Prediction of the upper tail of concentration distributions of a continuous point source release in urban environments

The peak values observed in a measured concentration time series of a dispersing gaseous pollutant released continuously from a point source in urban environments, and the hazard level associated with them, demonstrate the necessity of predicting the upper tail of concentration distributions. For the prediction of concentration distributions statistical models are preferably employed which provide information about the probability of occurrence. In this paper a concentration database pertaining to a field experiment is used for the selection of the statistical distribution. The inverses of the gamma cumulative distribution function (cdf) for 75th–99th percentiles of concentration are found to be more consistent with the experimental data than those of the log-normal distribution. The experimental values have been derived from measured high frequency time series by sorting first the concentrations and then finding the concentration which corresponds to each probability. Then the concentration mean and variance that are predicted with Computational Fluid Dynamics-Reynolds Averaged Navier–Stokes (RANS) methodology are used to construct the gamma distribution. The proposed model (“RANS-gamma”) is included in the framework of a computational code (ADREA-HF) suitable for simulating the dispersion of airborne pollutants over complex geometries. The methodology is validated by comparing the inverses of the model cdfs with the observed ones from two wind tunnel experiments. The evaluation is performed in the form of validation metrics such as the fractional bias, the normalized mean square error and the factor-of-two percentage. From the above comparisons it is concluded that the overall model performance for the present cases is satisfactory.     

Effect of electrokinetic transport on the vulnerability of PAH-degrading bacteria in a model aquifer

There has been increasing interest in employing electro-bioremediation, a hybrid technology of bioremediation and electrokinetics, to overcome the low bioavailability of hydrophobic organic contaminants (HOC) by homogenizing sorption-retarded HOC and immobilised microorganisms. Present electro-remediation approaches mainly aim at macroscale pollutant extraction and tend to neglect possible impacts of direct current (DC) on the physiology of microorganisms. The effect of weak electric fields (X = 1 V cm⁻¹) on the fitness of electrokinetically dispersed fluorene-degrading Sphingomonas sp. LB126 in bench-scale model aquifers was investigated by flow cytometry using propidium iodide (PI) as an indicator that distinguishes between PI-permeable (cells with porous membranes, i.e. dead or vulnerable) and PI-impermeable bacteria. After 15.5 h of DC treatment 56% of all cells recovered were dispersed at the centimetre scale relative to 29% in the absence of DC. There was no overall negative effect of the 15.5-h DC treatment on cell vulnerability, as 7.0% of the DC-treated bacteria exhibited PI-staining compared to 6.5% of the control population. Minor differences were observed in the subpopulation that had been mobilised by electroosmosis with an approximately twofold increase in the percentage of PI-stained cells relative to the control. Enhanced PI staining did not correlate with reduced culturability of the cells on rich-medium agar plates. Relative to the control, DC-treated cells mobilised by electroosmosis were threefold more culturable, confirming earlier data that that PI-cell membrane permeability does not always indicate reduced viability of oligotrophic environmental bacteria. Our findings suggest that electrokinetics is a valuable mechanism to transport viable and culturable polycyclic aromatic hydrocarbon (PAH)-degrading bacteria in soil or sediments.     

A note on a non-stationary point source spatial model

A point source, non-stationary covariance structure model is proposed, having only one additional parameter over a standard, stationary covariance structure, spatial model. Additionally, the proposed model is demonstrated to fit better than the three extra parameter, point source, non-stationary spatial model proposed by Ecker and De Oliveira (Commun Stat Theory Methods 37:2066–2078, 2008). The proposed model is fit from a Bayesian perspective and illustrated using a house sales dataset from Cedar Falls, Iowa.     

Scalar transport from point sources in the flow around a finite-height cylinder

This paper presents a large eddy simulation of mass transfer in the flow around a surface-mounted finite-height circular cylinder. The study was carried out for a cylinder with height-to-diameter ratio of 2.5 and a Reynolds number based on the cylinder diameter of 44000. The approach flow boundary layer had a thickness of about 10% of the cylinder height. A tracer was released at various levels upstream of the cylinder. The effect of the release position in the subsequent spreading and dilution of the plumes is analyzed. It is found that a tracer released at the top or at mid-height is entrained into the recirculation zone behind the cylinder, and therefore presents similar plume evolution in the far wake in both cases. If the tracer is released at around three-quarters of the height of the cylinder, it is not significantly entrained by the main recirculation region, leading to smaller rates of spreading of the plume. Finally, if the tracer is released near the floor, the plume is entrained by the horseshoe vortex that wraps around the cylinder, leading to a large lateral spreading of the plume, remaining always near the floor.     

