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1.
Greenhouse gas (GHG) emission factors are used with increased frequency for the accounting and reporting of GHG from waste management. However, these factors have been calculated for developed countries of the Northern Hemisphere and are lacking for developing countries. This paper shows how such factors have been developed for the collection, transport and landfilling of municipal waste in South Africa. As such it presents a model on how international results and methodology can be adapted and used to calculate country-specific GHG emission factors from waste. For the collection and transport of municipal waste in South Africa, the average diesel consumption is around 5 dm3 (litres) per tonne of wet waste and the associated GHG emissions are about 15 kg CO2 equivalents (CO2 e). Depending on the type of landfill, the GHG emissions from the landfilling of waste have been calculated to range from ?145 to 1016 kg CO2 e per tonne of wet waste, when taking into account carbon storage, and from 441 to 2532 kg CO2 e per tonne of wet waste, when carbon storage is left out. The highest emission factor per unit of wet waste is for landfill sites without landfill gas collection and these are the dominant waste disposal facilities in South Africa. However, cash strapped municipalities in Africa and the developing world will not be able to significantly upgrade these sites and reduce their GHG burdens if there is no equivalent replacement of the Clean Development Mechanism (CDM) resulting from the Kyoto agreement. Other low cost avenues need to be investigated to suit local conditions, in particular landfill covers which enhance methane oxidation.  相似文献   

2.
Hydrocarbon biodegradation is an important process for remediating petroleum hydrocarbons and managing large sites. However, this biodegradation results in what are essentially unavoidable CO2 emissions to the atmosphere. A feasibility assessment was conducted to quantitatively consider reuse options for petroleum brownfields that would offset contaminant respiration emissions rates in the 2 to 10 micromoles CO2 per meters squared per second (μmol CO2 m?2 s?1) typically observed. Under a wide range of solar resource scenarios, placement of solar panels over only a fraction (no more than 35%) of the site footprint is estimated as necessary to achieve an emissions offset. Similarly, placement of one 30‐meter tall wind turbine of moderate rating (approximately 30 to 50 kW) is sufficient to provide an offset for a nominal 1,000 square meters site. For spreading of spent calcium‐rich construction materials, under even a high emissions scenario, the required footprint for the offset is less than the site footprint. While these approaches appear feasible, revegetation as forestland is estimated as sufficient only at contaminant respiration rates up to 2 μmol CO2 m?2 s?1. Revegetation as rangeland and cropland, which sequesters CO2 mainly in soil organic carbon, is estimated as requiring more than the site footprint under many contaminant respiration rates. Revegetation as a wetland fares slightly better from a carbon storage perspective, but it also has the potential for N2O and CH4 emissions that may largely undo the benefit from sequestration in soil organic matter. Overall, the results indicate several methods that are viable for achieving emissions offsets and a quantitation method that can be honed with site‐specific input parameters as appropriate.  相似文献   

3.
First, this paper evaluates the current building material stock and future demolition waste for urban residential buildings in the cities of Jakarta and Bandung using a material-flow analysis. The actual on-site building measurements were conducted in Jakarta (2012) and Bandung (2011), focusing particularly on unplanned houses, to obtain building material inventory data. A total of 297 houses were investigated in Jakarta, whereas 247 houses were measured in Bandung. Second, this paper analyses the embodied energy and CO2 emissions of building materials through an input–output analysis. The results show that, overall, the total material input intensity for the houses is 2.67 ton/m2 in Jakarta and 2.54 ton/m2 in Bandung. Two scenarios with zero and maximum reuse/recycling rates were designed to predict future demolition waste and the embodied energy/CO2 emissions of building materials in Jakarta. Closed- and open-loop material flows were applied. If the maximum reuse/recycling rates are applied to the closed- and open-loop material flows in Jakarta, then it would become possible to not only decrease the final disposal waste (from 123.9 to 2.1 million ton) but also reduce the corresponding embodied energy (from 247.8 to 192.1 PJ) and CO2 emissions (from 24.3 to 19.2 million ton CO2-eq) compared with the zero reuse/recycling scenario from 2012 to 2020.  相似文献   

