Evaluating factors influencing groundwater vulnerability to nitrate pollution: developing the potential of GIS

The 1991 EU Nitrate Directive was designed to reduce water pollution from agriculturally derived nitrates. England and Wales implemented this Directive by controlling agricultural activities within their most vulnerable areas termed Nitrate Vulnerable Zones. These were designated by identifying drinking water catchments (surface and groundwater), at risk from nitrate pollution. However, this method contravened the Nitrate Directive because it only protected drinking water and not all waters. In this paper, a GIS was used to identify all areas of groundwater vulnerable to nitrate pollution. This was achieved by constructing a model containing data on four characteristics: the quality of the water leaving the root zone of a piece of land; soil information; presence of low permeability superficial (drift) material; and aquifer properties. These were combined in a GIS and the various combinations converted into a measure of vulnerability using expert knowledge. Several model variants were produced using different estimates of the quality of the water leaving the root zone and contrasting methods of weighting the input data. When the final models were assessed all produced similar spatial patterns and, when verified by comparison with trend data derived from monitored nitrate concentrations, all the models were statistically significant predictors of groundwater nitrate concentrations. The best predictive model contained a model of nitrate leaching but no land use information, implying that changes in land use will not affect designations based upon this model. The relationship between nitrate levels and borehole intake depths was investigated since there was concern that the observed contrasts in nitrate levels between vulnerability categories might be reflecting differences in borehole intake depths and not actual vulnerability. However, this was not found to be statistically important. Our preferred model provides the basis for developing a new set of groundwater Nitrate Vulnerable Zones that should help England and Wales to comply with the EU Nitrate Directive.     

A graphical screening method for assessing stream water quality using specific conductivity and alkalinity data

In areas of varying geology, it is difficult to infer water quality from specific conductance or electrical conductivity (EC) data without an understanding of the expected range of EC values based on local bedrock composition. This paper describes a user-friendly graphical screening method that addresses this issue by plotting the EC against concurrent alkalinity data, which correlates well with the presence of carbonate bedrock under natural conditions, and thus serves as an index of bedrock type. The upper limit of EC vs. alkalinity expected in a stream is determined using regional groundwater quality data, based on the assumption that stream chemistry reflects groundwater under baseflow conditions. Stream samples with EC/alkalinity values that consistently plot above this limit are considered impacted by anthropogenic sources. The effect of dilution and runoff on the EC vs. alkalinity plot of stream samples is considered using a simple baseflow/storm runoff-mixing model. The graphical method's utility as a screening tool is demonstrated by application to stream chemistry data from watersheds of southeastern Pennsylvania and northwestern New Jersey in several distinct geologic settings; however the method is general and widely applicable to watersheds in humid temperate regions. Its use is intended for watershed stewards of both professional and nonprofessional qualification.     

Attitudes and actions towards recycling behaviours in the Limerick,Ireland region

Recycling across Ireland has increased incrementally since the introduction and implementation of the Landfill Directive 1999/31/EC, the WEEE directive 2002/96/EC, and the Waste Framework Directive 2008/98/EC. As a result of the implementation of the aforementioned directives, the volume of waste sent to landfill has fallen, household composting increased and recovery of municipal waste recyclables continues to improve. The improvements witnessed, are in part achieved as a result of the introduction of the 2-bin and 3-bin collection service. The improvement of facilities at recycling centres and bring banks have been instrumental in the gains achieved in recycling rates.NIMBYism, however, remains a constant impediment to procuring suitable sites for the recycling receptacles. It is not unusual for people to seek convenience whilst not wanting the associated problems on their doorstep. NIMBYism is something that most individuals are guilty of and it is considered to be quite normal. The structural difficulties associated with recycling rates are the first that need to be confronted. By altering the landscape, behaviours can be changed and improved. In the instance of bring banks and the social problems that are associated with them such as fly-tipping, changing the visual aspect of the receptacles and their positioning may improve recycling rates and reduce the number of instances of fly-tipping and littering.This paper presents the results of 509 questionnaires distributed to nine schools in the Limerick City and County environs. The questionnaires, distributed to primary schools actively participating in the Green School Programme, were analysed so as to get an understanding of the motivations and the deterrents surrounding household recycling of waste. From the analysis recommendations are made to reduce the social problems associated with bring banks and to increase the percentage of householders availing of waste collection services.     

