THE STABILITY IN WATER OF A NEW CHLORAMINE DISINFECTANT AS A FUNCTION OF pH,TEMPERATURE, AND WATER QUALITY1

The stabilities in water and dry storage of two solid-state disinfectants (3-chloro-4, 4-dimethyl-2-oxazolidinone, agent I, and calcium hypochlorite) have been compared under a variety of conditions. Variables in the study included pH, temperature, and water quality. Agent I is considerably more stable in dry storage and in water, especially at pH 4.5 and 7.0, than is calcium hypochlorite. This is true for solutions of the two compounds in sterile, distilled, deionized, demandfree water or in a synthetic water containing heavy organic load. Prior work in these laboratories concerning use of agent I as a disinfectant for lake water in a laboratory-scale treatment plant had suggested that agent I has considerable potential for use as an alternative to cholorine gas for water disinfection. The present work suggests that agent I is of sufficient stability to be of use as a solid-state disinfectant for swimming pools and for potable water for remote areas.     

THE TENDENCY OF A NEW WATER DISINFECTANT TO PRODUCE TOXIC TRIHALOMETHANES1

A new organic N-chloramine disinfectant (3-chloro-4, 4-dimethyl-2-oxazolidinone, agent I) has been compared with calcium hypochlorite as to its tendency to react with organic matter in water to produce toxic trihalomethanes. Agent I reacts much less readily with organic demand than does calcium hypochlorite. This study shows that agent I should be safe to use as a disinfectant for water containing appreciable organic load in either sunlight or darkness. On the other hand, calcium hypochlorite may not be a satisfactory disinfectant from the toxicity standpoint for water which contains organic load which must be stored for extended time periods in either sunlight or darkness.     

PERFORMANCE OF A NEW POLYMERIC WATER DISINFECTANT1

ABSTRACT: A new insoluble N-halamine polymeric disinfectant material has been tested in a water filter application to determine (1) its tendencies to leach undesirable decomposition products, (2) its range of potential applicability, and (3) its regenerability. In flowing water tests, poly-1,3-dichloro-5-methyl-5-(4‘-vinylphenyl)hydantoin (Poly-I) leached only small amounts of total organic carbon, free and total chlorine, anions, and volatile organics such as trihalomethanes. Furthermore, Poly-I provided bactericidal efficacy over the pH range 4.5 to 9.5 and at temperatures as high as 37°C. Poly-I is deactivated by reducing agents such as sodium thiosulfate and by ethanol; following deactivation, it can be regenerated by exposure to flowing aqueous free chlorine. Poly-I appears suitable for use as a biocidal filter for small potable and recreational waters, for it is effective over a wide pH and temperature range and is readily regenerable. It would not be useful, however, for disinfection of large bodies of water such as in city treatment plants because of its cost and the large amount of the material that would be necessary.     

A NOVEL CHLORAMINE COMPOUND FOR WATER DISINFECTION1

A new chloramine agent, 3-chloio-4, 4-dimethyl-2-oxazolidinone, has been tested in a laboratory scale water treatment plant as to its efficacy in water disinfection. The agent seems to be equally effective as compared to chlorine gas in this application. The results of preliminary toxicity studies on the agent are very encouraging. The agent has a long shelf life both in water solution and in the solid state. Being a solid, the agent is clearly less hazardous to handle than chlorine gas. The agent appears to inhibit oxidative corrosion of metals as well. The agent is less likely to produce toxic halocarbons (e.g., chloroform) in water than is chlorine gas. Possibly most important from the standpoint of water disinfection, the agent is a “slow release” one for its positive chlorine, which provides prolonged bactericidal activity.     

饮用水消毒剂二氧化氯研究进展

随着人们对氯消毒副产物毒性的认识,寻求替代消毒荆成为了水处理行业重要的研究课题。本文概述二氧化氯在饮用水消毒应用中的特点,对其在水厂实际应用中的几个热点问题进行研究与分析,最后对其研究发展前景进行了展望。     

DISINFECTION WITH QUATERNARY AMMONIUM COMPOUNDS1

ABSTRACT: The most common disinfection method is chlorination, however, it has been known that the practice of chlorination for water treatment in the Mississippi River area has caused a significant increase in mortality. The objective of this research was to search for effective disinfectants to replace chlorine. Three cationic surfactants have been tested for their bactericidal properties under various conditions. It has been found that 1 mg of cetyldimethyl-benzylammonium chloride can destroy about 4500 coliforms in one liter water within 10 minutes, under neutral pH conditions and room temperature. Cationic quaternary ammonium compound, therefore, can be a potential candidate disinfectant for replacing chlorine when necessary.     

