Reducing the energy penalty of CO2 capture and compression using pinch analysis

Integration of CO₂ capture and storage (CCS) into coal-fired power stations is seen as a way of significantly reducing the carbon emissions from stationary sources. A large proportion of the estimated cost of CCS is because of the additional energy expended to capture the CO₂ and compress it for transport and storage, reducing the energy efficiency of the power plant. This study uses pinch analysis and heat integration to reduce the overall energy penalty and, therefore, the cost of implementing CCS for power plants where the additional heat and power for the CCS plant will be provided by the existing power plant. A combined pinch analysis and linear programming optimisation are applied to determine targets for the energy penalty of existing power plants. Two existing pulverised brown coal power plants with new CCS plants using solvent absorption are used as the basis for the study that show the energy penalty can be reduced by up to 50% by including effective heat integration. The energy penalty can be further reduced by pre-drying the coal.     

Carbon dioxide direct air capture for effective climate change mitigation based on renewable electricity: a new type of energy system sector coupling

Pathways for achieving the 1.5–2 °C global temperature moderation target imply a massive scaling of carbon dioxide (CO₂) removal technologies, in particular in the 2040s and onwards. CO₂ direct air capture (DAC) is among the most promising negative emission technologies (NETs). The energy demands for low-temperature solid-sorbent DAC are mainly heat at around 100 °C and electricity, which lead to sustainably operated DAC systems based on low-cost renewable electricity and heat pumps for the heat supply. This analysis is carried out for the case of the Maghreb region, which enjoys abundantly available low-cost renewable energy resources. The energy transition results for the Maghreb region lead to a solar photovoltaic (PV)-dominated energy supply with some wind energy contribution. DAC systems will need the same energy supply structure. The research investigates the levelised cost of CO₂ DAC (LCOD) in high spatial resolution and is based on full hourly modelling for the Maghreb region. The key results are LCOD of about 55 €/t_CO2 in 2050 with a further cost reduction potential of up to 50%. The area demand is considered and concluded to be negligible. Major conclusions for CO₂ removal as a new energy sector are drawn. Key options for a global climate change mitigation strategy are first an energy transition towards renewable energy and second NETs for achieving the targets of the Paris Agreement.

     

The role of uncertainty in future costs of key CO<Subscript>2</Subscript> abatement technologies: a sensitivity analysis with a global computable general equilibrium model

Deep emission cuts rely on the use of low carbon technologies like renewable energy or carbon capture and storage. There is considerable uncertainty about their future costs. We carry out a sensitivity analysis based on Gauss Quadrature for cost parameters describing these technologies in order to evaluate the effect of the uncertainty on total and marginal mitigation costs as well as composition changes in the energy system. Globally, effects in total cost often average out, but different regions are affected quite differently from the underlying uncertainty in costs for key abatement technologies. Regions can be either affected because they are well suited to deploy a technology for geophysical reasons or because of repercussions through international energy markets. The absolute impact of uncertainty on consumption increases over the time horizon and with the ambition of emission reductions. Uncertainty in abatement costs relative to expected abatement costs are however larger under a moderate ambition climate policy scenario because in this case the marginal abatement occurs in the electricity sector where the cost uncertainty is implemented. Under more ambitious climate policy in line with the two degree target, the electricity sector is always decarbonized by 2050, hence uncertainty has less effect on the electricity mix. The findings illustrate the need for regional results as global averages can hide distributional consequences on technological uncertainty.     

