Potential carbon sequestration in China’s forests

Forests are believed to be a major sink for atmospheric carbon dioxide. There are 158.94 million hectares (Mha) of forests in China, accounting for 16.5% of its land area. These extensive forests may play a vital role in the global carbon (C) cycle as well as making a large contribution to the country’s economic and environmental well-being. Currently there is a trend towards increased development in the forests. Hence, accounting for the role and potential of the forests in the global carbon budget is very important.In this paper, we attempt to estimate the carbon emissions and sequestration by Chinese forests in 1990 and make projections for the following 60 years based on three scenarios, i.e. “baseline”, “trend” and “planning”. A computer model F-CARBON 1.0, which takes into account the different biomass density and growth rates for the forests in different age classes, the life time for biomass oxidation and decomposition, and the change in soil carbon between harvesting and reforestation, was developed by the authors and used to make the calculations and projections. Climate change is not modelled in this exercise.We calculate that forests in China annually accumulate 118.1 Mt C in growth of trees and 18.4 Mt in forest soils, and release 38.9 Mt, resulting in a net sequestration of 97.6 Mt C, corresponding to 16.8% of the national CO₂ emissions in 1990. From 1990 to 2050, soil carbon accumulation was projected to increase slightly while carbon emissions increases by 73, 77 and 84%, and net carbon sequestration increases by −21, 52 and 90% for baseline, trend and planning scenarios, respectively. Carbon sequestration by China’s forests under the planning scenario in 2000, 2010, 2030 and 2050 is approximately 20, 48, 111 and 142% higher than projected by the baseline scenario, and 8, 18, 34 and 26% higher than by the trend scenario, respectively. Over 9 Gt C is projected to accumulate in China’s forests from 1990 to 2050 under the planning scenario, and this is 73 and 23% larger than projected for the baseline and trend scenarios, respectively. During the period 2008–2012, Chinese forests are likely to have a net uptake of 667, 565 and 452 Mt C, respectively, for the planning, trend and baseline scenarios. We conclude that China’s forests have a large potential for carbon sequestration through forest development. Sensitivity analysis showed that the biggest uncertainty in the projection by the F-CARBON model came from the release coefficient of soil carbon between periods after harvesting and before reforestation.     

The social and spatial distribution of temperature-related health impacts from urban heat island reduction policies

Cities are developing innovative strategies to combat climate change but there remains little knowledge of the winners and losers from climate-adaptive land use planning and design. We examine the distribution of health benefits associated with land use policies designed to increase vegetation and surface reflectivity in three US metropolitan areas: Atlanta, GA, Philadelphia, PA, and Phoenix, AZ. Projections of population and land cover at the census tract scale were combined with climate models for the year 2050 at 4 km × 4 km resolution to produce future summer temperatures which were input into a comparative risk assessment framework for the temperature-mortality relationship. The findings suggest disparities in the effectiveness of urban heat management strategies by age, income, and race. We conclude that, to be most protective of human health, urban heat management must prioritize areas of greatest population vulnerability.     

Spatiotemporal variation of methane and other trace hydrocarbon concentrations in the Valley of Mexico

Mexico City is the world’s largest and most polluted urban center. We examine the distribution of methane and other hydrocarbons within the Valley of Mexico, using it as a model for the role developing megacities will play in the next century of geochemical cycling. Seventy-five whole air samples were analyzed with multivariate statistical techniques, including factor analysis using principal components. Methane concentrations are highly variable in space and time, due to air circulations and source distribution. Landfills and open sewage canals are major inputs. Emissions into and out from the valley are modeled to be ∼515 t per day. Per capita emission is 0.01 t per annum per person, consistent with the global average for human related anaerobic generation. Natural gas leaks are small, and likely to be higher in other developing megacities; Mexican natural gas use has been discouraged out of earthquake safety concerns. In contrast, liquefied petroleum gas loss constitutes the major emission of propane and butane estimated at a leak rate of 5–10%. Kyoto and other environmental conventions have ignored methane as a greenhouse gas. Our analysis underscores the need to consider methane and other hydrocarbons, and the urbanization process, in future emission protocols.     

