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1.
Principal component analysis (PCA) is capable of handling large sets of data. However, lack of consistent method in data pre-treatment and its importance are the limitations in PCA applications. This study examined pre-treatments methods (log (x?+?1) transformation, outlier removal, and granulometric and geochemical normalization) on dataset of Mengkabong Lagoon, Sabah, mangrove surface sediment at high and low tides. The study revealed that geochemical normalization using Al with outliers removal resulted in a better classification of the mangrove surface sediment than that outliers removal, granulometric normalization using clay and log (x?+?1) transformation. PCA output using geochemical normalization with outliers removal demonstrated associations between environmental variables and tides of mangrove surface sediment, Mengkabong Lagoon, Sabah. The PCA outputs at high and low tides also provided to better interpret information about the sediment and its controlling factors in the intertidal zone. The study showed data pre-treatment method to be a useful procedure to standardize the datasets and reducing the influence of outliers. 相似文献
2.
Mauro Mele Diego Servida Domenico Lupis 《Environmental monitoring and assessment》2013,185(7):5891-5907
Sulphide-bearing mine dumps are potential sources of pollution when acid mine drainage (AMD) occurs. Because the generation of AMD depends on the volume and composition of waste materials, their characterisation is crucial for the evaluation of geochemical hazards and for the design of remediation strategies to minimise their environmental impact. In this paper, a cost-effective strategy for the characterisation of an inactive mine dump in the Rio Marina mining district (Elba Island, Italy) using earth resistivity imaging (ERI) is presented. As no information regarding the nature of waste rocks is found in reports for the mine, five ERI profiles were acquired at the top of the waste pile. The results show that waste rocks are heterogeneous with a maximum thickness of 30 m. Due to the large amounts of dispersed sulphide minerals, the waste rocks are characterised by an electrically conductive geophysical signature in comparison to the surrounding resistive metamorphic bedrock. A geostatistical approach was adopted to estimate the elevation of the edges of the mine dump, and the net volume of the waste rocks was computed through a raster analysis of the elevations of the upper and lower boundaries of the mine dump. High-conductivity anomalies were detected within the core of the mine dump. The integration of the hydrogeological, geochemical and geological framework of the Rio Marina mining district suggests that these anomalies could be a geophysical signature of subsurface regions where AMD is currently generated or stored, thus representing sources of environmental pollution. 相似文献
3.
Baba A Deniz O Ozcan H Erees SF Cetiner SZ 《Environmental monitoring and assessment》2008,145(1-3):361-374
Tuzla geothermal basin is situated in north-western Turkey on the Biga Peninsula, which is located at the west end of the Northern Anatolian Fault system. Soil and water samples were collected between August 2003 and June 2004 to initiate development of a geochemical profile of surface and subsurface waters in the geothermal basin and radionuclide concentrations in soils. All water samples were found to fall within Turkish Water Quality Class 4, meaning they were remarkably contaminated for any water consumption sector (industrial, human use or agricultural) based on sodium and chloride ions. Such waters could be used only after appropriate water treatment. The water samples are of the chloride type in terms of geochemical evaluation. Preliminary geochemical evidence shows that the N-S flowing part of the Tuzla River acts as a natural barrier within the basin. Heavy metal concentrations in the soil samples show slight elevations, especially those obtained from the east part of the basin where thermal springs are dominant. Geochemical calculations were carried out with PHREEQC software to determine equilibrium concentration of chemical species and saturation indices, by which it is suggested that chloride is the most important ligand to mobilize the heavy metals in the studied system. In addition, the activity concentration and gamma-absorbed dose rates of the terrestrial naturally occurring radionuclides were determined in the soil using gamma-ray spectrometry. The soil activity ranged from 42.77 to 988.66 Bq kg(-1) (averaging 138 Bq kg(-1)) for ( 238 )U, 13.27 to 106.31 Bq kg(-1) (averaging 32.42 Bq kg(-1)) for ( 232 )Th, and 99.28 to 935.36 Bq kg(-1) (averaging 515.44 Bq kg(-1)) for ( 40 )K. The highest value of ( 238 )U was found in the soil samples obtained from an area close to the hot spring. 相似文献
4.
