• MES was constructed for simultaneous ammonia removal and acetate production.• Energy consumption was different for total nitrogen and ammonia nitrogen removal.• Energy consumption for acetate production was about 0.04 kWh/g.• Nitrate accumulation explained the difference of energy consumption.• Transport of ammonia and acetate across the membrane deteriorated the performance. Microbial electrosynthesis (MES) is an emerging technology for producing chemicals, and coupling MES to anodic waste oxidation can simultaneously increase the competitiveness and allow additional functions to be explored. In this study, MES was used for the simultaneous removal of ammonia from synthetic urine and production of acetate from CO2. Using graphite anode, 83.2%±5.3% ammonia removal and 28.4%±9.9% total nitrogen removal was achieved, with an energy consumption of 1.32 kWh/g N for total nitrogen removal, 0.45 kWh/g N for ammonia nitrogen removal, and 0.044 kWh/g for acetate production. Using boron-doped diamond (BDD) anode, 70.9%±12.1% ammonia removal and 51.5%±11.8% total nitrogen removal was obtained, with an energy consumption of 0.84 kWh/g N for total nitrogen removal, 0.61 kWh/g N for ammonia nitrogen removal, and 0.043 kWh/g for acetate production. A difference in nitrate accumulation explained the difference of total nitrogen removal efficiencies. Transport of ammonia and acetate across the membrane deteriorated the performance of MES. These results are important for the development of novel electricity-driven technologies for chemical production and pollution removal. 相似文献
Industrial SO2 is the most important air pollutant in China. This paper outlines the technological impacts on industrial SO2 emissions in China in terms of: amount, intensity, structure of energy consumption and structure of energy-intensive industries. It shows that industrial SO2 emissions have linear growth alongside increases in energy consumption, particularly the rise in coal consumption. The contribution of technological factors to decreases in the intensity of energy consumption is 25%, while the structural factor is 75%. The power industry accounts for 52.6% of total industrial SO2. Optimisation of the structure of energy consumption can reduce SO2 emissions by 1.98 million tonnes per year. We propose the following technological strategies for industrial SO2 abatement: adjustment of the system and structure of thermal power generating units, acceleration of flue gas desulphurisation projects, transformation of industrial structures, development of eco-industries and a reduction in energy consumption per unit product. In addition, an effective way to abate industrial SO2 emissions is to promote governance strategies to stricly enforce SO2 emission standards, conduct emission trading, and formulate incentives for encouraging cleaner production and clean energy development. 相似文献
We develop a multi-effect evaluation method to assess integrated impact of VOCs. Enable policy-makers to identify important emission sources, regions, and key species. Solvent usage and industrial process are the most important anthropogenic sources. Styrene, toluene, ethylene, benzene, and m/p-xylene are key species to be cut. Volatile organic compounds (VOCs) play important roles in the atmosphere via three main pathways: photochemical ozone formation, secondary organic aerosol production, and direct toxicity to humans. Few studies have integrated these effects to prioritize control measures for VOCs sources. In this study, we developed a multi-effects evaluation methodology based on updated emission inventories and source profiles, by combining the ozone formation potential (OFP), secondary organic aerosol potential (SOAP), and VOC toxicity data. We derived species-specific emission inventories for 152 sources. The OFPs, SOAPs, and toxicity of each source were estimated, the contribution and sharing of source to each of these adverse effects were calculated. Weightings were given to the three adverse effects by expert scoring, and then the integrated effect was determined. Taking 2012 as the base year, solvent use and industrial process were found to be the most important anthropogenic sources, accounting for 24.2% and 23.1% of the integrated effect, respectively, followed by biomass burning, transportation, and fossil fuel combustion, each had a similar contribution ranging from 16.7% to 18.6%. The top five industrial sources, including plastic products, rubber products, chemical fiber products, the chemical industry, and oil refining, accounted for nearly 70.0% of industrial emissions. Beijing, Chongqing, Shanghai, Jiangsu, and Guangdong were the five provinces contributing the largest integrated effects. For the VOC species from emissions showed the largest contributions were styrene, toluene, ethylene, benzene, and m/p-xylene. 相似文献