Comparison between background concentrations of arsenic in urban and non-urban areas of Florida

Arsenic contamination is of great environmental concern due to its toxic effects as a carcinogen. Knowledge of arsenic background concentrations is important for land application of wastes and for making remediation decisions. The soil clean-up target level for arsenic in Florida (0.8 and 3.7 mg kg⁻¹ for residential and commercial areas, respectively) lies within the range of both background and analytical quantification limits. The objective of this study was to compare arsenic distribution in urban and non-urban areas of Florida. Approximately 440 urban and 448 non-urban Florida soil samples were compared. For urban areas, soil samples were collected from three land-use classes (residential, commercial and public land) in two cities, Gainesville and Miami. For the non-urban areas, samples were collected from relatively undisturbed non-inhabited areas. Arsenic concentrations varied greatly in Gainesville, ranging from 0.21 to approximately 660 mg kg⁻¹ with a geometric mean (GM) of 0.40 mg kg⁻¹, which were lower than Miami samples (ranging from 0.32 to 112 mg kg⁻¹; GM=2.81 mg kg⁻¹). Arsenic background concentrations in urban soils were significantly greater and showed greater variation than those from relatively undisturbed non-urban soils (GM=0.27 mg kg⁻¹) in general.     

Climate change impacts on groundwater resources in Mekong Delta under representative concentration pathways (RCPs) scenarios

Groundwater is the essential resource for various uses and have a great economic importance especially in the areas like Mekong Delta, which is the home for some 18 million people and produces a half of Vietnam’s rice and contributes substantial part of the country’s gross domestic product (GDP). Sustainable use of the groundwater resource is threatened by its uncontrolled abstraction and climate change. This study assesses groundwater resources in Mekong Delta aquifer system in the context of climate change. A set of models are used for the purpose. Groundwater recharge and its spatial variation are estimated using WETSPASS model, groundwater level and storage are estimated using MODFLOW and future climatic conditions in the area are developed by downscaling the data of five General Circulation Models (GCMs) retrieved from CMIP5 data portal. Two representative concentration pathways (RCPs) scenarios (RCP4.5 and RCP8.5) are considered for projecting future conditions of groundwater resources. Results reveal that the future average annual temperature is projected to increase by 1.5 °C and 4.9 °C by the end of the 21st century under RCP4.5 and RCP8.5 scenarios, respectively. Future rainfall is projected to increase in wet season and decrease in dry season. Groundwater recharge is projected to decline in short-, medium-, and long-terms. As a result, groundwater levels and storage are also projected to decline in future. These findings may help decision-makers and stakeholders for devising sustainable groundwater management strategies in Mekong Delta.     

Copper and zinc recycling in Australia: potential quantities and policy options

This paper presents relevant data for industry and governmental policy makers with the aim of increasing the recycling rate of end-of-life copper and zinc in Australia in a technically and economically feasible way. The methodology used to quantify and spatially distribute end-of-life flows of copper and zinc is based on existing and anticipated in-use stocks, their residence times, and their historical and anticipated future evolution. Australia currently (ca. 2000) generates about 72 Gg/year and 57 Gg/year of end-of-life copper and zinc, respectively. Some 70% of all discarded copper and 40% of all discarded zinc generated in Australia are currently being recycled. A detailed assessment shows that about 75% of all end-of-life material in Australia comes from the three states New South Wales, Victoria, and Queensland. In Australia, about 70–75% of waste copper and waste zinc is generated in urban areas. Residential applications account for about 40% (copper) and 60% (zinc) of the generated discards; commercial and industrial applications account for the remainder. By 2030, the discard flows are predicted to increase by about 105% and 155%, to 150 Gg Cu/year and 145 Gg Zn/year, providing substantially increased opportunities for recovery and re-use. Priority targets for the improvement of copper and zinc recycling in Australia are buildings under renovation, urban infrastructure, the transportation sector, and also consumer and business durables. Urban centres are particularly attractive locations for recycling facilities, especially in Perth and Adelaide.     

Nutrient flows in small-scale peri-urban vegetable farming systems in Southeast Asia—A case study in Hanoi