The source and transport of bioaerosols in the air: A review

• Emission of microbe from local environments is a main source of bioaerosols. • Regional transport is another important source of the bioaerosols. • There are many factors affecting the diffusion and transport of bioaerosols. • Source identification method uncovers the contribution of sources of bioaerosols. Recent pandemic outbreak of the corona-virus disease 2019 (COVID-19) has raised widespread concerns about the importance of the bioaerosols. They are atmospheric aerosol particles of biological origins, mainly including bacteria, fungi, viruses, pollen, and cell debris. Bioaerosols can exert a substantial impact on ecosystems, climate change, air quality, and public health. Here, we review several relevant topics on bioaerosols, including sampling and detection techniques, characterization, effects on health and air quality, and control methods. However, very few studies have focused on the source apportionment and transport of bioaerosols. The knowledge of the sources and transport pathways of bioaerosols is essential for a comprehensive understanding of the role microorganisms play in the atmosphere and control the spread of epidemic diseases associated with them. Therefore, this review comprehensively summarizes the up to date progress on the source characteristics, source identification, and diffusion and transport process of bioaerosols. We intercompare three types of diffusion and transport models, with a special emphasis on a widely used mathematical model. This review also highlights the main factors affecting the source emission and transport process, such as biogeographic regions, land-use types, and environmental factors. Finally, this review outlines future perspectives on bioaerosols.     

Reduction of hexavalent chromium with scrap iron in a fixed bed reactor

The reduction of hexavalent chromium by scrap iron was investigated in continuous long-term fixed bed system. The effects of pH, empty bed contact time (EBCT), and initial Cr(VI) concentration on Cr(VI) reduction were studied. The results showed that the pH, EBCT, and initial Cr(VI) concentration significantly affected the reduction capacity of scrap iron. The reduction capacity of scrap iron were 4.56, 1.51, and 0.57 mg Cr(VI)·g^-1 Fe⁰ at pH 3, 5, and 7 (initial Cr(VI) concentration 4 mg·L^-1, EBCT 2 min, and temperature 25°C), 0.51, 1.51, and 2.85 mg Cr(VI)·g^-1 Fe⁰ at EBCTs of 0.5, 2.0, and 6.0 min (initial Cr(VI) concentration 4 mg·L^-1, pH 5, and temperature 25°C), and 2.99, 1.51, and 1.01 mg Cr(VI)·g^-1 Fe⁰ at influent concentrations of 1, 4, and 8 mg·L^-1 (EBCT 2 min, pH 5, and temperature 25°C), respectively. Fe(total) concentration in the column effluent continuously decreased in time, due to a decrease in time of the iron corrosion rate. The fixed bed reactor can be readily used for the treatment of drinking water containing low amounts of Cr(VI) ions, although the hardness and humic acid in water may shorten the lifetime of the reactor, the reduction capacity of scrap iron still achieved 1.98 mg Cr⁶⁺·g^-1 Fe. Scanning electron microscope equipped with energy dispersion spectrometer and X-ray diffraction were conducted to examine the surface species of the scrap iron before and after its use. In addition to iron oxides and hydroxide species, iron-chromium complex was also observed on the reacted scrap iron.     

不同流速下零价铁调控污水管道节点硫转化的影响

研究了不同污水流速下,各粒径零价铁(ZVI)对实际污水中硫化物(S^2-)和硫化氢(H₂S)浓度以及pH值的影响,并考察了不同污水流速下各粒径ZVI的损失量和消耗量.结果表明,当污水流速为0.2 m·s^-1和0.6 m·s^-1时,ZVI粒径越小,S^2-和H₂S的去除效果越好,其中R3-ZVI对S^2-和H₂S的控制效果最好,但其损失量和消耗量最高且pH偏高(分别为8.5和8.3),而R2-ZVI对S^2-和H₂S的控制效果与R3-ZVI接近且pH适中(分别为8.1和8.0),当污水流速提高至1.2 m·s^-1时,R2-ZVI对S^2-和H₂S的控制效果最好且pH值适中(7.9),而R3-ZVI的损失量和消耗量因受水流速度影响而显著增加,从而导致其对S^2-和H₂S的控制效...     

Experimental and numerical investigations of the effect of imbricated gravel structures on flow and solute transport in a highly heterogeneous alluvial-proluvial fan aquifer,SW China

Environmental Fluid Mechanics - An alluvial-proluvial fan (APF) has heterogeneous characteristics, which result in the development of imbricated gravel channel networks formed by flow erosion. In...     

