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1.
The revised New Source Performance Standards (NSPS) for the utility industry mandates reduced particulate matter and sulfur dioxide emissions from new utility boilers. A wet scrubber system can be an advantage in controlling both of these emissions. Existing wet scrubber systems may meet the new standards with significant increase in power consumption. A careful design of the entire scrubber system, based on the experience gained at the existing installations, is necessary to ensure cost effectiveness. The experience with existing wet scrubber systems used on coal-fired utility boilers is reviewed and their performance is correlated with power consumptions. Based on a correlation of scrubber pressure drop against outlet concentration, conventional scrubber systems would be able to meet the revised NSPS for particulate matter with a theoretical scrubber pressure drop of 43±5 cm H2O. Overall system pressure drop, however, could easily run as high as 76 cm H2O. Novel scrubber systems such as the electrostatically augmented scrubber may provide the necessary collection performance at lower pressure drops. The performance of the various scrubber components such as mist eliminators and reheaters is reviewed. Operating problems are also discussed.  相似文献   

2.
Alternative fuels for diesel engine applications are gaining more prominence as they have numerous advantages compared to fossil fuels. They are renewable, biodegradable; provide food and energy security and foreign exchange savings. They address environmental concerns and socio-economic issues as well. Gaseous fuels such as compressed natural gas and hydrogenated compressed natural gas (HCNG) appear more attractive fuels for diesel engine applications operated in dual-fuel mode. Such dual fuel engines can replace considerable amount of liquid-injected pilot fuels by gaseous fuels besides being friendly to the environment. A small quantity of liquid fuel injected towards the end of the compression stroke initiates combustion of the inducted gas in the dual-fuel engines. The main advantage of dual-fuel engines is their lower nitrogen oxides (NOx) and particulate emissions. Hence renewable fuels such as biodiesels and gaseous fuels can be used predominantly for transportation and power generation applications. Gaseous fuels are clean burning and are more economical as well. A suitable carburettor was designed to supply a stoichiometric mixture of air and HCNG to the modified diesel engine operated in dual-fuel mode. The biodiesel used in this study is derived from Honge oil called the Honge oil methyl ester (HOME). This paper presents the performance, combustion and exhaust emission characteristics of a single cylinder, four stroke, direct injection, stationary diesel engine operated on HOME and HCNG in dual-fuel mode. From the results it is observed that HOME–HCNG combination gave lower brake thermal efficiency (BTE) and improved emission levels when compared with diesel/HOME in single fuel operation. Lower smoke and particulate matter were obtained with dual-fuel operation. Comparative measures of BTE, peak pressure, pressure–crank angle variation, smoke opacity, hydrocarbon, carbon monoxide and NOx emissions have been made and analysed.  相似文献   

3.
To appreciate the sustainabilty of these plantations of Eucalyptus, it is necessary to make a comparative study of energy, carbon, mineral and water balances of two ecosystems, i.e. the original savannah ecosystem, and the man-made ecosystem the Eucalyptus plantations that have succeeded it. The aim of this work is to study the water balance of the two ecosystems and more particularly their actual evapo-transpiration. Throughfall, net interception during the rainy seasons (1996–99) were 867. mm and 112 mm for the Eucalyptus plantation and 878 mm and 101 mm for the savannah, respectively. The mean total annual actual evapo-transpiration respectively 1127. mm for a plantation and 821 mm for a savannah. During the year transpiration/potential evapotranspiration ratio (T/E p ) is related to the soil-water depletion: The T/E p ratio of 0.79 was not reduced from field capacity until 65% of R FC , and then it decreased quickly to near zero at wilting point. The drainage out of rooting depths of savannah during the rainy season was of 827. mm, a total over 3 years; while the drainage out of rooting depths of Eucalyptus plantation was of 470 mm, a difference in drainage between two ecosystems of 357. mm a total over these three years. The Eucalyptus plantation is manmade ecosystem which takes up and transpires every day throughout the year and uses all available water. The succession of several rain-deficient years will reduce the wood production of the plantation but, knowing that between 1949 and 1998 four successive rain-deficient years have only occured once while the length of rotation is seven years; this dry episode does not compromise the survival of the plantation, although it reduces its wood production. The savannah has a cycle of vegetation such that at the end of the dry season the water remaining in the rooting depths of savannah is sufficient for three successive rain-deficient years to have no impact on its production.  相似文献   