In many peri-urban areas of Southeast Asia, land use has been transformed from rice-based to more profitable vegetable-based systems in order to meet the increasing market demand. The major management related flows of nitrogen (N), phosphorus (P), potassium (K), copper (Cu) and zinc (Zn) were quantified over a 1-year period for intensive small-scale aquatic and terrestrial vegetable systems situated in two peri-urban areas of Hanoi City, Vietnam. The two areas have different sources of irrigation water; wastewater from Hanoi City and water from the Red River upstream of Hanoi. The first nutrient balances for this region and farming systems are presented. The main sources of individual elements were quantified and the nutrient use efficiency estimated. The environmental risks for losses and/or soil accumulation were also assessed and discussed in relation to long-term sustainability and health aspects.The primary source of nutrient input involved a combination of chemical fertilisers, manure (chicken) and irrigation water. A variable composition and availability of the latter two sources greatly influenced the relative magnitude of the final total loads for individual elements. Despite relatively good nutrient use efficiencies being demonstrated for N (46–86%) and K (66–94%), and to some extent also for P (19–46%), high inputs still resulted in substantial annual surpluses causing risks for losses to surface and ground waters. The surplus for N ranged from 85 to 882 kg ha⁻¹ year⁻¹, compared to P and K which were 109–196 and 20–306 kg ha⁻¹ year⁻¹, respectively. Those for Cu and Zn varied from 0.2 to 2.7 and from 0.6 to 7.7 kg ha⁻¹ year⁻¹, respectively, indicating high risk for soil accumulation and associated transfers through the food chain.Wastewater irrigation contributed to high inputs, and excess use of organic and chemical fertilisers represent a major threat to the soil and water environment. Management options that improve nutrient use efficiency represent an important objective that will help reduce annual surpluses. A sustainable reuse of wastewater for irrigation in peri-urban farming systems can contribute significantly to the nutrient supply (assuming low concentrations of potential toxic or hazardous substances in the water). Nutrient inputs need to be better related to the crop need, e.g. through better knowledge about the nutrient concentrations in the wastewater and improved management of the amount of irrigation water being applied.     

Effects of grazing intensity and prescribed fire on soil physical and hydrological properties and pasture yield in the savanna woodlands of Burkina Faso

In West Africa policies for prescribed early fire and livestock grazing in the savanna woodlands are rarely based on long-term experimental studies. The inherently different management characteristics and their effects on the vegetation dynamics make landscape degradation a contentious issue. The effects of grazing intensity were investigated by a comparison of non-grazed areas, lightly grazed areas, moderately grazed areas, heavily grazed areas and very heavily grazed areas that received one of two fire treatments: early burning and fire protection in a long-term 12-year study. The parameters assessed reflected changes in herbaceous plant cover, biomass as well as soil physical and hydrological properties. The main findings were by and large specific for the grazing level. This supports the argument for devolution of management responsibility to the local level where there is indigenous site-specific knowledge but at the same time insufficient management capacity.A comparison of composite soil samples taken at a depth of 0–10 cm did not differentiate significantly between treatments. This is probably because the composite soil sampling procedure hid the properties of the top first few centimeters. Grazing pressure had a tendency to reduce total above ground biomass (p = 0.081). This was related to increased biomass removal and the trampling pressure (static load) exerted by the animals. The infiltration measurements indicated that the deleterious impact of cattle trampling increased as stocking rate increased. Livestock grazing significantly (p = 0.038) lowered the infiltrability. Prescribed early fire had a tendency (p = 0.073) to reduce the soil water infiltration rate. The subplots subjected to prescribed burning had a lower steady state infiltration rate compared to unburnt areas (means of 49.2 ± 27.5 mm h⁻¹ versus 78 ± 70.5 mm h⁻¹ for burnt and unburnt subplots, respectively). A partial least squares projection to latent structures showed that 34% of the steady state infiltrability was explained by the stocking rate and soil organic matter. Also all soil characteristics were significantly connected to steady state infiltrability suggesting that they are related to the soil hydrological response to trampling.From a management perspective, adoption of a short duration grazing system should avoid high stocking rates because they may adversely affect soil infiltrability, increase susceptibility to erosion in the savannas and decrease biomass productivity.     

Overstorey tree density and understorey regrowth effects on plant composition,stand structure and floristic richness in grazed temperate woodlands in eastern Australia