Foran J. Brosnan T. Connor M. Delfino J. DePinto J. Dickson K. Humphrey H. Novotny V. Smith R. Sobsey M. Stehman S. 《Environmental monitoring and assessment》2000,62(2):147-167
The International Life SciencesInstitute (ILSI) Risk Science Institute (RSI) convenedan expert panel of scientists to developrecommendations for a comprehensive monitoring programfor the Croton and Catskill/Delaware watersheds, whichprovide drinking water to New York City's residents. This effort was conducted as part of efforts topreserve and enhance the quality of New York City'sreservoir system through a watershed protectionprogram. The panel developed recommendations for astrategic framework on which to construct a monitoringprogram. As part of this activity, the paneldetermined whether existing monitoring activities weredeficient and, where activities were deficient, thepanel developed recommendations for additionalinformation that should be collected.The panel recommended the development and use of anintegrated approach to watershed monitoring, whichdraws on modeling, risk-based planning and analysis,statistical sampling and design, and basic compliancemonitoring. The approach should be designed toprovide an assessment of natural and anthropogenicsources of stress to the system as well as anassessment of water quality trends in response tostresses acting in concert, both over the long termand over the five-year New York City Memorandum ofAgreement (MOA) assessment time frame. It should alsoprovide an assessment of the human health andenvironmental risks posed by a variety of stressors,and the impact of management actions implemented toameliorate stressors. 相似文献
5.
The awareness regarding quality assurance (QA) and quality control (QC) for environmental monitoring has considerably increased in the past few years, especially with respect to the determination of chemical species, since errors occurring at various levels may considerably affect the interpretation of results (e.g. studies of toxic impact, geochemical pathways, etc.). QA for environmental analysis covers a broad range of activities from sample collection to laboratory work and the approach for ensuring quality data should be considered in a global context. However, whereas great emphasis has been placed on QA within the laboratory, there have been few systematic attempts to evaluate risks of discrepancies related, for example, to field manipulations. The situation is even worse when monitoring is applied to relatively new fields such as chemical speciation. This paper outlines some of the main aspects of quality control of environmental analysis, including the validation of methods, sampling and sample handling, storage, etc., with special emphasis on the monitoring of chemical forms of elements (e.g. species of tin, mercury, lead and selenium). 相似文献
6.
C. Schlumpf J. Behringer G. Dürrenberger C. Pahl-Wostl 《Environmental Modeling and Assessment》1999,4(1):1-12
Participatory Integrated Assessment (PIA) is an approach which aims at developing methods which allow to combine evaluations
of experts and lay people in the field of Integrated Assessment. Thus, policy recommendations derived from PIA exercises are
informed by scientific judgments and by valuations of “non-scientists”. For any PIA methodology the provision of insights,
facts and figures about the policy problem at hand is crucial.
In this paper we describe a PIA methodology which combines the social science research instrument “focus group” with a specific
computer information tool, the “Personal CO2 Calculator” (PCC). The tool supports citizens in discussing and recommending measures on climate change policy. Based on
our experiences, we plead for information instruments that are tuned to and assist concrete target groups with their specific
interests. This helps that policy recommendations derived from PIA exercises are based on both scientific knowledge as well
as citizens' and stakeholders' policy preferences.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
7.
Saumen Maiti V. C. Erram Gautam Gupta Ram Krishna Tiwari U. D. Kulkarni R. R. Sangpal 《Environmental monitoring and assessment》2013,185(4):3445-3465
Deplorable quality of groundwater arising from saltwater intrusion, natural leaching and anthropogenic activities is one of the major concerns for the society. Assessment of groundwater quality is, therefore, a primary objective of scientific research. Here, we propose an artificial neural network-based method set in a Bayesian neural network (BNN) framework and employ it to assess groundwater quality. The approach is based on analyzing 36 water samples and inverting up to 85 Schlumberger vertical electrical sounding data. We constructed a priori model by suitably parameterizing geochemical and geophysical data collected from the western part of India. The posterior model (post-inversion) was estimated using the BNN learning procedure and global hybrid Monte Carlo/Markov Chain Monte Carlo optimization scheme. By suitable parameterization of geochemical and geophysical parameters, we simulated 1,500 training samples, out of which 50 % samples were used for training and remaining 50 % were used for validation and testing. We show that the trained model is able to classify validation and test samples with 85 % and 80 % accuracy respectively. Based on cross-correlation analysis and Gibb’s diagram of geochemical attributes, the groundwater qualities of the study area were classified into following three categories: “Very good”, “Good”, and “Unsuitable”. The BNN model-based results suggest that groundwater quality falls mostly in the range of “Good” to “Very good” except for some places near the Arabian Sea. The new modeling results powered by uncertainty and statistical analyses would provide useful constrain, which could be utilized in monitoring and assessment of the groundwater quality. 相似文献
8.
