燃煤及城市废弃物排放的影响。利用水库汞活化指数模型,预测三峡水库蓄水后库区干流及４０条主要支流水域汞的活化效应将增强０．３５￣１．５倍,鱼体汞含量将是现在鱼汞含量的１．４￣２．５倍;并根据不同鱼种汞     

Characterization of monitor recycling in Seattle, Washington

With the rapid growth of electronic waste (e-waste), policies that aim to effectively manage this waste stream have been introduced globally in recent years. Seattle, Washington, has been on the forefront of introducing policies to divert e-waste from the landfills and maximize recycling. With the introduction of the Take-it-Back-Network, a solid recycling infrastructure has existed in the Greater Seattle region since 2003. In 2009, the E-Cycle Washington program took into effect and now allows recyclers to offer free recycling of certain e-waste to households and small entities. Although policies to divert e-waste from the landfill to reuse and recycling is effective, there is also a need to analyze the current regional recycling infrastructure’s capacity to handle changing equipment and material quantities. This study aims to characterize the Seattle regional e-waste management capacity, with a focus on retired monitors as an example of a changing e-waste technology. We investigated waste computer monitor recycling in the Greater Seattle region, which includes the counties of King, Pierce, Snohomish, and Kitsap. Interviews were conducted on 20 collectors, 1 handler, and 2 processors to collect information on their business models, computer monitor management processes, and collection/processing quantities. Using this information, we summarize the material flows of end-of-life (EOL) cathode ray tube (CRT) and liquid crystal display (LCD) monitors in the region, both from the qualitative and quantitative perspective.     

Is pork trade good for China's greenhouse gas emissions?

China produces the largest amount of pork in the world, which emits the largest amount of greenhouse gases (GHGs). This paper calculates GHG emissions from China’s hog production at the provincial level using newly published emission factors. Empirical results show that GHG emissions from China’s hog production mainly respond to the scale intensity. Capital abundance and income contribute positively to GHG emissions from hog production. Pork trade increases GHG emissions from China’s hog production with a significantly direct effect, reduces GHG emissions through indirect technique effects.     

Recovery of copper from small grain size fractions of municipal solid waste incineration bottom ash by means of density separation

Small grain size fractions of municipal solid waste incineration (MSWI) bottom ash (BA) contain elemental and chemically bonded metals in appreciable amounts, especially copper. Investigations with a centrifugal concentrator were carried out using samples, which had been treated with different impact devices. Partly the impacts of single devices were visible in outlines, but mostly the surfaces of the metals were still covered with mineral residues. To generate copper rich fractions, parameters of the separation process should ensure mass yields <2%, best between 0.5 and 1%. The density of the concentrates is then generally >3.2 g/cm³. Best results were achieved with material from a special treatment train which is adapted to grain sizes <2 mm. Reliable copper contents between 20 and 40% (single runs >50%) could be realised. However, considering the required mass yields, referred to this subset only 150–170 g copper would be recovered from 1 Mg MSWI BA. Furthermore, this copper is only in parts present in elemental form. A dependable added value of such treatment step seems to be given only, if that enables a recycling of the mineral aggregates (tailings) in parallel to avoid landfill costs.     

中国固体废物管理政策变迁逻辑与完善路径

系统梳理固体废物管理政策的变迁逻辑,研究固体废物管理政策的聚焦内容和发展趋向,有助于明晰固体废物管理政策完善路径。研究立足于已颁布的固体废物管理政策,运用统计方法分析固体废物管理政策的文本结构和内容,找出中国固体废物管理政策变迁的内在逻辑;紧密结合当前“无废城市”建设的政策需求,提出政策优化完善路径。研究发现:固体废物管理政策文本类型多元、效力级别多样,政策框架体系逐步优化完善;固体废物管理政策热点具有鲜明的时代发展烙印和动态演变特征,政策涉及的领域越来越广,政策内容更具针对性和全面性,政策执行更具指向性和可操作性;无害化、减量化、资源化,污染防治、监督管理、二次污染、回收利用、循环经济等是政策关注焦点;政府从宏观层面强化顶层设计,以政策引导规范为主,注重政策协同、技术支撑、治理水平提升等助推无害化、减量化、资源化目标实现;固体废物管理政策实施的工具手段多元化、要素支撑多样化,固体废物管理的技术支撑关注度逐步提升、管理模式与治理路径已进入适应性转型。立足现实需要,固体废物管理的市场化政策与激励机制不足,适用性技术关注度不高,综合管理水平和治理能力亟待提升。结合国外“无废城市”建设的理论研究、实践行动和政策举措,从固体废物生命周期管理政策、技术范式政策、主体协同政策、引导激励政策及法律法规政策等方面提出中国“无废城市”建设的政策完善路径方向。     

重庆市温室气体排放清单研究与核算

城市化进程所带来的大量能源消费和温室气体排放已成为制约城市健康快速发展的瓶颈因素,亟需进行定量核算和分析。开展温室气体清单研究对节能减排和低碳城市建设具有重要的理论和实践意义。本文以重庆市为案例,通过清单方法分析主要温室气体排放源和碳汇,考虑主要能源活动、工业、废弃物处置、农业、畜牧业、湿地过程和林业碳汇,核算排放总量和强度,剖析重庆温室气体排放结构和现状。结果显示:1997-2008年重庆市温室气体排放总量呈现出上升趋势,2008年比1997年增长了2.31倍,其中增长幅度较大的是一次能源消费过程、外购电力和工业非能源过程。此外,随着温室气体排放量的增加,单位产值温室气体排放量却呈现下降的趋势,反映重庆市温室气体排放控制取得了一定效果。最后根据重庆市温室气体排放结果进行分析,提出了改变能源结构和工业结构、提高能效和加强"森林重庆"建设等政策建议,为重庆市转型低碳经济发展提供参考。     

Life cycle assessment part 2: current impact assessment practice

Providing our society with goods and services contributes to a wide range of environmental impacts. Waste generation, emissions and the consumption of resources occur at many stages in a product's life cycle-from raw material extraction, energy acquisition, production and manufacturing, use, reuse, recycling, through to ultimate disposal. These all contribute to impacts such as climate change, stratospheric ozone depletion, photooxidant formation (smog), eutrophication, acidification, toxicological stress on human health and ecosystems, the depletion of resources and noise-among others. The need exists to address these product-related contributions more holistically and in an integrated manner, providing complimentary insights to those of regulatory/process-oriented methodologies. A previous article (Part 1, Rebitzer et al., 2004) outlined how to define and model a product's life cycle in current practice, as well as the methods and tools that are available for compiling the associated waste, emissions and resource consumption data into a life cycle inventory. This article highlights how practitioners and researchers from many domains have come together to provide indicators for the different impacts attributable to products in the life cycle impact assessment (LCIA) phase of life cycle assessment (LCA).