黄河口的水质、底质污染及其变化

分析了2001年在黄河口附近所取的3处水样和3处泥样中污染物的含量,并与历史数据进行了比较.利用<地表水环境质量标准>(GB3838-2002)和美国国家海洋大气管理局(NOAA)水体泥沙质量标准等分别对水体和底泥中的重金属(砷)和氮磷污染进行了评价.认为黄河口的水污染严重,主要污染物为汞和氮;泥沙污染尚不严重,但污染物的增长率高;水体中较高的氮含量和泥沙中氮含量的迅速增高可能会对渤海湾的富营养化情况产生影响.     

黄河、海河和辽河水体中3种常用除草剂的分布特征

系统研究了黄河、海河和辽河中3种常用除草剂 MCPA、2,4-D 和 Bentazone 的分布特征及其来源。结果表明,3种除草剂除 Bentazone在黄河水体中未检出外,其余均有检出。季节和空间分析表明,大部分目标物丰水期质量浓度高于枯水期,可能与夏季农作物除草剂使用量较大有关;从上游到下游化合物质量浓度逐渐升高,可能是河岸面源污染引起。水生态风险初步分析显示,3种除草剂对研究水体中的水生生物均为低风险。     

Contamination of Oxygen-Consuming Organics in the Yellow River of China

Contamination of oxygen-consuming organics (OCOs) was one of the most serious problems in the Yellow River of China. This study was conducted to analyze monitoring of the data on OCOs contamination for the river in 1980 and during 1992–1999 as well as examining the effect of suspended solids (SS) on chemical oxygen demand (COD_Mn) and biochemical oxygen demand (BOD₅) of river water. Several significant results have arisen from the study. First, COD_Mn and BOD₅ of the river water showed an increasing trend from the upper to the lower reaches of the mainstream. BOD₅ values of river water in 1992 were significantly higher than those in 1980 and showed an increasing trend during 1992–1999. Second, OCOs in river water of the mainstream was attributed mainly to point sources; the ratio of point to non-point sources of BOD₅ was about 2.81. The load from point sources showed an increasing trend during 1992–1998. In contrast, the load from non-point sources manifested a decreasing trend during this period; this was caused by the decreasing trend of SS content in river water. The total load of BOD₅ from point and non-point sources displayed an increasing trend during 1992–1998. Third, as the humic substances in SS can hardly be biologically oxidized in natural conditions but can be oxidized by chemical oxidants such as potassium permanganate, COD_Mn was not suitable for being regarded as a parameter reflecting the pollution degree of OCOs in river water with a high SS content.     

黄河多泥沙水体油污染物的测定

研究了石油醚的吸收光谱 ,分析了泥沙对紫外分光光度法测定油污染物的影响 ,探讨了消除泥沙影响的方法 ,提出了紫外分光光度法测定黄河多泥沙水体中油污染物的改进方法。     

黄河流域水质和工业污染源研究

为科学评价黄河流域的水质状况及工业企业污染源现状,根据黄河流域2018—2019年地表水和饮用水水源地水质监测数据,建立了综合反映流域水环境质量和可定量分析排名的城市水质指数;利用大数据技术分析工业企业水污染物排放数据,研究建立了企业环境信用动态评价体系。研究结果表明:2018—2019年,黄河流域城市水环境质量得到一定程度的改善,城市地表水环境质量优和良等级数量从17个增加到19个,饮用水水源地优等级城市数量从7个增加到11个;但黄河流域中游地区水污染问题较为严重,需要重点加强水污染控制。水质污染主要以点源工业污染为主,COD和氨氮排放量较多,COD和氨氮年日均排放浓度平均值分别为51.1、3.1 mg/L,工业废水处理率偏低;山西、陕西、河南等"高"风险企业数量较多,分别达到3 047、1 630、1 442家。建议加强黄河流域上下游、左右岸、干支流协同配合,加大水污染防治工作的深度和力度。     