As natural woodlands decline in both extent and quality worldwide, there is an increasing recognition of the biodiversity conservation value of production landscapes. In low-input, low-productivity grazing systems in Australia, the modification of natural woodlands through overstorey tree and woody regrowth removal are vegetation management options used by landholders to increase native grass production for livestock grazing; however, there is little empirical evidence to indicate at what tree densities biodiversity attributes are compromised. We examined the effects of overstorey tree density and understorey regowth on the floristic composition, stand structure and species richness of eucalypt woodlands in a grazing landscape in the Traprock region of southern Queensland, Australia. We sampled 47 sites stratified according to vegetation type (Eucalyptus crebra/Eucalyptus dealbata woodland; Eucalyptus melliodora/Eucalyptus microcarpa grassy woodland), density of mature trees (<6 trees/ha; 6–20 trees/ha; >20 trees/ha), and presence/absence of regrowth. Distinct patterns in composition were detected using indicator species analysis and non-metric multidimensional scaling, with low density areas compositionally indistinguishable, although distinct from other land management units. Within vegetation type, medium tree density woodlands were compositionally similar to high density and reference woodlands. Species richness ranged from 18 to 67 species per 500 m² across all sites. No differences in total or native species richness were detected across management units; however, some differences in exotic species richness were detected. Differences in grass cover existed between low and high density management units, yet no difference in grass cover was evident between low and medium density management units. Our results suggest that medium tree densities may provide biodiversity benefits concordant with more natural areas, yet not adversely impact on pasture production. Retaining trees in grazing landscapes provides significant landscape heterogeneity and important refuges for species that may be largely excluded from open grassland habitats. Maintaining a medium density of overstorey trees in grazed paddocks can provide both production and biodiversity benefits.     

Assessing the likelihood of catchments across England and Wales meeting ‘good ecological status’ due to sediment contributions from agricultural sources

This paper is concerned with estimating the gap between current and compliant losses of suspended sediment from the agricultural sector in England and Wales in relation to achieving ‘good ecological status’ (GES) in freshwaters by 2015. Given the emphasis on strategic information for policy support, the assessment necessitated a novel modelling methodology for predicting mean annual total suspended sediment loads (SSL) and time-weighted suspended sediment concentrations (SSC). GES was defined as the guideline annual average SSC of 25 mg l⁻¹ cited by the EC Freshwater Fish Directive. Total suspended sediment inputs to all rivers across England and Wales were estimated using a national sediment source apportionment exercise detailing the contributions from diffuse agricultural and urban sources, eroding channel banks and point sources. The total SSL estimated for each Water Framework Directive (WFD) sub-catchment (n = 7816) across England and Wales was used in conjunction with predicted flow exceedance to derive corresponding SSC time-exceedance plots. Spatial variations in modelled time-averaged SSC compared well with available monitoring data. Given the focus upon national scale, the predictive power of the SSC model (r² = 33%) was considered realistic. The modelling approach provided a means of mapping the probability of annual average SSC being less than the 25 mg l⁻¹ standard for GES due to sediment losses from all potential, as well as from agricultural sources only. In order to meet GES in non-compliant catchments, suspended sediment losses from diffuse agricultural sources will typically need to be reduced by up to 20%, but by as much as 80% in isolated cases.     

Evaluation of ecological design strategies in traditional houses in Diyarbakir,Turkey

This study focuses on the ecological design between traditional Diyarbak?r houses and their physical environment (topography and climate) and structural environment (building form, spatial organization, material, landscape and planting, and technical infrastructure). The basic principle was to identify the criteria that would use natural energy sources and provide the most benefit to the inhabitants. The influence of different seasons on thermal perception was investigated. The average temperature differences between the outdoor and indoor environment of the houses were 7 °C in winter, 6 °C in summer and ±2 °C in spring and autumn. Consequently, this paper discusses ecological design solutions used in traditional houses and their applicability to modern buildings and recognizes that architecture should coexist and maintain harmony with nature.     

Streamwater phosphorus and nitrogen across a gradient in rural–agricultural land use intensity

