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1.
AV Miljø is a modern waste disposal site receiving non-combustible waste with a low-organic content. The objective of the current project was to determine the gas generation, composition, emission, and oxidation in top covers on selected waste cells as well as the total methane (CH4) emission from the disposal site. The investigations focused particularly on three waste disposal cells containing shredder waste (cell 1.5.1), mixed industrial waste (cell 2.2.2), and mixed combustible waste (cell 1.3). Laboratory waste incubation experiments as well as gas modeling showed that significant gas generation was occurring in all three cells. Field analysis showed that the gas generated in the cell with mixed combustible waste consisted of mainly CH4 (70%) and carbon dioxide (CO2) (29%) whereas the gas generated within the shredder waste, primarily consisted of CH4 (27%) and nitrogen (N2) (71%), containing no CO2. The results indicated that the gas composition in the shredder waste was governed by chemical reactions as well as microbial reactions. CH4 mass balances from three individual waste cells showed that a significant part (between 15% and 67%) of the CH4 generated in cell 1.3 and 2.2.2 was emitted through leachate collection wells, as a result of the relatively impermeable covers in place at these two cells preventing vertical migration of the gas. At cell 1.5.1, which is un-covered, the CH4 emission through the leachate system was low due to the high gas permeability of the shredder waste. Instead the gas was emitted through the waste resulting in some hotspot observations on the shredder surface with higher emission rates. The remaining gas that was not emitted through surfaces or the leachate collection system could potentially be oxidized as the measured oxidation capacity exceeded the potential emission rate. The whole CH4 emission from the disposal site was found to be 820 ± 202 kg CH4 d−1. The total emission rate through the leachate collection system at AV Miljø was found to be 211 kg CH4 d−1. This showed that approximately ¼ of the emitted gas was emitted through the leachate collections system making the leachate collection system an important source controlling the overall gas migration from the site. The emission pathway for the remaining part of the gas was more uncertain, but emission from open cells where waste is being disposed of or being excavated for incineration, or from horizontal leachate drainage pipes placed in permeable gravel layers in the bottom of empty cells was likely.  相似文献   

2.
In a closed landfill, Japan, remedial actions have been undertaken to address the inadequate leachate collection and drainage systems. Part of this process included installing many passive gas vents in the landfill to promote stabilization of landfilled waste. This study focused on the gas velocity in vents by conducting tracer tests to elucidate the gas flow via passive gas vents. The gas composition and gas temperature in the vents was also measured.As the gas vents pass through the waste layer, both landfill gas and air flows through the vents. Therefore, passive gas vents can be used to aerate landfilled waste as well as to collect and release landfill gas. Aerobic biodegradation occurs when air migrates through the waste layer if organic matter is present; this increases the temperature of the waste layer. Inflow of air into the gas vents can occur at a wide range of depths, even 10–20 m below ground level. Air is induced not from the surface of the landfill, but horizontally along the waste layer. The driving force of air induction from outside is a buoyancy effect caused by the temperature rise due to aerobic biodegradation.  相似文献   

3.
Gas production and recovery from managed sanitary landfills can be simulated by describing the time and space variation of the total pressure and composition of the mixture of gases (CH4, CO2, and N2) in the landfill. The variation of the total pressure and the composition of the gas mixture is described by the equations for mass conservation for each component (including a generation term for CH4 and CO2), the equation of motion, and the equation of state. Simulations of gas production compare well with field data from the Mountain View controlled landfill project field experiment. The function used to approximate the shape of the methanogenesis curve (based on equations describing the biochemical processes) consists of a rising hyperbolic branch and a decaying exponential branch. The conceptual framework of the model has been designed to incorporate equations describing the physics, biology, and chemistry of gas production in landfills.  相似文献   

