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1.
The carcinogenic etfect of 210Po and 210Pb with respect to lung cancer is an important problem in many countries with very high cigarette consumption. Poland has one of the highest consumptions of cigarettes in the world. The results of 210Po determination on the 14 most frequently smoked brands of cigarettes which constitute over 70% of the total cigarette consumption in Poland are presented and discussed. Moreover, the polonium content in cigarette smoke was estimated on the basis of its activity in fresh tobaccos, ash, fresh filters and post-smoking filters. The annual effective doses were calculated on the basis of 210Po and 210Pb inhalation with the cigarette smoke. The results of this work indicate that Polish smokers who smoke one pack (20 cigarettes) per day inhale from 20 to 215 mBq of 210Po and 210Pb each. The mean values of the annual effective dose for smokers were estimated to be 35 and 70 microSv from 210Po and 210Pb, respectively. For persons who smoke two packs of cigarettes with higher radionuclide concentrations, the effective dose is much higher (471 microSv yr(-1)) in comparison with the intake in diet. Therefore, cigarettes and the absorption through the respiratory system are the main sources and the principal pathway of 210Po and 210Pb intake of smokers in Poland.  相似文献   

2.
Ventilation requirements in occupied spaces have traditionally derived largely from odor control. The requirements have rested on the notion that an environment that seems subjectively acceptable to a visitor will in fact be healthful and comfortable for both visitor and occupant alike. Ventilation requirements have derived secondarily from criterion concentrations of notable contaminants (e.g., carbon dioxide). The present investigation looked again at both sensory (odor, irritation) and physical criteria of acceptability, paying particular attention to the difference between smoking and nonsmoking occupancy in a well-controlled environmental chamber. More than 200 persons (visitors) made judgments of odor intensity and acceptability under various conditions of occupancy (up to 12 nonsmoking occupants; a temperature of up to 25.5°C; up to 16 cigarettes smoked per hour). The results implied that under nonsmoking conditions and moderate humidity only about 7.5 cfm (3.8 L sec−1) of fresh air per occupant sufficed to satisfy visitors, but that under smoking conditions at least 5 times as much fresh air is necessary. Our estimate of ventilation requirements for smoking were derived in part from measurements of carbon monoxide and total suspended particulate (TSP) mass concentration. Levels of TSP achieved during realistic smoking and ventilation rates exceeded levels deemed acceptable outdoors. Surfaces in the chamber played an important role in the elimination of particles, presumably via adsorption. Use of an electrostatic precipitator could keep TSP levels under control. Nevertheless, it remains to be seen whether control of TSP will eliminate the need for enormous ventilation for odor control during smoking occupancy.  相似文献   

3.
Exposure to sidestream tobacco smoke is concerned with constituents in suspension in the indoor atmosphere. The natural dissipation of sidestream tobacco smoke has been investigated in a static atmosphere in a 10 m3 experimental chamber, and the rate of dissipation is expressed as T0.5, the half-life of residence in the air. Respective T0.5 of smoke components are calculated from the various sample data points, assuming a kinetic equation of the first-order process. Sidestream smoke has been generated by a smoking machine according to the Coresta standard protocol and then left to age over an 8-hour period, with subsequent sampling at defined time intervals. The experiments have been repeated over five days, and eight data point samples are obtained for each experiment. Besides nicotine, CO, and smoke particulate matter, interest has been focused on polycyclic aromatic hydrocarbons (PAH). The initial concentrations, C0 for smoke particulate matter and nicotine (gas and particulate phases) are found to be 13.8 mg and 92 μg per cigarette per cubic meter, with T0.5 being 2.6 and 2.1 hours, respectively. Low molecular-weight PAH have T0.5 up to 20 hours, explainable only by their high concentrations in the gas phase, while the 3- to 7-ring PAH have T0.5 of about 2 hours. The contribution of CO to ambient concentration is 91 mg per cigarette per cubic meter. The data can be useful in mathematical modellization studies regarding ventilation or exposure to sidestream smoke.  相似文献   