Carbon capture and storage deployment rates: needs and feasibility

Carbon capture and storage (CCS) may become a key technology to limit human-induced global warming, but many uncertainties prevail, including the necessary technological development, costs, legal ramifications, and siting. As such, an important question is the scale of carbon dioxide abatement we require from CCS to meet future climate targets, and whether they appear reasonable. For a number of energy technology and efficiency improvement scenarios, we use a simple climate model to assess the necessary contribution from CCS to ‘fill the gap’ between scenarios’ carbon dioxide emissions levels and the levels needed to meet alternative climate targets. The need for CCS depends on early or delayed action to curb emissions and the characteristics of the assumed energy scenario. To meet a 2.5°C target a large contribution and fast deployment rates for CCS are required. The required deployment rates are much faster than those seen in the deployment of renewable energy technologies as well as nuclear power the last decades, and may not be feasible. This indicates that more contributions are needed from other low-carbon energy technologies and improved energy efficiency, or substitution of coal for gas in the first half of the century. In addition the limited availability of coal and gas by end of the century and resulting limited scope for CCS implies that meeting the 2.5°C target would require significant contributions from one or more of the following options: CCS linked to oil use, biomass energy based CCS (BECCS), and CCS linked to industrial processes.     

Pinch analysis approach to carbon-constrained planningfor sustainable power generation

A graphical pinch-based methodology for planning retrofits for carbon capture and storage (CCS) in the power generation sector is presented in this work. CCS is widely seen as one of the essential interim technologies to mitigate greenhouse gas emissions, while still being able to utilize fossil fuels, which are relatively inexpensive and reliable in comparison to inherently low-carbon renewable resources. However, retrofitting power plants for CCS entails major capital costs as well as a reduction of thermal efficiency and power output. Thus, it is essential for planning purposes to implement the minimal extent of CCS retrofit that meets the sectoral carbon footprint targets. At the same time, it is necessary to plan for additional power generation capacity or efficiency enhancements to compensate for energy losses resulting from CCS retrofits. The simple graphical approach used in this paper is designed to determine such targets, and shares the same intuitive, insight-driven characteristics of pinch analysis techniques. A case study is shown to illustrate the methodology.     

Fighting sustainability challenges on two fronts: Material efficiency and the emerging carbon capture and storage technologies

Technological and regulatory responses to large-scale environmental threats, such as depletion of the natural resources and climate change, tend to focus on one issue at time. Emerging carbon capture and storage (CCS) technologies that are in different stages of development offer a case that demonstrates this dilemma. This article approximates the implications of two emerging CCS applications on existing steel mill’s CO₂ emissions and its use of material resources. The evaluated applications are based on the mineralization method and the comparative case represents two versions of a geological CCS method. The results of the evaluation indicate that if technical bottleneck issues related to CO₂ sequestration with mineralization can be solved, it can be possible to achieve a similar CO₂ reduction performance with mineralization-based CCS applications as with more conventional CCS applications. If the CO₂ capturing potential of mineralization-based applications could be taken into use, it could also enable the significant improvement of material efficiency of industrial operations. Urgent problem hampering the development of mineralization-based CCS applications is that the policy regimes related to CCS especially in the European Union (EU) do not recognize mineralization as a CCS method. Article suggests that the focus in the future evaluations and in policy should not be directed only on CO₂ sequestration capacity of CCS applications. Similarly important is to consider their implications on material efficiency. Article also outlines modifications to the EU’s CCS policy in terms of the formal terminology.     

Renewable energy resources and technologies in Nigeria: present situation, future prospects and policy framework

Nigeria is endowed with abundant energy resources, both conventional and renewable, whichprovide her with immense capacity to develop an effective national energy plan. However, introduction of renewable energyresources into the nation's energy mix have implications on itsenergy budget. The national energy supply system has been projected intothe future using MARKAL, a large scale linear optimization model.However, this model may not be absolutely representative of the highlynon-linear future of renewable energy. Results of the model reveal that under onlya least cost constraint, only large hydro power technology is the prominentcommercial renewable energy technology in the electricity supply mix of thecountry. Despite the immense solar energy potentials available, solar electricity generation is attractive only under severeCO2 emissions mitigation of the nation's energy supply system. Similarly, the penetration of small-scale hydro power technology in theelectricity supply mix is favoured only under CO₂ emissionsconstraints. Due to economy of scale, large hydropower technology takes the lion share of all the commercial renewableenergy resources share for electricity generation under any CO₂emissions constraint. These analyses reveal that some barriers exist to thedevelopment and penetration of renewable energy resources electricity production in Nigeria's energy supplysystem. Barriers and possible strategies to overcome them arediscussed. Intensive efforts and realistic approachtowards energy supply system in the country will have to be adopted inorder to adequately exploit renewable energy resources and technologiesfor economic growth and development.     