This paper provides an overview of the impacts of rural land use on lowland streamwater phosphorus (P) and nitrogen (N) concentrations and P loads and sources in lowland streams. Based on weekly water quality monitoring, the impacts of agriculture on streamwater P and N hydrochemistry were examined along a gradient of rural–agricultural land use, by monitoring three sets of ‘paired’ (near-adjacent) rural headwater streams, draining catchments which are representative of the major geology, soil types and rural/agricultural land use types of large areas of lowland Britain. The magnitude and timing of P and N inputs were assessed and the load apportionment model (LAM) was applied to quantify ‘continuous’ (point) source and ‘flow-dependent’ (diffuse) source contributions of P to these headwater streams. The results show that intensive arable farming had only a comparatively small impact on streamwater total phosphorus (TP loads), with highly consistent stream diffuse-source TP yields of ca. 0.5 kg-P ha^?1 year^?1 for the predominantly arable catchments with both clay and loam soils, compared with 0.4 kg-P ha^?1 year^?1 for low agricultural intensity grassland/woodland on similar soil types. In contrast, intensive livestock farming on heavy clay soils resulted in dramatically higher stream diffuse-source TP yields of 2 kg-P ha^?1 year^?1. The streamwater hydrochemistry of the livestock-dominated catchment was characterised by high concentrations of organic P, C and N fractions, associated with manure and slurry sources. Across the study sites, the impacts of human settlement were clearly identifiable with effluent inputs from septic tanks and sewage treatment works resulting in large-scale increases in soluble reactive phosphorus (SRP) loads and concentrations. At sites heavily impacted by rural settlements, SRP concentrations under baseflow conditions reached several hundred μg-P L^?1. Load apportionment modelling demonstrated significant ‘point-source’ P inputs to the streams even where there were no sewage treatment works within the upstream catchment. This indicates that, even in sparsely populated rural headwater catchments, small settlements and even isolated groups of houses are sufficient to cause significant nutrient pollution and that septic tank systems serving these rural communities are actually operating as multiple point sources, rather than a diffuse input.     

Spatial characterisation of multi-level in-use copper and zinc stocks in Australia

A methodology has been developed to characterise the in-use stocks of copper and zinc at a variety of spatial levels. The approach employs representative concentrations of copper and zinc in their main in-use reservoirs (which account for virtually all the metal put into service) together with geographic information system (GIS) data sets of the spatial locations and densities of these reservoirs. The authors have applied this methodology to Australia at four spatial levels: central city, urban region, states/territories, and country, to produce what is believed to be the first multi-level spatial characterisations of the in-use stocks of technological materials. The results are presented quantitatively and as a series of stock density maps for Inner Sydney, Sydney Metro, all Australian states/territories, and Australia itself. The total stocks in Australia are estimated at about 4.3 Tg Cu (4.3 thousand million kg) and 3.8 Tg Zn (3.8 thousand million kg), or about 240 kg Cu/capita and 205 kg Zn/capita. A statistical analysis of the data shows that the metal stock density at a given spatial level is largely determined by a small number of high-density components at the next lower level. The spatial analysis of the in-use stocks indicates that 50% of all copper and zinc stock resides in just 10% of Australia's local government areas. The largest stocks occur in large urban regions, which can contain copper and zinc densities more than a hundred times higher than rural areas. These regions are expected to be major Australian “metal mines” in the future.     

Evaluation of two soil carbon models using two Kenyan long term experimental datasets

RothC and Century are two of the most widely used soil organic matter (SOM) models. However there are few examples of specific parameterisation of these models for environmental conditions in East Africa. The aim of this study was therefore, to evaluate the ability of RothC and the Century to estimate changes in soil organic carbon (SOC) resulting from varying land use/management practices for the climate and soil conditions found in Kenya. The study used climate, soils and crop data from a long term experiment (1976–2001) carried out at The Kabete site at The Kenya National Agricultural Research Laboratories (NARL, located in a semi-humid region) and data from a 13 year experiment carried out in Machang’a (Embu District, located in a semi-arid region). The NARL experiment included various fertiliser (0, 60 and 120 kg of N and P₂O₅ ha⁻¹), farmyard manure (FYM—5 and 10 t ha⁻¹) and plant residue treatments, in a variety of combinations. The Machang’a experiment involved a fertiliser (51 kg N ha⁻¹) and a FYM (0, 5 and 10 t ha⁻¹) treatment with both monocropping and intercropping. At Kabete both models showed a fair to good fit to measured data, although Century simulations for treatments with high levels of FYM were better than those without. At the Machang’a site with monocrops, both models showed a fair to good fit to measured data for all treatments. However, the fit of both models (especially RothC) to measured data for intercropping treatments at Machang’a was much poorer. Further model development for intercrop systems is recommended. Both models can be useful tools in soil C predictions, provided time series of measured soil C and crop production data are available for validating model performance against local or regional agricultural crops.     