黄河呼和浩特段水环境质量时空变化分析

水环境质量评价是水资源可持续利用的重要前提,同时也是水环境管理与治理决策的重要依据。为科学评价黄河呼和浩特段水环境质量,基于基础资料数据库,遵循全面性、区域性、易量化性等原则,采用综合污染指数法详细分析了黄河呼和浩特段水环境质量的时空变化情况,进一步揭示了2020年水质季节变化规律,并对主要超标因子进行了深度解析。结果表明：随着一系列环境保护政策和管理措施的实施,2015—2020年黄河呼和浩特段水环境质量综合指数下降了75.87%。在时间尺度上,各断面的水环境质量综合指数平均值由2015年的93.81下降至2020年的22.64,整体水环境质量评价等级由G4转为G2,对应的水环境质量状况由中度污染转为较好;在空间尺度上,上游水环境质量优于下游,城区段水环境质量较差。此外,评价结果显示,部分水体当前仍存在氨氮超标问题。评价结果较为客观地反映了黄河呼和浩特段的水环境质量,可为水环境管理提供决策依据。     

基于实测光谱的海河悬浮物浓度反演研究

悬浮物浓度是评价水质优劣的重要指标之一。以天津滨海新区海河为研究区域,进行光谱数据测量和水体样本采集,并在实验室进行水质参数提取,得到归一化光谱反射率和光谱一阶微分数据。然后对光谱测量数据和悬浮物浓度实测值进行相关性分析,发现896 nm归一化光谱反射率和光谱反射率比值(R_(896)/R_(546))与悬浮物浓度相关性较好。最后,分别建立单波段、波段比值和一阶微分函数拟合模型,进行对比分析。结果表明,基于R_(896)/R_(546)的二次多项式模型拟合效果最好,方差齐性检验(F)值也是最高的,可用于该地区水体的悬浮物浓度反演和预测。     

Distribution of PAEs in the middle and lower reaches of the Yellow River, China

Samples of water, sediment and suspended particulates were collected from 13 sites in the middle and lower reaches of the Yellow River in China. Phthalic acid esters (PAEs) concentrations in different phases of each sample were determined by Gas Chromatogram GC-FID. The results are shown as follows: (1) In the Xiao Langdi–Dongming Bridge section, PAEs concentrations in water phase from the main river ranged from 3.99 × 10⁻³ to 45.45 × 10⁻³ mg/L, which were similar to those from other rivers in the world. The PAEs levels in the tributaries of the Yellow River were much higher than those of the main river. (2) In the studied branches, the concentration of PAEs in sediment for Luoyang Petrochemical Channel (331.70 mg/Kg) was the highest. The concentrations of PAEs in sediment phase of the main river were 30.52 to 85.16 mg/Kg, which were much higher than those from other rivers in the world. In the main river, the concentration level of PAEs on suspended solid phases reached 94.22 mg/Kg, and it reached 691.23 mg/Kg in the Yiluo River – one tributary of the Yellow River. (3) Whether in the sediment or on the suspended solid phases, there was no significant correlation between the contents of PAEs and TOC or particle size of the solid phase; and the calculated Koc of Di (2-Ethylhexyl) Phthalate (DEHP) in the river were much less than the theoretical value, which inferred that PAEs were not on the equilibrium between water and suspended solid phases/sediment. (4) Among the measured PAEs compounds, the proportions of DEHP and di-n-butyl phthalate (DBP) were much higher than the others. The concentrations of DEHP exceeded the Quality Standard in all the main river and tributary stations except those in the Mengjin and Jiaogong Bridge of the main river. This indicates that more attention should be paid to pollution control and further assessment in understanding risks associated with human health.     

