我国环境分析化学研究概况与展望

环境分析化学是环境科学研究和环境保护工作的耳目和重要手段.多年来,我国各省、市、自治区普遍开展了本地区的水、大气、土壤、作物等的环境监测分析,编制了环境质量报告书,为环境质量评价和综合防治提供了大量的重要信息. 环境标准分析方法的研究,是建立全国统一的环境监测方法的基础,是环境监测标准化、规范化的前提.1979年提出了酚、氰、     

环境监测点的模糊优化设置及其问题探讨

应用模糊聚类方法，结合贵阳市的实例，对环境监测点的模糊优化设置进行了研究。提出根据实测数据分布形态选用标定方法的建议和具体作法，可使环境监测点的模糊优化设置更趋合理，从而可为有关部门在进行监测点的科学合理设置时提供参考。     

试论环境监测报告的审核

环境监测报告的审核是环境监测质最保证工作的最后环节。作者从审核程序、审核人员资质、审核脚容等方面对报告的审核进行了阐述。     

关于环境监测转型的思考

从宏观社会环境方面，客观分析了制约环境监测发展的体制因素、社会因素、技术因素。根据这一背景，提出了环境监测转型的对策，即创新监测体制，加强能力建设，构建文化平台。     

现阶段环境监测在市场经济中的地位浅析

环境监测是一项政府行为，如何在社会主义市场经济条件下，正确处理“政府行为”与市场经济的矛盾，已成为各级环保部门共同探讨的、需要妥善解决的问题。因此，根据经济学的有关理论，对环境监测这一领域在社会主义市场经济中所处的地位、作用作了全面论述，并对理解环境监测的“政府行为”提出看法和见解。     

硝基苯类污染物还原反应分析系统误差的讨论

硝基苯类的物质在测定中，不能因操作过程的复杂，使用的玻璃器皿多，就存在着较大的系统误差，如锌渣吸附和滤纸吸附误差。如果严格按照国家标准方法分析操作，这两种误差几乎没有，否则，工作时绘制的标准曲线斜率不会在规定要求内。因此，《环境研究与监测》和《环境监测管理与技术》刊载的两篇文章存在一些错误。     

浙江省辐射环境监测现状及对策研究

辐射环境是生态环境的重要组成部分,核与辐射环境安全是国家环境安全的重要内容.详述了目前浙江省辐射环境监测网络的建设情况,以及对核设施、铀矿及伴生矿放射性污染源、核技术运用、电磁辐射环境、辐射应急等进行辐射环境监测的情况,分析了存在的主要问题,并提出了相应的对策,为浙江省辐射环境监管提供技术支撑和科学依据,同时也对全国辐射环境监测和管理具有积极的指导意义.     

快速制作环境质量多媒体声像报告的方法

介绍了由普通环境质量报告快速制作成声像报告的主要过程，并介绍了如何利用Powerpoint软件与其他常用软件的配合来综合多媒体技术快速制作环境质量声像的报告，对相关软件使用的关键步骤给予了详细说明，并根据经验提出了编制的注意事项。     

环境监测现场室管理实践与探索

环境监测现场室管理工作是环境监测中一项基础性管理和技术工作,监测现场的管理工作是否科学有序,关系到环境监测效率的高低,对环境监测数据质量的准确性、可靠性、可比性、完整性和公正性也有着十分重要影响。因此,做好环境监测现场室管理工作已成为环境监测管理工作者必须掌握的一项基础性科学技术。文中从环境监测现场室管理工作的实践经验出发,进一步进行探索研究,力求环境监测现场室管理工作高效可行。     

生物传感器在环境监测中的应用

介绍了生物传感器在环境监测中的应用，主要分析了酶传感器、微生物传感器、免疫传感器及DNA传感器在环境监测中的作用机理及监测方法，并针对环境中的杀虫剂、爆炸类物质、有毒污染物及水体中的BOD负荷等的监测进行了较详细的论述，对生物传感器的发展方向及前景进行了展望。     

Estimating net changes in life-cycle emissions from adoption of emerging civil infrastructure technologies