Lourdes M. Cooper 《Environmental Impact Assessment Review》2011,31(5):465-480
This paper examines how cumulative effects assessment (CEA) has been considered in Strategic Environmental Assessments (SEA) of regional and local plans in a number of case studies in the UK. Initially, the paper presents the legislative and regulatory requirements for assessing cumulative effects in plans and programmes in the UK. The two approaches for assessing plans in the UK, Sustainability Appraisal (SA) and SEA are discussed and in most cases, a combined SA and SEA process is undertaken by Regional and Local Planning Authorities. The strengths and weaknesses of this approach are explored, as well as their usefulness in decision making. There are problems relating to baseline, establishing trends and predicting cumulative effects at the strategic level. The issues in assessing cumulative effects within this SA/SEA framework are discussed and recommendations for improvements are made. 相似文献
9.
Kahnert M Lazaridis M Tsyro S Torseth K 《Journal of environmental monitoring : JEM》2004,6(7):646-655
The European Monitoring and Evaluation Programme (EMEP) has been established to provide information to Parties to the Convention on Long Range Transboundary Air Pollution on deposition and concentration of air pollutants, as well as on the quantity and significance of long-range transmission of pollutants and transboundary fluxes. To achieve its objectives with the required scientific credibility and technical underpinning, a close integration of the programme's main elements is performed. These elements are emission inventories, chemical transport modelling, and the monitoring of atmospheric chemistry and deposition fluxes, which further are integrated towards abatement policy development. A critical element is the air pollution monitoring that is performed across Europe with a focus not only on health effect aspects and compliance monitoring, but also on process studies and source receptor relationships. Without a strong observational basis a predictive modelling capacity cannot be developed and validated. Thus the modelling success strongly depends on the quality and quantity of available observations. Particulate matter (PM) is a relatively recent addition to the EMEP monitoring programme, and the network for PM mass observations is still evolving. This article presents the current status of EMEP aerosol observations, followed by a critical evaluation in view of EMEP's main objectives and its model development requirements. Specific recommendations are given for improving the PM monitoring programme within EMEP. 相似文献
10.
综述了我国不同介质中挥发性有机物(VOCs)的环境监测方法标准,介绍了样品采集和前处理、分析方法、质量保证与质量控制等技术内容,以及VOCs监测技术的研究进展。分析了国内VOCs监管控制的现状和重点需求,并在此基础上提出了健全VOCs环境标准体系、完善分类监管的优先控制物种清单、尽快实现VOCs监测工作的常态化、推广应用先进的VOCs监测技术等建议。 相似文献
11.
Previous studies have proposed several methods for integrating characterized environmental impacts as a single index in life cycle assessment. Each of them, however, may lead to different results. This study presents internal and external normalization methods, weighting factors proposed by panel methods, and a monetary valuation based on an endpoint life cycle impact assessment method as the integration methods. Furthermore, this study investigates the differences among the integration methods and identifies the causes of the differences through a case study in which five elementary school buildings were used. As a result, when using internal normalization with weighting factors, the weighting factors had a significant influence on the total environmental impacts whereas the normalization had little influence on the total environmental impacts. When using external normalization with weighting factors, the normalization had more significant influence on the total environmental impacts than weighing factors. Due to such differences, the ranking of the five buildings varied depending on the integration methods. The ranking calculated by the monetary valuation method was significantly different from that calculated by the normalization and weighting process. The results aid decision makers in understanding the differences among these integration methods, and, finally, help them select the method most appropriate for the goal at hand. 相似文献
12.