4.
Determination of the amount of greenhouse gas (GHG) emitted during municipal solid waste incineration (MSWI) is complex because both contributions and savings of GHGs exist in the process. To identify the critical factors influencing GHG emissions from MSWI in China, a GHG accounting model was established and applied to six Chinese cities located in different regions. The results showed that MSWI in most of the cities was the source of GHGs, with emissions of 25–207 kg CO2-eq t?1 rw. Within all process stages, the emission of fossil CO2 from the combustion of MSW was the main contributor (111–254 kg CO2-eq t?1 rw), while the substitution of electricity reduced the GHG emissions by 150–247 kg CO2-eq t?1 rw. By affecting the fossil carbon content and the lower heating value of the waste, the contents of plastic and food waste in the MSW were the critical factors influencing GHG emissions of MSWI. Decreasing food waste content in MSW by half will significantly reduce the GHG emissions from MSWI, and such a reduction will convert MSWI in Urumqi and Tianjin from GHG sources to GHG sinks. Comparison of the GHG emissions in the six Chinese cities with those in European countries revealed that higher energy recovery efficiency in Europe induced much greater reductions in GHG emissions. Recovering the excess heat after generation of electricity would be a good measure to convert MSWI in all the six cities evaluated herein into sinks of GHGs.  相似文献   

5.
Increased energy consumption due to industrial growth has increased the levels of carbon dioxide (CO2) emission being released into the atmosphere. CO2 emission is a type of greenhouse gas which is a major cause of global warming. Since the issue of CO2 emissions has drawn much attention in recent years, the development of CO2 capture technology has become a necessity. Although CO2 adsorbents are still at the early development stage, it has been suggested that CO2 adsorbents are the most effective technology in controlling CO2 emissions. Solid adsorbents have great potential as an alternative method to conventional adsorbents in adsorbing CO2. In this paper, low cost adsorbents including activated carbon, zeolites, mesoporous silica and clays are discussed in terms of adsorbent preparation methods and CO2 adsorption capacity. The low cost adsorbents are mainly derived from waste materials such as fly ash, steel slag, red mud, bagasses wastes and wood wastes. Besides that, natural resources such as clays have also been applied as low cost CO2 adsorbents. Surface modifications have also been applied to the low cost adsorbents, including metal ion exchange and amine impregnation to enhance CO2 adsorption capacity. In the last section, the current status of CO2 adsorbents is summarized and future trends are discussed briefly to predict the potential materials which can be applied as CO2 adsorbents.  相似文献   

6.
We utilize life cycle assessment to trace conversion of degradable organic carbon (DOC) contained in organic waste from city markets in Da Nang, Vietnam. Our methodology makes explicit the process of conversion of DOC under aerobic and anaerobic conditions, as well as the balance of nutrients. Greenhouse gas emissions were calculated for six alternative scenarios: (i) anaerobic landfilling (current situation); (ii) semi-aerobic landfilling; (iii) landfill gas capture; (iv) composting; (v) pre-composting before landfill; and (vi) biogas production. We calculate that 1 t of waste in anaerobic landfilling emits 1.70 t CO2-eq. with life-cycle perspective. Lowest emission occurs in biogas scenario with 0.26 t CO2-eq./t. Composting occupies an intermediate position with 0.39 t CO2-eq./t. Likewise, we estimate that cost of emission reduction in solid waste sector of Vietnam is 15.13 US$/t CO2-eq., given by alternative of composting and taking anaerobic landfilling as reference. On the other hand, if social cost of carbon (SCC) is incorporated lowest cost to treat 1 t of waste is given by composting and semi-aerobic landfilling at discount rate of 5 %. However, using lower discount rates, and consequently higher values of SCC, composting and biogas production become the alternatives with lowest treatment costs.  相似文献   