稳定型含氯消毒剂的稳定性及消毒效果研究

用传统含氯消毒剂与一种磺酸基化合物络合，形成氯稳定体系的水溶液。对该消毒剂在6个月内的有效氟、pH值、氧化还原电位的监测结果表明：其稳定性相当好，pH基本保持不变，有效氯及氧化还原电位的变化率分别为0.51％与9.47％。定量消毒试验结果表明，稳定型含氟消毒剂的消毒能力强，其消毒能力仅略低于二氟异氰尿酸钠等含氯消毒剂，存放6个月后，对表皮葡萄球菌的杀灭率无明显变化。对加5％牛血清白蛋白的表皮葡萄球菌20min的杀灭率无变化。这种稳定型的含氯消毒剂将具有广阔的应用前景。     

THE EFFECTWENESS OF PRICING AS A STAND-ALONE WATER CONSERVATION PROGRAM1

ABSTRACT: Economic theory clearly indicates that the use of increasing rate structures will reduce the demand for water and produce monetary incentives for consumers to conserve. One problem with estimating the effectiveness of using rate structures as a conservation program is that they are usually accompanied by other conservation efforts. Thus, it is difficult to determine the effectiveness of any one conservation component. This paper examines the effectiveness of increasing rate structures in a situation where no other conservation program was introduced. The paper uses customer data from the Spalding County (Georgia) Water Authority where an increasing rate structure replaced a descending rate structure in January 1991. Since the imposition of the increasing rate structure, the number of customers has increased 21 percent while total water demand has gone up only 15 percent and per customer water use has declined 5 percent. The daily water use per connection has declined from 243 gallons in 1990 to 231 in 1993, and monthly use has gone from 7,381 gallons to 7,028 per connection over the same period. Statistical tests indicate that water consumption during the two periods was significantly different while weather factors were not.     

采油污水中化学药剂对COD的影响及可生化性研究

油田采油污水中含有多种源于石油生产的化学药剂,会对污水中的COD及处理效果产生影响。文章以目前某油田使用的几种主要化学药剂为研究对象,分析了药剂浓度对COD的影响,并通过SBR反应器考察了其生物降解性能。结果表明,油田使用的化学药剂对COD有明显的影响,药剂浓度与COD呈线性关系,药剂的种类与结构不同,其对COD影响的显著程度也各异。生物降解性能差是现有油田化学药剂的共同特点,这可能是油田含油污水难处理,特别是采用生物技术处理效果欠佳的重要原因。     

THE EFFECTS OF CHLORINE,ELEVATED TEMPERATURE AND EXPOSURE DURATION OF POWER PLANT EFFLUENTS ON LARVAL WHITE PERCH Morone americana (Gmelin)1

ABSTRACT: Chlorine-temperature interaction studies with various exposure times were conducted on 25–day old larval white perch, Morone Americana, using total residual chlorine (TRC) concentrations of 0.0, 0.15, and 0.30 mg/1 TRC in combination with ΔTs of 2, 6, and 10 C above a base temperature of 18 C. Larval fish were exposed to the chlorine-temperature test conditions for exposure periods of 0.08, 2.0 and 4.0 hours. After each respective exposure period, chlorine concentrations were decayed naturally over a 1.0 to 1.5 hour period to < 0.01 mg/1 TRC; temperatures were decayed over a 4 hour period to 2.0 C above the base temperature. These test conditions were used to simulate chlorine and temperature conditions encountered in power plant discharge canals and near field receiving streams. The interactions of chlorine, ΔT and exposure duration as factors which caused death up to 36 hours after the exposure periods were established by regression model techniques. An initial interaction model showed that ΔT was not a factor which contributed to death. A predictive model for chlorine and exposure duration was constructed which showed that potential impact to larval white perch from chlorine at power facilities with once through cooling systems can be minimized by 1) using short duration exposures (< 1 hour) to chlorine in plants that chlorinate intermittently or 2) by rapid mixing in the receiving stream in plants that chlorinate on a low level (< 0.05 mg/1) continuous basis. Similar considerations should be given to cooling tower blowdown which contain chlorinated water.     

TECHNIQUES FOR DETECTING TRENDS IN LAKE WATER QUALITY1

ABSTRACT: With the advent of standards and criteria for water quality variables, there has been an increasing concern about the changes of these variables over time. Thus, sound statistical methods for determining the presence or absence of trends are needed. A Trend Detection Method is presented that provides: 1) Hypothesis Formulation - statement of the problem to be tested, 2) Data Preparation - selection of water quality variable and data, 3) Data Analysis - exploratory data analysis techniques, and 4) Statistical Tests - tests for detecting trends. The method is utilized in a stepwise fashion and is presented in a nonstatistical manner to allow use by those not well versed in statistical theory. While the emphasis herein is on lakes, the method may be adopted easily to other water bodies.     