Implementation of the European IPPC Directive—BAT guidelines for the cement industry in Cyprus

The European Integrated Pollution Prevention and Control (IPPC) Directive 96/61/EC aims to introduce a European-wide system of integrated prevention and control of pollution in order to secure a high level of protection to the environment as a whole. It places obligations on the Member States (MS) to introduce controls that ensure operators comply with the Directive. In this framework, as a part of the implementation process leading to formal accession of Cyprus to the European Union, the National Technical University of Athens has examined all documents related to the Best Available Techniques (BATs) published by Institutes and Organisations, such as the Institute for Prospective Technological Studies in Spain, the Environmental Protection Agency in Ireland, the World Bank Group and the Ministry for the Environment, Planning and Public Works in Greece. A series of guidelines were developed for the application of BATs for 14 categories of the Cypriot industry that fall into the IPPC Directive. The concept of BATs plays a central role in the Directive because it provides a basis for setting Emission Limit Values (ELVs) as well as the principal benchmark for determining the obligations of industrial operators in respect of pollution prevention and control. This paper presents the guidelines for cement manufacture in Cyprus.     

Streamflow Depletion Modeling: Methods for an Adaptable and Conjunctive Water Management Decision Support Tool

Groundwater pumping depletes streamflow, which can have significant ecological impacts depending on the magnitude of depletion relative to environmental flow needs. Streamflow depletion estimates from groundwater pumping have been quantified using both analytical and numerical methods, but are not routinely compared to environmental flow needs or used in practical water management tools. Decision support tools that incorporate groundwater dynamics are becoming increasingly necessary for water managers as groundwater regulations become more important in environmental policy, particularly concerning the preservation of environmental flow needs. We develop and apply methods for a web‐based decision support tool for conjunctive groundwater and surface water management, demonstrated using a case study watershed in British Columbia, Canada. Open‐source data are analyzed with a combination of spatial algorithms and previously developed analytical models, such that the tool can be applied to other regions. Streamflow depletion estimates are calculated in four regions in the largely undeveloped Bulkley Valley, British Columbia. Our transparent methodology has geographic and data input flexibility which is a significant improvement on currently existing water management tool methods.     

An integrated assessment of long-term changes in the hydrology of three lowland rivers in eastern England

The flow records of the Rivers Bure, Nar and Wensum in eastern England have been examined with the aim of identifying long-term changes in flow behaviour relating to variations in rainfall amount, land use, land drainage intensity and water resources use. In the study area, and since 1931, there is no evidence of long-term change in rainfall amount or distribution, on either an annual or seasonal basis. Despite changes in water resources use and catchment characteristics since the beginning of the century, such as the ending of water milling and increased land drainage and arable farming, rainfall-runoff modelling over the period 1964-1992 showed that the relationship between rainfall and runoff has remained essentially unchanged in the three study rivers. A catchment resource model used to 'naturalise' the historic flow records for the period 1971-1992 to account for the net effect of water supply abstractions and discharges revealed that mean river flows have been altered by surface water and groundwater abstractions, although the average losses to mean weekly flows due to net abstractions for all water uses was no greater than 3%. Greater losses occurred during drought periods as a result of increased consumptive use of water for spray irrigation and amounted to a maximum loss of 24% in the Nar catchment. In lowland areas such as eastern England that are prone to summer dry weather and periodic drought conditions, an integrated approach to river basin management, as advocated by the EU Framework Directive, is recommended for future management of surface and groundwater resources for public water supplies, river regulation purposes and industrial and agricultural demands.     

