Reducing Fertilizer‐Nitrogen Losses from Rowcrop Landscapes: Insights and Implications from a Spatially Explicit Watershed Model

We present conceptual and quantitative models that predict changes in fertilizer‐derived nitrogen delivery from rowcrop landscapes caused by agricultural conservation efforts implemented to reduce nutrient inputs and transport and increase nutrient retention in the landscape. To evaluate the relative importance of changes in the sources, transport, and sinks of fertilizer‐derived nitrogen across a region, we use the spatially explicit SPAtially Referenced Regression On Watershed attributes watershed model to map the distribution, at the small watershed scale within the Upper Mississippi‐Ohio River Basin (UMORB), of: (1) fertilizer inputs; (2) nutrient attenuation during delivery of those inputs to the UMORB outlet; and (3) nitrogen export from the UMORB outlet. Comparing these spatial distributions suggests that the amount of fertilizer input and degree of nutrient attenuation are both important in determining the extent of nitrogen export. From a management perspective, this means that agricultural conservation efforts to reduce nitrogen export would benefit by: (1) expanding their focus to include activities that restore and enhance nutrient processing in these highly altered landscapes; and (2) targeting specific types of best management practices to watersheds where they will be most valuable. Doing so successfully may result in a shift in current approaches to conservation planning, outreach, and funding.     

Changes in Shallow Groundwater Quality Beneath Recently Urbanized Areas in the Memphis,Tennessee Area1

Barlow, Jeannie R.B., James A. Kingsbury, and Richard H. Coupe, 2012. Changes in Shallow Groundwater Quality Beneath Recently Urbanized Areas in the Memphis, Tennessee Area. Journal of the American Water Resources Association (JAWRA) 48(2): 336‐354. DOI: 10.1111/j.1752‐1688.2011.00616.x Abstract: Memphis, the largest city in the state of Tennessee, and its surrounding suburbs depend on a confined aquifer, the Memphis aquifer, for drinking water. Concern over the potential for downward movement of water from an overlying shallow aquifer to the underlying Memphis aquifer provided impetus for monitoring groundwater quality within the shallow aquifer. The occurrence of volatile organic compounds (VOCs), nitrate, and pesticides in samples from the shallow well network indicate a widespread affect on water quality from the overlying urban land use. Total pesticide concentration was generally higher in more recently recharged groundwater indicating that as the proportion of recent water increases, the occurrence of pesticides related to the current urban land use also increases. Groundwater samples with nitrate concentrations greater than 1.5 mg/l and detectable concentrations of the pesticides atrazine and simazine also had higher concentrations of chloroform, a VOC primarily associated with urban land use, than in other samples. The age of the water from these wells indicates that these concentrations are most likely not representative of past agricultural use, but of more recent urban use of these chemicals. Given that the median age of water represented by the shallow well network was 21 years, a lag time likely exists between changes in land use and the occurrence of constituents related to urbanization in shallow groundwater.     

THE IMPACT OF RUNOFF GENERATION MECHANISMS ON THE LOCATION OF CRITICAL SOURCE AREAS1

ABSTRACT: Identifying phosphorus (P) source areas and transport pathways is a key step in decreasing P loading to natural water systems. This study compared the effects of two modeled runoff generation processes ‐ saturation excess and infiltration excess ‐ on total phosphorus (TP) and soluble reactive phosphorus (SRP) concentrations in 10 catchment streams of a Catskill mountain watershed in southeastern New York. The spatial distribution of runoff from forested land and agricultural land was generated for both runoff processes; results of both distributions were consistent with Soil Conservation Service‐Curve Number (SCS‐CN) theory. These spatial runoff distributions were then used to simulate stream concentrations of TP and SRP through a simple equation derived from an observed relation between P concentration and land use; empirical results indicate that TP and SRP concentrations increased with increasing percentage of agricultural land. Simulated TP and SRP stream concentrations predicted for the 10 catchments were strongly affected by the assumed runoff mechanism. The modeled TP and SRP concentrations produced by saturation excess distribution averaged 31 percent higher and 42 percent higher, respectively, than those produced by the infiltration excess distribution. Misrepresenting the primary runoff mechanism could not only produce erroneous concentrations, it could fail to correctly locate critical source areas for implementation of best management practices. Thus, identification of the primary runoff mechanism is critical in selection of appropriate models in the mitigation of nonpoint source pollution. Correct representation of runoff processes is also critical in the future development of biogeochemical transport models, especially those that address nutrient fluxes.     