4.
Alpha and beta activities per unit volume air due to radon, thoron and their decay products were evaluated in the air of various cafe rooms polluted by cigarette smoke. Both CR-39 and LR-115 type II solid state nuclear track detectors (SSNTD) were used. Equilibrium factors between radon and its progeny and thoron and its daughters have been evaluated in the air of the studied cafe rooms. The committed equivalent doses due to short-lived radon decay products were determined in different regions of the respiratory tract of non-smoker members of the public. The influence of cigarette smoke pollution, ventilation rate and exposure time on committed equivalent dose in the respiratory systems of non-smokers was investigated. Committed equivalent doses ranged from 1.15 x 10(-11)-2.7 x 10(-7) Sv.y(-1)/h of exposure in the extrathoracic region and from 0.8 x 10(-12)-1.7 x 10(-8) Sv.y(-1)/h of exposure in the thoracic region of the respiratory tract of non-smokers.  相似文献   

5.
Due to the relatively high activity concentrations of (210)Po and (210)Pb that are found in tobacco and its products, cigarette smoking highly increases the internal intake of both radionuclides and their concentrations in the lung tissues. That might contribute significantly to an increase in the internal radiation dose and in the number of instances of lung cancer observed among smokers. Samples of most frequently smoked fine and popular brands of cigarettes were collected from those available on the Egyptian market. (210)Po activity concentrations were measured by alpha spectrometry, using surface barrier detectors, following the radiochemical separation of polonium. Samples of fresh tobacco, wrapping paper, fresh filters, ash and post-smoking filters were spiked with (208)Po for chemical recovery calculation. The samples were dissolved using mineral acids (HNO(3), HCl and HF). Polonium was spontaneously plated-out on stainless steel disks from diluted HCl solution. The (210)Po activity concentration in smoke was estimated on the basis of its activity in fresh tobacco and wrapping paper, fresh filter, ash and post-smoking filters. The percentages of (210)Po activity concentrations that were recovered from the cigarette tobacco to ash, post-smoking filters, and smokes were assessed. The results of this work indicate that the average (range) activity concentration of (210)Po in cigarette tobacco was 16.6 (9.7-22.5) mBq/cigarette. The average percentages of (210)Po content in fresh tobacco plus wrapping paper that were recovered by post-smoking filters, ash and smoke were 4.6, 20.7 and 74.7, respectively. Cigarette smokers, who are smoking one pack (20 cigarettes) per day, are inhaling on average 123 mBq/d of (210)Po and (210)Pb each. The annual effective doses were calculated on the basis of (210)Po and (210)Pb intake with the cigarette smoke. The mean values of the annual effective dose for smokers (one pack per day) were estimated to be 193 and 251 microSv from (210)Po and (210)Pb, respectively.  相似文献   

6.
The indoor and outdoor air quality of two staff quarters of Hong Kong Polytechnic University at Tsim Sha Tsui East (TSTE) and Shatin (ST) were investigated. The air sampling was carried out in winter for about two months starting from January to February of 1996. Fifteen flats from each staff quarter were randomly selected for indoor/outdoor air pollutant measurements. The pollutants measured were NOx, NO, NO2, SO2, CO, and O3. The variations of pollutant concentrations between indoor and outdoor air were investigated on weekday mornings, weekday evenings, weekend mornings, and weekend evenings. All indoor/outdoor pollutant concentrations measured did not exceed the ASHRAE/NAAQS standard. The carbon monoxide concentrations indoors were systemically higher than those outdoors at the TSTE and the ST quarters, both on weekdays and Sunday, which indicates there are CO sources indoors. Except for CO, the indoor levels of other pollutants (NOx, NO, NO2, SO2, and O3) are lower than those outdoors. There was a significant correlation (P < 0.05) between indoor and outdoor concentrations for SO2 and O3 at both the TSTE and the ST quarters. Except for O3, the mean concentrations of all the pollutants in the TSTE quarters, both indoor and outdoor, were higher than that of the ST quarters in all sampling periods. All indoor and outdoor O3 levels were lower at the TSTE quarters than those at the ST quarters. The O3 ratios of TSTE/ST were 0.72 outdoor and 0.79 indoor. This can be explained by the NO titration reaction through NO conversion to NO2.  相似文献   