Valuing power plant flexibility with CCS: the case of post-combustion capture retrofits

An important development in recent years has been increased interest in retrofitting CO₂ capture at existing power plants. In parallel, it has also been suggested that flexible operation of power plants with CO₂ capture could be important in at least some jurisdictions. It is likely that retrofitted power plants could have significant ??built-in?? flexibility, but this potential is often not considered in studies of the economic performance of power plants with CO₂ capture. This paper makes a contribution to filling this gap by developing methods for first order screening analysis of flexible operation of power plants with CO₂ capture and applying them to the case study example of an appropriately integrated retrofit of post-combustion capture at a coal-fired power plant. The quantitative analysis suggests that rich solvent storage could be an attractive option on a short-run basis for some fuel, CO₂ and electricity price combinations. Results from first order analysis can then be used to determine which operating modes should (and shouldn??t) be included in further, more detailed design studies.     

Carbon emissions and management scenarios for consumer-owned utilities

An important subset of the utility sector has been scarcely explored for its ability to reduce carbon dioxide emissions: consumer-owned electric utilities significantly contribute to U.S. greenhouse gas emissions, but are often excluded from energy efficiency and renewable energy policies. They sell a quarter of the nation's electricity, yet the carbon impact of these sales is not well understood, due to their small size, unique ownership models, and high percentage of purchased power for distribution. This paper situates consumer-owned utilities in the context of emerging U.S. climate policy, quantifying for the first time the state-by-state carbon impact of electricity sales by consumer-owned utilities. We estimate that total retail sales by consumer-owned utilities account for roughly 568 million metric tons of CO₂ annually, making this sector the 7th largest CO₂ emitter globally, and examine state-level carbon intensities of the sector in light of the current policy environment and the share of COU distribution in the states. Based on efficiency and fuel mix pathways under conceivable regulations, carbon scenarios for 2030 are developed.     

CO2-emission reduction in China’s residential building sector and contribution to the national climate change mitigation targets in 2020

Between 1980 and 2007, in the Chinese building sector in urban and rural areas, coal was mainly substituted with electricity and natural gas. Growing income will further increase energy consumption and CO₂-emissions in the building sector. Using an econometric model, disaggregated energy demand and related CO₂-emissions in the residential sector as well for the whole economy are estimated and forecasted until 2050. In 2009, the Chinese government pledged itself to reduce CO₂-intensity by 40%?C45% in 2020 compared to 2005. Aim of this article is to assess to which extent the measures in the building sector in China can contribute to this target. Main results of the analysis are: (a) The primary energy source coal was mainly substituted by electricity generated with coal. Apart from convenience gains, the environmental advantages are questionable. (b) Between 2010 and 2050, energy demand in the building sector will grow by 2.0%?C4.1% per annum leading to CO₂-emissions at least almost tripling from about 560 mill. tons in 2010 to about 1,500 mill. tons in 2050. (c) The energy efficiency gains in the building sector and other sectors of the Chinese economy, however, are not enough to fulfill the national CO₂-intensity targets. The reduction of the CO₂-intensity of GDP would be 37.2% in the BAU-scenario, and 31.9% in the LOW-scenario. Only in the HIGH-scenario (46.3%), the economy is growing efficient enough relative to the induced CO₂-emissions. The remaining CO2-emission reductions could be gained by additional promotion of renewable energies (mainly solar and geo-thermal) in the building sector.     