Grass‐Shrub Riparian Buffer Removal of Sediment,Phosphorus, and Nitrogen From Simulated Runoff1

Abstract: Riparian buffer forests and vegetative filter strips are widely recommended for improving surface water quality, but grass‐shrub riparian buffer system (RBSs) are less well studied. The objective of this study was to assess the influence of buffer width and vegetation type on the key processes and overall reductions of total suspended solids (TSS), phosphorus (P), and nitrogen (N) from simulated runoff passed through established (7‐year old) RBSs. Nine 1‐m RBS plots, with three replicates of three vegetation types (all natural selection grasses, two‐segment buffer with native grasses and plum shrub, and two‐segment buffer with natural selection grasses and plum shrub) and widths ranging from 8.3 to 16.1 m, received simulated runoff having 4,433 mg/l TSS from on‐site soil, 1.6 mg/l total P, and 20 mg/l total N. Flow‐weighted samples were collected by using Runoff Sampling System (ROSS) units. The buffers were very efficient in removal of sediments, N, and P, with removal efficiencies strongly linked to infiltration. Mass and concentration reductions averaged 99.7% and 97.9% for TSS, 91.8% and 42.9% for total P, and 92.1% and 44.4% for total N. Infiltration alone could account for >75% of TSS removal, >90% of total P removal, and >90% of total N removal. Vegetation type induced significant differences in removal of TSS, total P, and total N. These results demonstrate that adequately designed and implemented grass‐shrub buffers with widths of only 8 m provide for water quality improvement, particularly if adequate infiltration is achieved.     

EMPIRICAL MODELING OF HYDROLOGIC AND NFS POLLUTANT FLUX IN AN URBANIZING BASIN1

ABSTRACT: Long term effects of precipitation and land use/land cover on basin outflow and nonpoint source (NFS) pollutant flux are presented for up to 24 years for a rapidly developing headwater basin and three adjacent headwater basins on the urban fringe of Washington, D.C. Regression models are developed to describe the annual and seasonal responses of basin outflow and IMPS pollutant flux to precipitation, mean impervious surface (IS), and land use. To quantify annual change in mean IS, a variable called delta IS is created as a temporal indicator of urban soil disturbance. Hydrologic models indicate that total annual surface outflow is significantly associated with precipitation and mean IS (r²= 0.65). Seasonal hydrologic models reveal that basin outflow is positively associated with IS during the summer and fall growing season (June to November). NPS pollutant flux models indicate that total and storm total suspended solids (TSS) flux are significantly associated with precipitation and urban soil disturbance in all seasons. Annual NPS total nitrogen flux is significantly associated with both urban and agricultural soil disturbance (r²= 0.51). Seasonal models of phosphorus flux indicate a significant association of total phosphorus flux with urban soil disturbance during the growing season. Total soluble phosphorus (TSP) flux is significantly associated with IS (r²= 0.34) and urban and agricultural soil disturbance (r²= 0.58). In urbanizing Cub Run basin, annual TSP concentrations are significantly associated with IS and cultivated agriculture (r²= 0.51).     

Assessing the Hydrologic and Water Quality Benefits of a Network of Stormwater Control Measures in a SE U.S. Piedmont Watershed

The hydrologic and water quality benefits of an existing engineered stormwater control measures (SCMs) network, along with the alternative stormwater control simulations, were assessed in the rapidly urbanizing Beaverdam Creek watershed located in SE U.S. Piedmont region through the use of distributed Model of Urban Stormwater Improvement Conceptualization stormwater model. When compared with predevelopment conditions, the postdevelopment watershed simulation without SCMs indicated a 2 times increase in total runoff volume, 3 times average increase in peak flow for 1.5‐3.2 cm 6‐h storm events, and 30 times, 12 times, and 3 times higher total suspended solids (TSS), total phosphorous (TP), and total nitrogen (TN) loadings, respectively. The existing SCMs network, in comparison with the postdeveloped watershed without SCMs, reduced the average peak flow rates for 1.5‐3.2 cm 6‐h storm events by 70%, lowered the annual runoff volume by 3%, and lowered TSS, TP, TN annual loads by 57, 51, and 10%, respectively. A backyard rain garden simulation resulted in minimal additional reduction in TSS (1.6%), TP (0.4%), and TN (4%). Model simulations indicate that mandatory 85% TSS and 70% TP annual load reductions in comparison with the predevelopment levels would require the diversion of runoff from at least 70% of the contributing drainage areas runoff into additional offline bioretention basins.     