7.
Given the shrinking spatial contrasts in outdoor air pollution in Switzerland and the trends toward tightly insulated buildings, the Swiss Cohort Study on Air Pollution and Lung and Heart Diseases in Adults (SAPALDIA) needs to understand to what extent outdoor air pollution remains a determinant for residential indoor exposure. The objectives of this paper are to identify determining factors for indoor air pollution concentrations of particulate matter (PM), ultrafine particles in the size range from 15 to 300 nm, black smoke measured as light absorbance of PM (PMabsorbance) and nitrogen dioxide (NO2) and to develop predictive indoor models for SAPALDIA. Multivariable regression models were developed based on indoor and outdoor measurements among homes of selected SAPALDIA participants in three urban (Basel, Geneva, Lugano) and one rural region (Wald ZH) in Switzerland, various home characteristics and reported indoor sources such as cooking. Outdoor levels of air pollutants were important predictors for indoor air pollutants, except for the coarse particle fraction. The fractions of outdoor concentrations infiltrating indoors were between 30% and 66%, the highest one was observed for PMabsorbance. A modifying effect of open windows was found for NO2 and the ultrafine particle number concentration. Cooking was associated with increased particle and NO2 levels. This study shows that outdoor air pollution remains an important determinant of residential indoor air pollution in Switzerland.  相似文献   

8.
Two studies evaluating the levels and sources of nitrogen dioxide in approximately 90 employee homes in the Richmond area with continuous sampling during the weeks of August 5, 1980, and February 9, 1981, were performed using samplers in the living room, bedroom, kitchen, and outdoors. Additional data were collected concerning appliance usage, heating/cooling plant, ventilation and cigarette smoking. Results were analyzed using BMDP routines. The largest contributor to NO2 concentration was found to be gas-fired kitchen appliances. The mean kitchen level for homes with gas appliances during the winter study was 188 μg/m3. Excluding participants with gas kitchens, incremental influence due to cigarette smoking was detected. The 7-day, 3-room average level of NO2 in the homes of nonsmokers and smokers without gas-fired appliances was 12 and 15 μg/m3, respectively, in the summer. The corresponding winter values were 19 and 22 μg/m3. Furthermore, the individual levels of NO2 in the homes of smokers were generally below both the adjacent outdoor level and the National Ambient Air Quality Standard limit for annual exposure.  相似文献   

9.
This paper describes results of a study that examined NO and NO2 formation on range-top burners and in diffusion flames. These flames were characterized by composition and temperature profiles. Range-top burner flames and pilot flames displayed qualitatively similar behavior with respect to the kinds of flame regions in which relatively high NO2/NO ratios were identified. These regions of high NO2/NO ratios were consistently either regions of low oxygen concentration or flame surfaces subjected to thermal quenching. A limited series of experiments with modified burners indicated that reduced emissions from both the RTB and pilot flames could be achieved by (1) improved primary aeration, using 50% or greater primary air, and (2) using flame geometries designed to minimize flame surface, e.g., flat-flame burners or other designs having effectively fewer distinct ports. Both NO and NO2 are readily produced in diffusion and partially premixed Bunsen-type flames, mainly in the vicinity of the hot visible zone. High NO2/NO ratios are associated with the cooler regions of the flame, as, for example, at the base of the flame in the highly diluted downstream region and in the fuel-rich regions of the flames. A simplified reaction mechanism based on CN and NH radicals being oxidized to NO followed by NO + HO2 → NO2 + OH appears to explain the high NO2/NO ratios observed. A practical implication of the study is that a burner designed with improved aeration and mixing minimization of flame surface should emit less NO2.  相似文献   