Equal Opportunity for Biomass in Greenhouse Gas Accounting of CO2 Capture and Storage: A Step Towards More Cost-Effective Climate Change Mitigation Regimes

Carbon dioxide capture and permanent storage (CCS) is one of the most frequently discussed technologies with the potential to mitigate climate change. The natural target for CCS has been the carbon dioxide (CO₂) emissions from fossil energy sources. However, CCS has also been suggested in combination with biomass during recent years. Given that the impact on the earth's radiative balance is the same whether CO₂ emissions of a fossil or a biomass origin are captured and stored away from the atmosphere, we argue that an equal reward should be given for the CCS, independent of the origin of the CO₂. The guidelines that provide assistance for the national greenhouse gas (GHG) accounting under the Kyoto Protocol have not considered CCS from biomass (biotic CCS) and it appears that it is not possible to receive emission credits for biotic CCS under the first commitment period of the Kyoto Protocol, i.e., 2008–2012. We argue that it would be unwise to exclude this GHG mitigation alternative from the competition with other GHG mitigation options. We also propose a feasible approach as to how emission credits for biotic CCS could be included within a future accounting framework.     

Challenge of global climate change: Prospects for a new energy paradigm

Perspectives on the challenge posed by potential future climate change are presented including a discussion of prospects for carbon capture followed either by sequestration or reuse including opportunities for alternatives to the use of oil in the transportation sector. The potential for wind energy as an alternative to fossil fuel energy as a source of electricity is outlined including the related opportunities for cost effective curtailment of future growth in emissions of CO₂.     

Global Biomass Energy Potential

The intensive use of renewable energy is one of the options to stabilize CO₂atmospheric concentration at levels of 350 to 550ppm. A recent evaluation of the global potential of primary renewable energy carried out by Intergovernmental Panel on Climate Change (IPCC) sets a value of at least 2800EJ/yr, which is more than the most energy-intensive SRES scenario forecast for the world energy requirement up to the year 2100. Nevertheless, what is really important to quantify is the amount of final energy since the use of renewable sources may involve conversion efficiencies, from primary to final energy, different from the ones of conventional energy sources. In reality, IPCC does not provide a complete account of the final energy from renewables, but the text claims that using several available options to mitigate climate change, and renewables is only one of them, it is possible to stabilize atmospheric carbon dioxide (CO₂) concentration at a low level. In this paper, we evaluate in detail biomass primary and final energy using sugarcane crop as a proxy, since it is one of the highest energy density forms of biomass, and through afforestation/reforestation using a model presented in IPCC Second Assessment Report (SAR). The conclusion is that the primary-energy potential for biomass has been under-evaluated by many authors and by IPCC, and this under-evaluation is even larger for final energy since sugarcane allows co-production of electricity and liquid fuel. Regarding forests we reproduce IPCC results for primary energy and calculate final energy. Sugarcane is a tropical crop and cannot be grown in all the land area forecasted for biomass energy plantation in the IPCC/TAR evaluation (i.e. 1280Mha). Nevertheless, there are large expanses of unexploited land, mainly in Latin America and Africa that are subject to warm weather and convenient rainfall. With the use of 143Mha of these lands it is possible to produce 164EJ/yr (1147GJ/hayr or 3.6W/m²on average) of primary energy and 90EJ/yr of final energy in the form of liquid fuel (alcohol) and electricity, using agricultural productivities near the best ones already achievable and biomass gasification technology. More remarkable is that these results can be obtained with the operation of 4,000 production units with unitary capacity similar to the largest currently in operation. These units should be spread over the tropical land area yielding a plantation density similar to the one presently observed in the state of São Paulo, Brazil, where alcohol and electricity have been commercialized in a cost-effective way for several years. Such an amount of final energy would be sufficiently large to fulfill all the expected global increase in oil demand, as well as in electricity consumption by 2030, assuming the energy demand of such sources continues to grow at the same pace observed over the last two decades. When sugarcane crops are combined with afforestation/reforestation it is possible to show that carbon emissions decline for some IPCC SRES scenarios by 2030, 2040 and 2050. Such energy alternatives significantly reduce CO₂emissions by displacing fossil fuels and promote sustainable development through the creation of millions of direct and indirect jobs. Also, it opens an opportunity for negative CO₂emissions when coupled with carbon dioxide capture and storage.     