Estimation of Catchment Nutrient Loads in New Zealand Using Monthly Water Quality Monitoring Data

Causes of variation between loads estimated using alternative calculation methods and their repeatability were investigated using 20 years of daily flow and monthly concentration samples for 77 rivers in New Zealand. Loads of dissolved and total nitrogen and phosphorus were calculated using the Ratio, L5, and L7 methods. Estimates of loads and their precision associated with short‐term records of 5, 10, and 15 years were simulated by subsampling. The representativeness of the short‐term loads was quantified as the standard deviation of the 20 realizations. The L7 method generally produced more realistic loads with the highest precision and representativeness. Differences between load estimates were shown to be associated with poor agreement between the data and the underlying model. The best method was shown to depend on the match between the model and functional and distributional characteristics of the data, rather than on the contaminant. Short‐term load estimates poorly represented the long‐term load estimate, and deviations frequently exceeded estimated imprecision. The results highlight there is no single preferred load calculation method, the inadvisability of “unsupervised” load estimation and the importance of inspecting concentration‐flow, unit load‐flow plots and regression residuals. Regulatory authorities should be aware that the precision of loads estimated from monthly data are likely to be “optimistic” with respect to the actual repeatability of load estimates.     

Reduced Soil Macropores and Forest Cover Reduce Warm‐Season Baseflow below Ecological Thresholds in the Upper Delaware River Basin

We examined the impacts of changes in land cover and soil conditions on the flow regime of the upper Delaware River Basin using the Water Availability Tool for Environmental Resources. We simulated flows for two periods, c. 1600 and 1940, at three sites using the same temperature and precipitation conditions: the East Branch, West Branch, and mainstem Delaware River at Callicoon, New York. The 1600 period represented pristine forest and soils. The 1940 period included reduced forest cover, increased agriculture, and degraded soils with reduced soil macropore fractions. A model‐sensitivity test examined the impact of soil macropore and land cover change separately. We assessed changes in flow regimes between the 1600 and 1940 periods using a variety of flow statistics, including established ecological limits of hydrologic alteration (ELOHA) thresholds. Reduced forest soil macropore fraction significantly reduced summer and fall baseflows. The 1940 period had significantly lower Q50 flows (50% exceedance) than the 1600 period, as well as summer and fall Q90 and Q75–Q90 flows below the ELOHA thresholds. The one‐ to seven‐day minimum flows were also lower for the 1940 period, by 17% on the mainstem. 1940 flows were 6% more likely than the 1600 period to fall below the low‐flow threshold for federally endangered dwarf wedgemussel (Alasmidonta heterodon) habitat. In contrast, the 1940 period had higher flows than the 1600 period from late fall to early winter.     

PATTERNS OF WATERSHED URBANIZATION AND IMPACTS ON WATER QUALITY1

ABSTRACT: Urban runoff contributes to nonpoint source pollution, but there is little understanding of the way that pattern and extent of urbanization contributes to this problem. Indicators of type and density of urbanization and access to municipal services were examined in six urban watersheds in Durham, North Carolina. Principal components analysis (PCA) was used to identify patterns in the distribution of these variables across the urban landscape. While spatial variation in urban environments is not perfectly captured by any one variable, the results suggest that most of the variation can be explained using several variables related to the extent and distribution of urban development. Multiple linear regression models were fit to relate these urbanization indicators to total phosphorus, total kjeldahl nitrogen, total suspended solids, and fecal coliforms. Development density was correlated to decreased water quality in each of the models. Indicators of urbanization type such as the house age, amount of contiguous impervious surface, and stormwater connectivity explained additional variation. In the nutrient models, access to city services was also an important factor. The results indicate that while urbanization density is important in predicting water quality, indicators of urbanization type and access to city services help explain additional variation in the models.     