7.
Risk assessment of two sections (I and II) of an old landfill (ALH) in Styria (Austria) in terms of reactivity of waste organic matter and the related potential of gaseous emissions was performed using conventional parameters and innovative tools to verify their effectiveness in practice. The ecological survey of the established vegetation at the landfill surface (plant sociological relevés) indicated no relevant emissions over a longer period of time. Statistical evaluation of conventional parameters reveals that dissolved organic carbon (DOC), respiration activity (RA4), loss of ignition (LOI) and total inorganic carbon (TIC) mostly influence the variability of the gas generation sum (GS21). According to Fourier Transform Infrared (FT-IR) spectral data and the results of the classification model the reactivity potential of the investigated sections is very low which is in accordance with the results of plant sociological relevés and biological tests. The interpretation of specific regions in the FT-IR spectra was changed and adapted to material characteristics. Contrary to mechanically–biologically treated (MBT) materials, where strong aliphatic methylene bands indicate reactivity, they are rather assigned to the CH vibrations of plastics in old landfill materials. This assumption was confirmed by thermal analysis and the characteristic heat flow profile of plastics containing landfill samples. Therefore organic carbon contents are relatively high compared to other stable landfills as shown by a prediction model for TOC contents based on heat flow profiles and partial least squares regression (PLS-R). The stability of the landfill samples, expressed by the relation of CO2 release and enthalpies, was compared to unreactive landfills, archeological samples, earthlike materials and hardly degradable organic matter. Due to the material composition and the aging process the landfill samples are located between hardly degradable, but easily combustible materials and thermally resistant materials with acquired stability.  相似文献   

8.
CO2-loads from combustible waste are important inputs for national CO2 inventories and life-cycle assessments (LCA). CO2 emissions from waste incinerators are often expressed by emission factors in kg fossil CO2 emitted per GJ energy content of the waste. Various studies have shown considerable variations between emission factors for different incinerators, but the background for these variations has not been thoroughly examined. One important reason may be variations in collection of recyclable materials as source separation alters the composition of the residual waste incinerated. The objective of this study was to quantify the importance of source separation for determination of emission factors for incineration of residual household waste. This was done by mimicking various source separation scenarios and based on waste composition data calculating resulting emission factors for residual waste routed to incineration. Emission factors ranged from 27 to 40 kg CO2/GJ. The results appeared most sensitive towards variations in waste composition and water content. Recycling rates and lower heating values could not be used as simple indicators of the resulting emission factors for residual household waste; however the fossil carbon ratio of the waste after source separation was found to be appropriately correlated with the emission factor. Based on the results, it is recommended to carefully evaluate the source separation and collection systems behind reported literature values when comparing different studies and when using the values for environmental assessment purposes.  相似文献   

9.
In recent years thermal utilization of mixed wastes and solid recovered fuels has become of increasing importance in European waste management. Since wastes or solid recovered fuels are generally composed of fossil and biogenic materials, only part of the CO2 emissions is accounted for in greenhouse gas inventories or emission trading schemes. A promising approach for determining this fraction is the so-called radiocarbon method. It is based on different ratios of the carbon isotopes 14C and 12C in fossil and biogenic fuels. Fossil fuels have zero radiocarbon, whereas biogenic materials are enriched in 14C and reflect the 14CO2 abundance of the ambient atmosphere. Due to nuclear weapons tests in the past century, the radiocarbon content in the atmosphere has not been constant, which has resulted in a varying 14C content of biogenic matter, depending on the period of growth. In the present paper 14C contents of different biogenic waste fractions (e.g., kitchen waste, paper, wood), as well as mixtures of different wastes (household, bulky waste, and commercial waste), and solid recovered fuels are determined. The calculated 14C content of the materials investigated ranges between 98 and 135 pMC.  相似文献   