2001-2015年松花江流域水污染变化特征研究

利用2001-2015年松花江流域国家监测网30个可比断面监测数据,从流域和断面水质变化、各项指标超标情况和浓度变化、污染负荷等方面分析了松花江流域水质变化情况。结果表明,松花江流域水质总体呈好转趋势,特别是2007年以来有比较明显的改善。该流域长期以来主要污染指标为高锰酸盐指数、石油类、五日生化需氧量和氨氮。高锰酸盐指数、石油类和五日生化需氧量污染均有明显改善,但氨氮污染改善不明显。在继续加强COD排放总量控制的基础上,有效削减氨氮排放是促进松花江水质改善的重点。     

基于“哨兵3号”卫星OLCI影像和C2RCC算法的南黄海叶绿素a及总悬浮物反演效果分析

利用遥感数据处理软件SNAP中基于神经网络技术的C2RCC算法,对2019年5月9日南黄海“哨兵3号”卫星OLCI影像数据进行了叶绿素a及总悬浮物浓度反演,将其与5月间江苏省海洋环境监测预报中心的海水表层叶绿素a和悬浮物实测数据进行了比较分析。结果表明,叶绿素a的遥感反演尚未能达到业务化应用,总悬浮物遥感反演结果的空间分布与实测值的一致性相对较好。但在星地同日或相差一天监测的南通海域,遥感反演叶绿素a浓度的空间分布趋势以及总悬浮物遥感反演结果与海面实测结果的一致性较好,可达到一定的业务化应用效果。     

三江源畜牧业示范区土壤重金属含量特征及评价

为了明确三江源智慧生态畜牧业示范区内土壤重金属元素含量特征及潜在风险,2015年7月在三江源智慧生态畜牧业示范区11个示范村镇进行土壤样品采集,带回实验室分析Pb、Cd、Hg、Cr、Cu、Zn、Ni含量。对数据进行统计分析并采用内梅罗综合污染指数和生态危害指数进行风险等级评价。结果显示:部分采样点重金属元素含量高于青海省背景值;Pb、Cr、Cu、Zn、Ni主要受土壤母质的影响,Cd受自然和人为因素的双重影响,Hg主要受人为因素影响;内梅罗综合污染指数显示11个点位的指数都小于1,该地未出现污染状况;生态危害指数显示除GMY点位处于轻微风险等级,其余采样点为中等风险等级。总体上示范区内土壤未出现强污染和面源污染状况,但需要加强点源污染的风险防范。     

以北运河（北京段）为例模拟评估北京市“水十条”水质改善效果

基于MIKE11构建北运河(北京段)一维水质模型,以氨氮、COD为目标污染物,建立污染源与水质响应关系。以2013年为基准年,考虑不同人口疏解情景预测2020年北运河(北京段)流域人口,并结合北京市"水十条"设置减排情景方案,对2020年水质改善效果进行量化评估。模拟结果表明:北京市"水十条"可实现显著的水质改善效果,到2020年,在中人口疏解方案下,北运河氨氮、COD平均质量浓度相比2013年分别下降40.8%~77.7%、39.3%~59.7%。COD质量浓度可稳定达标,氨氮质量浓度离达标还有一定差距,但日浓度可稳定在8mg/L以下,基本消除了黑臭水体。     

城市生活污染对浏阳河长沙城区段水质的影响

对浏阳河长沙城区段的水质现状和污染来源进行了调查。结果表明,浏阳河河水流经长沙城区后,氨氮和总磷浓度分别升高了9.49倍和7.75倍,但铁、锰和高锰酸盐指数等其他监测指标无显著变化。浏阳河长沙城区段的污染主要是由于区域内生活污水直接排入和污水处理厂尾水排入导致清污比例严重失调引起的,城市生活污染对浏阳河长沙城区段水质下降的贡献最大。此外,湘江长沙综合枢纽工程库区回水的顶托作用对浏阳河长沙城区段水质也有一定影响。     