Study on the concentration distribution in a trapezoidal open-channel flow with a side discharge

The number and distribution of pollutant concentration in a trapezoidal open channel flow with a side discharge is calculated and effects of the bank gradient are investigated in this paper. A sigma-coordinate water quality numerical model is used to simulate the process of both water and pollutant transportation in the trapezoidal channel open flow. The diffusion coefficient used in the prediction is determined by two methods including constant coefficient and the depth-averaged k-epsilon turbulence closure model. The change of the concentration with the bank gradient is acquired based on the simulation of cases with different bank gradients. An analytical formula is derived by using the mirror image method and related diffusion theories, ignoring the discharge momentum and the influence of the opposite bank. The formula can predict the number and distribution of pollutant concentration with some acceptable errors. The results demonstrate that the bank gradient has great influence on the concentration distribution which will decrease with the increase of the bank gradient approximately following a hyperbolic law.     

A model system of four species with a unique equilibrium point

A four component model of two competing organisms, each with a specific parasite, has been exercised so as to investigate its equilibria. In addition to the equilibrium to which the model is known to return after moderate disturbance, severe perturbation led to a new steady state which had the appearance of an equilibrium but which was not maintained in the long term. Some discussion of what constitutes equilibrium and of stability of equilibria is presented.     

Natural attenuation of MTBE and BTEX compounds in a petroleum contaminated shallow coastal aquifer

Natural attenuation of MTBE and BTEX compounds in a petroleum contaminated coastal aquifer in the Tel-Aviv area was investigated. Significant decrease in MTBE concentration and complete disappearance of BTEX compounds occur within 100 m groundwater flow. Highly anaerobic conditions were determined in the close vicinity to the spill source. In order to examine the contribution of microbial degradation to the attenuation process at anaerobic conditions, compound-specific carbon isotope ratio analysis was employed. Carbon isotope enrichment of toluene up to 2.4% along with the drop in its concentration up to 80% was observed within 20 cm below the water table. The lack of isotope fractionation despite the significant concentration decrease for other studied compounds indicates significant contribution of abiotic processes to the natural attenuation.     

Hierarchical spatial point process analysis for a plant community with high biodiversity

A complex multivariate spatial point pattern of a plant community with high biodiversity is modelled using a hierarchical multivariate point process model. In the model, interactions between plants with different post-fire regeneration strategies are of key interest. We consider initially a maximum likelihood approach to inference where problems arise due to unknown interaction radii for the plants. We next demonstrate that a Bayesian approach provides a flexible framework for incorporating prior information concerning the interaction radii. From an ecological perspective, we are able both to confirm existing knowledge on species’ interactions and to generate new biological questions and hypotheses on species’ interactions.

Combined integral and particle model for describing the dispersion,dilution, terminal layer formation and influence area from a point source discharge into a water body

Contamination of coastal water is a persistent threat to ecosystems around the world. In this study, a novel model for describing the dispersion, dilution, terminal layer formation and influence area from a point source discharge into a water body is presented and compared with field measured data. The model is a Combined Integral and Particle model (CIPMO). In the initial stage, the motion, dispersion and dilution of a buoyant jet are calculated. The output from the buoyant jet model is then coupled with a Lagrangian Advection and Diffusion model describing the far-field. CIPMO ensures that both the near- and far-field processes are adequately resolved. The model either uses empirical data or collects environmental forcing data from open source hydrodynamic models with high spatial and temporal resolution. The method for coupling the near-field buoyant jet and the particle tracking model is described and the output is discussed. The model shows good results when compared with measurements from a field study.

     

SWAT模型在国内外非点源污染研究中的应用进展

模型模拟是定量估算非点源污染负荷的有效工具,也是对其进行规划、控制和管理的前提.近年来SWAT模型在国内外得到了快速的发展和应用,是目前全球评价大范围和环境变化条件下非点源污染问题的一个有效工具.简介SWAT模型的发展历程及原理,概述了SWAT模型目前在国内外的水文评价、污染物流失模拟、输人参数、土地利用及气候变化对水文响应的影响等方面的研究现状,并对SWAT模型的发展方向提出了建议,为模型的进一步完善与应用提供参考.结果显示,SWAT模型对水文评价(如径流量、泥沙量)可得到较好的模拟和预测结果,能够模拟污染物(如农药和化肥)在农田和河网中的迁移过程,模拟与分析土地利用/覆被变化及气候变化对水文过程的影响.模型参数的确定及其对地下水流与溶质运移的模拟是模型的主要问题,需要进一步研究与完善.     