Quantitative catchment profiling to apportion faecal indicator organism budgets for the Ribble system, the UK's sentinel drainage basin for Water Framework Directive research

Under the EU Water Framework Directive (WFD) 20/60/EC and the US Federal Water Pollution Control Act 2002 management of water quality within river drainage basins has shifted from traditional point-source control to a holistic approach whereby the overall contribution of point and diffuse sources of pollutants has to be considered. Consequently, there is a requirement to undertake source-apportionment studies of pollutant fluxes within catchments. The inclusion of the Bathing Water Directive (BWD), under the list of 'protected areas' in the WFD places a requirement to control sources of faecal indicator organisms within catchments in order to achieve the objectives of both the BWD (and its revision - 2006/7/EC) and the WFD. This study was therefore initiated to quantify catchment-derived fluxes of faecal indicator compliance parameters originating from both point and diffuse sources. The Ribble drainage basin is the single UK sentinel WFD research catchment and discharges to the south of the Fylde coast, which includes a number of high profile, historically non-compliant, bathing waters. Faecal indicator concentrations (faecal coliform concentrations are reported herein) were measured at 41 riverine locations, the 15 largest wastewater treatment works (WwTWs) and 15 combined sewer overflows (CSOs) across the Ribble basin over a 44-day period during the 2002 bathing season. The sampling programme included targeting rainfall-induced high flow events and sample results were categorised as either base flow or high flow. At the riverine sites, geometric mean faecal coliform concentrations showed statistically significant elevation at high flow compared to base flow. The resultant faecal coliform flux estimates revealed that over 90% of the total organism load to the Ribble Estuary was discharged by sewage related sources during high flow events. These sewage sources were largely related to the urban areas to the south and east of the Ribble basin, with over half the load associated with the relatively small subcatchment of the River Douglas. The majority of this load was attributed to two WwTWs that discharge through a common outfall close to the tidal limit of this catchment. Budgets adjusted to accommodate the impact of proposed UV disinfection of these effluents showed that the load from these sources would be reduced significantly during base flow conditions. However, during high flow events loads would still remain high due to the operation of storm sewage overflows from stormwater retention tanks. The study identified untreated storm sewage spills from urban infrastructure and WwTW stormwater retention tanks as the dominant component of the high flow flux of faecal indicators to receiving waters of the Fylde coast and the associated bathing waters.     

Potential health hazard of drinking water in restaurants and tea stalls

Potable and equitable drinking water (DW) is a fundamental human right and essential for human health. This study is conducted to assess the groundwater and jar water quality of the roadside restaurants and tea stalls used for drinking by the local people around the Gazipur City area in Bangladesh. Water samples from 173 restaurants and tea stalls are collected. The physico-chemical and biological parameters are analyzed according to the guidelines and standards. The results illustrate that the color, EC, and Mn of 41%, 80%, and 62% of the samples, respectively, exceed the WHO and Environmental Conservation Rules (ECR) standards. In addition, E. coli and total coliform exceeding the threshold standards are found in 47% and 64% of the water samples, respectively. The contamination of DW by fecal coliforms is confirmed and supported by prior studies, which indicates that the DW supplied in restaurants and tea stalls are unsafe because of the possible presence of pathogens. These may cause potential health hazards to consumers from various water-borne diseases. Poor sanitation, unhygienic practices, and improper disposal of wastewater are responsible for the microbial contamination of DW. So, the authorities in charge of these places should take the right regulatory steps, such as regular sanitation inspections, DW quality monitoring, hand-washing practices, and better sanitation in these places.     

HOW MUCH UNDERGROUND WATER STORAGE CAPACITY DOES TEXAS HAVE?1

Water imported into Texas under the Texas Water Plan must be stored in surface or underground reservoirs. Ground-water levels are being drawn down heavily in many parts of Texas. This is causing a shift of much water from a surface- to a groundwater environment. The lowering water tables have resulted in a great reduction in wastage of water through evapotranspiration and spring and well flow. The methods used in estimating the quantities of underground storage capacity available in Texas are discussed. Some problems will be encountered in the use of dewatered underground storage capacity by artificial recharge. In spite of these problems, probably 60 to 70 percent of the dewatered storage capacity of Texas aquifers can be reused for groundwater storage. Most of this capacity is located where it can be used in conjunction with the Texas Water Plan.     