水生态环境质量评价方法及在黄河流域的应用进展

开展水生态环境质量评价方法研究,建立合适的河流健康评价体系是解决河流健康问题的前提和实现河流健康管理的重要手段。黄河自上而下生态环境现状迥异,水生态环境脆弱,寻求一种或多种适合黄河流域水生态环境质量的评价方法具有重要意义。该文介绍了国内外水生态环境质量评价方法及在黄河流域的应用进展,总结了鱼类生物完整性指数(F-IBI)、底栖无脊椎动物完整指数(B-IBI)、着生藻类生物完整性指数(P-IBI)及水生态环境质量综合评价法的主要指标,以及黄河流域不同区域生物种类的评价指标,分析了各评价方法优缺点及应用范围,并根据目前研究基础评述了黄河流域水生态环境质量评价存在的问题,对黄河流域水生态环境质量评价方法、指示生物的选择及水生态环境质量综合评价法的研究等提出了具体建议。     

黄河流域水生生物资源评估及问题诊断

近几十年来,随着全球气候的变化和社会经济的发展,受筑坝建闸、河道断流、水质恶化、酷渔滥捕、人工引种、海水入侵、调水调沙等因素影响,黄河流域水生生物多样性及资源量呈下降趋势。在目前流域内多目标同步推进的要求下,黄河流域生态保护和高质量发展正不断面临新的挑战。通过分析黄河流域水生生物多样性和资源量在时空分布上的演变规律,明确了是水资源短缺、工程建设、水环境恶化等因素的共同作用导致了黄河流域的水生态危机。基于绿色生态、高质量发展的科学管理理念,提出了新时代黄河流域水文-环境-生态协同保护与修复的发展策略,为促进黄河流域水资源保护和生态系统可持续发展提供数据支持与理论参考。     

黄河流域甘肃段面源污染估算与空间分析

采用遥感分布式面源污染评估模型（DPeRS）,对2018年黄河流域(甘肃段)面源污染空间分布特征进行分析,具体包括多类型污染量产排特征解析和流域优先管控单元识别。结果表明,污染量上,2018年黄河流域（甘肃段）总氮(TN)、总磷(TP)、氨氮(NH₃^-N)、化学需氧量(COD_Cr)的面源污染排放负荷分别为65.6,11.8,19.1和77.2 kg/km²,入河量分别为836.7,33.3,220.2和1 353.3 t;空间分布上,氮型(TN和NH₃^-N)排放负荷高值区主要分布在流域中部和东部局部地区,流域大部分地区TP排放负荷均较高,COD_Cr面源污染排放负荷高值区分布较为零散。与排放负荷相比,黄河流域（甘肃段）面源污染入河负荷并不突出,这与该地区水资源量少有密切关系。筛选出黄河流域（甘肃段）面源污染优先控制单元15个,面积占比为85.2%,I类优控单元主要分布在庆阳市、天水市、兰州市和白银市等地区,II类优控单元主要分布在甘南藏族自治州,且TN、TP、NH₃^-N和COD_Cr面源污染优控单元识别结果的平均精度达到80%。     

Contaminants-Induced Oxidative Damage on the Carp Cyprinus carpio Collected from the Upper Yellow River, China

The Yellow River, the second largest river in China, is the most important resource of water supply in North China. In the last 40 years, even in the upper Yellow River, with the development of industry and agriculture, more and more contaminants have been discharged into this river and greatly polluted the water. Although a routine chemical component analysis has been performed, little is known about the real toxic effects of the polluted water on organisms at environmental level. To explore whether the pollutants induced oxidative stress and damage to aquatic organisms, malondialdehyde (MDA) level and activities of superoxide dismutase (SOD), catalase (CAT), glutathione peroxidase (GPx) and glutathione S-transferase (GST) in hepatopancreas, kidney and intestine of the field-collected carp Cyprinus carpio from a mixed polluted (Lanzhou Region, LZR) and a relatively unpolluted (Liujiaxia Region, LJXR) sites of the upper Yellow River were measured. The results showed that when the values of LZR compared with those of LJXR, SOD and GST activities increased and GPx activity decreased significantly in all the three organs (P < 0.05–0.01); CAT activity decreased but MDA level increased significantly (P < 0.05–0.01) only in kidney and intestine. In conclusion, the results of this study suggest that the pollutants can induce obvious oxidative damage in the carp, and the SOD, GST and GPx might be better indicators for the oxidative damage in aquatic organisms.     