Emotion as a source of moral understanding in conservation

Recent debates around the meaning and implications of compassionate conservation suggest that some conservationists consider emotion a false and misleading basis for moral judgment and decision making. We trace these beliefs to a long-standing, gendered sociocultural convention and argue that the disparagement of emotion as a source of moral understanding is both empirically and morally problematic. According to the current scientific and philosophical understanding, reason and emotion are better understood as partners, rather than opposites. Nonetheless, the two have historically been seen as separate, with reason elevated in association with masculinity and emotion (especially nurturing emotion) dismissed or delegitimated in association with femininity. These associations can be situated in a broader, dualistic, and hierarchical logic used to maintain power for a dominant male (White, able-bodied, upper class, heterosexual) human class. We argue that emotion should be affirmed by conservationists for the novel and essential insights it contributes to conservation ethics. We consider the specific example of compassion and characterize it as an emotional experience of interdependence and shared vulnerability. This experience highlights conservationists’ responsibilities to individual beings, enhancing established and widely accepted beliefs that conservationists have a duty to protect populations, species, and ecosystems (or biodiversity). We argue compassion, thus understood, should be embraced as a core virtue of conservation.     

Evaluation of numerical simulations of CO2 transport in a city block with field measurements

Studying urban air-transport phenomena is highly complex, because of the heterogenous flow patterns that can arise. The main reason for these is the variable topology of urban areas, however, there is a large number of influencing variables such as meteorological conditions (e.g., wind situation, temperature) and anthropogenic factors such as traffic emissions. During a one-year CO₂ measurement campaign in the city of Basel, Switzerland, steep CO₂ gradients were measured around a large building. The concentration differences showed a strong dependency on the local flow regimes. Analysis of the field data alone did not provide a complete explanation for the mechanisms underlying the observed phenomena. The key numerical parameters were defined and the influence of turbulent kinetic energy dependency on the time interval for the Reynolds decomposition was studied. A Reynolds-Average Navier-Stokes Computational Fluid Dynamics (CFD) approach was applied in the study area and the CO₂ concentrations were simulated for six significant meteorological situations and compared to the measured data. Two flow regimes dependent on the wind situation, which either enhanced or suppressed the concentration of CO₂ in the street canyon, were identified. The enhancement of CO₂ in the street canyon led to a large difference in CO₂ concentration between the backyard- and street-sides of a building forming the one wall of the canyon. The specific characteristics of the flow patterns led to the identification of the processes determining the observed differences in CO₂ concentrations. The combined analysis of measurement and modeling showed the importance of reliable field measurements and CFD simulations with a high spatial resolution to assess transport mechanisms in urban areas.     

Instantaneous transport of a passive scalar in a turbulent separated flow

The results of large-eddy simulations of flow and transient solute transport over a backward facing step and through a 180° bend are presented. The simulations are validated successfully in terms of hydrodynamics and tracer transport with experimental velocity data and measured residence time distribution curves confirming the accuracy of the method. The hydrodynamics are characterised by flow separation and subsequent recirculation in vertical and horizontal directions and the solute dispersion process is a direct response to the significant unsteadiness and turbulence in the flow. The turbulence in the system is analysed and quantified in terms of power density spectra and covariance of velocity fluctuations. The injection of an instantaneous passive tracer and its dispersion through the system is simulated. Large-eddy simulations enable the resolution of the instantaneous flow field and it is demonstrated that the instabilities of intermittent large-scale structures play a distinguished role in the solute transport. The advection and diffusion of the scalar is governed by the severe unsteadiness of the flow and this is visualised and quantified. The analysis of the scalar mass transport budget quantifies the mechanisms controlling the turbulent mixing and reveals that the mass flux is dominated by advection.     

Structure of turbulent plumes from a momentumless source in a smooth bed

The spatial development of a passive scalar plume is studied within the inhomogeneous turbulence of a boundary layer flow in a recirculating laboratory flume with a smooth bed. The source of the scalar is located flush with the bed, and the low-momentum source design is intended to simulate a diffusive-type scalar release. A weakly diffusive fluorescent dye is used as the scalar. Planar laser-induced fluorescence (PLIF) techniques were used to record the structure of the plume at a spatial resolution of 150 μm. The measured structure of the mean concentration field is compared to an analytical solution for shear-free, homogeneous turbulence. The laboratory plume exhibits spatial development in the mean concentration field that deviates from the self-similar behavior predicted by the analytical solution; this deviation is due to the mean shear and inhomogeneity of the turbulence. In particular, the influence of the viscous sublayer on the plume development is seen to be significant. Nonetheless, the analytical solution replicates some of the features seen in the laboratory plume, and the solution suggests methods of reducing the laboratory data even for cases where the results deviate from the analysis. We also examine the spatial development of the root-mean-square (rms) fluctuating concentration field, and use scalar probability density functions to examine the relationship between the mean and fluctuating concentrations.     

Seasonal variations of particle number concentration and its relationship with PM2.5 mass concentration in industrial-residential airshed

Environmental Geochemistry and Health - The smaller particles that dominate the particle number concentration (PNC) in the ambient air only contribute to a small percentage of particulate matter...