环境监测用高锰酸盐指数和氨氮标准溶液量值比对研究

针对高锰酸盐指数(COD_Mn)和氨氮(NH₃-N)标准溶液(以下简称液标)制造商、浓度水平和使用情况进行调研,根据调研结果选择常用的7个品牌COD_Mn液标和9个常用NH₃-N液标品牌开展量值比对和质量评价研究,匿名采购129支液标经盲样编码后采用《地表水环境质量标准》(GB 3838—2002)推荐标准进行分析测定,计算和评定测定结果的不确定度,以En法进行量值比对评价。研究表明,NH₃-N液标量值均满意,COD_Mn测试中的加盖操作会使测定结果偏高,按照证书要求操作时COD_Mn液标量值合格,未按照液标证书中要求进行液标样品前处理测定会造成测定结果的偏离,影响评价结果。建议监测人员合理选用和规范使用环境用液标,加强环境用液标的选购和管理,确保检测过程得到有效控制。     

水污染源氨氮自动监测设备比对试验考核指标探讨

对15家氨氮自动监测设备比对试验考核不合格的污水厂及印染厂的考核情况进行了分析，发现目前水污染源氨氮自动监测设备比对试验考核指标存在一些问题。结合水污染源在线监测系统运行与考核技术规范以及地表水自动监测技术规范，提出了水污染源氨氮自动监测系统按照不同排放浓度实施不同比对试验考核指标的建议。     

Recent Trends and Patterns of Nutrient Concentrations in Small Agricultural Streams in Sweden

Long-term median total phosphorus (TotP) and total nitrogen (TotN) concentrations were 0.08 and 5.5 P/N (mg L^-1), respectively, in 10 agricultural streams monitored since 1988 in Sweden. The areas ofthe respective catchments are 2–20 km². The period 1992/2002 was characterised by stable hydrological conditions without any flow trends in nearly all of the streams. The highest average TotP concentration, 0.17 mg P L^-1, was found in a small agriculturalstream in the largest Swedish agricultural plain. The soil texture is here characterised by a large specific surface area of the soil particles, and the agriculture by cereal production. The second highestaverage TotP concentration, 0.14 mg P L ^-1, was measured in the surface water from a catchment characterised partly by clay soils andby production of potato, spring cereals and grass. This catchment had twice as many fields with a calculated high risk for P losses comparedwith another monitored catchment in the same watershed (River Rönneå). There was a significant downward TotP trend during 1992/2002 of 0.0012 mg P L^-1 yr^-1 (Sen's slope estimator) in the catchment where many fields risk P losses and which had a reduced P manure application rate of –20% during 1995/2000. In recent years practically no manure has been spread during autumn. Bypass flow of nitrate through one soil has been suggested to influence the LOWESS (LOcally WEighted Scatterplot Smothing) fitting curve of TotN. Total nitrogen concentration decreased in most of the catchment. The average downward slope was similar to a general TotN reduction of 0.069 mg N L^-1 yr^-1. During the period 1992/2002 this was equal to slightly more than 10 per cent. Cultivation of catch crops wasrelatively uncommon until 2002, but this practice is expected to expandto larger areas during 2003 and in the future.     

氨气敏电极法和纳氏试剂分光光度法对地表水中氨氮的比对测试

采用不同质量浓度的氨氮标准样品和实际样品,用氨气敏电极法和纳氏试剂分光光度法进行同步测试。结果表明,2种分析方法在水样氨氮质量浓度在0. 159～2. 81 mg/L范围内具有良好的可比性、精密性和准确性。氨气敏电极法的检出限为0. 03 mg/L,平行6次测定样品的相对标准偏差为0. 4%～4. 2%,加标回收率为85. 0%～110%;纳氏试剂分光光度法的检出限为0. 025 mg/L,平行6次测定样品的相对标准偏差为0. 5%～6. 4%,加标回收率为93. 0%～99. 8%。同时氨气敏电极法在样品预处理、试剂配制和分析时间上要优于纳氏试剂分光光度法。氨气敏电极法能够满足地表水自动监测在线比对实际工作的需求,该方法具有良好的适用性。     

Nitrogen Content of Letharia vulpina Tissue from Forests of the Sierra Nevada, California: Geographic Patterns and Relationships to Ammonia Estimates and Climate