10.
A photochemical air quality simulation model was applied to an area covering a large portion of The Netherlands and nearby source areas in Belgium and Germany. Simulations of an O3 episode typical of those that occur during summer months yielded good agreement between predicted and observed O3 levels. The level of performance for NO2 and NO was somewhat less than that for O3. The model was used to study the influence of mobile and stationary sources within the region, as well as the inflow of pollutants from outside the region on predicted O3, NO2, and NO levels within the modeling region. Pollutants transported into the region appear to have a significant influence on O3 levels. The influence of stationary source emissions on O3 and NO2 levels is greater than that of mobile source emissions. The model has been a valuable tool in evaluating the possible influence of different source categories and control regulations on pollutant concentration levels.  相似文献   

11.
Long-term exposure to ambient air pollution can lead to chronic health effects such as cancer, cardiovascular and respiratory disease. Systemic inflammation has been hypothesized as a putative biological mechanism contributing to these adverse health effects. We evaluated the effect of long-term exposure to air pollution on blood markers of systemic inflammation.We measured a panel of 28 inflammatory markers in peripheral blood samples from 587 individuals that were biobanked as part of a prospective study. Participants were from Varese and Turin (Italy) and Umea (Sweden). Long-term air pollution estimates of nitrogen oxides (NOx) were available from the European Study of Cohorts for Air Pollution Effects (ESCAPE). Linear mixed models adjusted for potential confounders were applied to assess the association between NOx and the markers of inflammation.Long-term exposure to NOx was associated with decreased levels of interleukin (IL)-2, IL-8, IL-10 and tumor necrosis factor-α in Italy, but not in Sweden. NOx exposure levels were considerably lower in Sweden than in Italy (Sweden: median (5th, 95th percentiles) 6.65 μg/m3 (4.8, 19.7); Italy: median (5th, 95th percentiles) 94.2 μg/m3 (7.8, 124.5)). Combining data from Italy and Sweden we only observed a significant association between long-term exposure to NOx and decreased levels of circulating IL-8.We observed some indication for perturbations in the inflammatory markers due to long-term exposure to NOx. Effects were stronger in Italy than in Sweden, potentially reflecting the difference in air pollution levels between the two cohorts.  相似文献   

12.
Dilution of indoor air contaminants with less contaminated outdoor air is the most common strategy for control of indoor air quality. Unfortunately this strategy frequently imposes a substantial energy burden. If the contaminants are associated with occupants and their activities, a ventilation control system based on the carbon dioxide level in the controlled space is shown to relieve this energy burden. A test was carried out in the Fridley, MN, Junior High School Music Department to obtain air quality, energy, and subjective response data on an Automatic Variable Ventilation System. A control system with both CO2 and temperature inputs was devised to control the use of outdoor air. Infiltration measurements lead to a quantitative measure of ventil3tion efficiency. This in turn led to recommendations for air circulation patterns in rooms. The measured ventilation efficiency enabled energy and CO2 models to fit measured data. Energy savings of approximately 20% were found for this application. Subjective response of the occupants also was measured. A special questionnaire, subjected to statistical analysis, showed that the subjects felt warmer with increased CO2 in the room air.  相似文献   