Embedding CCS infrastructure into the European electricity system: a policy coordination problem

Carbon dioxide capture and storage (CCS) has recently been receiving increasing recognition in policy debates. Various aspects of possible regulatory frameworks for its implementation are beginning to be discussed in Europe. One of the issues associated with the wide use of CCS is that it requires the establishment of a carbon dioxide (CO₂) transport network, which could result in the spatial restructuring of power generation and transmission systems. This poses a significant coordination problem necessitating public planning and regulation. This paper provides a survey over multiple research strands on CCS, particularly energy system modeling and spatial optimization, pertaining to the efficient installment of CCS-related infrastructure throughout Europe. It integrates existing findings and highlights the factors that determine policy coordination needs for a potential wide implementation of CCS in the next decades.     

CO2收集封存战略及其对我国远期减缓CO2排放的潜在作用

碳收集封存(CCS)已被广泛地认为是一种潜在的、可供选择的CO₂减排方案,以稳定大气中CO₂浓度、减缓气候变化.本文介绍了CCS的3大环节：碳的捕获、运输与储存,对不同捕获技术及其技术经济参数进行分析评价,介绍了不同碳地质储存的机理、潜力与成本, 以及CCS的应用对全球减缓碳排放的作用.更新中国MARKAL模型,加入各种可能的CCS技术,特别是考虑CCS的煤间接液化以及多联产技术,以同时考虑石油安全与CO₂减排.通过设置不同的情景,应用中国MARKAL模型研究了CCS对我国远期（到2050年）减缓CO₂排放的潜在作用,结果表明,CCS技术的应用不仅可能减少我国的碳排放,降低边际碳减排成本（碳减排率50%时,下降率达45%）,减轻高减排率时对核电的高度依赖,还可能使我国更长时间地清洁利用煤炭资源（在C70情景下,2050年煤在一次能源消费中的比例可从10%增到30%）.我国应重视对CCS技术的研发以及示范项目的建设.     

Brazil's Electric Power Choices and Their Corresponding Carbon Emissions Implications

This study analyzes the options for meeting power demand in the Brazilianpower sector through the year 2015. Three policy cases are constructedto test economic and environmental policy measures against a baseline:advanced technologies scenario, environmental control scenario and carbon(C) elimination scenario. Least-cost modeling simulated these scenarios throughchanges in emissions fees and caps, costs for advanced technologies,demand side efficiency, and clean energy supplies. Results show that, in theabsence of alternative policies, new additions to Brazil's electric powersector will shift rapidly from hydroelectricity to combined-cycle natural gasplants. When the cost of environmental impacts are incorporated in theprice of power, the least-cost mix of electric power generation technologycould change in other ways. In all scenarios, energy efficiency andcogeneration play an important role in the least-cost power solution. Savingelectricity through increased efficiency offsets the needs for new supply andhas enormous potential in Brazil's industrial sector. Efficiency also reducesthe environmental burden associated with electricity production andtransmission, without compromising the quality of the services demandedby end users. Interesting enough, carbon dioxide (CO₂) emissions will remainrelatively low under almost every conceivable scenario.     

CO2 Capture in Pulp and Paper Mills: CO2 Balances and Preliminary Cost Assessment

This paper investigates overall CO₂ balances of combined heat and power (CHP) plants with CO₂ capture and storage (CCS) in Kraft pulp and paper mills. The CHP plants use biomass-based fuels and feature advanced gasification and combined cycle technology. Results from simple process simulations of the considered CHP plants are presented. Based on those results and taking into account the major direct and indirect changes in CO₂ emissions, the study shows that implementing CCS leads to steep emission reductions. Furthermore, a preliminary cost assessment is carried out to analyse the CO₂ mitigation cost and its dependence on the distance that the CO₂ must be transported to injection sites.     