离子交换树脂再生水回用的实验研究

在油田稠油注蒸汽所需的离子交换树脂系统中,再生盐水仅能一次性使用,外排盐水会对水体、耕地和环境产生不良的影响。对离子交换树脂再生盐水回用工艺进行了实验研究。实验结果表明:当HJ-1与HJ-3、HJ-4、HJ-5联合使用时,再生盐水中镁离子的浓度可大幅度地降低。几种药剂对再生盐水中钙离子的去除作用效果各不相同,HJ-4对钙的处理效果明显优于HJ-3与HJ-5。现场实验表明:采用复配药剂处理含盐废水,可以实现含盐废水的回用。目前该处理工艺已在某些油田应用,取得了良好的运行效果。     

WATER POLLUTION FROM OIL AND GAS RECOVERY IN EASTERN KENTUCKY WATERSHEDS1

The effects of water quality on brine discharged from oil and gas recovery operations are described for surface water and ground water in two small watersheds in eastern Kentucky. The brine, which had salinity that was often several times that of sea water, led to significantly higher concentrations of several minerals in surface water, particularly in the first and second order streams. Concentractions as high as 50,000 mg/I for sodium and 64,000 mg/I for chloride were measured in streams. The. differences in chemical concentrations for various chemicals over the period of the study were ascribed to temporal variability, particularly due to differences between wet and dry seasons, and to spatial variability, particularly due to dilution and other chemical decay processes. Chemical decay coefficients for sodium and chloride were developed as a function of watershed area for possible application to similar watersheds. There was some evidence that the brine was influencing the Licking River, the major stream that drains the eastern part of Kentucky.     

WATER PRICE RESPONSIVENESS OF COMMERCIAL ESTABLISHMENTS1

ABSTRACT: Pricing policy in water allocation has become of more concern as some areas find water is indeed a scarce resource. Demand estimates, where the quantity purchased-value in use relationships are of concern, have been made in other studies for residential, industrial, and agricultural uses in many areas of the country. The price-quantity relations for water use in commercial firms are estimated and discussed for several different types of stores in this study. A derived demand model is used to estimate commercial demand in the Miami, Florida, area. The price elasticity was generally low (inelastic) for all groups studied except for department stores. This group was found to have an elastic demand for water at all prices above $0.93 per thousand gallons purchased per month, where the mean price for this part of the sample was $1.24. The major implication of the study is that commercial establishments may be responsive to price changes over the long run, much as has already been shown for other types of user groups in other studies.     

INACTIVATION OF GIARDIA MURIS CYSTS BY CHLORAMINES1

ABSTRACT: In a study to measure the efficacy of chioramines at inactivating Giardia cysts, the ability of cysts to excyst was measured after exposure to different concentrations of chloramines, for different times, and at different temperatures and pH. The chloramines were generated by mixing ammonium sulfate and sodium hypochlorate in water to approximate a 7:1 chlorine:ammonia ratio by weight. Times of 40, 80, 180, and 270 minutes; temperatures of 3, 10, and 18°C; target chioramine concentrations of 0.4, 1.4, 2.0, and 2.6 mg/L; and pH of 7.0 and 8.5 were the actual values tested. The combinations of these variables that were able to inactivate >99.8 percent of the cysts were a minimum chloramine concentration of 2.26 mg/L applied for 270 minutes at a water temperature of 10°C; and at 18°C, averaged minimum chloramine concentrations of 2.14 and 1.55 mg/L applied for 180 and 270 minutes, respectively. The minimum CT values corresponding to these combinations capable of >99.8 percent cyst inactivation, are 610 at 10°C and 385 at 18°C. Temperature was noted to exert a major effect on the ability of chloramines to inactivate cysts. Modifications of the methods used to generate chloramines may have an effect on the capacity of this disinfectant to inactivate cysts.     

