基于GIS技术的危险废物资源管理系统的研究

文章将地理信息技术引入到危险废物管理中,主要通过对基于GIS危险废物管理信息系统的设计,将危险废物管理、计算机和GIS技术结合在一起,为城市的危险废物提供一个快捷、方便、科学的管理和决策支持的计算机系统。通过该系统的开发,能有效管理分布在城市各处的危险废物,减轻其对城市及周边环境的污染,对城市的开发建设和环境保护起到一定的借鉴作用。     

云南省危险废物初期管理探讨

简介了危险废物的概念,危险废物的来源和危害.根据云南省危险废物调查结果,分析了危险废物现行管理中存在的问题,提出了建立危险废物管理信息系统的重要性,并提出了系统建立的构想.     

云南省危险废物初期管理探讨

简介了危险废物的概念,危险废物的来源和危害。根据云南省危险废物调查结果,分析了危险废物现行管理中存在的问题,提出了建立危险废物管理信息系统的重要性,并提出了系统建立的构想。     

危险废物分类、识别、监控一体化管理技术研究概述

研究运用环境统计信息系统(ESIS),建立黑龙江省典型危险废物的数据库系统,使其具备系统、完善的查询与追踪功能;提出危险废物易燃性、腐蚀性、反应性和毒性方面定量化的定义,建立基于危险废物成分分析基础上的分类体系,使危险废物的处理与处置具有良好的可操作性;开发危险废物在线识别技术,促进对危险废物进行监管及预警的时效性和有效性;运用GPS、GSM、GPRS、GIS、计算机网络通信和数据处理等监控技术,实施对危险废物运输车辆的远程在线监控;提出危险废物收集、贮存、分离、运输、处理、处置、回收利用过程中的管理法律、法规,促进危险废物全过程管理的有效实现.     

我国危险废物特性鉴别技术体系研究

详细深入地调查分析了国外危险废物鉴别技术体系的特点和适用条件,以及我国危险废物管理的特点.在借鉴国内外经验与教训的基础上,提出了我国危险废物特性鉴别的技术路线及危险废物鉴别的环境保护目标,建立了危险废物鉴别技术的方法学.在充分研究的基础上,编制完成了全新的<国家危险废物名录>和<危险废物鉴别标准>,以及相应的规范和方法标准.这些技术文件形成了我国独特、完整的危险废物鉴别技术体系,为全面开展危险废物无害化管理提供了有力的技术支持.      

广州市危险废物动态监管系统应用研究

本文通过分析国内外危险废物监管的研究动态,指出了危险废物动态监管系统的发展趋势,并以广州市固体废物管理中心为例,对广州市固体废物GIS管理信息系统融合危险废物动态监管系统功能架构进行研究,该系统既能满足固体废物的静态业务管理功能,又能对危险废物运输车辆进行动态监管,可以实现危险废物从"摇篮"到"坟墓"的全过程管理。     

江苏省危险废物动态管理信息系统应用及优化设计研究

为进一步加大危险废物监管力度,江苏省实施了危险废物市内转移网上报告试点工作,开发了危险废物动态管理信息系统软件,利用信息技术加强环境监管,简化审批环节,实现线上线下一体化管理.通过分析危险废物动态管理信息系统的主要结构和应用,阐述申报登记、经营台账、查询统计、信息预警、网上转移、日常监督等模块内容,针对系统在危险废物转移实时监控方面的不足之处,提出了开发电子联单的二维码标签和系统的手机操作软件,并共享交通部门GPS监控数据的优化建议.优化后的系统有助于降低危险废物转移过程中的环境风险,真正实现危险废物的全过程安全监控与管理.     

我国工业危险废物产生特性研究

工业生产是危险废物的主要来源,工业危险废物是世界各国固体废物管理的重要方面.以我国历年环境统计数据为基础,全面分析了我国工业危险废物产生现状和特点.研究了工业危险废物产生量、利用量和处置量、工业危险废物区域和行业分布特点、工业危险废物与工业固体废物的关系、工业危险废物产生量与工业产值的关系及工业危险废物产生的变化趋势等.提出今后我国既要重视对传统的石油化工、化学工业和冶金工业等行业产生的危险废物管理,又要重视对高新技术产业和西部资源省份产生工业危险废物的管理.     