4.
The present study aims to assess the effect of redox conditions existing within the tailings dump on the stability of phosphogypsum (e.g. sulphate reduction) and uranium(VI). Phosphogypsum sampling and in-situ measurements were carried out at a coastal tailings dump in Vasiliko Cyprus, pH, EH and solubility experiments were performed in simulated laboratory systems and thermodynamic calculations using MINTEQA2. Generally, in the open tailings dump oxidizing conditions predominate stabilizing sulphur and uranium in their hexavalent oxidation states. On the other hand, after the application of a soil/vegetative cover and in the presence of natural organic matter, anoxic conditions prevail (EH < −70 mV) resulting in S(VI) and U(VI) reduction to S(−II) and U(IV), respectively. Although, the sulphide anion can form very insoluble compounds with heavy metal ions (e.g. Cd(II), Pb(II) etc.) and U(IV) oxide has very low solubility, partial reduction of sulphate to sulphide within gypsum may affect the stability of phosphogypsum resulting in enhanced erosion of the material by rain- and seawater and washing out of contaminants in particulate/colloidal form.  相似文献   

5.
This paper presents a feasibility study of Marotti oil biodiesel as an alternative to diesel fuel for a compression ignition engine. Marotti oil is inedible and available mainly in the state of Kerala. The oil is extracted from Marotti seeds. However, the high viscosity, poor volatility and cold flow characteristics of many vegetable oils in general, and Marotti oil in particular, can cause problems such as injector coking, severe engine deposits, filter gumming, piston ring sticking and thickening of lubrication from long-term use in diesel engines. These problems can be eliminated or minimised by transesterification of the vegetable oils to form monoesters. Although transesterification improves the fuel properties of vegetable oil, the viscosity and volatility of biodiesel are still worse than for petroleum diesel fuel. Subsequently, Marotti oil was converted into its methyl ester by the process of transesterification. The methyl ester was blended with diesel in various proportions to obtain different blends of Marotti oil with diesel. The performance, emission and combustion characteristics of Marotti methyl ester and its blends with diesel were studied and the results were compared with the base line data generated for diesel operation. Experiments were conducted using an injection timing of 23° before top dead centre (BTDC) and an injection pressure of 205 bar at various power outputs and at a constant rated speed of 1500 rpm. The engine manufacturer specifies an injection timing of 23° BTDC and injection pressure of 205 bar for the standard diesel fuel operation. The heat release rates, maximum rate of pressure rise, ignition delay and combustion duration for these fuel combinations were obtained.

From the results obtained, it was observed that the biodiesel produced from Marotti oil and its blends with diesel have slightly reduced brake thermal efficiency and increased smoke, hydrocarbon, carbon monoxide and reduced NO x emissions compared with diesel-only operation. The investigation showed that the B20 biodiesel blend of Marotti oil with diesel produced better performance in terms of higher brake thermal efficiency, lower specific fuel consumption and comparatively lower emissions compared to the other blend ratios considered.  相似文献   

6.
Leaf gas exchange and chlorophyll fluorescence of Glycyrrhiza uralensis Fisch at two water supplies (equivalent to 240 mm for present precipitation and to 120 mm for future decreasing precipitation) were compared. There was a midday depression in net photosynthetic rate (P N) for either treatment, but stomatal limitation was dominant for present precipitation treatment and non-stomatal limitation for the drought treatment. Compared with present precipitation treatment, P N, stomatal conductance (g s) and transpiration rate (E) were always lower at drought stress, but stomatal limitation value (L s) and water use efficiency (WUE) were higher in the morning. The decrease in carboxylation efficiency (CE), apparent quantum yield (AQY), light-saturated photosynthetic rate and maximal photochemical efficiency of photosystem 2 (PS 2) (F v/F m) suggested that rubisco activity reduced and PS 2 partially inactivated during the day under drought. However, part of this inactivation of PS 2 might be alleviated due to increased thermal dissipation under drought.  相似文献   