SEA spread around the world as has SEA effectiveness research. International SEA evaluations show mixed findings on SEA effectiveness. In this article, the quality and procedural effectiveness of SEA in Germany is analysed pursuing the hypothesis that SEA is influenced by planning and administrative traditions that tend to counteract to more ambitious SEA approaches. Three SEA case studies were analysed according to a set of criteria and indicators based on international research outcomes involving SEA integration into decision-making, scoping, selection and assessment of alternatives, cumulative effects assessment, tiering, public participation, and monitoring. The analysis draws on documents analysis and interviews with representatives from responsible agencies and involved SEA consultancies.The analysis shows that SEA is facilitating informed decision-making as the responsible agencies used the SEA, the interaction with consultancies, and the participation processes as a source of information. However, the case studies show various degrees of SEA quality in Germany based on the evaluated criteria and indicators. Results demonstrate that procedural effectiveness is limited. Unclear legal regulations, an expert-based planning approach instead of a collaborative approach, and organisational constraints limit the SEA quality. Furthermore, SEA performance is highly influenced by administrations' legalistic tradition, the expert-based planning culture, the home-grown planning system, and the bounded importance of SEA consultancies in the era of staff cuts and under-resourced agencies. Thus, the recommendations aim to strengthen a more collaborative planning approach, to build SEA capacity within SEA responsible agencies, and to clarify SEA regulations.The overall question for SEA evaluation research and practice may be how more collaborative planning approaches can effectively be implemented in planning and SEA practice through institutional learning. 相似文献
13.
There is a great need for indicators to monitor the use and potential impacts of hazardous chemicals. Today there is a huge lack of data, methods and results and method development and studies should be given urgent priority. The aim of this paper was to develop and test an approach to calculate the potential environmental impacts of chemicals for a whole country using the E-PRTR (European Pollutant Release and Transfer Register) as a database and Sweden as an example. Swedish data from 2008 on emissions to air and water for 54 substances from point sources were retrieved from an open database. The data were transformed and aggregated using USEtox, a life-cycle impact assessment (LCIA) method for calculating potential human toxicity and ecotoxicity, both from industrial emissions directly and after input–output analysis (IO analysis) to reallocate emissions to product categories. Zinc to air and water contributed most to human toxicity followed by mercury to air. The largest contribution by industry to potential human toxicity came from the metal industry, followed by the paper and paper product industry. For potential ecotoxicity, zinc, fluoranthene and copper contributed the most. The largest contributions by industry came from the paper and paper products manufacturing sector, followed by the basic metals manufacturing sector. The approach used here can be seen as the first step towards a chemical footprint for nations. By adding data from other countries and other sources, a more complete picture can be gained in line with other footprint calculations. Furthermore, diffuse emissions from, for example, transport or emissions of pesticides could also be added for a more holistic assessment. Since the area of chemicals is complicated, it is probably necessary to develop and use several indicators that complement each other. It is suggested that the approach outlined here could be useful in developing a method for establishing a national chemical footprint. 相似文献
14.
A 100 year sedimentary record of heavy metal pollution in a shallow eutrophic lake, Lake Chaohu, China 总被引:4,自引:0,他引:4
Zan F Huo S Xi B Su J Li X Zhang J Yeager KM 《Journal of environmental monitoring : JEM》2011,13(10):2788-2797
This study has worked on the evaluation of the temporal and spatial evolution of heavy metal contamination in sediment taken from a shallow eutrophic lake, Lake Chaohu, China, over the last 100 years, and thereby used (137)Cs and (210)Pb dating, a PIRLA procedure, statistical analysis, geochemical normalization and a enrichment factor calculation (EF). Concentrations of 5174, 29?325, 10.7, 36.4, 20.4, 386.0, 21.1 and 38.4 mg kg(-1) for Ti, Fe, Co, Cr, Cu, Mn, Pb and Zn, respectively, are proposed as natural background values for the Lake Chaohu based on a PIRLA procedure. The contamination history from the last 100 years can be divided into two periods. Before the 1960s, heavy metal contamination did not occur and there was no spatial difference for heavy metal distribution. Since the 1960s, heavy metal enrichment and contamination has occurred, and the west half of the lake region showed a higher degree of contamination than the east half to various intensified anthropogenic activities. In the east half of the lake region, the anthropogenic source of heavy metals mainly originated from agricultural intensification, whereas in the west half of the lake it originated from city runoff and industry as well as agriculture. In all anthropogenic heavy metals, Co is only from industry. 相似文献
15.