Ten Years On: An Empirical Analysis of UK Environmental Statement Submissions since the Implementation of Directive 85/337/EEC

Regulations to implement Directive 85/337/EEC have been in operation in the UK for over 10 years. Implementation of the amended Directive (97/11/EC) in March 1999 marked the start of a new phase in environmental impact assessment (EIA), and so a review of the impact of the original Directive upon EIA activity is timely. This paper examines the implementation of the Directive in the UK through an empirical analysis of the publication of environmental statements (ESs) between July 1988 and April 1998. ES submissions are analysed under Annexes I and II of the Directive and under the main UK regulations, and then development control decision outcomes are considered. The implications of selected legislation and policy initiatives for ES submissions are then investigated in detail for four types of project. The Directive has been a major force in stimulating the development and growth of EIA in the UK, although the interaction of policies and legislation (environmental and otherwise) can exert an important influence upon trends in ES submissions.     

Identifying crop vulnerability to groundwater abstraction: modelling and expert knowledge in a GIS

Water use is expected to increase and climate change scenarios indicate the need for more frequent water abstraction. Abstracting groundwater may have a detrimental effect on soil moisture availability for crop growth and yields. This work presents an elegant and robust method for identifying zones of crop vulnerability to abstraction. Archive groundwater level datasets were used to generate a composite groundwater surface that was subtracted from a digital terrain model. The result was the depth from surface to groundwater and identified areas underlain by shallow groundwater. Knowledge from an expert agronomist was used to define classes of risk in terms of their depth below ground level. Combining information on the permeability of geological drift types further refined the assessment of the risk of crop growth vulnerability. The nature of the mapped output is one that is easy to communicate to the intended farming audience because of the general familiarity of mapped information. Such Geographic Information System (GIS)-based products can play a significant role in the characterisation of catchments under the EU Water Framework Directive especially in the process of public liaison that is fundamental to the setting of priorities for management change. The creation of a baseline allows the impact of future increased water abstraction rates to be modelled and the vulnerability maps are in a format that can be readily understood by the various stakeholders. This methodology can readily be extended to encompass additional data layers and for a range of groundwater vulnerability issues including water resources, ecological impacts, nitrate and phosphorus.     

Will participation foster the successful implementation of the water framework directive? The case of agricultural groundwater protection in northwest Germany

The Water Framework Directive (WFD) calls for various modes of public. These participation and involvement. These are judged as key factors to support the successful implementation in terms of attaining a good water status. This paper aims to explore the role of the 'active involvement' of stakeholders for the effective implementation of the WFD regarding the specific problem of reducing agricultural nitrate pollution of groundwater. Our case of reference is the Hase river catchment in northwest Germany, which is a paradigmatic example of an intensive livestock farming region with high nitrate intakes in groundwater. Emphasis is placed on the various forms of involvement that have recently been or will soon be established in northwest Germany at different spatial and administrative scales. We argue that although the WFD refers to whole river basins as the central unit of governance, it is particularly the regional and local scales that will strongly influence the implementation process. We identify different influencing factors and scenario paths, demonstrating both the uncertainties at stake and the range of possible effects that different outcomes of participatory processes will have. These, in turn, are closely linked to the interests, perceptions and strengths of different actors. Identification of critical paths and decision points enables corridors to be mapped out regarding the anticipated success or failure of regional public participation to reduce diffuse agricultural groundwater pollution.     