Thermal Characteristics of Stormwater Runoff from Asphalt and Sod Surfaces1

Abstract: Urban impervious surfaces absorb and store thermal energy, particularly during warm summer months. During a rainfall/runoff event, thermal energy is transferred from the impervious surface to the runoff, causing it to become warmer. As this higher temperature runoff enters receiving waters, it can be harmful to coldwater habitat. In an urban watershed, impervious asphalt surfaces (roads, parking lots, and driveways) and pervious residential lawns comprise a significant portion of the watershed area. A paired asphalt‐turfgrass sod plot was constructed to compare the thermal runoff characteristics between asphalt and turfgrass sod surfaces, to identify meteorological variables that influence these thermal characteristics, and to evaluate evaporative heat loss for runoff from asphalt surfaces. Rainfall simulations were conducted during the summers of 2004 and 2005 under a range of climatic conditions. Asphalt surface temperatures immediately prior to rainfall simulations averaged 43.6°C and decreased an average of 12.3°C over 60 min as rain cooled the surface. In contrast, presimulation sod surface temperatures averaged only 23.3°C and increased an average of 1.3°C throughout the rainfall events. Heat transferred from the asphalt to the runoff resulted in initial asphalt runoff temperatures averaging 35.0°C that decreased by an average of 4.1°C at the end of the event. Sod runoff temperatures averaged only 25.5°C and remained fairly constant throughout the simulations. Multivariable regression equations were developed to predict (1) average asphalt surface temperature (R² = 0.90) and average asphalt runoff temperature (R² = 0.92) as a function of solar radiation, rain temperature, and wind speed, and (2) average sod surface temperature (R² = 0.85) and average sod runoff temperature (R² = 0.94) as a function of solar radiation, rain temperature, rain intensity, and wind speed. Based on a heat balance analysis, existing evaporation equations developed from studies on lakes were not adequate to predict evaporation from runoff on a heated impervious surface. The combined heat from the asphalt and sod plots was an average of 38% less than the total heat had the total area consisted solely of asphalt.     

A Multilevel Model of the Impact of Farm‐Level Best Management Practices on Phosphorus Runoff1

Abstract: Multilevel or hierarchical models have been applied for a number of years in the social sciences but only relatively recently in the environmental sciences. These models can be developed in either a frequentist or Bayesian context and have similarities to other methods such as empirical Bayes analysis and random coefficients regression. In essence, multilevel models take advantage of the hierarchical structure that exists in many multivariate datasets; for example, water quality measurements may be taken from individual lakes, lakes are located in various climatic zones, lakes may be natural or man‐made, and so on. The groups, or levels, may effectively yield different responses or behaviors (e.g., nutrient load response in lakes) that often make retaining group membership more effective when developing a predictive model than when working with either all of the data together or working separately with the individuals. Here, we develop a multilevel model of the impact of farm level best management practices (BMPs) on phosphorus runoff. The result of this research is a model with parameters which vary with key practice categories and thus may be used to evaluate the effectiveness of these practices on phosphorus runoff. For example, it was found that the effect of fertilizer application rate on farm‐scale phosphorus loss is a function of the application method, the hydrologic soil group, and the land use (crop type). Further, results indicate that the most effective method for controlling fertilizer loss is through soil injection. In summary, the resultant multilevel model can be used to estimate phosphorus loss from farms and hence serve as a useful tool for BMP selection.     