Nitrogen (N) pollution is a growing concern in forests of the greater Sierra Nevada, which lie downwind of the highly populated and agricultural Central Valley. Nitrogen content of Letharia vulpina tissue was analyzed from 38 sites using total Kjeldahl analysis to provide a preliminary assessment of N deposition patterns. Collections were co-located with plots where epiphytic macrolichen communities are used for estimating ammonia (NH₃) deposition. Tissue N ranged from 0.6% to 2.11% with the highest values occurring in the southwestern Sierra Nevada (range: 1.38 to 2.11). Tissue N at 17 plots was elevated, as defined by a threshold concentration of 1.03%. Stepwise regression was used to determine the best predictors of tissue N from among a variety of environmental variables. The best model consisted only of longitude (r ² = 0.64), which was reflected in the geographic distribution of tissue values: the southwestern Sierra Nevada, the high Sierras near the Tahoe Basin, and the Modoc Plateau, are three apparent N hotspots arranged along the tilted north–south axis of the study area. Withholding longitude and latitude, the best regression model suggested that NH₃ estimates and annual number of wetdays interactively affect N accumulation (r ² = 0.61; % N ∼ NH₃ + wetdays + (NH₃ × wetdays)). We did not expect perfect correspondence between tissue values and NH₃ estimates since other N pollutants also accumulate in the lichen thallus. Additionally, other factors potentially affecting N content, such as growth rate and leaching, were not given full account.     

Spatial and Temporal Variation of Ozone Concentrations at High Altitude Monitoring Sites in Germany

The present study deals with the characterisation and interpretation of hourly taken maximum ozone concentrations of each day at various high altitude monitoring sites in Germany and contributes to the understanding of ozone transport processes. The relation between long range transport of ozone as well as its precursors and high ozone concentrations is of special interest. Aim of this paper is to investigate the influence and importance of large scale meteorological circulation and source regions of anthropogenic ozone precursors to local ozone concentrations using 2-dimensional backward trajectories. Further, reasons for the spatial and temporal variation of ozone concentration levels will be shown. Investigating numerous cases a similar origin of air masses causing high ozone concentrations in Germany and uniform patterns at various sites could be identified.     

太湖蓝藻水华的自动监测和手工监测比对分析

对夏季太湖野外水华蓝藻样本进行梯度稀释,将自动监测法与手工监测法(人工镜检法和分光光度法)进行比对分析,同时通过对野外样品的连续监测对实验结果进行验证.结果表明,对于以微囊藻为绝对优势种的夏季太湖水体,YSI-6600型和EXO2型便携式水质监测仪测得的叶绿素与人工镜检法测得的藻密度的调整后相关系数(R2adj)均值分...     

Gold Concentrations in Abiotic Materials, Plants, and Animals: A Synoptic Review

Gold (Au) is ubiquitous in the environment and mined commercially at numerous locations worldwide. It is also an allergen that induces dermatitis in sensitive individuals. Gold concentrations were comparatively elevated in samples collected near gold mining and processing facilities, although no data were found for birds and non-human mammals. Maximum gold concentrations reported in abiotic materials were 0.001 microg L(-1) in rainwater; 0.0015 microg L(-1) in seawater near hydrothermal vents vs. < 0.00004-0.0007 microg L(-1) elsewhere; 5.0 microg kg(-1) dry weight (DW) in the Earth's crust; 19.0 microg L(-1) in a freshwater stream near a gold mining site; 440 microg kg(-1) DW in atmospheric dust near a high traffic road; 843 microg kg(-1) DW in alluvial soil near a Nevada gold mine vs. < 29 microg kg(-1) DW premining; 2.53 mg kg(-1) DW in snow near a Russian smelter vs. < 0.35 mg kg(-1) DW at a reference site; 4.5 mg kg(-1) DW in sewage sludge; 28.7 mg kg(-1) DW in polymetallic sulfides from the ocean floor; and 256.0 mg kg(-1) DW in freshwater sediments near a gold mine tailings pile vs. < 5 microg kg(-1) DW prior to mining. In plants, elevated concentrations of 19 microg Au kg(-1) DW were reported in terrestrial vegetation near gold mining operations vs. < 4 microg kg(-1) DW at a reference site; 37 microg kg(-1) DW in aquatic bryophytes downstream from a gold mine; 150 microg Au kg(-1) DW in leaves of beans grown in soil containing 170 microg kg(-1) DW; up to 1.06 mg kg(-1) DW in algal mats of rivers receiving gold mine wastes; and 0.1-100 mg kg(-1) DW in selected gold accumulator plants. Fish and aquatic invertebrates contained 0.1-38.0 microg Au kg(-1) DW. In humans, gold concentrations up to 1.1 microg L(-1) were documented in urine of dental technicians vs. 0.002-0.85 microg L(-1) in reference populations; 2.1 microg L(-1) in breast milk, attributed to gold dental fillings and jewelry of mothers; 1.4 mg kg(-1) DW in hair of goldsmiths vs. a normal range of 6-880 microg kg(-1) DW; 2.39 mg L(-1) in whole blood of rheumatoid arthritis patients receiving gold thiol drugs to reduce inflammation (chrysotherapy) vs. a normal range of 0.2-2.0 microg L(-1); and 60.0 to 233.0 mg kg(-1) fresh weight (FW) in kidneys of rheumatoid arthritis patients undergoing active chrysotherapy vs. < 42.0 mg kg(-1) FW kidney 140 months posttreatment.     