There is a net emissions change when adopting new materials for use in civil infrastructure design. To evaluate the total net emissions change, one must consider changes in manufacture and associated life-cycle emissions, as well as changes in the quantity of material required. In addition, in principle one should also consider any differences in costs of the two designs because cost savings can be applied to other economic activities with associated environmental impacts. In this paper, a method is presented that combines these considerations to permit an evaluation of the net change in emissions when considering the adoption of emerging technologies/materials for civil infrastructure. The method factors in data on differences between a standard and new material for civil infrastructure, material requirements as specified in designs using both materials, and price information. The life-cycle assessment approach known as economic input-output life-cycle assessment (EIO-LCA) is utilized. A brief background on EIO-LCA is provided because its use is central to the method. The methodology is demonstrated with analysis of a switch from carbon steel to high-performance steel in military bridge design. The results are compared with a simplistic analysis that accounts for the weight reduction afforded by use of the high-performance steel but assuming no differences in manufacture.     

A carbon balance method for paper and wood products

The approach used to track the flow of carbon sequestered in the forest through harvest, processing into products, and final disposition of products is described. The methodology is broadly flexible and applicable to forest-based carbon balance assessments. A carbon balance is computed across all forestland ownerships for the production facility of interest. The balance considers forest uptake, harvest, combustion of fuels, emissions from process steps and losses from product use, disposition and recycling. The method also allows for sensitivity and marginal assessments of a variety of real and hypothetical situations using variable assumptions. Example results for a vertically integrated pulp and paper mill are presented. Results suggest that integrated forest products facilities drawing their raw material from sustainably managed forests can achieve a net positive carbon balance over the product cycle. The amount of net carbon sequestration attributable to such facilities depends upon a number of factors. The most critical of these include net forest growth, the method for allocating the growth in forest carbon among all of those harvesting from the drain area of a given facility, and the use and disposal patterns for the paper or wood products manufactured.     

Fractional factorial experiments using a test atmosphere to assess the accuracy and precision of a new passive sampler for the determination of formaldehyde in the atmosphere

A new analytical method was developed for the determination of formaldehyde in ambient air based on the use of a modified configuration of the Analyst^® passive sampler. It consists of a polyethylene cylinder filled with appropriate reactive adsorbent and a special anti-turbulence net which works as an ozone scrubber.The performance of a diffusive sampler depends critically on the selection and use of a suitable adsorbent and on environmental factors, such as temperature, humidity and the interference of oxidant species. In this study two adsorbent types were investigated: 2,4-dinitrophenylhydrazine (2,4-DNPH) coated silica gel and Florisil^® particles. Interference of ozone was removed by using a silver net upstream as an anti-turbulence device. The performance of this net was then compared with that of stainless steel. Furthermore, the aim of the work was the optimization of the adsorbent type and the study of the interference of ozone with particular attention placed on the effect of relative humidity and temperature.A dynamic system for generating a known concentration of the test gas (formaldehyde) in an appropriate exposure chamber was used to evaluate the performance of the passive sampler and to allow the calibration of the methodology. Inter-comparisons with a reference method, active sampling using 2,4-DNPH-silica gel coated cartridges, were also carried out. Results were in accordance with each other.Tests were planned using a statistical method based on Design of Experiment methodology. The operating conditions were chosen in order to obtain the best configuration of the passive device by evaluating the statistical significance of the different factors and their interactions by analysis of variance.Results showed that the best configuration was achieved using 2,4-DNPH Florisil^® coated particles as an adsorbent and a silver anti-turbulence net as an ozone scrubber.With the aim of achieving further results in realistic conditions, some field experiments were also carried out.     