4.
Traditionally EfW (Energy from Waste) plants apply a reciprocating grate to combust waste fuel. An integrated steam generator recovers the heat of combustion and converts it to steam for use in a steam turbine/generator set. This is followed by an array of flue gas cleaning technologies to meet regulatory limitations.Modern combustion applies a two-step method using primary air to fuel the combustion process on the grate. This generates a complex mixture of pyrolysis gases, combustion gases and unused combustion air. The post-combustion step in the first pass of the boiler above the grate is intended to “clean up” this mixture by oxidizing unburned gases with secondary air.This paper describes modifications to the combustion process to minimize exhaust gas volumes and the generation of noxious gases and thus improving the overall thermal efficiency of the EfW plant. The resulting process can be coupled with an innovative SNCR (Selective Non-Catalytic Reduction) technology to form a clean and efficient solid waste combustion system.Measurements immediately above the grate show that gas compositions along the grate vary from 10% CO, 5% H2 and 0% O2 to essentially unused “pure” air, in good agreement with results from a mathematical model. Introducing these diverse gas compositions to the post combustion process will overwhelm its ability to process all these gas fractions in an optimal manner. Inserting an intermediate step aimed at homogenizing the mixture above the grate has shown to significantly improve the quality of combustion, allowing for optimized process parameters. These measures also resulted in reduced formation of NOx (nitrogenous oxides) due to a lower oxygen level at which the combustion process was run (2.6 vol% O2, wet instead of 6.0 vol% O2, wet).This reduction establishes optimal conditions for the DyNOR? (Dynamic NOx Reduction) NOx reduction process. This innovative SNCR technology is adapted to situations typically encountered in solid fuel combustion. DyNOR? measures temperature in small furnace segments and delivers the reducing reagent to the exact location where it is most effective. The DyNOR? distributor reacts precisely and dynamically to rapid changes in combustion conditions, resulting in very low NOx emissions from the stack.  相似文献   

5.
Gas cleaning systems of MSW (Municipal Solid Waste) incinerators are characterised by the process employed to remove acid gases. The commonly used technologies for acid gas removal are: (1) dry treatment with Ca(OH)2 or (2) with NaHCO3, (3) semi-dry process with Ca(OH)2 and (4) wet scrubbing. In some recent plants beside a wet cleaning system, a dry neutralization with Ca(OH)2 is used. The goal is to reduce the amount of acid to be removed in the wet treatment and the liquid effluents produced. The influence of these different technologies on the electrical efficiency was investigated by a detailed simulation of a WTE (Waste To Energy) plant with a capacity of about 100,000 t/y of MSW. The effects of the different gas cleaning systems on electrical efficiency were significant. The difference of efficiency between the most advantageous technology, which is dry treatment with NaHCO3, and the least advantageous technology which is semi-dry treatment, is about 0.8%. A simple economic analysis showed that the few advantages of dry technologies can often be lost if the costs of chemicals and the disposal of products are considered.  相似文献   

6.
Temporal variability of soil gas composition in landfill covers   总被引:1,自引:0,他引:1  
In order to assess the temporal variability of the conditions for the microbial oxidation of methane in landfill cover soils and their driving variables, gas composition at non-emissive and strongly emissive locations (hotspots) was monitored on a seasonal, daily and hourly time scale on an old, unlined landfill in northern Germany. Our study showed that the impact of the various environmental factors varied with the mode of gas transport and with the time scale considered. At non-emissive sites, governed by diffusive gas transport, soil gas composition was subject to a pronounced seasonal variation. A high extent of aeration, low methane concentrations and a high ratio of CO2 to CH4 were found across the entire depth of the soil cover during the warm and dry period, whereas in the cool and moist period aeration was less and landfill gas migrated further upward. Statistically, variation in soil gas composition was best explained by the variation in soil temperature. At locations dominated by advective gas transport and showing considerable emissions of methane, this pattern was far less pronounced with only little increase in the extent of aeration during drier periods. Here, the change of barometric pressure was found to impact soil gas composition. On a daily scale under constant conditions of temperature, gas transport at both types of locations was strongly impacted by the change in soil moisture. On an hourly scale, under constant conditions of temperature and moisture, gas migration was impacted most by the change in barometric pressure. It was shown that at diffusion-dominated sites complete methane oxidation was achieved even under adverse wintry conditions, whereas at hotspots, even under favorable dry and warm conditions, aerobic biological activity can be limited to the upper crust of the soil.  相似文献   