The Comparison of Lagrangian and Gaussian Models in Predicting of Air Pollution Emission Using Experimental Study,a Case Study: Ammonia Emission

Ammonia, as a colorless gas with a sharp odor, is considered as one of the created odors in the composting and landfill of solid waste. We used experimental data to study the robustness of AERMOD and the forward Lagrangian stochastic (FLS) in predicting ammonia emission in short range. The study area was Kahrizak landfill and composting plants, Tehran, Iran. The boundary layer parameters for the FLS were calculated on the basis of mean values of temperature, wind speed, and direction. While, the boundary layers of AERMOD were computed on the basis of exact meteorological data. The results depicted that AERMOD prediction at distances less than 1000 m from the sources and the locations inside the sources were poor. However, the results of FLS indicated more agreement with the field measurement, which the coefficient of determination was 0.83. Both models predicted, in the distance of 2000 m from the source, the ammonia concentration would be insignificant.     

Biomonitoring in the Boulder River Watershed, Montana, USA: Metal Concentrations in Biofilm and Macroinvertebrates, and Relations with Macroinvertebrate Assemblage

Portions of the Boulder River watershed contain elevated concentrations of arsenic, cadmium, copper, lead, and zinc in water, sediment, and biota. We measured concentrations of As, Cd, Cu, Pb, and Zn in biofilm and macroinvertebrates, and assessed macroinvertebrate assemblage and aquatic habitat with the objective of monitoring planned remediation efforts. Concentrations of metals were generally higher in downstream sites compared with upstream or reference sites, and two sites contained metal concentrations in macroinvertebrates greater than values reported to reduce health and survival of resident trout. Macroinvertebrate assemblage was correlated with metal concentrations in biofilm and macroinvertebrates. However, macroinvertebrate metrics were significantly correlated with a greater number of biofilm metals (8) than metals in invertebrates (4). Lead concentrations in biofilm appeared to have the most significant impact on macroinvertebrate assemblage. Metal concentrations in macroinvertebrates were directly proportional to concentrations in biofilm, indicating biofilm as a potential surrogate for monitoring metal impacts in aquatic systems.     

Comparison of Chemical Concentrations in Mussels and Oysters from the United States and France

Results from two 'Mussel Watch'-type monitoring programs were compared: the Réseau National d'Observation de la qualité du milieu marin (RNO), the French monitoring network, and the Mussel Watch Project of the U.S. National Status and Trends (NS&T) Program. 80 RNO sites (47 for mussels and 33 for oysters) and 89 NS&T sites (45 for mussels and 44 for oysters) provided a basis for the comparison of median concentrations of commonly measured trace metals (mercury, lead, zinc, cadmium and copper) and organic chemicals. Lower lead and lindane concentrations in the U.S. were explained by their respective history of use. Differences in Zn and Cu, essential elements for both mussels and oysters, could be due to specific internal regulation processes. Higher cadmium concentrations in the U.S. are possibly related to U.S. coastal areas being richer in nutrients or to a lesser use of this element as a general anticorrosive in France. We could not find any plausible explanation for higher mercury concentrations in France. This first attempt of a comparison of national chemical monitoring programs raises the need for deeper understanding of possible contamination sources.     