How can net petroleum importers achieve risk aversion in a globalized world: a multi-regional input–output perspective

Net embodied petroleum importers face greater petroleum security risks in international trade due to their high foreign dependence. Therefore, paying better attention to the national flows and drivers of embodied petroleum consumption can effectively serve net embodied petroleum importers to avoid petroleum security risks and formulate environmental protection policy. This study utilized the multi-regional input–output model to determine the top five embodied petroleum net importers (i.e., the USA, Japan, Germany, the UK, and France) under the economic globalization, and traced the flows of embodied petroleum consumption through international trade. Combined with the logarithmic mean Divisia index method, this study also deeply investigated the drivers of changes embodied petroleum in net imports. The results show that from the perspective of international trade, the USA was not only the largest importer but also the largest exporter of embodied petroleum. Among the trade flows of embodied petroleum, the largest trade flow was from China to the USA, which indicated that China was the world factory and the USA was the consumer power. The embodied petroleum trade markets of Germany, the UK, and France was mainly distributed in Europe & Eurasia resulted from European economic integration. The largest contributor to the decrease of embodied petroleum imports in the top 4 net importers was the petroleum intensity effect. Meanwhile, the import dependence effect was the largest contributor to the increase of France’s embodied petroleum net imports. In order to further avoid the risk of petroleum security, it is an effective path worth exploring to construct the diversified petroleum product import strategy and improve energy efficiency.

     

An analytically solved kinetic model for pesticide degradation in single compartment systems

An analytical kinetic model was developed to simulate the degradation of pesticides in systems such as soil or water. Based on a single compartment system, a set of simultaneous first-order differential equations was analytically solved by the eigenvalue and eigenvector method. The developed model is capable of simulating the concentrations of parent compound and any net of degradation products connected by irreversible reactions.     

National-scale estimation of changes in soil carbon stocks on agricultural lands

Average annual net change in soil carbon stocks under past and current management is needed as part of national reporting of greenhouse gas emissions and to evaluate the potential for soils as sinks to mitigate increasing atmospheric CO2. We estimated net soil C stock changes for US agricultural soils during the period from 1982 to 1997 using the IPCC (Intergovernmental Panel on Climate Change) method for greenhouse gas inventories. Land use data from the NRI (National Resources Inventory; USDA-NRCS) were used as input along with ancillary data sets on climate, soils, and agricultural management. Our results show that, overall, changes in land use and agricultural management have resulted in a net gain of 21.2 MMT C year(-1) in US agricultural soils during this period. Cropped lands account for 15.1 MMT C year(-1), while grazing land soil C increased 6.1 MMT C year(-1). The land use and management changes that have contributed the most to increasing soil C during this period are (1) adoption of conservation tillage practices on cropland, (2) enrollment of cropland in the Conservation Reserve Program, and (3) cropping intensification that has resulted in reduced use of bare fallow.     

The impact of an urban-industrial region on the magnitude and variability of persistent organic pollutant deposition to Lake Michigan

A predictive model for gas-phase PCBs and trans-nonachlor over Lake Michigan has been constructed and the resulting data examined for trends. In this paper, we describe the model results to show how the magnitude and variability of a plume of contaminants from the Chicago area contributes to a highly variable region of net contaminant deposition over the entire lake. For the whole lake, gross annual deposition of PCBs is approximately 3200 kg, although the net annual gas exchange is not significantly different from zero. The data-driven model illustrates that on a daily basis, the net exchange of persistent organic pollutants (POPs) can change from net deposition to net volatilization depending on the area of plume impact. These findings suggest that i) control of urban areas can accelerate the rate of volatilization from lakes; and ii) release of POPs from urban areas is largely a result of volatilization processes.     

Evaluation of N2O emission from rainfed wheat field in northwest agricultural land in China

Environmental Science and Pollution Research - The net greenhouse gas (NGHG) emissions and net greenhouse gas intensity (NGHGI) were investigated via the determination of nitrous oxide (N2O)...     

不同再生工艺对活性炭吸附性能的影响分析

吸附法油气回收技术中,吸附剂的再生是一个难点和研究重点。微波加热作为一种新的再生技术,受到人们日益的重视。实验利用比表面积及孔隙分析仪测定了经多次微波真空,加热真空和加热再生后的活性炭的表面结构变化,通过对比分析,探讨了3种工艺多次再生活性炭对活性炭表面结构的影响。结果表明,3种工艺均对活性炭结构都有所破坏,但微波真空再生对活性炭比表面积和孔容破坏最小,净吸附容量最大,从效率及能耗上都比较好。