7.
Several laboratory techniques are reviewed in this paper, which yield reliable data on carbonate equilibria. In particular, it is emphasized that pco2 variation is necessary in order to potentiometrically distinguish between hydrogen carbonato and caronato complexes. The essential features of reliable solubility measurements of carbonate phases are summarized. A neglected autoclave technque is described which has been successfully applied for the synthesis of pure, crystalline, MnCO3, FeCO3 and CoCO3. Details of a continuously operating solubility cell for experiments at 5–95°C are also given.Solubilty constants for different ionic media are related by the respective equilibrium vapor pressure of H2O and the standard potentials of the respective metal electrodes. It is shown that a thermodynamic cycle can be exploited for an indirect determination of the Fe2+/Fe standard potential. The application of solubility data is discussed using the pco2 control in the recent geologic past an an example.  相似文献   

8.
Stringent environmental policies and the ever increasing demand for energy have triggered interest in novel combustion technologies that use alternative fuels as energy sources. Of these, pilot-ignited compressed natural gas (CNG) engines that employ small biodiesel pilot to ignite a premixed natural gas–air mixture have received considerable attention. This paper discusses the effect of mixing chamber venturi, injection timing, compression ratio and exhaust gas recirculation (EGR) on the performance of dual-fuel engine operated on biodiesel derived from honge oil and is called honge oil methyl ester (HOME) and CNG. The proposed study mainly focuses on the manifold induction of CNG along with HOME injection. However, CNG can also be injected using port or direct gas injector (Lakshmanan and Nagarajan 2010, Energy 35, pp. 3172–3178). The future study will involve these methods of CNG injection. From this study, it is concluded that an advanced injection timing and an increased compression ratio resulted in increased brake thermal efficiency and reduced smoke, hydrocarbons and carbon monoxide emissions. However, nitrogen oxides (NO x ) emission increased significantly. The increased NO x emission was effectively reduced with EGR method. A mixing chamber venturi of 3 mm size, injection timing of 27° before top dead centre (BTDC), compression ratio of 17.5 and 10% EGR were found to be optimum for the modified compression ignition engine that was operated on CNG–HOME dual-fuel mode.  相似文献   

9.
Varioys analytical methodologies for the monitoring of formaldehyde (CH2O) concentrations in domestic environments have been developed and evaluated. A modified CEA Instruments, Inc., analyzer has near-real-time CH3O-specific analysis capability with an 0.01 mg/m3 detection limit. A solid sorbent, 13X molecular sieve has been utilized in a pumped collection unit with a demonstrated 0.03–12.5 mg/m3 linear dynamic range using sampling periods of ≤ 15 min. The development of screening-type techniques has included (1) a semipermeable-membrane passive sampler for measurements of average CH2O concentrations over 8–24-h periods, and (2) a visual colorimetric analysis method for semiquantitative CH2O determinations using solid chemical reagents. A preliminary field evaluation has been completed. The results show excellent agreement between the new CH2O monitoring methods and a reference sampling and analysis technique. A generation apparatus for the production of CH2O vapor is also reported with a demonstrated linear dynamic range between 0.003 and 12.5 mg/m3.  相似文献   

10.
This paper reports a performance analysis for a new sustainable engineering application to beneficially reuse an abundant agricultural waste, coconut coir (Cocos nucifera), in evaporative cooling pads. Two small coconut coir pads of different configurations were fabricated and tested using a laboratory‐scale experimental arrangement. The air supply velocity was controlled and varied between 1.88 and 2.79 m s?1. Heat and mass transfer coefficients, evaporative cooling efficiency and pressure drop across the two types of coconut coir pad were analysed and compared with those of a commercial rigid media paper pad. Results show that the cooling efficiency of the manufactured coconut coir evaporative cooling pad was fairly good (about 50%) and close to that of the commercial paper pad (about 47%). The average pressure drop across the two coconut coir pads was 1.5 and 5.1 Pa respectively. Correlations for heat and mass transfer coefficients expressed using Nusselt and Sherwood numbers are also reported. In addition, the cooling potential of the coconut coir pads was analysed using the average climatic conditions of the central region in Thailand throughout the year. The analysis showed that the air temperature leaving the coconut coir pad varied from 23 to 28°C. Commercial development appears feasible given the coconut coir pad's good performance, lower cost and its availability throughout the country.  相似文献   