The natural grassland ecosystem of the Xilingol steppe has traditionally been the source of the most productive and highest quality agriculture in northern China. Unfortunately, the area is now experiencing degradation due to resource overuse. In an attempt to forecast grassland production and to sustain the ecosystem, we built a time-dependent simulation model of the ecosystem based on long-range weather forecasts (several weeks to several months). The model incorporated five state variables including above- and belowground biomass, the amount of standing dead plant material, livestock (sheep) weight, and the amount of excrement per unit ground area. Within the model, solar light energy is fixed by grassland vegetation and flows through the other variables via a variety of organism-environment interactions. The model was written using a set of simultaneous differential equations and was numerically analyzed. The values of the time-dependent parameters controlling energy flow were determined based on data accumulated in experiments and field surveys executed at a grassland experimental station located in Xilingol, as well as by reference to related literature. We used daily meteorological data including air temperature and rainfall recorded at the Xilinhot Meteorological Observatory. Simulated results for several stocking densities coincided well with the data of aboveground plant biomass observed at the experimental station in 1990, 1993, and 1997. We obtained reasonable simulation results for five stocking densities, three air temperature patterns, and five rainfall patterns. When a month-long drought, which sometimes occurs in this area, was forecast by a local weather station, a decrease in grassland production was forecast by the model. Such forecasts will assist in the management of livestock, forage preservation, and grassland conservation. 相似文献
Ammonia has emerged as a promising hydrogen carrier with applications as an energy source in recent years. However, in addition to being toxic, gaseous ammonia is a precursor of secondary inorganic aerosols. The concentration of ambient fine particulate matter (PM2.5) is intrinsically connected to public health. In this study, PM2.5-related health impacts of utilizing ammonia-hydrogen energy in Kanto Region, Japan, were investigated. It was assumed that 20% of the electricity consumption in Kanto Region, the most populated area in Japan, was supplied by ammonia-hydrogen energy. The PM2.5 resulted from incomplete ammonia decomposition was simulated by a chemical transport model: ADMER-PRO (modified version). Based on the incremental PM2.5 concentration, health impacts on the elderly (individuals over 65 years old) were quantitatively evaluated. The ammonia emission in this scenario increased PM2.5 by 11.7% (0.16 μg·m–3·y–1) in winter and 3.5% (0.08 μg ·m–3·y–1) in summer, resulting in 351 premature deaths per year. This study suggests that costeffective emissions control or treatment and appropriate land planning should be considered to reduce the associated health impacts of this type of energy generation. In addition, further in-depth research, including cost-benefit analysis and security standards, is needed.
A complete energy balance equation was estimated for the common octopus Octopus vulgaris at a constant temperature of 20°C, fed ad libitum on anchovy fillet (Engraulis encrasicolus). Energy used for growth and respiration or lost with faeces and excreted ammonia was estimated, along with total energy
consumption through food, for six specimens of O. vulgaris (with masses between 114 and 662 g). The energy balance equation was estimated for the specimens at 10-day intervals. During
each 10-day interval, food consumed, body mass increase and quantity of faeces voided were measured. The calorific values
of octopus flesh, anchovy flesh and faeces were measured by bomb calorimetry. Oxygen consumption and ammonia excretion rates
were monitored for each specimen during three 24-h experiments and daily oxygen consumption and ammonia excretion were estimated.
It was found that 58% of the energy consumed was used for respiration. The amount of energy invested in somatic and gonadal
growth represented 26% of the total energy budget. The energy discarded through faeces was 13% of consumed energy. The estimated
assimilation efficiency (AE) values of O. vulgaris feeding on anchovy (80.9–90.7%) were lower than the AE values estimated for other cephalopod species with different diets
of lower lipid content such as crabs or mussels. Specific growth rates (SGR) ranged 0.43–0.95 and were similar to those reported
for other high-lipid diets (bogue, sardine) and lower than SGR values found for low-lipid, high-protein diets (squid, crab,
natural diet). Ammonia excretion peak (6 h after feeding) followed the one of oxygen consumption (1 h after feeding). The
values of atomic oxygen-to-nitrogen (O:N) ratio indicated a protein-dominated metabolism for O. vulgaris. 相似文献