13.
Ambient air pollution and children's lung function in China   总被引:1,自引:0,他引:1  
ObjectiveTo describe the correlations between ambient air pollutants (TSP, SO2, NOx) and the level of children's lung function (FVC, FEV1, MMEF) in China.MethodsWe collected the research articles on ambient air pollution and children's lung function published from 1985 to 2006 and selected 11 articles finally according to the following criteria: (1) Children between the age of 7 and 15 as objects; (2) Local air quality monitoring results were reported; (3) Strict quality control was taken when testing children's lung function; (4) The results were expressed by the average of measured value. Then we analyzed the correlation relationship between the level of ambient air pollutants and children's lung function and compared the effects of ambient air pollutants on children's lung function of boy and girl.ResultsThe selected articles included the results of 7 cities in China. Among them, the results of 6 cities' studies revealed that the levels of children's lung function were significantly lower in the areas with heavy ambient air pollution than those in the areas with light ambient air pollution. According to the articles, the average levels of TSP were at the range of 0.084 mg/m3–0.835 mg/m3, SO2 were 0.013 mg/m3–0.929 mg/m3, NOx were 0.044 mg/m3–0.229 mg/m3. Correlation analysis showed significant negative correlation between the levels of TSP and SO2 and children's FVC and FEV1, as well as the levels of NOx and children's MMEF. The correlation coefficient was ? 0.797 (t = ? 4.384, P = 0.001) between TSP and FVC, ? 0.693 (t = ? 4.190, P < 0.001) between Ln (SO2) and FVC, ? 0.886 (t = ? 5.392, P = 0.001) and ? 0.685 (t = ? 4.101, P = 0.001) between FEV1 and TSP and Ln (SO2), and ? 0.973 (t = ? 5.993, P = 0.027) between NOxNOx and MMEF, respectively. The results also suggested that the decreases of lung function for girl with the increasing of ambient air pollution were significantly greater for boy.ConclusionThe levels of ambient air TSP and SO2 correlated with the damage of the big airway function of children, while NOxNOx affected the small airway function chiefly. Furthermore, lung function of girl was more susceptible to ambient air pollutants than boy.  相似文献   

14.
Determinants of outdoor, indoor and personal concentrations of nitrogen dioxide (NO2) were assessed in a subset of pregnant women of the Spanish INMA (Environment and Childhood) Study. Home indoor and outdoor NO2 concentrations were measured during 48 h with passive samplers for 50 and 58 women from the INMA cohorts of Valencia and Sabadell, respectively. Women from Sabadell also carried personal NO2 samplers during the same period. Data on time–activity patterns, socio-economic characteristics, and environmental exposures were obtained through questionnaires. Multiple linear regression models were developed to predict NO2 levels.In Valencia, median outdoor NO2 levels (42 µg/m3) were higher than median indoor levels (36 µg/m3). In Sabadell, personal NO2 showed the highest median levels (40 µg/m3), followed by indoor (32 µg/m3) and outdoor (29 µg/m3) levels. Personal exposure to NO2 correlated best with the indoor NO2 levels. Temporal and traffic-related variables were significant predictors for outdoor NO2 levels. Thirty-two percent of the indoor NO2 variability in the two cohorts was explained by outdoor NO2 levels and the use of the gas appliances. The model for personal exposure accounted for 59% of the variance in NO2 levels in Sabadell with four predictor variables (outdoor and indoor NO2 levels, time spent in outdoor environments and time exposed to a gas cooker). No significant association was found between personal or indoor NO2 levels and exposure to environmental tobacco smoke (ETS) at home.Personal NO2 levels were found to be strongly influenced by indoor NO2 concentrations. The study supports the use of time–activity patterns along with indoor measurements to predict personal exposure to traffic-related air pollution.  相似文献   

15.
A sample of 58 occupied homes in Rochester, NY, most of which incorporated special builder-designed weatherization components, were studied to assess (1) the effectiveness of construction techniques designed to reduce air leakage; (2) the indoor air quality and air-exchange rates in selected airtight houses, and (3) the impact on indoor air quality of mechanical ventilation systems employing air-to-air heat exchangers. The “specific leakage area” was measured in each house using the fan pressurization technique. Houses built with polyethylene vapor barriers and joint-sealing were as a group 50% tighter than a similar group of houses without such components. Mechanical ventilation systems with air-to-air heat exchangers were installed in nine relatively airtight houses, some of which had gas stoves and/or tobacco smoking occupants. Air-exchange rates and indoor concentrations of radon (Rn), formaldehyde (HCHO), nitrogen dioxide (NO2), and humidity were measured in each house for 1-week periods with and without mechanical ventilation. More detailed measurements, including concentrations of carbon monoxide and inhalable particulates, were made in two of these houses by a mobile laboratory. In all nine houses, air-exchange rates were relatively low (0.2–0.5 ach) without mechanical ventilation, and yet indoor concentrations of Rn, HCHO, and NO2 were below existing guidelines. Mechanical ventilation systems were effective in further reducing indoor contaminant concentrations. We conclude that when contaminant source strengths are low, acceptable indoor air quality can be compatible with low air-exchange rates.  相似文献   