Small cetacean bycatch as estimated from stranding schemes: The common dolphin case in the northeast Atlantic

Death in fishing gear of non-target species (called ‘bycatch’) is a major concern for marine wildlife, and mostly worrying for long-lived species like cetaceans, considering their demographic characteristics (slow population growth rates and low fecundity). In European waters, cetaceans are highly impacted by this phenomenon. Under the Common Fishery Policy, the EC 812/2004 regulation constitutes a legal frame for bycatch monitoring on 5–10% of fishing vessels >15 m. The aim of this work was to compare parameters and bycatch estimates of common dolphins (Delphinus delphis) provided by observer programmes in France and UK national reports and those inferred from stranding data, through two approaches. Bycatch was estimated from stranding data, first by correcting effectives from drift conditions (using a drift prediction model) and then by estimating the probability of being buoyant. Observer programmes on fishing vessels allowed us to identify the specificity of the interaction between common dolphins and fishing gear, and provided low estimates of annual bycaught animals (around 550 animals year⁻¹). However, observer programmes are hindered by logistical and administrative constraints, and the sampling scheme seems to be poorly designed for the detection of marine mammal bycatches. The analyses of strandings by considering drift conditions highlighted areas with high levels of interactions between common dolphins and fisheries. Since 1997, the highest densities of bycaught dolphins at sea were located in the southern part of the continental shelf and slope of the Bay of Biscay. Bycatch numbers inferred from strandings suggested very high levels, ranging from 3650 dolphins year⁻¹ [2250–7000] to 4700 [3850–5750] dolphins year⁻¹, depending on methodological choices. The main advantage of stranding data is its large spatial scale, cutting across administrative boundaries. Diverging estimates between observer programmes and stranding interpretation can set very different management consequences: observer programmes suggest a sustainable situation for common dolphins, whereas estimates based on strandings highlight a very worrying and unsustainable process.     

‘Formiguers’, a historical system of soil fertilization (and biochar production?)

‘Formiguers’ are structures similar to charcoal-kilns that were used to burn piles of biomass with a soil cover in order to produce fertilizers for agricultural plots. Their use was widespread in Spain up to the 1960s and similar structures are still in use in India and Bhutan. Our objective was to study the effects of the ‘formiguer’ on its soil cover in terms of changes in nutrient availability. We built an experimental 0.5-m³ ‘formiguer’ with 68 kg of plant material with a 12% moisture content and 550 kg of soil with a 16% moisture content. The content of organic carbon and mineral nitrogen decreased in the soil cover as a result of burning. After aerobic incubation all samples had a similar content of mineral nitrogen. Exchangeable potassium and total and labile phosphorus increased after burning as a result of the soil cover mixing with the ashes of the biomass as the ‘formiguer’ collapsed during burning in the first two cases, while mineralization of organic compounds produced the increase in labile phosphorus. This input of nutrients for the agricultural plots occurs at a net loss of 0.4–2.5 Mg organic C ha^?1. Very small amounts of charcoal were produced and this may be the reason for their low occurrence in soils today. Burning of ‘formiguers’ required the harvest of vegetation from a considerable forest area (10–25 ha per hectare of agricultural land) and represented a significant disturbance of these systems.     

Are soils of Iowa USA currently a carbon sink or source? Simulated changes in SOC stock from 1972 to 2007

Upscaling the spatial and temporal changes in carbon (C) stocks and fluxes from sites to regions is a critical and challenging step toward improving our understanding of the dynamics of C sources and sinks over large areas. This study simulated soil organic C (SOC) dynamics within 0–100 cm depth of soils across the state of Iowa in the USA from 1972 to 2007 using the General Ensemble biogeochemical Modeling System (GEMS). The model outputs with variation coefficient were analyzed and assembled from simulation unit to the state scale based upon major land use types at annual step. Results from this study indicate that soils (within a depth of 0–100 cm) in Iowa had been a SOC source at a rate of 190 ± 380 kg C ha^?1 yr^?1. This was likely caused by the installation of a massive drainage system which led to the release of SOC from deep soil layers previously protected under poor drainage conditions. The annual crop rotation was another major force driving SOC variation and resulted in spatial variability of annual budgets in all croplands. Annual rate of change of SOC stocks in all land types depended significantly on the baseline SOC levels; soils with higher SOC levels tended to be C sources, and those with lower levels tended to be C sinks. Management practices (e.g., conservation tillage and residue management practices) slowed down the C emissions from Iowa soils, but could not reverse the general trend of net SOC loss in view of the entire state due mainly to a high level of baseline SOC stocks.     