广西贝江大型底栖动物群落结构时空分布特征

为了解贝江大型底栖动物群落结构特征并对其水质进行生物学评价,于2015年1、8月对贝江流域17个采样点进行了调查,共采集大型底栖动物146个分类单元,隶属于8纲20目52科,其中昆虫纲所占比例最高(86.99%),软体动物次之(6.16%)。贝江底栖动物群落结构存在季节性差异,群落数量特征和结构复杂性均表现为冬季>夏季。无度量多维标定排序和ANOSIM分析发现,贝江流域冬季和夏季底栖动物群落组成存在显著差异(r=0.26,P<0.001)。群落相似性分析表明,贝江底栖动物存在显著的空间差异,整个流域可以分为2组,组1基本分布在自然河段,组2主要包括电站采样点和贝江下游采样点,各组间差异显著(P<0.01)。底栖动物功能摄食类群以集食者(55%)和撕食者为主(16%),其次为滤食者(14%)和捕食者(11%),刮食者(4%)所占比例较小。水质评价结果显示,Shannon-Wiener生物多样性指数(H′)评价贝江水质为轻污-清洁。Hilsenhoff生物指数(BI)评价贝江流域水质属于清洁,与实际水质情况最接近。总体上,贝江流域自然河段底栖动物群落结构复杂多样,整体水质清洁。     

Distribution and partitioning of trace metals in sediments of the lower reaches of the New Calabar River,Port Harcourt,Nigeria

The distribution of trace metals in sediments of the lower reaches of the New Calabar River, Nigeria was evaluated togetherwith the partitioning of their chemical species between fivegeochemical phases. Samplings were made in five zones at the lower reaches of the New Calaber River. All the trace metals were determined by AAS after selective chemical extractions andconcentrations given in g gm^-1 (dry weight basis). The average totalconcentrations found for trace metals in the sediment were (mean ± rsd.) Pb: 41.6 ± 0.29, Zn: 31.60 ± 0.42, Cd: 12.80 ± 0.92, Co: 92 ± 0.25, Cu: 25.5 ± 0.65 and Ni: 3.2 ± 0.25. Maxima and minima concentrations are inconsistent with previous studies in other rivers of this region. Spatial distribution revealed that the sources of trace metals into theriver appeared to be of non-point. Five contamination indices were applied in studying the partitioning of the trace metals inthe sediment. These indices provided bases for ascertaining the potential environmental risk of trace metals in the river system.The results denote high partition levels in the more mobile andmore dangerous phases.     

污染治理前后小清河上游浮游植物群落变化与水质评价

为研究小清河污染治理前后浮游植物群落与水质变化,分别于2015年(治理前)和2020年(治理后)在小清河上游进行采样调查。调查结果显示,2015年样品中共检出浮游植物6门35种,2020年样品中共检出4门31种。配对样本t检验结果显示,污染治理前后的浮游植物种类、密度都发生了显著改变。相比治理前,治理后的硅藻门和绿藻门相对丰度分别上升了51.6个百分点和13.3个百分点,蓝藻门下降了62.9个百分点,小环藻(Cyclotella spp.)取代微囊藻(Microcysitis spp.)成为绝对优势种,群落类型由蓝藻型演替为硅藻型。相似性分析结果和相似度百分比分析结果表明,小清河上游群落特征发生显著改变。非度量多维标度分析结果显示,治理后的S2与S3采样点群落特征表现出差异,S4与S1采样点群落特征相似。通过冗余分析发现,治理后,TP、DO对浮游植物群落的影响明显减弱,TN、NH₃-N、pH是目前影响群落特征的主要指标,主城区氮磷污染对浮游植物的影响范围由S2、S3、S4采样点缩小到S2采样点。治理前后的小清河上游Shannon-Wiener多样性指数、Pielou均匀度指数和Marglef丰富度指数存在显著差异。总体来看,治理后的小清河上游水质处于α-中污染状态,较治理前有明显改善。