16.
Since the last decade the WHO Collaborating Centre for Air Quality Management and Air Pollution Control, Berlin, Germany, operates a quality assurance and control (QA/QC) programme on air quality monitoring in the WHO European Region. As main activity Intercomparison workshops have been established for air monitoring network laboratories on a regular basis to harmonise air quality measurements, analysis and calibration techniques. 36 air hygiene laboratories of public health and environmental institutions of 24 countries participated in twelve Intercomparisons between 1994 and 2004. The majority was carried out for NO, NO2, SO2 and O3. The results were predominantly satisfactory for automatic methods. The results of manual methods were mainly in a good, and for several concentration levels partly very good accordance with the data obtained by the monitors.  相似文献   

17.
A spatial comparison of pollutant concentrations within the residential environment is undertaken, comparing pollutant concentrations from three indoor sampling locations (zones). The indoor air quality base was obtained from sampling the indoor air of 12 residential sites and two office buildings in the metropolitan Boston area. Each residential site was monitored continuously for two weeks, and data were reduced into hourly averages. Interzonal comparisons of the mean of hourly averages, 24-h averages, and daily maximum hourly concentrations were made at all sites. Linear regressions were computed between daily maximum hourly concentrations and mean 24-h concentrations of NO, NO2, and CO for kitchens to determine whether maximum hourly concentrations could be predicted from the 24-h concentration. These pollutants show interzonal statistical differences in residences with gas-fired cooking facilities but not in residences with electric cooking facilities. It was determined that, while one indoor sampling zone is not sufficient to specify indoor pollutant concentration maxima in residences having indoor sources of pollution, the daily mean of hourly pollutant concentrations obtained from one indoor zone can adequately describe the indoor environment. In addition, the maximum indoor hourly concentration for NO, NO2, and CO can be estimated for residences with all electric facilities, by using the mean 24-h concentration. The reliability of similar estimates for NO, NO2, and CO in residences with unvented gas appliances is reduced because of substantially more scatter in the paired data point, particularly at higher pollutant concentrations.  相似文献   

18.
IntroductionEvidence has accumulated on the association between ambient air pollution and adverse birth outcomes. However, most of the previous studies were conducted in geographically distinct areas and suffer from lack of important potential covariates. We examined the effect of ambient air pollution on term low birth weight (LBW) using data from a nationwide population-based longitudinal survey in Japan that began in 2001.MethodsWe restricted participants to term singletons (n = 44,109). Air pollution concentrations during the 9 months before birth were obtained at the municipality level and were assigned to the participants who were born in the corresponding municipality. We conducted multilevel logistic regression analyses adjusting for individual and municipality-level variables.ResultsWe found that air pollution exposure during pregnancy was positively associated with the risk of term LBW. In the fully adjusted models, odds ratios following one interquartile range increase in each pollutant were 1.09 (95% confidence interval: 1.00, 1.19) for suspended particulate matter (SPM), 1.11 (0.99, 1.26) for nitrogen dioxide (NO2), and 1.71 (1.18, 2.46) for sulfur dioxide (SO2). Specifically, effect estimates for SPM and NO2 exposure at the first trimester were higher than those at other trimesters, while SO2 was associated with the risk at all trimesters. Nonsmoking mothers were more susceptible to SPM and NO2 exposure compared with smoking mothers.ConclusionsAmbient air pollution increases the risk of term LBW in a nationally representative sample in Japan.  相似文献   