Linking Nitrogen Export to Landscape Heterogeneity: The Role of Infrastructure and Storm Flows in a Mediterranean Urban System

Urban ecosystems are often sources of nonpoint source (NPS) nitrogen (N) pollution to aquatic ecosystems. However, N export from urban watersheds is highly variable. Examples of densely urbanized watersheds are not well studied, and these may have comparatively low export rates. Commonly used metrics of landscape heterogeneity may obscure our ability to discern relationships among landscape characteristics that can explain these lower export rates. We expected that differences not often captured by these metrics in the relative cover of vegetation, structures, and impervious surfaces would better explain observed variation in N export. We examined these relationships during storms in residential watersheds. Contrary to expectations, land cover did not directly predict variation in N or water export. Instead, N export was strongly linked to drainage infrastructure density. Our research highlights the role of fine‐scaled landscape attributes, mainly infrastructure, in explaining patterns of N export from densely urbanized watersheds. Changes to hydrologic flow paths by infrastructure explained more variation in N export than land cover. Our findings support further development of landscape ecological models of urban N export that focus on hydrologic modification by infrastructure rather than traditional landscape measures such as land use, as indicators for evaluating patterns of NPS nitrogen pollution in densely urbanized watersheds.     

Estimating Relevance of Organic Carbon,Nitrogen, and Phosphorus Loads to a Blackwater River Estuary1

Abstract: In blackwater river estuaries, a large portion of external carbon, nitrogen, and phosphorus load are combined in complex organic molecules of varying recalcitrance. Determining their lability is essential to establishing the relationship between anthropogenic loads and eutrophication. A method is proposed in which organic C, N, and P are partitioned into labile and refractory forms, based upon first‐order decay estimated by biochemical oxygen demand relative to total organic carbon, and C:N and C:P ratios as a function of organic carbon lability. The technique was applied in developing total maximum daily loads for the lower St. Johns, a blackwater Atlantic coastal plain river estuary in Northeast Florida. Point source organic nutrients were determined to be largely labile. Urban runoff was found to have the highest relative labile organic N and P content, followed by agricultural runoff. Natural forest and silviculture runoff were high in refractory organic N and P. Upstream labile C, N, and P loads were controlled by autochthonous production, with 34‐50% of summer total labile carbon imported as algal biomass. Differentiation of labile and refractory organic forms suggests that while anthropogenic nutrient enrichment has tripled the total nitrogen load, it has resulted in a 6.7‐fold increase in total labile nitrogen load.     

Seasonal Flushing of Pollutant Concentrations and Loads in Urban Stormwater1

Schiff, Kenneth C. and Liesl L. Tiefenthaler, 2011. Seasonal Flushing of Pollutant Concentrations and Loads in Urban Stormwater. Journal of the American Water Resources Association (JAWRA) 47(1):136‐142. DOI: 10.1111/j.1752‐1688.2010.00497.x Abstract: Despite broad observations of first flush within storms, the scientific understanding of seasonal flushing remains incomplete. Seasonal flushing occurs when initial storms of the season have greater concentrations or loads than storms later in the season. The goal of this study was to census stormwater concentrations and loads from an arid, urban watershed to quantify seasonal flushing. Samples were collected every 15 min during the 1997‐1998 wet season from the Santa Ana River and analyzed for total suspended solids. Initial storms of the season generated event mean concentrations 3‐10 times the event mean concentration of storms later in the season. Cumulative flow‐weighted mean concentrations were calculated as the season progressed. Early season storms discharged only 6% of the annual volume, but influenced flow‐weighted mean concentrations well past the midpoint of the wet season. Mass‐based estimates also indicated a disproportionate load in the early portion of the year; over 52% of the annual load was discharged in the first 30% of the annual volume from the highly urbanized lower watershed. Other stormwater pollutants, including six trace metals (Cd, Cr, Cu, Pb, Ni, Zn), were highly correlated with total suspended solids and also exhibited a significant seasonal flush.     

Impacts of Land‐Cover Change on Suspended Sediment Transport in Two Agricultural Watersheds1