10.
A process model of municipal solid waste incinerators (MSWIs) and new technologies for metal recovery from combustion residues was developed. The environmental impact is modeled as a function of waste composition as well as waste treatment and material recovery technologies. The model includes combustion with a grate incinerator, several flue gas treatment technologies, electricity and steam production from waste heat recovery, metal recovery from slag and fly ash, and landfilling of residues and can be tailored to specific plants and sites (software tools can be downloaded free of charge). Application of the model to Switzerland shows that the treatment of one tonne of municipal solid waste results on average in 425 kg CO2-eq. generated in the incineration process, and 54 kg CO2-eq. accrue in upstream processes such as waste transport and the production of operating materials. Downstream processes, i.e. residue disposal, generates 5 kg CO2-eq. Savings from energy recovery are in the range of 67 to 752 kg CO2-eq. depending on the assumptions regarding the substituted energy production, while the recovery of metals from slag and fly ash currently results in a net saving of approximately 35 kg CO2-eq. A similar impact pattern is observed when assessing the MSWI model for aggregated environmental impacts (ReCiPe) and for non-renewable resource consumption (cumulative exergy demand), except that direct emissions have less and no relevance, respectively, on the total score. The study illustrates that MSWI plants can be an important element of industrial ecology as they provide waste disposal services and can help to close material and energetic cycles.  相似文献   

11.
The management of greenhouse gases (GHGs) emissions is currently a very important environmental issue. Mega-event organizers and host cities have attached great importance to GHGs emissions associated with event-related activities. However, GHGs emissions from event solid waste have never been thoroughly discussed. This study investigated GHGs emissions of major event’s solid waste using life cycle assessment, based on Shanghai Expo case. The results showed that GHGs from collecting and sorting, transportation and landfill treatment amount to 9790 t CO2e. And the emission intensity is estimated to be 134 g CO2e per event service. GHGs reduction from recycling amounts to 48 kt CO2e, with 78 % of these the result of construction waste recycle. It illustrates that waste recycle plays a vital role in GHGs mitigation. Finally, the study suggests that the concept of waste avoidance, waste reuse and waste recycle is an effective waste management to mitigate climate change and should be implemented in major event to achieve the goal of green event.  相似文献   

12.
This paper analyzes the amount and characteristics of municipal solid waste (MSW) according to the inhabitant density of population and the business concentration in 25 districts in Seoul. Further, the heat energy recovery and avoided CO2 emissions of four incineration plants located in residential and commercial areas in Seoul are examined. The amount of residential waste per capita tended to increase as the density of inhabitants decreased. The amount of commercial waste per capita tended to increase as the business concentration increased. The examination of the heat energy recovery characteristics indicated that the four incineration plants produced heat energy that depended on residential or commercial areas based on population and business. The most important result regarding avoided CO2 emissions was that commercial areas with many office-type businesses had the most effective CO2 emission savings by combusting 1 kg of waste. Assuming the full-scale operation of the four incineration plants, the amount of saved CO2 emissions per year was 444 Gg CO2 and 57,006 households in Seoul can be provided with heat energy equivalent to 542,711 Nm3 of LNG.  相似文献   

13.
In this study, we propose a process making calcium carbonate and calcium sulfate and recovering absorbent using ammonia absorbent, carbon dioxide, and industrial waste. The main objective of this study is to confirm the possibility of carbon capture and utilization based on waste materials. We assumed desulfurization gypsum and construction waste (ready mixed concrete washing water, waste concrete, etc.) are CaSO4, Ca(OH)2, respectively. And concentration of simulated carbon dioxide gas was 15 vol% similar to flue gas. Calcium carbonate was produced by combination reaction between ionic CO2 in absorbent and metal ion in the solid waste. Experiments were conducted at normal temperature and pressure. Furthermore, the generated products were characterized by X-ray diffraction, and scanning electron microscope.  相似文献   

14.
Mechanical–biological treatments (MBTs) of urban waste are growing in popularity in many European countries. Recent studies pointed out that their contribution in terms of volatile organic compounds (VOCs) and other air pollutants is not negligible. Compared to classical removal technologies, non-thermal plasmas (NTP) showed better performances and low energy consumption when applied to treat lowly concentrated streams. Therefore, to study the feasibility of the application of NTP to MBTs, a Dielectric Barrier Discharge reactor was applied to treat a mixture of air and methyl ethyl ketone (MEK), to simulate emissions from MBTs. The removal efficiency of MEK was linearly dependent upon time, power and specific input energy. Only 2–4% of MEK was converted to carbon dioxide (CO2), the remaining carbon being involved in the formation of byproducts (methyl nitrate and 2,3-butanedione, especially). For future development of pilot-scale reactors, acting on residence time, power, convective flow and catalysts will help finding a compromise between energy consumption, desired abatement and selectivity to CO2.  相似文献   