A Gis-Based Assessment of Groundwater Suitability for Irrigation Purposes in Flat Areas of the Wet Pampa Plain, Argentina

The Pampa in Argentina is a large plain with a quite obvious dependence on agriculture, water availability and its quality. It is a sensitive environment due to weather changes and slope variations. Supplementary irrigation is a useful practice for compensating the production in the zone. However, potential negative impacts of this type of irrigation in salinization and sodification of soils are evident. Most conventional methodologies for assessing water irrigation quality have difficulties in their application in the region because they do not adjust to the defined assumptions for them. Consequently, a new GIS-based methodology integrating multiparametric data was proposed for evaluating and delineating groundwater suitability zones for irrigation purposes in flat areas. Hydrogeological surveys including water level measurements, groundwater samples for chemical analysis and electrical conductivity (EC) measurements were performed. The combination of EC, sodium adsorption ratio, residual sodium carbonate, slopes and hydraulic gradient parameters generated an irrigation water index (IWI). With the integration of the IWI 1 to 3 classes (categories of suitable waters for irrigation) and the aquifer thickness the restricted irrigation water index (RIWI) was obtained. The IWI's index application showed that 61.3?% of the area has "Very high" to "Moderate" potential for irrigation, while the 31.4?% of it has unsuitable waters. Approximately, 46?% of the tested area has high suitability for irrigation and moderate groundwater availability. This proposed methodology has advantages over traditional methods because it allows for better discrimination in homogeneous areas.     

Hydrogeochemical Indicators of Groundwater Flow Systems in the Yangwu River Alluvial Fan,Xinzhou Basin,Shanxi, China

Based on analysis of groundwater hydrochemical and isotopic indicators, this article aims to identify the groundwater flow systems in the Yangwu River alluvial fan, in the Xinzhou Basin, China. Groundwater δ²H and δ¹⁸O values indicate that the origin of groundwater is mainly from precipitation, with local evaporative influence. d-excess values lower than 10% in most groundwaters suggest a cold climate during recharge in the area. Major ion chemistry, including rCa/rMg and rNa/rCl ratios, show that groundwater salinization is probably dominated by water–rock interaction (e.g., silicate mineral weathering, dissolution of calcite and dolomite and cation exchange) in the Yangwu River alluvial fan, and locally by intensive evapotranspiration in the Hutuo River valley. Cl and Sr concentrations follow an increasing trend in shallow groundwater affected by evaporation, and a decreasing trend in deep groundwater. ⁸⁷Sr/⁸⁶Sr ratios reflect the variety of lithologies encountered during throughflow. The groundwater flow systems (GFS) of the Yangwu River alluvial fan include local and intermediate flow systems. Hydrogeochemical modeling results, simulated using PHREEQC, reveal water–rock interaction processes along different flow paths. This modeling method is more effective for characterizing flow paths in the intermediate system than in the local system. Artificial exploitation on groundwater in the alluvial fan enhances mixing between different groundwater flow systems.     

Full Water‐Cycle Monitoring in an Urban Catchment Reveals Unexpected Water Transfers (Detroit MI,USA)

A goal in urban water management is to reduce the volume of stormwater runoff in urban systems and the effect of combined sewer overflows into receiving waters. Effective management of stormwater runoff in urban systems requires an accounting of various components of the urban water balance. To that end, precipitation, evapotranspiration (ET), sewer flow, and groundwater in a 3.40‐hectare sewershed in Detroit, Michigan were monitored to capture the response of the sewershed to stormwater flow prior to implementation of stormwater control measures. Monitoring results indicate that stormflow in sewers was not initiated unless rain depth was 3.6 mm or greater. ET removed more than 40% of the precipitation in the sewershed, whereas pipe flow accounted for 19%–85% of the losses. Flows within the sewer that could not be associated with direct precipitation indicate an unexpected exchange of water between the leaky sewer and the groundwater system, pathways through abandoned or failing residential infrastructure, or a combination of both. Groundwater data indicate that groundwater flows into the leaky combined sewer rather than out. This research demonstrates that urban hydrologic fluxes can modulate the local water cycle in complex ways which affect the efficiency of the wastewater system, effectiveness of stormwater management, and, ultimately, public health.     