7.
When landfill gas is collected, air inflow into the landfill can reduce CH4 productivity. The decline of CH4 content in landfill gas (LFG) negatively affects energy projects. We studied air inflow rates and LFG characteristics from 699 vertical collection facilities (VCFs) in the 2nd landfill at the Sudokwon Landfill in South Korea. We first determined whether or not N2 was an effective indicator of air inflow at this site using argon assays. The results of this analysis showed that the denitrification processes could be disregarded and that N2 was an effective indicator of air inflow. Using the composition of N2 in LFG samples, we found that air inflow occurred at 73.6 % of the VCFs, and 25.6 % of samples from these facilities showed more than 80 vol% of air inflow. In addition, we observed that the O2 consumption rate was more than 70 % of the volume in all samples. $ R_{{{\text{CH}}_{ 4} }} $ , which is the ratio of CH4 to the sum of CH4 and CO2, decreased with increasing air inflow. Finally, we found that, as air inflow increased, the variation in $ R_{{{\text{CH}}_{ 4} }} $ values for samples with equal air inflow ratios also increased due to differences in air inflow routes.  相似文献   

8.
Mugla is a city that is located in the southwest part of Turkey. Three thermo-electric power plants called Yatagan (3 × 210 MW) and Yenikoy (2 × 210 MW)and Kemerkoy (Gokova, 3 × 210 MW) havebeen constructed in this region and also have begun operation in 1982 – 1983 – 1984 (three units), in 1988 and in 1995, respectively. The Pinus brutia forests in Yerkesik–Denizova region have been under the common effects of Yenikoy and Yatagan thermo-electric power plants. Therefore, these Pinus brutia forests have startedto dry in groups since 1988. In addition, Kemerkoy thermo-electric power plant, began operation in 1995.Polluting gases arrived in Denizova-Yerkesik throughKoca Stream Valley Forests.Increasing quantities of polluting gases and especially SO2 have dried the trees in large amounts in this 1650 ha forestland area. YataganThermo-electric power plant has caused drying of Pinus brutia in Bencik Mountain, which was on the south in 1984–1985. The same phenomenon was seen in Denizova-Yerkesik Forest in 1999–2000. It was observed that sulphur content was varying between 4218–6676 ppm at the Pinus brutia needle samples taken in this region on 16 December 2000. Sulphur contents were correlated with the age of needle (1–2 yr old), density of yellow stains on the needles and amount of drying needles. Particularly in 1996–2000 period, the destruction of chlorophyll in needles due to the impacts of SO2 was also correlated with narrowing of the annual rings from one year to another. The narrowing ratio of yearly rings reached 60–504% for 94–95 yr old, and 375–661% for 58–63 yr old Pinus brutia trees during the 1986–1990, 1991–1995 and 1996–2000 periods.All these results clearly showed that the decrease in the chlorophyll content in needles under the effect of air pollution caused important reduction in the raw timber production and its inputs to the economy. In other words, drying due to increased ecological sensitivity or direct hazard of pollutants emitted by the power plants and cutting of trees have been notably increased in the region. This has created serious economic losses.  相似文献   

9.
World primary energy demand increases with increases in population and economic development. Within the last 25 yr, the total energy consumption has almost doubled. For the purpose of meeting this demand, fossil energy sources are used and various pollutants are generated. CO2 is also one of these gases, which cannot be removed like other pollutants, and it causes greenhouse effect and climate change. Reducing the CO2 emission is very important because of the environmental concerns and regulations, especially the Kyoto Protocol. This paper reviews the estimated world carbon emissions, Turkey's situation in electrical energy production, emission amounts estimated until the year 2020 and emission factors for dust, SO2, NOx and CO2. The estimated results show that CO2 emissions from thermal power plants in Turkey will make about 0.66 % of the global CO2 emissions in 2020.  相似文献   