15.
The greenhouse gases (GHGs) generated in municipal solid waste (MSW) incineration are carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O). In South Korea case, the total of GHGs from the waste incineration facilities has been increasing at an annual rate 10%. In these view, waste incineration facilities should consider to reduce GHG emissions.This study is designed to estimate the N2O emission factors from MSW incineration plants, and calculate the N2O emissions based on these factors. The three MSW incinerators examined in this study were either stoker or both stoker and rotary kiln facilities. The N2O concentrations from the MSW incinerators were measured using gas chromatography-electron capture detection (GC-ECD) equipment.The average of the N2O emission factors for the M01 plant, M02 plant, and M03 plant are 71, 75, and 153 g-N2O/ton-waste, respectively. These results showed a significant difference from the default values of the intergovernmental panel on climate change (IPCC), while approaching those values derived in Japan and Germany. Furthermore, comparing the results of this study to the Korea Energy Economics Institute (KEEI) (2007) data on waste incineration, N2O emissions from MSW incineration comprised 19% of the total N2O emissions.  相似文献   

16.
The municipal solid waste management significantly contributes to the emission in the atmosphere of greenhouse gases (e.g. CO2, CH4, N2O) and therefore the management process from collection to treatment and disposal has to be optimized in order to reduce these emissions. In this paper, starting from the average composition of undifferentiated municipal solid waste in Italy, the effect of separate collection on greenhouse gases emissions from municipal waste management has been assessed. Different combinations of separate collection scenarios and disposal options (i.e. landfilling and incineration) have been considered. The effect of energy recovery from waste both in landfills and incinerators has also been addressed. The results outline how a separate collection approach can have a significant effect on the emission of greenhouse gases and how wise municipal solid waste management, implying the adoption of Best Available Technologies (i.e. biogas recovery and exploitation system in landfills and energy recovery system in Waste to Energy plants), can not only significantly reduce greenhouse gases emissions but, in certain cases, can also make the overall process a carbon sink. Moreover it has been shown that separate collection of plastic is a major issue when dealing with global warming relevant emissions from municipal solid waste management.  相似文献   

17.
Most of the standardized biodegradation tests used to assess the ultimate biodegradation of environmentally degradable polymers are based solely on the determination of net evolved carbon dioxide. However, under aerobic conditions, it has to be considered that heterotrophic microbial consortia metabolize carbon substrates both to carbon dioxide and in the production of new cell biomass. It is generally accepted that in the relatively short term, 50% of the carbon content of most organic substrates is converted to CO2, with the remaining carbon being assimilated as biomass or incorporated into humus. The latter is particularly important when the metabolism of the organic matter occurs in a soil environment. A straightforward relationship between the free-energy content of a carbon substrate (expressed as the standard free-energy of combustion) and its propensity for conversion to new microbial biomass rather than mineralization to CO2 has been established. This can potentially lead to underestimation of biodegradation levels of test compounds, especially when they consist of carbon in a fairly low formal oxidation state and relatively high free-energy content. In the present work, the metabolism of different kind of carbon substrates, especially in soil, is reviewed and compared with our own experimental results from respirometric tests. The results show that conversion of highly oxidized materials, such as the commonly used reference materials, cellulose or starch, to CO2 may be significantly overestimated. The addition of glucosidic material to soil leads to greatly increased respiration and is accompanied by a very low conversion to biomass or humic substances. In contrast, relatively less oxidized substrates metabolize more slowly to give both CO2 and biomass to an extent which may be significantly underestimated if glucosidic materials are used as the reference. The need for an overall carbon balance taking into account both the carbon immobilized as biomass and that volatized as CO2 must be considered in standard respirometric procedures for assessing the biodegradability of slowly degrading macromolecules.  相似文献   