Schilling, Keith E., Thomas M. Isenhart, Jason A. Palmer, Calvin F. Wolter, and Jean Spooner, 2011. Impacts of Land‐Cover Change on Suspended Sediment Transport in Two Agricultural Watersheds. Journal of the American Water Resources Association (JAWRA) 47(4):672‐686. DOI: 10.1111/j.1752‐1688.2011.00533.x Abstract: Suspended sediment is a major water quality problem, yet few monitoring studies have been of sufficient scale and duration to assess the effectiveness of land‐use change or conservation practice implementation at a watershed scale. Daily discharge and suspended sediment export from two 5,000‐ha watersheds in central Iowa were monitored over a 10‐year period (water years 1996‐2005). In Walnut Creek watershed, a large portion of land was converted from row crop to native prairie, whereas in Squaw Creek land use remained predominantly row crop agriculture. Suspended sediment loads were similar in both watersheds, exhibiting flashy behavior typical of incised channels. Modeling suggested that expected total soil erosion in Walnut Creek should have been reduced 46% relative to Squaw Creek due to changes in land use, yet measured suspended sediment loads showed no significant differences. Stream mapping indicated that Walnut Creek had three times more eroding streambank lengths than did Squaw Creek suggesting that streambank erosion dominated sediment sources in Walnut Creek and sheet and rill sources dominated sediment sources in Squaw Creek. Our results demonstrate that an accounting of all sources of sediment erosion and delivery is needed to characterize sediment reductions in watershed projects combined with long‐term, intensive monitoring and modeling to account for possible lag times in the manifestation of the benefits of conservation practices on water quality.     

Using Multiple Watershed Models to Predict Water,Nitrogen, and Phosphorus Discharges to the Patuxent Estuary1

Boomer, Kathleen M.B., Donald E. Weller, Thomas E. Jordan, Lewis Linker, Zhi‐Jun Liu, James Reilly, Gary Shenk, and Alexey A. Voinov, 2012. Using Multiple Watershed Models to Predict Water, Nitrogen, and Phosphorus Discharges to the Patuxent Estuary. Journal of the American Water Resources Association (JAWRA) 1‐25. DOI: 10.1111/j.1752‐1688.2012.00689.x Abstract: We analyzed an ensemble of watershed models that predict flow, nitrogen, and phosphorus discharges. The models differed in scope and complexity and used different input data, but all had been applied to evaluate human impacts on discharges to the Patuxent River or to the Chesapeake Bay. We compared predictions to observations of average annual, annual time series, and monthly discharge leaving three basins. No model consistently matched observed discharges better than the others, and predictions differed as much as 150% for every basin. Models that agreed best with the observations in one basin often were among the worst models for another material or basin. Combining model predictions into a model average improved overall reliability in matching observations, and the range of predictions helped describe uncertainty. The model average was not the closest to the observed discharge for every material, basin, and time frame, but the model average had the highest Nash–Sutcliffe performance across all combinations. Consistently poor performance in predicting phosphorus loads suggests that none of the models capture major controls. Differences among model predictions came from differences in model structures, input data, and the time period considered, and also to errors in the observed discharge. Ensemble watershed modeling helped identify research needs and quantify the uncertainties that should be considered when using the models in management decisions.     

IMPACTS OF URBANIZATION ON NUTRIENT CONCENTRATIONS IN SMALL SOUTHEASTERN COASTAL STREAMS1

ABSTRACT: Coastal watersheds in the southeastern United States are rapidly changing due to population growth and attendant increases in residential development, industry, and tourism related commerce. This research examined spatial and temporal patterns of nutrient concentrations in streams from 10 small watersheds (< 4 km²) that drain into Murrells Inlet (impacted) and North Inlet (pristine), two high salinity estuaries along the South Carolina coast. Monthly grab samples were collected during baseflow during 1999 and analyzed for total and dissolved inorganic and organic forms of nitrogen and phosphorus. Data were grouped into forested wetland creeks (representing predevelopment reference sites), urban creeks, and urban ponds. DON and NH4 concentrations were greater in forested streams than in urban streams. NO3 and TP concentrations were greatest in urban streams. Seasonally, concentrations were highest during summer for TN, NH4, DON, and TP, while NO3 concentrations were greatest during winter. Nutrient ratios clearly highlighted the reduction in organic nitrogen due to coastal development. Multiple regression models to predict instream nutrient concentrations from land use in Murrells Inlet suggest that effects are not significant (small r²). The findings indicate that broad land use/land cover classes cannot be used to predict nutrient concentrations in streams in the very small watersheds in our study areas.     