11.
In the periods of summer and autumn bloom of the Stephanodiscus hantzschii Crun. in recreational water bodies, studies on the vertical distribution of chlorophyll a, its contents per unit biomass, efficiency in using photosynthetically active radiation (EPhAR), and assimilative activity of microalgae were performed. The results confirmed the existence of two ecophysiological forms of St. hantzschii and provided evidence that both forms are typically autotrophic and can efficiently use low-intensity PhAR for photosynthesis.  相似文献   

12.
This study aims at evaluation of the effect of injection timing on the combustion, performance and emissions of a small power diesel engine, commonly used for agriculture purpose, running on pure bio-diesel, prepared from Karanj (Pongamia pinnata) vegetable oil. The effect of varying injection timing was evaluated in terms of thermal efficiency, specific fuel consumption, power and mean effective pressure, exhaust temperature, cylinder pressure, rate of pressure rise and the heat release rate. Furthermore, the effects on emissions of unburnt hydrocarbons, oxides of nitrogen, carbon monoxide and carbon dioxide and smoke were also studied. It was found that retarding the injection timing by 3° enhances the thermal efficiency by about 8.2% with reduction in emission of oxides of nitrogen.  相似文献   

13.
The aim of this work is to study the actual evapotranspiration and surface resistance of the savannah using the Bowen-ratio method for two contrasted periods, dry and rainy season. The reliability of this method has been assessed by comparison with the Monteith equation and the soil-water balance method in a 90% Loudetia arundinacea dominated savannah (Pointe Noire, Congo). Our results relate to the period from 18 September to 11 October 1998 (24 days): (a) from 18 to 29 September (“dry season”), the soil-water content was less than 70% of the soil-water content at field capacity (63–70% of R FC; large soil-water stress; T/E P from 0.2 to 0.4); (b) from 30 September to 11 October (“rainy season”) soil-water content close to 90–92% of RFC; no soil-water stress; T/E P from 0.73 to 0.77). The mean daily surface resistance reulting from the Bowen-ratio method was 317 s m?1, 355 s m?1 during the “dry season” and 279 s m?1 during the “rainy season”. The total actual evapotranspiration (E a) resulting from the Bowen-ratio method, Penman-Monteith equation and soil-water balance method were, respectively of 58.6–57.8 and 56.2 mm, with the mean daily Ea of 2.4–2.4 and 2.3 mm day?1 (2.4–1.5 and 2.2 mm day?1 in “dry season” and of 2.5–3.4 and 2.5 mm day?1 in “rainy season”). The Bowen-ratio method was used for the assessment of the actual evapotranspiration from the temperature and specific humidity differences, net radiation and the soil heat flux measurement: its advantages are a rapidity of installation, a temporal resolution of measurement in less than one hour and a good integration of the heterogeneousness of the savannah’s latent flux of vaporization. This method is adapted to eco-physiological studies in tropical conditions with reduced teams.  相似文献   

14.
ABSTRACT

Renewable and sustainable fuels for diesel engine applications provide energy protection, overseas exchange saving and address atmospheric and socio-economic concerns. This study presents the investigational work carried out on a single cylinder, four-stroke, direct injection diesel engine operated in dual fuel (DF) mode using renewable and sustainable fuels. In the first phase, a Y-shaped mixing chamber or venture was developed with varied angle facility for gas entry at 30°, 45° and 60°, respectively, to enable homogeneous air and gas mixing. Further effect of different gas and air mixture entry on the DF engine performance was studied. In the next phase of the work, hydrogen flow rate influence on the combustion and emission characteristics of a compression ignition (CI) engine operated in DF mode using diesel, neem oil methyl ester (NeOME) and producer gas has been investigated. During experimentation, hydrogen was mixed in different proportions varied from 3 to 12 l/min (lpm) in step of 3 lpm along with air-producer gas and the mixtures were directly inducted into engine cylinder during suction stroke. Experimental investigation showed that 45° Y-shaped mixing chamber resulted in improved performance with acceptable emission levels. Further, it is observed that investigation showed that at maximum operating conditions and hydrogen flow rate of 9 lpm, Diesel–producer gas and NeOME–producer gas combination showed increased thermal efficiency by 13.2% and 3.8%, respectively, compared to the DF operation without hydrogen addition. Further, it is noticed that hydrogen-enriched producer gas lowers the power derating by 5–10% and increases nitric oxide (NOx) emissions. However, increased hydrogen addition beyond the 12 lpm leads to sever knocking.