10.
The purpose of this study was to investigate the possibility of light gases produced from polypropylene, specifically hydrogen. In particular, we examined the effect of operating conditions on gaseous product and compositions in the catalytic cracking of polypropylene. We also characterized the gaseous product generated from polypropylene cracking. The feedstock (2.0 g) mixed with NiO/SiO2–Al2O3 (Si–Al) was used, under non-isothermal conditions at low temperature range between 380 and 500 °C. Argon gas was used to carry the pyrolyzed gas, and the gas collected in a tedlar bag was analyzed for its behavior. We observed the behavior of major gases (H2, CH4, C2H4 and C3H6, etc.) according to reaction time and temperature. Finally, the effect of reaction conditions on evolved gases from catalytic cracking of polypropylene was analyzed.  相似文献   

11.
Municipal solid waste (MSW) landfills are one of the major sources of offensive odors potentially creating annoyance in adjacent communities. At the end of May 2007, an odor pollution incident occurred at the Tianziling landfill site, Hangzhou, China, where the residents lodged complaints about the intense odor from the landfill, which drew a significant attention from the government. In this study, ambient air monitoring was conducted at the Tianziling landfill site. The main odor composition of the gas samples collected on June 1st 2007 and the reduction of various odorous gases from the samples collected on June 1st 2009 due to the applied odor control techniques were determined using gas chromatography-mass spectrometry (GC-MS). In addition, variations of primary odorous gaseous (NH3 and H2S) concentrations at different locations in the landfill site from July 2007 to June 2009 were also investigated by using classical spectrophotometric methods. Results showed that a total of 68 volatile compounds were identified among which H2S (56.58-579.84 μg/m3) and NH3 (520-4460 μg/m3) were the notable odor components contributing to 4.47-10.92% and 83.91-93.94% of total concentrations, respectively. Similar spatial and temporal shifts of H2S and NH3 concentrations were observed and were significantly affected by environmental factors including temperature, air pressure and wind direction. Odor pollution was worse when high temperature, high humidity, low air pressure, and southeast, northeast or east wind appeared. Moreover, the environmental sampling points of the dumping area and the leachate treatment plant were found to be the main odor sources at the Tianziling landfill site. The odor control technologies used in this project had a good mitigating effect on the primary odorous compounds. This study provides long-term valuable information concerning the characteristics and control of odors at landfill sites in a long run.  相似文献   

12.
The work deals with catalytic gasification, pyrolysis and non-catalytic gasification of tar from an industrial dumping site. All experiments were carried out in a vertical stainless steel gasification reactor at 800 °C. Crushed calcined dolomite was used as the gasification catalyst. Parameters such as addition of water and air, and the influence of the catalyst in regard to the composition of the process gas were investigated. The catalytic gasification experiment in the steady state produced process gas with the composition: 56 % of H2, 9 % of CO, 11 % of CH4 and 12 % of CO2 (mol.%). Concentration of the C2 fraction was lower than 1 mol.%. Volume flow of air was later changed from 120 to 230 ml min?1 reducing the amount of hydrogen to 51 mol.% and that of methane to 10 mol.%. Process gas created in a non-catalytic gasification process contained 26–30 mol.% of methane, 13–15 mol.% of carbon monoxide and 15–17 mol.% of the C2 fraction and lower amounts of hydrogen (20 mol.%) and carbon dioxide (2–3 mol.%). The highest apparent conversion of tar was reached in the catalytic gasification processes. A higher rate of catalyst deactivation can be observed when water or air is not added.  相似文献   

13.
Oil refining is among the industrial activities that emit considerable amounts of air pollutants into the atmosphere. Nitrogen oxides are important air pollutants that are emitted by oil refineries as products of combustion processes. The ambient air concentrations of nitrogen oxide (NO) and nitrogen dioxide (NO2) were monitored continuously at a site close to an oil refinery, near the city of Corinth in Greece, during autumn 1997 together with the main meteorological parameters. The contribution of the oil refinery to the measured atmospheric levels of nitrogen oxides was estimated. The ambient air concentration of nitrogen oxides in the area surrounding the oil refinery were generally lower than the ambient air concentrations in the urban area of Athens in Greece, and the NO2 levels were always below the existing air quality standards. The influence of the refinery emitted NOx in the photochemical production of ozone seems to be more important in terms of human and vegetation exposure given the high ozone backgrounds measured in the area.  相似文献   