Modelling hydroenvironmental and health risk assessment parameters along the South Wales Coast

This paper highlights the increasing concerns relating to hydroenvironmetal issues and cites recent examples of the challenges now being regularly faced by hydroenvironmetal scientists and engineers. The limitations and restrictions of both physical (or laboratory) and numerical (or computer based) hydraulic models used in the planning and management of aquatic basins are discussed. General details are given of numerical models used for flow and water quality concentration predictions in estuarine waters, with particular application to the challenges occurring along the South Wales coast. A highly accurate and non-diffusive finite difference scheme that solves the transport equation for predicting water quality indicators and suspended sediment concentration distributions is also discussed. In particular, details are outlined of the extension of the water quality indicators of faecal coliforms, as required to comply with the EU Bathing Water Directive, to predict health risk assessment, in the form of predicting the risk of gastroenteritis. Three example research projects along the South Wales coast are described; the projects involve the application of two-dimensional and three-dimensional hydroenvironmetal models to predict flow patterns and water quality indicator organism distributions in the coastal receiving waters. These studies include: (i) a curvilinear finite difference approach to modelling flows in the Bristol Channel, (ii) coastal health risk predictions in Swansea Bay using combined water quality and epidemiological models, and (iii) combined sewer overflow discharges into Cardiff Bay.     

Impact of Urban Growth and High Residential Irrigation on Streamflow and Groundwater Levels in a Peri‐Urban Semiarid Catchment

The impact of urbanization on groundwater is not simple to understand, as it depends on a variety of factors such as climate, hydrogeology, water management practices, and infrastructure. In semiarid landscapes, the urbanization processes can involve high water consumptions and irrigation increases, which in turn may contribute to groundwater recharge. We assessed the hydrological impacts of urbanization and irrigation rates in an Andean peri‐urban catchment located in Chile, in a semiarid climate. For this purpose, we built and validated a coupled surface–groundwater model that allows the verification of a strong stream–aquifer interaction in areas with shallow groundwater, higher than some sewers and portions of the stream. Moreover, we also identified a significant local recharge associated with pipe leaks and inefficient urban irrigation. From the evaluation of different future scenarios, we found a sustainable water conservation scenario will decrease the current groundwater levels, while the median flow reduces from 408 to 389 L/s, and the low flow (Q_95%) from 43 to 22L/s. Overall, our results show the relevance of integrating the modeling of surface and subsurface water resources at different spatial and temporal scales, when assessing the effect of urban development and the suitability of urban water practices.     

塔里木盆地南缘和田地区生活用水地下水质分析

干旱区水资源短缺，生产用水、生态用水与人民群众的生活用水矛盾突出。针对和田地区农村改水的地下饮用水状况的分析和评价，结果表明，地下饮用水的色度、浑浊度以及砷、泵、镉、铬、铅、硝酸盐等超标率均为零。总硬度、Cl^-、SO4^2-及F^-等指标的超标率较高，而这些物质的存在对于水质的理化性状影响较大，并因此而引发人体健康教育改变。和田地区总体饮用I级水的人口数量多，但局部的超标水依然存在。应通过对区域自然地理状况和人文因素的系统研究和科学论证，加强水源保护，改进卫生条件和卫生观念，建立农村饮水监测网，加强系统监测、监督和管理，以保障人民群众安全的生活用水。     

Spatial assessment of groundwater quality in Guna Tana landscape

This study focuses on investigating the quality of groundwater for irrigation and drinking water purposes. Spatial distribution of physicochemical and microbiological parameters was assessed from samples collected from springs, hand‐dug wells, and boreholes found the Guna Tana landscape. A total of 70 samples were considered for physical, chemical, and bacteriological water quality determination. The results revealed that most of the groundwater quality index (WQI) values lie between good and excellent. The maximum, minimum, mean, and standard deviation of each water quality parameter were prepared for evaluating groundwater quality. According to the WQI values, more than 83% of the water samples were classified as excellent water for drinking. More than 92% of the water samples showed low sodium hazards for irrigation and about 48% and 46% of the water samples were classified as within the excellent and good water classes for irrigation based on their electrical conductance levels. Therefore, the groundwater that is found in the Guna Tana landscape could be used for drinking and irrigation purposes without any advanced treatment.