Assessing soil chemical and physical property responses to deforestation and subsequent cultivation in smallholders farming system in Ethiopia

In Ethiopia land degradation in the forms of soil erosion and declining soil fertility are serious challenges to agricultural productivity and economic growth. Despite the general recognition of the threat from land degradation on agricultural productivity, few studies have been made to quantify the extent, rate and process of soil fertility depletion under various land use systems and management practices in the country. In this study we assessed soil chemical and physical property responses to deforestation and subsequent cultivation along a chronosequence of closely located farmlands of different ages (7, 10, 26, 34 and 53 years) since conversion from a tropical dry Afromontane natural forest in Ethiopia. These properties were compared with soil properties under an adjacent natural forest. The changes were used as indicators to evaluate the sustainability of the farm management. All the soils in the study were Mollic Andosols/Humic Haplustands. Soil bulk density (g cm⁻³) in the 0–10 and 10–20 cm soil layers increased significantly while percent pore space decreased significantly in a continuum with increasing cultivation period. Soil C and total N contents (g kg⁻¹) in the 0–10 cm soil layer declined significantly and exponentially with increasing years under cultivation. However, in the 10–20 cm soil layer both soil C and total N on the farmlands were significantly higher until after 34 years of continuous cultivation compared to the same soil layer under the natural forest. Consequently, the soil C stock (g m⁻²) of the upper 0.20 m mineral soil was not significantly lower on the farmlands until after 26 years of continuous cultivation compared to the natural forest soil. Available P and K (mg kg⁻¹) in the 0–10 cm layer were higher in the soils of the farmlands throughout the 53 years of continuous cultivation compared to the soil under the natural forest. Exchangeable Ca, CEC and base saturation in the 0–10 cm soil layer declined more or less throughout the cultivation period while in the 10–20 cm soil layer they followed the patterns of soil C of that depth. Generally, the magnitudes and rates of degradation of the soil properties following conversion and subsequent cultivation were lower than expected for a low input tropical farming system as the one investigated. Nevertheless, almost all soil quality attributes showed overall declining trends in the long perspective. This continuous decline, albeit slowly, in soil quality with increasing cultivation period indicated that the present land management is not sustainable. Therefore, improved management is imperative to sustain the soil quality and maintain long-term productivity of the farmlands.     

Metal-cored arc welding process for joining of modified 9Cr-1Mo (P91) steel

In the present work, metal-cored arc welding process was used for joining of modified 9Cr-1Mo (P91) steel. Metal-cored arc welding process is characterized by high productivity, slag-free process, defect-free weldments that can be produced with ease, and good weldability. Toughness is essential in welds of P91 steel during hydro-testing of vessels. There is a minimum required toughness of 47 J for welds that has to be met as per the EN1557:1997 specification. In the present study, welds were completed using two kinds of shielding gases, each composition being 80% Argon + 20% CO₂, and pure argon respectively. Microstructural characterization and toughness evaluation of welds were done in the as – weld, PWHT at 760 °C – 2 h and PWHT at 760 °C – 5 h conditions. The pure argon shielded welds (‘A2’ and ‘B2’) have higher toughness than 80% argon + 20% CO₂ shielded welds (‘A1’ and ‘B1’). Pure argon shielded welds show less microinclusion content with low volume fraction of δ-ferrite (<2%) phase. Themo-calc windows (TCW) was used for the prediction of equilibrium critical transformation points for the composition of the welds studied. With increase in post-weld heat treatment (PWHT) duration from 2 h to 5 h, there was increase in toughness of welds above 47 J. Using metal-cored arc welding process, it was possible to achieve the required toughness of more than 47 J after PWHT at 760 °C – 2 h in P91 steel welds.     

On the relationship between PM2.5 concentrations and regional-scale primary PM emissions for the United Kingdom: an issue of subsidiarity

A site-specific particulate matter PM source apportionment model has been used to estimate the contributions from local primary PM emissions, regional primary PM emissions and the regional background to PM_2.5 concentrations at 102 monitoring site locations and to the centres of 1 km × 1 km grid squares across the United Kingdom. The local primary PM contributions have then been compared with Europe-wide urban PM_2.5 increments estimated at 50 km × 50 km in European-scale integrated assessment models. It is concluded that Europe-wide PM increments used in policy analyses grossly underestimate urban PM concentrations obtained from the site-specific PM source apportionment model for the United Kingdom. Europe-wide urban PM_2.5 increments estimated at 5 km × 5 km scale are significantly improved, particularly for London, but underestimate those for smaller towns and cities by factors of 2–3. These underestimations have important air quality policy ramifications. Although environmental policies may well be best formulated at the European scale, the underpinning air quality modelling may be best carried out at the local scale.