水杨酸-次氯酸盐光度法测量氨氮时pH对氨氮在线监测仪测量结果的影响

采用水杨酸-次氯酸盐光度法,研究了pH对KS2301氨氮在线监测仪测量结果的影响。研究结果表明,酸碱度对仪器测量结果的准确性均有影响,其中,酸度的影响较碱度的影响要大。当PH为11.6~11.7时,显色剂的显色效果最好,仪器在这个值附近测量结果最稳定。     

A Comparison Between Regression Models and Genetic Programming for Predictions of Chlorophyll-a Concentrations in Northern Lakes

Chlorophyll-a (chl-a) concentrations are often used as a proxy for water quality problems as well as phytoplankton blooms. Available chl-a models range from simple phosphorus loading models to complex regression and dynamic models. A comparison of multiple regression models was made with genetic programming (GP) techniques to predict chl-a concentrations over a large range of 104 Swedish lakes. Independent variables used were lake area, mean depth, iron, latitude, ammonium, nitrogen + nitrate, pH, phosphate, secchi depth, silicon, temperature, total phosphorus, total nitrogen and total organic carbon. GP is a method based on the Darwinian evolution theory. This implies that a program will be able to test different mathematical equations, iterating and improving each equation using fundamental ideas from evolution theory to increase the predictive power. A good correspondence was found between the multiple regression and the GP modelling approach. No significant improvement of the predictive power was found using GP, and it is therefore recommended that multiple regression methods should be preferred when predicting chl-a concentrations as these models tend to be less complex and the modelling approach is easier to use. Results from GP were in some cases more accurate compared to multiple regressions; however, the best model was created by multiple regressions which used concentrations of total phosphorus, total nitrogen and latitude as independent variables. These findings will be an important note for limnologists and modelling managers when developing future models of chl-a concentrations in lakes.     

Retrieval And Monitoring of Atmospheric Trace Gas Concentrations in Nadir and Limb Geometry Using the Space-Borne Sciamachy Instrument

The Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY) onboard the European Envisat spacecraft performs continuous spectral observations of reflected, scattered and transmitted sunlight in various observation geometries. A unique feature of SCIAMACHY is the capability of probing the atmosphere in three different observation geometries:The nadir, limb, and occultation measurement modes. In nadir mode, column densities of trace gases are retrieved with a spatial resolution of typically 30× 60 km using the Differential Optical Absorption Spectroscopy (DOAS) technique (Platt and Perner, 1983). Alternating with the nadir measurement, vertical profiles of absorber concentration in the stratosphere are derived in limb and occultation. In this paper we present an overview over some applications of SCIAMACHY data in space-based monitoring of atmospheric pollution. The DOAS algorithms for the retrieval of total column amounts from nadir spectra are briefly described and case studies of pollution events are presented. We also illustrate the technique used to derive stratospheric concentration profiles from limb observations and show comparisons with other remote sensing systems. Special emphasis will be given to techniques, which take advantage of SCIAMACHY's different viewing geometries. In particular, we will discuss the potential and limits of strategies to infer tropospheric abundances of O₃and NO₂.     

Concentrations of Cu, Fe, Mn, and Zn in tropical soils amended with sewage sludge and composted sewage sludge

Sewage sludge may be used as an agricultural fertilizer, but the practice has been criticized because sludge may contain trace elements and pathogens. The aim of this study was to compare the effectiveness of total and pseudototal extractants of Cu, Fe, Mn, and Zn, and to compare the results with the bioavailable concentrations of these elements to maize and sugarcane in a soil that was amended with sewage sludge for 13 consecutive years and in a separate soil that was amended a single time with sewage sludge and composted sewage sludge. The 13-year amendment experiment involved 3 rates of sludge (5, 10, and 20 t ha^?1). The one-time amendment experiment involved treatments reflecting 50, 100, and 200 % of values stipulated by current legislation. The metal concentrations extracted by aqua regia (AR) were more similar to those obtained by Environmental Protection Agency (EPA) 3052 than to those obtained by EPA3051, and the strongest correlation was observed between pseudo(total) concentrations extracted by AR and EPA3052 and bioavailable concentrations obtained by Mehlich III. An effect of sewage sludge amendment on the concentrations of heavy metals was only observed in samples from the 13-year experiment.     

Genetic Patterns as a Tool for Monitoring and Assessment of Environmental Impacts: the Example of Genetic Ecotoxicology

Genetic techniques are widely applied to assess the effects of environmental variation or exogenous impacts on populations. Many studies fail to provide convincing evidence that genetic patterns are attributable to the factors proposed. We assert that a rigorous approach must be followed to distinguish patterns of natural genetic variation from genetic change. We review the principles of natural genetic variation and population structure and present them in the context of their interaction with biological and stochastic sources of genetic change. Key steps are articulated which are often overlooked when applying genetic techniques. These are consideration of population structure when comparing populations, developing a specific test against a model of genetic change, and testing for evidence of direct effects and mechanisms of impact. Use of these steps in genetic ecotoxicology is described in detail and includes three primary methods of linking genetic patterns to the effects of contaminants. We propose that this combined approach is critical to the use of genetic techniques to assess and predict long-term effects of environmental impacts on populations or ecosystems.     