Until now, monitoring of large-scale regional funding programmes has been rare, although their large scope and abstract planning targets generally involve high levels of uncertainty. This study applies and examines a newly developed methodological approach for monitoring such programmes. It also critically reflects to what extent the Strategic Environmental Assessment (SEA) contributes to a better consideration of environmental sustainability and to a learning effect among the stakeholders as well as within the decision-making process. The interviews conducted during the SEA monitoring revealed a very low recognition of the SEA, and its content, among project applicants of the transnational regional funding programme. They further show that more information on the SEA and its recommendations to mitigate negative environmental impacts would be beneficial in the future. Overall, the monitoring confirmed, however, that the institutions responsible for the programme were aware of the benefits of considering environmental sustainability. The long-term application of SEA in an iterative process provided positive learning effects on environmental sustainability and awareness for environmental aspects. This study also shows how SEA monitoring can serve as a tool to enhance visibility and foster communication among decision makers and applicants. 相似文献
16.
The UNEP GEMS/Water Programme is the leading international agency responsible for the development of water quality indicators and maintains the only global database of water quality for inland waters (GEMStat). The protection of source water quality for domestic use (drinking water, abstraction etc) was identified by GEMS/Water as a priority for assessment. A composite index was developed to assess source water quality across a range of inland water types, globally, and over time. The approach for development was three-fold: (1) Select guidelines from the World Health Organisation that are appropriate in assessing global water quality for human health, (2) Select variables from GEMStat that have an appropriate guideline and reasonable global coverage, and (3) determine, on an annual basis, an overall index rating for each station using the water quality index equation endorsed by the Canadian Council of Ministers of the Environment. The index allowed measurements of the frequency and extent to which variables exceeded their respective WHO guidelines, at each individual monitoring station included within GEMStat, allowing both spatial and temporal assessment of global water quality. Development of the index was followed by preliminary sensitivity analysis and verification of the index against real water quality data. 相似文献
17.
The spring waters of Tuzla–Icmeler are on the Marmara Sea coast in Tuzla town of Istanbul city. The springs discharge a natural
sodium chloride mineral water that consumed for ages for therapeutic purposes attributed to their chemical properties. Development
of springs commenced during the Ottoman times and a surface collection structure was built at the discharge point of the main
spring. Two deep wells were drilled to tap mineral water within the past decades. The bottled water of these springs is also
sold for a couple of years and its consumption as a beverage is increasing. The geochemical properties of these springs were
investigated by several researchers in the past. This study comprises geochemical and geophysical measurements performed between
July 2001 and July 2002 in order to construct a conceptual hydrogeological model for environmental and land use planning purposes.
The seasonal evaluation of Tuzla–Icmeler (mineral spring) shows that the chemical properties fluctuate from the beginning
of summer until the beginning of winter. This indicates that the overdraft of water during the summer season causes the movement
and mix of normal groundwater with the mineralized groundwater. As a result, mixing of less mineralized groundwater decreases
the salinity of mineralized groundwater. Using the site-specific hydrogeological, geochemical and geophysical data, zones
of protection areas were delineated in order to prevent a possible pollution access to the springs and surroundings from nearby
dockyards, dwellings and vehicle traffic. For this purpose, a new land use plan was proposed using the existing settlement
sustainability plans. 相似文献
18.