三峡库区危险废物污染与处置现状及对策

通过调查研究,从危险废物的产生、分类、处理处置、排放和管理方式等方面分析了三峡库区危险废物的污染与处置现状.结果表明目前三峡库区的绝大部分危险废物是已关、停企业的遗留废物,应针对其特点,加快危险废物管理和市场经营体系的建设,进一步建立和完善管理机构,杜绝其对环境的污染,保护三峡库区生态环境.针对危险废物管理中存在的问题和今后的发展规划,结合国内外危险废物管理经验,从管理、技术发展、处理处置设施建设和运行方面提出了建议,并对二期清库暂存的危险废物提出了具体的处置方案.     

中国工业危险废物的环保管理现状与对策建议研究

从危险废物的涵义出发,指出了危险废物的特性和分类,分析了中国工业危险废物的产生和处置现状,工业危险废物对水体、大气、土壤和人体健康的危害.从工业企业、经营单位和环保部门三个层面,指出了工业企业危废业务薄弱和管理不规范,危险废物经营单位处置能力不足和结构不合理以及危险废物环境监管能力不足的三大问题,提出了解决好危险废物的出路问题、抓好重点种类危废管理和深化重点企业规范化管理的三项对策建议,做出了必须强化危险废物规范化管理的结论.     

Effects of two sludge application on fractionation and phytotoxicity of zinc and copper in the soil

The potential harm of heavy metals is a primary concern in application of sludge to the agricultural land. A pot experiment was conducted to evaluate the effect of two sludges on fractionation of Zn and Cu in soil and their phytotoxicity to pakchoi. The loamy soil was mixed with 0%, 20%, 40%, 60% and 80% (by weight) of digested sewage sludge (SS) and composted sludge (SC). The additions of both sludges caused a significant raise in all fractions, resulting in that exchangeable (EXCH) and organic bound (OM) became predominance of Zn and organic bound Cu occupied the largest portion. There was more available amount of Zn and Cu in SS treatments than SC treatments. During the pot experiment, the concentration of Zn in EXCH, carbonate (CAR) and OM and Cu in EXCH and OM fractions decreased in all treatments, so their bioavailability reduced. Germination rate and plant biomass decreased when the addition rate was high and the best yield appeared in 20% mixtures at the harvest of pakchoi. The two sludges increased tissue contents of Zn and Cu especially in the SS treatments. Zn in pakchoi was not only in relationship to ΔEXCH and ΔCAR forms but also in ΔOM forms in the sludge-soil mixtures. Tissue content of Cu in pakchoi grown on SC-soils could not be predicted by ΔEXCH. These correlation rates between Zn and Cu accumulation in pakchoi and variation of different fractions increased with time, which might indicate that sludges represented stronger impacts on the plant in long-term land application.     

Intraspecific differences in effects of co-contamination of cadmium and

A hydroponic experiment was carried out to study intraspecific differences in the effects of different concentrations of cadmium (Cd)(0-10 mg/L) and arsenate (As(V)) (0-8 mg/L) on the growth parameters and accumulation of Cd and As in six wheat varieties Jing-9428, Duokang-1, Jingdong-11, Jing-411, Jingdong-8 and Zhongmai-8. The endpoints of wheat seedlings, including seed germination,biomass, root length and shoot height, decreased with increasing the Cd and As concentrations. Significant differences in seed germination, biomass, root length, shoot height and the accumulation of Cd and As were observed between the treatments and among the varieties (p ＜ 0.05). The lethal dosage 50% were about 20, 80, 60, 60, 80 and 20 mg As/L for Jing-9428, Duokang-1, Jingdong-11,Jing-411, Jingdong-8 and Zhongmai-8, respectively, and the corresponding values for Cd were about 30, 80, 20, 40, 60 and 10 mg Cd/L, respectively. Among the six varieties, Duokang-1 was found to be the most resistant to Cd and As toxicity, and Zhongmai-8 was the most sensitive to Cd and As co-contamination. The resistance of the six varieties was found dependant on the seedling uptake of Cd and As. Duokang-1 was the most suitable for cultivation in Cd and As co-contaminated soils.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.