SUSCEPTIBILITY OF INDIANA WATERSHEDS TO HERBICIDE CONTAMINATION1

ABSTRACT: An index of watershed susceptibility to surface water contamination by herbicides could be used to improve source water assessments for public drinking water supplies, prioritize watershed restoration projects, and direct funding and educational efforts to areas where the greatest environmental benefit can be realized. The goal of this study is to use streamflow and herbicide concentration data to develop and evaluate a method for estimating comparative watershed susceptibility to herbicide loss. United States Geological Survey (USGS) concentration data for five relatively water soluble herbicides (alachlor, atrazine, cyanazine, metolachlor, and simazine) were analyzed for 16 Indiana watersheds. Correlation was assessed between observed herbicide losses and: (1) a herbicide runoff index using GIS‐based land use, soil type, SCS runoff curve number, tillage practice, herbicide use estimates, and combinations of these factors; and (2) predicted herbicide losses from a non‐point source pollution model (NAPRA‐Web, an Internet‐based interface for GLEAMS). The highest adjusted R²value was found between herbicide concentration and the runoff curve number alone, ranging from 0.25 to 0.56. Predictions from the simulation model showed a poorer correlation with observed herbicide loss. This indicates potential for using the runoff curve number as a simple herbicide contamination susceptibility index.     

Stormwater Runoff Quality and Quantity From Traditional and Low Impact Development Watersheds1

Abstract: The quality and quantity of residential stormwater runoff from a control, traditional, and low impact development (LID) watershed were compared in a paired watershed study. A traditional neighborhood was built using typical subdivision standards while a LID design was constructed with best management practices including grass swales, cluster housing, shared driveways, rain gardens, and a narrower pervious concrete‐paver road. Weekly, flow‐weighted, composite samples of stormwater were analyzed for nitrate + nitrite‐nitrogen (NO₃ + NO₂‐N), ammonia‐nitrogen (NH₃‐N), total Kjeldahl nitrogen (TKN), total phosphorus (TP), and total suspended solids (TSS). Monthly composite samples were analyzed for total copper (Cu), lead (Pb), and zinc (Zn). Mean weekly storm flow increased (600x) from the traditional watershed in the postconstruction period. Increased exports of TKN, NO₃ + NO₂‐N, NH₃‐N, TP, Cu, Zn, and TSS in runoff were associated with the increased storm flow. Postconstruction storm flow in the LID watershed was reduced by 42% while peak discharge did not change from preconstruction conditions. Exports were reduced from the LID watershed for NH₃‐N, TKN, Pb, and Zn, while TSS and TP exports increased.     

Hydrologic and Phosphorus Export Behavior of Small Streams in Commercial Poultry‐Pasture Watersheds1

Romeis, J. Joshua, C. Rhett Jackson, L. Mark Risse, Andrew N. Sharpley, and David E. Radcliffe, 2011. Hydrologic and Phosphorus Export Behavior of Small Streams in Commercial Poultry‐Pasture Watersheds. Journal of the American Water Resources Association (JAWRA) 1‐19. DOI: 10.1111/j.1752‐1688.2011.00521.x Abstract: Few watershed‐scale studies have evaluated phosphorus export in streamflow from commercial poultry‐pasture operations. Continuous streamflow and mixed‐frequency water quality datasets were collected from nine commercial poultry‐pasture (AG) and three forested (FORS) headwater streams (2.4‐44 ha) in the upper Etowah River basin of Georgia to estimate total P (TP) loads and examine variability of hydrologic response and water quality of storm and nonstorm‐flow regimes. Data collection duration ranged from 18 to 22 months, and approximately 1,600 water quality samples were collected. Significant (p < 0.1) inverse relationships were detected between peak flow response variables and both drainage area and fraction of forest cover. Order‐of‐magnitude differences in TP and dissolved reactive P (DRP) concentration were observed between AG and FORS sites and among AG sites. TP yields of FORS sites ranged from 0.01 to 0.1 kg P/ha. Yields of AG sites ranged from 0.031 to 3.17 kg P/ha (median = 0.354 kg P/ha). With 95% confidence intervals, AG yields ranged from 0.025 to 13.1 kg P/ha. These small‐watershed‐scale yields were similar to field‐scale yields measured in other studies in other regions. TP yields were significantly related to area‐weighted Mehlich‐1 soil test P concentrations (p = 0.0073) and base‐flow water sample P concentrations (p ≤ 0.0005). Water quality sampling during base‐flow conditions may be a useful screening tool for P risk‐based management programs.