A Comparison of Sediment and Monitoring Data: Implications for Paleomonitoring a Small Lake

Long-term limnological monitoring data (from 1971 to 2001) were compared with sediment core record in Lake Viitna Linajärv (hereafter L. Viitna), a small lake in northern Estonia. The monitoring data show that L. Viitna changed from mesotrophic in the 1970s to eutrophic in the 1990s. The trends of paleodata thatintegrate the changes in the biogeochemical matter cycling in the lake over 2–3 years have clear signals about changes in the state ofthe ecosystem in L. Viitna during the last decades. A gradual increase in organic productivity should reflect a greater oxygen demand in the hypolimnion. As a result the hypolimnion becameseasonally anoxic earlier and its pH level remained low for a longer time. These fundamental changes near the sediment-water interface were recorded in the sediment core. The greatest changes occurred at the beginning of the 1980s (layers at a depthof ca. 20 cm), when the meso(eu?)trophic conditions in L. Viitnastarted to become increasingly more eutrophic. The variations ofpaleorecords in the upper part of the sediment core coincide temporally with changes in the water level of the lake.     

北京市大气污染物浓度空间分布与优化布点研究

基于地统计学方法对北京市2012年11—12月的大气污染物SO2、NO2、PM10和PM2.5浓度数据进行了空间分析。结果表明,4种污染物浓度数据均符合正态分布,满足地统计学分析的使用条件且均呈现中等强度的变异性。4种污染物半变异函数的块金效应值分别是29%、24%、7%、4%,表现出很强的空间相关性。4种污染物长轴变程分别是63、58、62、90 km,短轴变程分别是31、37、48、50 km,空间分布呈现出各向异性,变程范围与中尺度天气系统相当。研究大气污染物的空间分布特性对于整体把握区域环境空气质量和监测点位优化十分重要,以北京市区域空气质量中PM2.5监测站点设置为例,其监测站点在长轴方向上的间隔设置应取20~25 km,短轴方向上布点间隔应为8~12 km。     

Temporal and Spatial Variations in Nitrogen Dioxide Concentrations Across an Urban Landscape: Cambridge, UK

The acquisition of a comprehensive air quality dataset for a small city environment is described for use in statistical modelling of dispersion processes and micro-scale assessment of polluted zones. The dataset is based on a nitrogen dioxide diffusion tube survey for Cambridge where up to 80 roadside and background sites have been monitored continuously over two years, using a two week exposure period. Site categories are defined by their function within the urban landscape. Spatial and temporal features of the data set are explained in terms of urban location, street geometry, meteorology and traffic behaviour. The highest levels of NO2 are found in central canyon streets which are narrow with enclosing architecture and slow-moving traffic. In contrast lower levels are found for the wider, more open radial routes where traffic is free-flowing. The influence of street geometry on NO2 levels for central streets is demonstrated, where canyon sections adjacent to open sections having the same traffic flow record higher concentrations. Whilst all roadside sites are affected by a photochemical pollution 'episode', the greater potential for elevated NO2 concentrations within the canyon sections is significant. The close proximity of low background levels of NO2 to roadside 'hot-spots' is important for public exposure assessment. The variation in background levels across the urban landscape is very small and unrelated to location; whether central, suburban or outer city. Seasonal variation, not seen in roadside data, is clearly apparent in background data with a winter maximum and summer minimum.     

Monitoring global change: Comparison of forest cover estimates using remote sensing and inventory approaches

Satellite-based remote sensing offers great potential for frequent assessment of forest cover over broad spatial scales, however, calibration and validation using ground-based surveys are needed. In this study, forest cover estimates for the United States from a recently developed land surface cover map generated from satellite remote sensing data were compared to state-level inventory data from the U.S. National Resources Planning Act Timber Database. The land cover map was produced at the U.S. Geological Survey EROS Data Center and is based on imagery from the AVHRR sensor (spatial resolution 1.1 km). Vegetation type was classified using the temporal signal in the Normalized Difference Vegetation Index derived from AVHRR data. Comparisons revealed close agreement in the estimate of forest cover for extensively forested states with large polygons of relatively similar vegetation such as Oregon. Larger forest cover differences were observed in other states with some regional patterns in the level of agreement apparent.Comparisons in inventory- and remote sensing-based estimates of current forested area with potential vegetation maps indicated the magnitude of past land use change and the potential for future changes. The remote sensing approach appears to hold promise for conducting surveys of forest cover where inventory data are limited or where rates of vegetation change, due to human or climatic factors, are rapid.