18.
Climate change has become an important political priority in the environmental field, and beyond. To revert the increase in the Earth’s temperature, developed country parties to the Kyoto Protocol committed to limit their greenhouse gas emissions. The 15 Member States that made up the European Community in 1997 have a combined reduction target of 8% in CO2-equivalent emissions in the period 2008–2012 compared to 1990. The role of soil, both as a source and a sink for carbon, is particularly important. How can soil organic matter be maintained or increased? There is no single answer, and a broad range of options need to be explored. Among the different measures proposed, the promotion of organic input on arable land (crop residues, cover crops, farm yard manure, compost, sewage sludge) has been mentioned. The challenge is to ensure that organic wastes of good quality are used to increase soil organic matter in carbon depleted soils and that appropriate monitoring is established. On the waste management front, the European Commission intends to produce guidance for Member States on the management of biowaste that will take into account all related environmental issues, including soil aspects. As for monitoring, the European Commission has put forward legislation according to which Member States would have to identify the areas at risk of soil organic matter decline in their national territory. Such legislation should be regarded as a major step forward for Europe, as it would ensure a high level of soil protection across the Community. This development will have the potential to enable the kind of estimation, measurement or modelling of crop or grazing land management needed for accounting under Article 3.4 of the Kyoto Protocol.  相似文献   

19.
Environmental impacts associated to different waste treatments are of interest in the decision-making process at local, regional and international level. However, all the environmental burdens of an organic waste biological treatment are not always considered. Real data on gaseous emissions released from full-scale composting plants are difficult to obtain. These emissions are related to the composting technology and waste characteristics and therefore, an exhaustive sampling campaign is necessary to obtain representative and reliable data of a single plant. This work proposes a methodology to systematically determine gaseous emissions of a composting plant and presents the results obtained in the application of this methodology to a plant treating source-separated organic fraction of municipal solid waste (OFMSW) for the determination of ammonia and total volatile organic compounds (VOC). Emission factors from the biological treatment process obtained for ammonia and VOC were 3.9 kg Mg OFMSW−1 and 0.206 kg Mg OFMSW−1 respectively. Emissions associated to energy use and production were also quantified (60.5 kg CO2 Mg OFMSW−1 and 0.66 kg VOC Mg OFMSW−1). Other relevant parameters such as energy and water consumption and amount of rejected waste were also determined. A new functional unit is presented to relate emission factors to the biodegradation efficiency of the composting process and consists in the reduction of the Respiration Index of the treated material. Using this new functional unit, the atmospheric emissions released from a composting plant are directly related to the plant specific efficiency.  相似文献   

20.
Affected energy production is often decisive for the outcome of consequential life-cycle assessments when comparing the potential environmental impact of products or services. Affected energy production is however difficult to determine. In this article the future long-term affected energy production is identified by use of energy system analysis. The focus is on different uses of waste for energy production. The Waste-to-Energy technologies analysed include co-combustion of coal and waste, anaerobic digestion and thermal gasification. The analysis is based on optimization of both investments and production of electricity, district heating and bio-fuel in a future possible energy system in 2025 in the countries of the Northern European electricity market (Denmark, Norway, Sweden, Finland and Germany). Scenarios with different CO2 quota costs are analysed. It is demonstrated that the waste incineration continues to treat the largest amount of waste. Investments in new waste incineration capacity may, however, be superseded by investments in new Waste-to-Energy technologies, particularly those utilising sorted fractions such as organic waste and refuse derived fuel. The changed use of waste proves to always affect a combination of technologies. What is affected varies among the different Waste-to-Energy technologies and is furthermore dependent on the CO2 quota costs and on the geographical scope. The necessity for investments in flexibility measures varies with the different technologies such as storage of heat and waste as well as expansion of district heating networks. Finally, inflexible technologies such as nuclear power plants are shown to be affected.  相似文献   

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