Biomass-based negative emission technology options with combined heat and power generation

Biomass-based combined heat and power (CHP) generation with different carbon capture approaches is investigated in this study. Only direct carbon dioxide (CO₂) emissions are considered. The selected processes are (i) a circulating fluidized bed boiler for wood chips connected to an extraction/condensation steam cycle CHP plant without carbon capture; (ii) plant (i), but with post-combustion CO₂ capture; (iii) chemical looping combustion (CLC) of solid biomass connected to the steam cycle CHP plant; (iv) rotary kiln slow pyrolysis of biomass for biochar soil storage and direct combustion of volatiles supplying the steam cycle CHP plant with the CO₂ from volatiles combustion escaping to the atmosphere; (v) case (iv) with additional post-combustion CO₂ capture; and (vi) case (iv) with CLC of volatiles. Reasonable assumptions based on literature data are taken for the performance effects of the CO₂ capture systems and the six process options are compared. CO₂ compression to pipeline pressure is considered. The results show that both bioenergy with carbon capture and storage (BECCS) and biochar qualify as negative emission technologies (NETs) and that there is an energy-based performance advantage of BECCS over biochar because of the unreleased fuel energy in the biochar case. Additional aspects of biomass fuels (ash content and ash melting behavior) and sustainable soil management (nutrient cycles) for biomass production should be quantitatively considered in more detailed future assessments, as there may be certain biomass fuels, and environmental and economic settings where biochar application to soils is indicated rather than the full conversion of the biomass to energy and CO₂.

     

北京市减污降碳协同控制情景模拟和效应评估

将能源、建筑、产业和交通作为减污降碳重点领域,设置了基准情景、政策情景和强化情景,以2020年为基准年,2035年为目标年,开展北京市大气污染物和CO₂减排潜力测算,并构建了一种协同控制效应分级评估方法,对政策情景和强化情景下大气污染和CO₂协同控制效应进行量化评估.结果表明,与基准情景相比,政策情景和强化情景下大气污染物减排率分别在11%～75%和12%～94%,CO₂分别为41%和52%.优化机动车结构对于NO_x、 VOCs和CO₂的减排贡献最大,政策情景下减排率分别达到74%、 80%和31%,强化情景下分别达到68%、 74%和22%;完成农村地区散煤清洁能源改造对SO₂的减排贡献最大,政策和强化情景下分别达到47%和35%;提升新建建筑绿色化水平对PM₁₀的减排贡献最大,政策和强化情景下分别达到79%和74%.优化出行结构和推动数字基础设施绿色发展的协同控制效应最佳;强化情景下,完成农村地区散煤清洁能源改造、优化机动车结构和...     

Modern Biomass Conversion Technologies

This article gives an overview of the state-of-the-art of key biomass conversion technologies currently deployed and technologies that may play a key role in the future, including possible linkage to CO₂ capture and sequestration technology (CCS). In doing so, special attention is paid to production of biofuels for the transport sector, because this is likely to become the key emerging market for large-scale sustainable biomass use. Although the actual role of bio-energy will depend on its competitiveness with fossil fuels and on agricultural policies worldwide, it seems realistic to expect that the current contribution of bio-energy of 40–55 EJ per year will increase considerably. A range from 200 to 300 EJ may be observed looking well into this century, making biomass a more important energy supply option than mineral oil today. A key issue for bio-energy is that its use should be modernized to fit into a sustainable development path. Especially promising are the production of electricity via advanced conversion concepts (i.e. gasification and state-of-the-art combustion and co-firing) and modern biomass derived fuels like methanol, hydrogen and ethanol from ligno-cellulosic biomass, which can reach competitive cost levels within 1–2 decades (partly depending on price developments with petroleum). Sugar cane based ethanol production already provides a competitive biofuel production system in tropical regions and further improvements are possible. Flexible energy systems, in which biomass and fossil fuels can be used in combination, could be the backbone for a low risk, low cost and low carbon emission energy supply system for large scale supply of fuels and power and providing a framework for the evolution of large scale biomass raw material supply systems. The gasification route offers special possibilities to combine this with low cost CO₂ capture (and storage), resulting in concepts that are both flexible with respect to primary fuel input as well as product mix and with the possibility of achieving zero or even negative carbon emissions. Prolonged RD&D efforts and biomass market development, consistent policy support and international collaboration are essential to achieve this.