14.
Emissions trading in the European Union (EU), covering the least uncertain emission sources of greenhouse gas emission inventories (CO2 from combustion and selected industrial processes in large installations), began in 2005. During the first commitment period of the Kyoto Protocol (2008–2012), the emissions trading between Parties to the Protocol will cover all greenhouse gases (CO2, CH4, N2O, HFCs, PFCs, and SF6) and sectors (energy, industry, agriculture, waste, and selected land-use activities) included in the Protocol. In this paper, we estimate the uncertainties in different emissions trading schemes based on uncertainties in corresponding inventories. According to the results, uncertainty in emissions from the EU15 and the EU25 included in the first phase of the EU emissions trading scheme (2005–2007) is ±3% (at 95% confidence interval relative to the mean value). If the trading were extended to CH4 and N2O, in addition to CO2, but no new emissions sectors were included, the tradable amount of emissions would increase by only 2% and the uncertainty in the emissions would range from −4 to +8%. Finally, uncertainty in emissions included in emissions trading under the Kyoto Protocol was estimated to vary from −6 to +21%. Inclusion of removals from forest-related activities under the Kyoto Protocol did not notably affect uncertainty, as the volume of these removals is estimated to be small.  相似文献   

15.
About 20 million tonnes of sludge (with 80% moisture content) is discharged by the sewage treatment plants per year in China, which, if not treated properly, can be a significant source of greenhouse gases (GHGs) emissions. Anaerobic digestion is a conventional sewage sludge treatment method and will continue to be one of the main technologies in the following years. This research has taken into consideration GHGs emissions from typical processes of sludge thickening + anaerobic digestion + dewatering + residue land application in China. Fossil CO2, biogenic CO2, CH4, and avoided CO2 as the main objects is discussed respectively. The results show that the total CO2-eq is about 1133 kg/t DM (including the biogenic CO2), while the net CO2-eq is about 372 kg/t DM (excluding the biogenic CO2). An anaerobic digestion unit as the main GHGs emission source occupies more than 91% CO2-eq of the whole process. The use of biogas is important for achieving carbon dioxide emission reductions, which could reach about 24% of the total CO2-eq reduction.  相似文献   

16.
Landfill sites are emerging in climate change scenarios as a significant source of greenhouse gases. The compacted final soil cover at landfill sites plays a vital role for the emission, fate and transport of landfill gases. This study investigated the effects of dry bulk density, ρ(b), and particle size fraction on the main soil-gas transport parameters - soil-gas diffusivity (D(p)/D(o), ratio of gas diffusion coefficients in soil and free air) and air permeability (k(a)) - under variably-saturated moisture conditions. Soil samples were prepared by three different compaction methods (Standard and Modified Proctor compaction, and hand compaction) with resulting ρ(b) values ranging from 1.40 to 2.10 g cm(-3). Results showed that D(p) and k(a) values for the '+gravel' fraction (<35 mm) became larger than for the '-gravel' fraction (<2mm) under variably-saturated conditions for a given soil-air content (ε), likely due to enhanced gas diffusion and advection through less tortuous, large-pore networks. The effect of dry bulk density on D(p) and k(a) was most pronounced for the '+gravel' fraction. Normalized ratios were introduced for all soil-gas parameters: (i) for gas diffusivity D(p)/D(f), the ratio of measured D(p) to D(p) in total porosity (f), (ii) for air permeability k(a)/k(a)(,pF4.1), the ratio of measured k(a) to k(a) at 1235 kPa matric potential (=pF 4.1), and (iii) for soil-air content, the ratio of soil-air content (ε) to total porosity (f) (air saturation). Based on the normalized parameters, predictive power-law models for D(p)(ε/f) and k(a)(ε/f) models were developed based on a single parameter (water blockage factor M for D(p) and P for k(a)). The water blockage factors, M and P, were found to be linearly correlated to ρ(b) values, and the effects of dry bulk density on D(p) and k(a) for both '+gravel' and '-gravel' fractions were well accounted for by the new models.  相似文献   