The Impacts of Water Conservation Strategies on Water Use: Four Case Studies1

Tsai, Yushiou, Sara Cohen, and Richard M. Vogel, 2011. The Impacts of Water Conservation Strategies on Water Use: Four Case Studies. Journal of the American Water Resources Association (JAWRA) 47(4):687‐701. DOI: 10.1111/j.1752‐1688.2011.00534.x Abstract: We assessed impacts on water use achieved by implementation of controlled experiments relating to four water conservation strategies in four towns within the Ipswich watershed in Massachusetts. The strategies included (1) installation of weather‐sensitive irrigation controller switches (WSICS) in residences and municipal athletic fields; (2) installation of rainwater harvesting systems in residences; (3) two outreach programs: (a) free home indoor water use audits and water fixture retrofit kits and (b) rebates for low‐water‐demand toilets and washing machines; and (4) soil amendments to improve soil moisture retention at a municipal athletic field. The goals of this study are to summarize the effectiveness of the four water conservation strategies and to introduce nonparametric statistical methods for evaluating the effectiveness of these conservation strategies in reducing water use. It was found that (1) the municipal WSICS significantly reduced water use; (2) residences with high irrigation demand were more likely than low water users to experience a substantial demand decrease when equipped with the WSICS; (3) rainwater harvesting provided substantial rainwater use, but these volumes were small relative to total domestic water use and relative to the natural fluctuations in domestic water use; (4) both the audits/retrofit and rebate programs resulted in significant water savings; and (5) a modeling approach showed potential water savings from soil amendments in ball fields.     

Revealing the economic channels of natural impacts: an extended input–output subsystems application to GHG gases and water use

While a small set of economic activities generates most of the direct environmental burdens, the complexity of connections within an economic system requires consideration of the effects caused by the interdependences between its different agents. To date, however, the input–output (I–O) subsystems literature has been limited to uncovering the intersectoral linkages of direct and indirect environmental impacts within an economy and the connections between sectors and private consumption have thus not attracted much attention. This paper proposes an I–O subsystems model that endogenously incorporates not only production sectors but also household consumption to capture the entire channel of environmental impacts. The empirical application focuses on carbon dioxide equivalent (CO₂-eq.) emissions and water use associated with production sectors and households defined in the I–O table for a Spanish region, Extremadura. The results highlight the key role of the effects induced by private consumption on the environmental burdens of services.     

Policy Frameworks Influencing Outdoor Water‐use Restrictions

Water‐use efficiency in the United States (U.S.) has improved in recent years. Yet continued population growth coupled with increasingly conservation‐oriented regulatory frameworks suggest that residential water suppliers will have to realize additional efficiency gains in coming decades. Outdoor water‐use restrictions (OWRs) appear to be an increasingly prevalent demand‐side management policy tool. To date little research has investigated the policy mechanisms that govern OWR adoption and influence the prevalence of OWRs. This article fills this gap with an assessment of state‐level policies influencing local‐level restrictions on residential outdoor water use in each of the 48 contiguous U.S. states, and with a detailed illustration of the cross‐scalar dynamic of one state's policy framework in practice. An examination of the implementation of OWRs in 24 neighboring towns in Massachusetts across the 2003‐2012 period indicates the interplay between state‐level and local‐level policies leads to OWRs implementation over extended time‐periods, even when drought conditions are not present. This finding suggests OWRs are being used as a tool for general‐purpose water conservation rather than as a stopgap measure justified by temporary water shortage conditions. Future research should investigate how local‐level water savings vary with differing state‐level approaches.     

WATER CONSTRAINTS ON ENERGY DEVELOPMENT: A FRAMEWORK FOR ANALYSIS1

ABSTRACT: The pressure on water resources from energy resource development and transformation is likely to be greater in the future than it has been in the past. A rational resolution of the political problems that this situation will generate requires that: 1) planning based on predictions of future energy supply and demand be replaced by scenario, or “what if?” analysis; 2) full attention be paid to the uncertainties in per-unit-energy water requirements; 3) suitable stochastic measures of water availability be used to compare water supply with water demand; 4) realistic ecological criteria, and other alternative use criteria, be developed for estimating impacts of water withdrawn or consurned for energy development; 5) human consequences of ecological impaccts are described in a manner that will allow the political process to intervene in an optimum manner to allocate water resources.     

THE ECONOMIC EFFECTS OF CHANGES IN WATER USE IN THE TUCSON BASIN,ARIZONA1

ABSTRACT: The ground water in the Tucson basin is being drawn faster than it is replenished by nature. The water table is falling, giving rise to several conflicts between water users in the basin. At present, several lawsuits are in progress, including an action by the Papago Tribe against some of the major water users in the basin. Largely because of these difficulties, the State Legislature has established a commission to make proposals for the reform of Arizona's ground water law. The pattern of water use in the basin will undoubtedly be changed by the outcome of the present litigation and the coming reform of Arizona's ground water law. This paper describes how water use in the basin might be affected by changes in the availability of water and gives an account of the effects that these changes in water use could have on the region's economy. The paper concludes that the water problems of the Tucson basin will have little effect on the region at large and that these problems are simply a matter for the Indians and the other water users in the basin to sort out amongst themselves.