Abbreviations: NeOME: Neem oil methyl ester; BTE: brake thermal efficiency; CI: compression ignition; ITE: indicated thermal efficiency; PG: producer gas; CA: crank angle; K: Kelvin; BP: brake power; IP: indicated power; H2: hydrogen; HC: unburnt hydrocarbon; CO: carbon dioxide; CO2: carbon dioxide; NOx: nitric oxide; HRR: heat release rate; %: percentage; PPM: parts per million; CMFIS: conventional mechanical fuel injection system.  相似文献   

15.
The diminishing resources and continuously increasing cost of petroleum in association with their alarming pollution levels from diesel engines have caused an interest in finding alternative fuels to diesel which are renewable and sustainable. Emission control and engine efficiency are two most important parameters in current engine design. The impending introduction of emission standards such as Euro IV and Euro V is forcing the research towards developing new technologies for combating engine emissions. The classification of Euro IV and V norms is applicable to heavy-duty engines in Europe, where as Euro 5 is applicable to light-duty engines. This paper presents the effects of exhaust gas recirculation (EGR), swirl augmentation techniques and ethanol addition on the combustion of Honge oil methyl ester (HOME) and its blends with ethanol in a diesel engine. From the experimental work conducted, it is found that the combustion of HOME plus up to 15% ethanol blend in a diesel engine operated with optimised parameters of injection timing 23° Before Top Dead Centre and compression ratio 17.5 results in acceptable combustion emissions and improved brake thermal efficiency (BTE). The addition of ethanol increased BTE with reduced hydrocarbons (HCs), CO and smoke emissions. However, NO x emissions increased dramatically. Use of appropriate EGR reduces NO x to acceptable levels. The implementation of swirl augmentation techniques further resulted in increased BTE and considerable reduction in tail pipe emissions such as smoke, HCs, CO and NO x . The effect of swirl by providing grooves on the piston was taken into consideration to find the overall biodiesel engine performance, which gives scope for further studies.  相似文献   

16.
Alternative and renewable fuels have numerous advantages compared with fossil fuels as they are renewable and biodegradable, besides providing food and energy security and foreign exchange savings and addressing environmental and socio-economic issues. Therefore, these renewable fuels can be used predominantly in compression ignition (CI) engines for transportation purposes and power generation applications. Today, the use of biomass-derived producer gas is more relevant for addressing rural power generation and is also a promising technique for controlling both NOx and soot emission levels. Although a producer gas–biodiesel-operated dual-fuel diesel engine exhibits lower performance, they are independent from the use of fossil fuels. The lower performance of the engine could be due to the slow-burning and lower calorific value of producer gas. For this purpose, exhaustive experiments on the use of Honge oil methyl ester (HOME)–producer gas in a dual-fuel CI engine were carried out for the improvement of its fuel efficiency. This paper presents the effect of the compression ratio (CR) on the performance, combustion and exhaust emission characteristics of a single-cylinder, four-stroke, direct injection stationary diesel engine operated using HOME and producer gas in a dual-fuel mode. The results indicated that the HOME–producer gas combination exhibited lower brake thermal efficiency (BTE) with comparable emission levels with the diesel–producer gas combination at different CRs. Comparative measures of BTE, peak pressure, pressure–crank angle variation, heat release rate, smoke opacity, and hydrocarbon (HC), carbon monoxide (CO) and nitric oxide (NOx) emission levels are presented and analysed.  相似文献   