17.
Approximately 1.5 billion tyres are produced each year which will eventually enter the waste stream representing a major potential waste and environmental problem. However, there is growing interest in pyrolysis as a technology to treat tyres to produce valuable oil, char and gas products. The most common reactors used are fixed-bed (batch), screw kiln, rotary kiln, vacuum and fluidised-bed. The key influence on the product yield, and gas and oil composition, is the type of reactor used which in turn determines the temperature and heating rate. Tyre pyrolysis oil is chemically very complex containing aliphatic, aromatic, hetero-atom and polar fractions. The fuel characteristics of the tyre oil shows that it is similar to a gas oil or light fuel oil and has been successfully combusted in test furnaces and engines. The main gases produced from the pyrolysis of waste tyres are H2, C1–C4 hydrocarbons, CO2, CO and H2S. Upgrading tyre pyrolysis products to high value products has concentrated on char upgrading to higher quality carbon black and to activated carbon. The use of catalysts to upgrade the oil to a aromatic-rich chemical feedstock or the production of hydrogen from waste tyres has also been reported. Examples of commercial and semi-commercial scale tyre pyrolysis systems show that small scale batch reactors and continuous rotary kiln reactors have been developed to commercial scale.  相似文献   

18.
With limited assessment, leachate treatment of a specified landfill is considered to be a significant source of greenhouse gas (GHG) emissions. In our study, the cumulative GHG emitted from the storage ponds and process configurations that manage fresh or aged landfill leachate were investigated. Our results showed that strong CH4 emissions were observed from the fresh leachate storage pond, with the fluxes values (2219–26,489 mg C m?2 h?1) extremely higher than those of N2O (0.028–0.41 mg N m?2 h?1). In contrast, the emission values for both CH4 and N2O were low for the aged leachate tank. N2O emissions became dominant once the leachate entered the treatment plants of both systems, accounting for 8–12% of the removal of N-species gases. Per capita, the N2O emission based on both leachate treatment systems was estimated to be 7.99 g N2O–N capita?1 yr?1. An increase of 80% in N2O emissions was observed when the bioreactor pH decreased by approximately 1 pH unit. The vast majority of carbon was removed in the form of CO2, with a small portion as CH4 (<0.3%) during both treatment processes. The cumulative GHG emissions for fresh leachate storage ponds, fresh leachate treatment system and aged leachate treatment system were 19.10, 10.62 and 3.63 Gg CO2 eq yr?1, respectively, for a total that could be transformed to 9.09 kg CO2 eq capita?1 yr?1.  相似文献   

19.
Increased energy consumption due to industrial growth has increased the levels of carbon dioxide (CO2) emission being released into the atmosphere. CO2 emission is a type of greenhouse gas which is a major cause of global warming. Since the issue of CO2 emissions has drawn much attention in recent years, the development of CO2 capture technology has become a necessity. Although CO2 adsorbents are still at the early development stage, it has been suggested that CO2 adsorbents are the most effective technology in controlling CO2 emissions. Solid adsorbents have great potential as an alternative method to conventional adsorbents in adsorbing CO2. In this paper, low cost adsorbents including activated carbon, zeolites, mesoporous silica and clays are discussed in terms of adsorbent preparation methods and CO2 adsorption capacity. The low cost adsorbents are mainly derived from waste materials such as fly ash, steel slag, red mud, bagasses wastes and wood wastes. Besides that, natural resources such as clays have also been applied as low cost CO2 adsorbents. Surface modifications have also been applied to the low cost adsorbents, including metal ion exchange and amine impregnation to enhance CO2 adsorption capacity. In the last section, the current status of CO2 adsorbents is summarized and future trends are discussed briefly to predict the potential materials which can be applied as CO2 adsorbents.  相似文献   

20.
以宝鸡第二发电厂间接空冷机组为例,分别采用德国AUSTAL2000大气预测模式与美国AERMOD大气预测模式,对烟塔合一和烟囱两种排放方式的大气环境影响进行分析预测,并分析了地形因素对预测结果的影响。通过对比分析得知,烟塔合一排放的地面浓度分布较分散,而烟囱排放造成的地面浓度分布较集中。考虑地形影响时采用AUSTAL2000计算的烟塔合一地面浓度比AERMOD计算的烟囱小,不考虑地形时则反之。  相似文献   

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