19.
Comparative overview of indoor air quality in Antwerp, Belgium   总被引:2,自引:0,他引:2  
This comprehensive study, a first in Belgium, aimed at characterizing the residential and school indoor air quality of subgroups that took part in the European Community Respiratory Health Survey and the International Study of Asthma and Allergy in Childhood [Masoli M, Fabian D, Holt S, Beasley R. Global Burden of Asthma, Medical Research Institute of New Zealand, University of Southampton; 2004.] questionnaire-based asthma and related illnesses studies. The principal aim was to perform a base-line study to assess the indoor air quality in Antwerp in terms of various gaseous and particulate pollutants. Secondly, it aimed to establish correlations between these pollutants investigated, the pollutant levels in the indoor and outdoor micro-environments, findings of the previous questionnaire-based studies and an epidemiological study which ran in conjunction with this study. Lastly, these results were compared and evaluated with current indoor and ambient guidelines in various countries This paper presents selected results on PM1, PM2.5 and PM10 mass concentrations and elemental C estimates as black smoke, as well as gaseous NO(2), SO(2), O(3) and BTEX concentrations of 18 residences and 27 schools. These are related to current guidelines of Flanders, Germany, Norway, China and Canada and evaluated with reference to selected similar studies. It was found that indoor sources such as tobacco smoking and carpets, the latter causing re-suspension of dust, are responsible for elevated indoor respirable particulate matter and place school children and residents at risk. Both PM2.5 and PM10 equalled or exceeded the current guidelines adopted by Flanders, noting that 12-h and 24-h PM2.5 were compared with an annual limit value. Indoor and ambient NO(2) concentrations in the school campaign were higher than the annual EU ambient norm. The other studied pollutant levels were below the current guidelines.  相似文献   

20.
This paper presents an assessment of air quality of the city Eskişehir, located 230 km southwest to the capital of Turkey. Only five of the major air pollutants, most studied worldwide and available for the region, were considered for the assessment. Available sulphur dioxide (SO2), particulate matter (PM), nitrogen dioxide (NO2), ozone (O3), and non-methane volatile organic carbons (NMVOCs) data from local emission inventory studies provided relative source contributions of the selected pollutants to the region.The contributions of these typical pollution parameters, selected for characterizing such an urban atmosphere, were compared with the data established for other cities in the nation and world countries. Additionally, regional ambient SO2 and PM concentrations, determined by semi-automatic monitoring at two sites, were gathered from the National Ambient Air Monitoring Network (NAAMN). Regional data for ambient NO2 (as a precursor of ozone as VOCs) and ozone concentrations, through the application of the passive sampling method, were provided by the still ongoing local air quality monitoring studies conducted at six different sites, as representatives of either the traffic-dense-, or coal/natural gas burning residential-, or industrial/rural-localities of the city. Passively sampled ozone data at a single rural site were also verified with the data from a continuous automatic ozone monitoring system located at that site. Effects of variations in seasonal-activities, newly established railway system, and switching to natural gas usage on the temporal changes of air quality were all considered for the assessment. Based on the comparisons with the national [AQCR (Air Quality Control Regulation). Ministry of Environment (MOE), Ankara. Official Newspaper 19269; 1986.] and a number of international [WHO (World Health Organization). Guidelines for Air Quality. Geneva; 2000. Downloaded in January 2006, website: http://www.who.int/peh/; EU (European Union). Council Directive 1999/30/EC relating to limit values for sulfur dioxide, nitrogen dioxide and lead in ambient air. Of J Eur Communities L 163: 14–30; 29.6.1999; EU (European Union). Council Directive 2002/3/EC relating to ozone in ambient air. Of J Eur Communities. L 67: 14–30; 9.3.2002.; USEPA (U.S. Environmental Protection Agency). National Ambient Air Quality Standards (NAAQS). Downloaded in January 2006, website: http://www.epa.gov/ttn/naaqs/] ambient air standards, among all the pollutants studied, only the annual average SO2 concentration was found to exceed one specific limit value (EU limit for protection of the ecosystem). A part of the data (VOC/NOx ratio), for determining the effects of photochemical interactions, indicated that VOC-limited regime was prevailing throughout the city.  相似文献   

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