17.
The objective of this paper is to analyse the impacts of climate change on a pine forest stand in Central Siberia (Zotino) to assess benefits and risks for such forests in the future. We use the regional statistical climate model STARS to develop a set of climate change scenarios assuming a temperature increase by mid-century of 1, 2, 3 and 4 K. The process-based forest growth model 4C is applied to a 200-year-old pine forest to analyse impacts on carbon and water balance as well as the risk of fire under these climate change scenarios. The climate scenarios indicate precipitation increases mainly during winter and decreases during summer with increasing temperature trend. They cause rising forest productivity up to about 20 % in spite of increasing respiration losses. At the same time, the water-use efficiency increases slightly from 2.0 g C l?1 H2O under current climate to 2.1 g C l?1 H2O under 4 K scenario indicating that higher water losses from increasing evapotranspiration do not appear to lead to water limitations for the productivity at this site. The simulated actual evaporation increases by up to 32 %, but the climatic water balance decreases by up to 20 % with increasing temperature trend. In contrast, the risk of fire indicated by the Nesterov index clearly increases. Our analysis confirms increasing productivity of the boreal pine stand but also highlights increasing drought stress and risks from abiotic disturbances which could cancel out productivity gains.  相似文献   

18.
This work evaluated the sludge potential of the Wastewater Treatment Plant (ETA) in the city of Brasília to be used as a fuel by gasification. It is known that ETA sludge is a significant environmental liability, since current legislation restricts its final disposal. For this, the chemical characterisation of ETA sludge was performed by immediate and elemental analysis. No traces of heavy metals were observed, and the moisture (ω) and ash contents were 31.17 and 51.77%, respectively, different from those already reported in the literature because the composition depends on the water treatment technology employed. The gasification process was numerically simulated; once dry, it constitutes a residue with an energy content (HHV) of 22.4498 MJ kg?1, comparable with other types of biomass currently used for large-scale energy generation by thermochemical processes (e.g. agricultural residues, wood and sugar cane bagasse). For the numerical simulation with an equivalence ratio (Φ) near 3, higher concentrations of CO and H2 can only be achieved with ω lower than 15%. The results showed that gasification can be an attractive option for the disposal and use of a renewable waste resource, such as ETA sludge, in an environmentally safe way, and it is allowed by local legislation.  相似文献   

19.
The electrostatic granular filter developed by Combustion Power Company combines a moving-bed filter with an electrostatic grid for high-efficiency collection of particulate. The coulomb charge occurring naturally on particulate from combustion or other processes in which tribocharging occurs is sufficient such that imposition of an electric field substantially enhances mechanical collection in the packed filter. A mathematical model is presented which accounts for the major parameters affecting electrostatic performance. Experimental data developed in an industrial unit retrofitted with electrostatic equipment and a pilot-scale filter demonstrates dramatic improvement in opacity and outlet loading; the industrial unit achieved 99% collection efficiency with less that 4 Iwd (1kPa) pressure drop. Data from the pilot-scale filter has shown that collection of micron-size particulate is especially enhanced with the electric field and has confirmed the 99% overall collection capability demonstrated in the industrial unit. The design of a 420,000 acfm (1200 m3/min) system being installed at Weyerhaeuser Company's Longview, Washington plant is also discussed.  相似文献   

20.
ABSTRACT

The essay uses the term “charismatic life” to describe representations of nature that emphasize vitality and vibrancy. Beginning with how life is reified when nature becomes spectacle, the essay discusses how a fetishism of life was part of the early structuring logic of biodiversity science in a way that undermined crafting other ethical and political responses to loss. When biodiversity emerged as a popular science concept in the 1980s, it was described as a scientific replacement for the sentimental attachment to charismatic megafauna that previously structured conservation priorities. But this essay argues, in a historicized reading of conservation biologist E.O. Wilson’s popular science memoir Biophilia [Wilson, E. O. (1984). Biophilia. Cambridge: Harvard University Press] alongside the seminal edited collection Biodiversity [Wilson, E. O. (Ed.). (1988). Biodiversity. Washington, DC: National Academy of Sciences], that Wilson’s sentimental biopolitics renders the world as if a collection of living souvenirs – tokens by which to remember forms of life that will have been lost.  相似文献   

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