Human rights impact assessment (HRIA) is a process for systematically identifying, predicting and responding to the potential impact on human rights of a business operation, capital project, government policy or trade agreement. Traditionally, it has been conducted as a desktop exercise to predict the effects of trade agreements and government policies on individuals and communities. In line with a growing call for multinational corporations to ensure they do not violate human rights in their activities, HRIA is increasingly incorporated into the standard suite of corporate development project impact assessments. In this context, the policy world's non-structured, desk-based approaches to HRIA are insufficient. Although a number of corporations have commissioned and conducted HRIA, no broadly accepted and validated assessment tool is currently available. The lack of standardisation has complicated efforts to evaluate the effectiveness of HRIA as a risk mitigation tool, and has caused confusion in the corporate world regarding company duties. Hence, clarification is needed. The objectives of this paper are (i) to describe an HRIA methodology, (ii) to provide a rationale for its components and design, and (iii) to illustrate implementation of HRIA using the methodology in two selected corporate development projects—a uranium mine in Malawi and a tree farm in Tanzania. We found that as a prognostic tool, HRIA could examine potential positive and negative human rights impacts and provide effective recommendations for mitigation. However, longer-term monitoring revealed that recommendations were unevenly implemented, dependent on market conditions and personnel movements. This instability in the approach to human rights suggests a need for on-going monitoring and surveillance. 相似文献
19.
Dario Di Giuseppe Gianluca Bianchini Livia Vittori Antisari Annalisa Martucci Claudio Natali Luigi Beccaluva 《Environmental monitoring and assessment》2014,186(5):2925-2940
This geochemical study is focused on the easternmost part of the Po River alluvial plain in Northern Italy, which is interested by widespread agricultural activities, investigating a reclaimed sector of the Province of Ferrara, known as “Valle del Mezzano” (Mezzano Low Land, hereafter reported as MLL) characterized by peat-rich soils. The chemical–mineralogical characterization of these reclaimed soils is important to compare the local geochemical backgrounds with those recorded in other sectors of the River Po plain and to monitor if the observed concentration exceeds critical thresholds. The reported analyses include (a) measurement of the soil salinity, (b) nutrient evaluation, (c) major and trace element concentrations carried out on bulk soils, (d) tests of metal extraction with both aqua regia and EDTA to highlight the distinct elemental mobility and (e) phyto-toxicological measurement of heavy metal concentrations in plants (Lactuca sativa acephala) grown on the studied soils. The results indicate (1) high soil salinity, often with drastic increase of sodium and chloride along the soil profiles, (2) high nitrogen content (in part related to anthropogenic activities) on superficial horizons and nitrate decrease along the soil profiles and (3) comparative enrichments in heavy metals with respect to other soils of the province, which indicate that peat deposits are effective in trapping metals from anthropogenic sources. This, in turn, implies potential geochemical risks for the agricultural activities. In this regard, specific concerns are related to the high nickel and arsenic content of MLL soils due to the mobility of these elements and their attitude to be taken up by plants. 相似文献
20.
Biodiversity in Latin America is at risk today due to habitat loss, land conversion to agriculture and urbanization. To grow their economies the developing countries of Latin America have begun to invest heavily in new road construction. An assessment of research on the impacts of roads on wildlife in Latin America will help define science-based conservation strategies aimed at mitigating road expansion. The aim of this review was to qualitatively and quantitatively assess scientific research papers addressing road impacts on vertebrate species in Latin America. We searched for scientific papers published as early as 1990 to 2017. We reviewed a total of 197 papers. Published research showed an increasing trend in the last decade with a strong geographic bias with a majority of papers from Brazil. Mammals were the most studied taxa followed by birds, reptiles and amphibians. The majority of studies focused on road mortality and at the individual species level. Studies documented an increase in deforestation rates, in land conversion to agriculture, illegal activities (hunting, logging) and the establishment of human settlements. The effects of roads on species richness and populations abundance varied among taxa with no apparent pattern within taxa. Forest-dependent species tended to avoid crossing roads. Amphibians had the highest median road-kill rate, followed by reptiles, mammals and birds. Our results suggest that there is an urgent need for more research, particularly in Central America and to employ predictive tools for difficult-to-sample or understudied species and critical conservation areas. We recommend a two-speed approach to guide future research: one focusing on quantifying individual species responses towards roads and their implications on population viability; a second consisting of regional or continental-scale analyses and modelling of road risks to species and populations to inform road planning immediately. 相似文献